CN109370680A - High heating value biomass energy material and preparation method thereof - Google Patents
High heating value biomass energy material and preparation method thereof Download PDFInfo
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- CN109370680A CN109370680A CN201811334325.8A CN201811334325A CN109370680A CN 109370680 A CN109370680 A CN 109370680A CN 201811334325 A CN201811334325 A CN 201811334325A CN 109370680 A CN109370680 A CN 109370680A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/445—Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/42—Solid fuels essentially based on materials of non-mineral origin on animal substances or products obtained therefrom, e.g. manure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/442—Wood or forestry waste
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biodiversity & Conservation Biology (AREA)
- Ecology (AREA)
- Forests & Forestry (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Treatment Of Sludge (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a kind of high heating value biomass energy materials and preparation method thereof, using stalk, sawdust, fowl and animal excrement, nanofiller, used oil, carboxymethyl cellulose, capacitive starch, coarse sand are high as high heating value biomass energy material calorific value made from raw material, efficiency of combustion is good, the calorific value that can be improved biomass energy material reduces the discharge of waste.In addition, raw material sources of the present invention are extensive, gather materials on the spot conveniently, biomass energy material density obtained is big, and ratio of briquetting is high, belongs to efficient, clean energy products, it is easy to save, transports, facilitating popularization and use, and meets environmental protection, energy-efficient using energy source and development trend.
Description
Technical field
The present invention relates to biomass energy fields more particularly to a kind of high heating value biomass energy material and preparation method thereof.
Background technique
Biomass energy refers to the various organisms generated using big gas and water, soil etc. by photosynthesis, i.e., one cuts with
The organic substance that can be grown of life is commonly referred to as biomass.It includes plant, animal and microorganism.Generalized concept: biomass
Including all plants, microorganism and using plant, microorganism as the animal of food and its waste of production.It is representational
Biomass such as crops, agricultural waste material, timber, timber waste and animal wastes.Narrow sense concept: biomass is primarily referred to as
The lignocellulosics such as stalk, trees in agriculture and forestry production process in addition to grain, fruit (abbreviation lignin), processing of farm products
The substances such as fowl and animal excrement and waste during industry leftover bits and pieces, agriculture and forestry organic waste material and Animal husbandry production.Feature: renewable, low
It pollutes, is widely distributed.
Currently, many countries all utilize biomass energy being actively researched and developed.Wherein, biomass energy compress solid
Change, so that it is converted into the important method that high-grade composition is biomass economy, generally use single component both at home and abroad at present
The mode of biological particles composition burn fever obtains thermal energy, and the existing particulate composition source in China is mainly crops straw
Stalk, process are as follows: collecting after agricultural crop straw raw material is dried, pulverizer crushes plus water and be mixed with blender
After even through steam softening, be resent in pelletizer and carry out extrusion granulation.Use biomass energy made of agricultural crop straw raw material
The particulate composition degree of packing is poor, calorific value is low.
Summary of the invention
In view of this, can be solved the object of the present invention is to provide a kind of high heating value biomass energy material and preparation method thereof
The certainly existing biomass energy material degree of packing is poor, the low technical problem of calorific value.
To achieve the goals above, the invention provides the following technical scheme:
A kind of high heating value biomass energy material, the raw material including following parts by weight:
Preferably, the stalk is one of corn stover, wheat stalk, rice straw or a variety of.
Preferably, the fowl and animal excrement be chicken manure, duck excrement, goose excrement, cow dung, horsehit, sheep dung, pig manure it is one or more.
Preferably, the nanofiller includes potassium permanganate, cinder, calcium chloride, active carbon, tourmaline powder and carbon dust.
Preferably, the partial size of the nanofiller is 50~100 μm, and the partial size of the coarse sand is 1000~2000 μm.
The present invention also provides a kind of above-mentioned preparation method of high heating value biomass energy material as described in claim 1,
The following steps are included:
A) stalk, sawdust are dried respectively, and stalk is crushed to≤15mm；
B) the smashed stalk that step a) is obtained is mixed with the obtained sawdust of step a), and into mixed substance
Nanofiller, used oil, carboxymethyl cellulose, soluble starch and coarse sand is added to stir evenly by blender；
C) it will be added to be sent into granulator in mixture that step b) is obtained and squeeze to obtain the final product.
Preferably, the moisture content in step a) after drying in the stalk and the sawdust is below 12%.
A kind of high heating value biomass energy material provided by the invention and preparation method thereof, with stalk, sawdust, fowl and animal excrement,
Nanofiller, used oil, carboxymethyl cellulose, capacitive starch, coarse sand are high heating value biomass energy material heat made from raw material
Value is high, efficiency of combustion is good, can be improved the calorific value of biomass energy material, reduces the discharge of waste.In addition, raw material sources of the present invention
Extensively, it gathers materials on the spot conveniently, biomass energy material density obtained is big, and ratio of briquetting is high, belong to efficient, clean energy products,
It is easy to save, transports, facilitating popularization and use, and meets environmental protection, energy-efficient using energy source and development trend.
Specific embodiment
In order to further appreciate that the present invention, the preferred embodiments of the invention are described below with reference to embodiment, but
It is it should be appreciated that these descriptions only require the invention patent to further illustrate the features and advantages of the present invention
Limitation.
The present invention provides a kind of high heating value biomass energy material, the raw material including following parts by weight:
In above-mentioned technical proposal, the present invention is with stalk, sawdust, fowl and animal excrement, nanofiller, used oil, carboxymethyl cellulose
Element, capacitive starch, coarse sand are that high heating value biomass energy material calorific value made from raw material is high, efficiency of combustion is good, can be improved life
The calorific value of substance energy material, reduces the discharge of waste.In addition, raw material sources of the present invention are extensive, gather materials on the spot conveniently, life obtained
Substance energy density of material is big, and ratio of briquetting is high, belongs to efficient, clean energy products, is easy to save, transport, facilitating popularization and use,
And meet environmental protection, energy-efficient using energy source and development trend.
In an embodiment of the present invention, stalk is one of corn stover, wheat stalk, rice straw or a variety of.
In the present invention, the parts by weight of stalk are 300~500 parts；In an embodiment of the present invention, the parts by weight of stalk
Number is 350~450 parts.
In the present invention, the parts by weight of sawdust are 100~200 parts；In an embodiment of the present invention, the parts by weight of sawdust
Number is 130~160 parts.
In an embodiment of the present invention, fowl and animal excrement is chicken manure, duck excrement, goose excrement, cow dung, horsehit, sheep dung, one kind of pig manure
Or it is a variety of.
Fowl and animal excrement can be improved the calorific value of biomass energy material.In the present invention, the parts by weight of fowl and animal excrement are 50
~100 parts；In an embodiment of the present invention, the parts by weight of fowl and animal excrement are 65~85 parts.
In an embodiment of the present invention, nanofiller include potassium permanganate, cinder, calcium chloride, active carbon, tourmaline powder and
Carbon dust；In other embodiments, the mass ratio of potassium permanganate, cinder, calcium chloride, active carbon, tourmaline powder and carbon dust is (0.5
~0.7): (2~3): (1~2): (3~5): (1~2): (3~5).Above-mentioned filler can reduce the kindling of biomass energy material
Temperature reduces soot emissions.
In the present invention, the parts by weight of nanofiller are 40~80 parts；In an embodiment of the present invention, nanofiller
Parts by weight are 50~70 parts.
Used oil is conducive to biomass energy material completely burned.In the present invention, the parts by weight of used oil are 30~50
Part；In an embodiment of the present invention, the parts by weight of used oil are 35~45 parts.
Carboxymethyl cellulose and soluble starch are conducive to each raw material of biomass energy material and are combined together, and improve biomass energy
The density of material.
In the present invention, the parts by weight of carboxymethyl cellulose are 20~30 parts；In an embodiment of the present invention, carboxymethyl
The parts by weight of cellulose are 23~27 parts.
In the present invention, the parts by weight of soluble starch are 40~60 parts；In an embodiment of the present invention, soluble to form sediment
The parts by weight of powder are 45~55 parts.
Coarse sand is used to improve the efficiency of combustion of biomass energy material.In the present invention, the parts by weight of coarse sand are 4~6 parts；
In an embodiment of the present invention, the parts by weight of coarse sand are 4.5~5.5 parts.
It should be noted that the partial size of nanofiller is 50~100 μm, the partial size of coarse sand is 1000~2000 μm.
The present invention also provides a kind of preparation methods of high heating value biomass energy material, comprising the following steps:
A) stalk, sawdust are dried respectively, and stalk is crushed to≤15mm；
B) the smashed stalk that step a) is obtained is mixed with the obtained sawdust of step a), and into mixed substance
Nanofiller, used oil, carboxymethyl cellulose, soluble starch and coarse sand is added to stir evenly by blender；
C) it will be added to be sent into granulator in mixture that step b) is obtained and squeeze to obtain the final product.
Wherein, stalk, sawdust, fowl and animal excrement, nanofiller, used oil, carboxymethyl cellulose, capacitive starch, coarse sand
Same as above, details are not described herein.
Above-mentioned technical proposal method is simple, facilitates production, and high heating value biomass energy material efficiency of combustion obtained is good, can
The calorific value for improving biomass energy material, reduces the discharge of pollutant.
The present invention is further illustrated, below with reference to embodiment to high heating value biomass energy material provided by the invention and its system
Preparation Method is described in detail, but they cannot be interpreted as limiting the scope of the present invention.
Raw material used in following embodiment is commercially available.
Embodiment 1
High heating value biomass energy material, the raw material including following parts by weight:
350 parts of corn stovers, 160 parts of sawdusts, 85 parts of cow dungs, 40 parts of nanofillers, 35 parts of used oil, 27 parts of carboxymethyl fibres
Tie up element, 45 parts of capacitive starch, 4.5 parts of coarse sands；
It include potassium permanganate, cinder, the calcium chloride, work that mass ratio is 0.5:2.4:2:3.5:1.3:4.5 in nanofiller
Property charcoal, tourmaline powder and carbon dust；
The partial size of nanofiller is 100 μm, and the partial size of the coarse sand is 1000 μm；
The preparation method of high heating value biomass energy material, comprising the following steps:
A) stalk, sawdust are dried respectively, and stalk is crushed to≤15mm；Water after drying in stalk and sawdust
Divide content below 12%；
B) the smashed stalk that step a) is obtained is mixed with the obtained sawdust of step a), and into mixed substance
Nanofiller, used oil, carboxymethyl cellulose, soluble starch and coarse sand is added to stir evenly by blender；
C) it will be added to be sent into granulator in mixture that step b) is obtained and squeeze to obtain the final product.
Embodiment 2
High heating value biomass energy material, the raw material including following parts by weight:
450 parts of wheat stalks, 200 parts of sawdusts, 20 parts of chicken manures, 20 parts of duck excrements, 10 parts of goose excrement, 50 parts of nanofillers, 30 parts
Used oil, 23 parts of carboxymethyl celluloses, 55 parts of capacitive starch, 5.5 parts of coarse sands；
It include potassium permanganate, cinder, the calcium chloride, activity that mass ratio is 0.65:3:1.3:4.5:2:3 in nanofiller
Charcoal, tourmaline powder and carbon dust；
The partial size of nanofiller is 50 μm, and the partial size of the coarse sand is 2000 μm
The preparation method of high heating value biomass energy material, comprising the following steps:
A) stalk, sawdust are dried respectively, and stalk is crushed to≤15mm；Water after drying in stalk and sawdust
Divide content below 12%；
B) the smashed stalk that step a) is obtained is mixed with the obtained sawdust of step a), and into mixed substance
Nanofiller, used oil, carboxymethyl cellulose, soluble starch and coarse sand is added to stir evenly by blender；
C) it will be added to be sent into granulator in mixture that step b) is obtained and squeeze to obtain the final product.
Embodiment 3
High heating value biomass energy material, the raw material including following parts by weight:
250 parts of corn stovers, 250 parts of wheat stalks, 130 parts of sawdusts, 50 parts of cow dungs, 50 parts of horsehits, 70 parts of nanofillers,
50 parts of used oil, 30 parts of carboxymethyl celluloses, 60 parts of capacitive starch, 4 parts of coarse sands；
Include in nanofiller mass ratio be the potassium permanganate of 0.55:2:1.7:5:1:5, cinder, calcium chloride, active carbon,
Tourmaline powder and carbon dust；
The partial size of nanofiller is 50 μm, and the partial size of the coarse sand is 1000 μm；
The preparation method of high heating value biomass energy material, comprising the following steps:
A) stalk, sawdust are dried respectively, and stalk is crushed to≤15mm；Water after drying in stalk and sawdust
Divide content below 12%；
B) the smashed stalk that step a) is obtained is mixed with the obtained sawdust of step a), and into mixed substance
Nanofiller, used oil, carboxymethyl cellulose, soluble starch and coarse sand is added to stir evenly by blender；
C) it will be added to be sent into granulator in mixture that step b) is obtained and squeeze to obtain the final product.
Embodiment 4
High heating value biomass energy material, the raw material including following parts by weight:
100 parts of corn stovers, 100 parts of wheat stalks, 100 parts of rice straws, 100 parts of sawdusts, 35 parts of sheep dungs, 30 portions of pigs
Excrement, 80 parts of nanofillers, 45 parts of used oil, 20 parts of carboxymethyl celluloses, 40 parts of capacitive starch, 6 parts of coarse sands；
It include potassium permanganate, cinder, the calcium chloride, activity that mass ratio is 0.7:2.6:1:3:1.8:3.5 in nanofiller
Charcoal, tourmaline powder and carbon dust；
The partial size of nanofiller is 100 μm, and the partial size of the coarse sand is 2000 μm；
The preparation method of high heating value biomass energy material, comprising the following steps:
A) stalk, sawdust are dried respectively, and stalk is crushed to≤15mm；Water after drying in stalk and sawdust
Divide content below 12%；
B) the smashed stalk that step a) is obtained is mixed with the obtained sawdust of step a), and into mixed substance
Nanofiller, used oil, carboxymethyl cellulose, soluble starch and coarse sand is added to stir evenly by blender；
C) it will be added to be sent into granulator in mixture that step b) is obtained and squeeze to obtain the final product.
Embodiment 5
High heating value biomass energy material, the raw material including following parts by weight:
200 parts of corn stovers, 200 parts of rice straws, 140 parts of sawdusts, 45 parts of cow dungs, 30 parts of pig manures, 60 parts of nanofillers,
40 parts of used oil, 25 parts of carboxymethyl celluloses, 50 parts of capacitive starch, 5 parts of coarse sands；
It include potassium permanganate, cinder, the calcium chloride, activity that mass ratio is 0.6:2.5:1.5:4:1.5:4 in nanofiller
Charcoal, tourmaline powder and carbon dust；
The partial size of nanofiller is 80 μm, and the partial size of coarse sand is 1500 μm；
The preparation method of high heating value biomass energy material, comprising the following steps:
A) stalk, sawdust are dried respectively, and stalk is crushed to≤15mm；Water after drying in stalk and sawdust
Divide content below 12%；
B) the smashed stalk that step a) is obtained is mixed with the obtained sawdust of step a), and into mixed substance
Nanofiller, used oil, carboxymethyl cellulose, soluble starch and coarse sand is added to stir evenly by blender；
C) it will be added to be sent into granulator in mixture that step b) is obtained and squeeze to obtain the final product.
High heating value biomass energy material made from Examples 1 to 5 is tested, as a result see the table below.
A kind of high heating value biomass energy material provided by the invention and preparation method thereof is described in detail above,
Used herein a specific example illustrates the principle and implementation of the invention, and the explanation of above embodiments is only used
In facilitating the understanding of the method and its core concept of the invention, it is noted that for those skilled in the art,
Without departing from the principle of the present invention, can be with several improvements and modifications are made to the present invention, these improvement and modification
It falls into the protection scope of the claims in the present invention.
Claims (7)
1. a kind of high heating value biomass energy material, which is characterized in that the raw material including following parts by weight:
2. high heating value biomass energy material as described in claim 1, which is characterized in that the stalk is corn stover, wheat
One of stalk, rice straw are a variety of.
3. high heating value biomass energy material as described in claim 1, which is characterized in that the fowl and animal excrement be chicken manure, duck excrement,
Goose excrement, cow dung, horsehit, sheep dung, pig manure it is one or more.
4. high heating value biomass energy material as described in claim 1, which is characterized in that the nanofiller includes permanganic acid
Potassium, cinder, calcium chloride, active carbon, tourmaline powder and carbon dust.
5. high heating value biomass energy material as described in claim 1, which is characterized in that the partial size of the nanofiller be 50~
100 μm, the partial size of the coarse sand is 1000~2000 μm.
6. a kind of preparation method of high heating value biomass energy material as described in claim 1, which is characterized in that including following step
It is rapid:
A) stalk, sawdust are dried respectively, and stalk is crushed to≤15mm；
B) the smashed stalk that step a) is obtained is mixed with the obtained sawdust of step a), and is added into mixed substance
Nanofiller, used oil, carboxymethyl cellulose, soluble starch and coarse sand are stirred evenly by blender；
C) it will be added to be sent into granulator in mixture that step b) is obtained and squeeze to obtain the final product.
7. preparation method as described in claim 1, which is characterized in that in step a) after drying in the stalk and the sawdust
Moisture content below 12%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811334325.8A CN109370680A (en) | 2018-11-09 | 2018-11-09 | High heating value biomass energy material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201811334325.8A CN109370680A (en) | 2018-11-09 | 2018-11-09 | High heating value biomass energy material and preparation method thereof |
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| CN109370680A true CN109370680A (en) | 2019-02-22 |
Family
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111363600A (en) * | 2020-03-04 | 2020-07-03 | 宿志强 | Method for producing mild carbonized biomass fuel by utilizing biological treatment fermentation |
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| CN1810940A (en) * | 2006-03-03 | 2006-08-02 | 清华大学 | Sludge fuel stick and its prepn |
| US20110283705A1 (en) * | 2006-07-24 | 2011-11-24 | Troy Oliver | EXPLO-DYNAMICS™: a method, system, and apparatus for the containment and conversion of explosive force into a usable energy resource |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111363600A (en) * | 2020-03-04 | 2020-07-03 | 宿志强 | Method for producing mild carbonized biomass fuel by utilizing biological treatment fermentation |
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Application publication date: 20190222 |