CN109370021A - A kind of Grille lamp lampshade composite material and preparation method - Google Patents
A kind of Grille lamp lampshade composite material and preparation method Download PDFInfo
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- CN109370021A CN109370021A CN201810880404.2A CN201810880404A CN109370021A CN 109370021 A CN109370021 A CN 109370021A CN 201810880404 A CN201810880404 A CN 201810880404A CN 109370021 A CN109370021 A CN 109370021A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/085—Copper
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0856—Iron
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0881—Titanium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses a kind of Grille lamp lampshade composite material and preparation methods, belong to new material technology field.Its main constituents and quality proportioning are as follows: 40-80 parts of POE resin, 35-50 parts of polycarbonate resin, 30-45 parts of polystyrene, 6-10 parts of acrylate, 1.5-3 parts of nanometer anion powder, 1-1.2 parts of alumino-silicate, 5-10 parts of fluorescent powder, 0.5-1.2 parts of organosilicon light diffusing agent, 0.3-1.2 parts of antioxidant, 0.3-1.2 parts of light stabilizer, 5-20 parts of composite metal powder, the main composition of the composite metal powder and proportion are titanium valve: magnesium powder: copper powder: iron powder is equal to 1:1:0.5:1.The present invention has the advantages that simple process, it is easily controllable, it is suitble to produce in enormous quantities, and the preparation method can guarantee that various auxiliary agents and filler are uniformly dispersed in POE resin matrix, keep good compatibility, to guarantee that the dispersion performance of the lampshade material of preparation is obviously improved, light transmittance and mist degree are obviously improved, and mechanical property and surface hardness have clear improvement.
Description
Technical field
The present invention relates to new material technology field, specially a kind of Grille lamp lampshade composite material and preparation method.
Background technique
LED light source belongs to point light source as existing most common lighting apparatus, because point light source illumination range itself is narrow
And dazzle can be generated, therefore existing LED generally can add lampshade, point light source is changed by area source by lampshade, is led
It acts on and eliminates light scattering, and make LED illumination softer, the meeting that the material of existing LED light lampshade is commonplace makes
With polycarbonate, and in order to assign polycarbonate light scattering function, often need some polymer with different refractivity or
Inorganic particulate is typed into continuous phase as dispersed phase and obtains in thermoplastic resin, and the polymer of existing addition does not often have very
Good translucency, and substantially increase the thermal expansion coefficient of lampshade material, affect the overall structure stability of LED etc. and make
Use the service life.
Summary of the invention
The purpose of the present invention is to provide a kind of Grille lamp lampshade composite material and preparation methods, are mainly used in solution
State problem.
The present invention solves technical problem and adopts the following technical scheme that
There is provided a kind of Grille lamp lampshade composite material, main constituents and quality proportioning are as follows: 40-80 parts of POE resin, poly- carbon
35-50 parts of sour rouge resin, 30-45 parts of polystyrene, 6-10 parts of acrylate, 1.5-3 parts of nanometer anion powder, alumino-silicate 1-
1.2 parts, 5-10 parts of fluorescent powder, 0.5-1.2 parts of organosilicon light diffusing agent, 0.3-1.2 parts of antioxidant, 0.3-1.2 parts of light stabilizer,
5-20 parts of composite metal powder, the main composition of the composite metal powder and proportion are titanium valve: magnesium powder: copper powder: iron powder is equal to 1:
1:0.5:1.
A kind of preparation method of Grille lamp lampshade composite material, mainly includes the following steps:
(1) it stocks up: by POE resin, polycarbonate resin, polystyrene, acrylate, nanometer anion powder, alumino-silicate, glimmering
Light powder, organosilicon light diffusing agent, antioxidant, light stabilizer, composite metal powder carry out ingredient according to quality proportioning；
(2) POE resin for one third of stocking up and whole organosilicon light diffusing agents light diffusion masterbatch preparation: are put into mixer
In, at 220~250 DEG C, the time is not less than 10 minutes for smelting temperature control, after, it is crushed through high speed disintegrator, obtains light
Spread masterbatch A；
(3) organic silicon original material preparation: the POE resin for one third of stocking up and alumino-silicate are put into mixer, smelting temperature
At 220~250 DEG C, the time is not less than 10 minutes for control, after, it is crushed through high speed disintegrator, obtains organic silicon original material B；
(4) prepared by auxiliary agent: the POE resin for one third of stocking up and nanometer anion powder being put into mixer, smelting temperature control
At 220~250 DEG C, the time is not less than 10 minutes system, after, it is crushed through high speed disintegrator, obtains aid master batches C；
(5) product: by above-mentioned (2) obtain light diffusion masterbatch A, polycarbonate resin, polystyrene, acrylate, fluorescent powder,
Antioxidant, composite metal powder and light stabilizer put into double screw extruder hopper, and the organic silicon original material B of step (3) (4), auxiliary agent are female
Material C feeds through side feed mouth, is melted, is blended, squeezes out, cools down, is granulated.
The present invention compared with prior art, it has the advantage that: simple process, easily controllable, is suitble to produce in enormous quantities,
And the preparation method can guarantee that various auxiliary agents and filler are uniformly dispersed in POE resin matrix, keep good compatibility,
To guarantee that the dispersion performance of the lampshade material of preparation is obviously improved, light transmittance and mist degree are obviously improved, and mechanical property and surface are hard
Degree has clear improvement.
Specific embodiment
The present invention is specifically described below by specific embodiment.
A kind of Grille lamp lampshade composite material, main constituents and quality proportioning are as follows: 40-80 parts of POE resin, poly- carbon
35-50 parts of sour rouge resin, 30-45 parts of polystyrene, 6-10 parts of acrylate, 1.5-3 parts of nanometer anion powder, alumino-silicate 1-
1.2 parts, 5-10 parts of fluorescent powder, 0.5-1.2 parts of organosilicon light diffusing agent, 0.3-1.2 parts of antioxidant, 0.3-1.2 parts of light stabilizer,
5-20 parts of composite metal powder, the main composition of the composite metal powder and proportion are titanium valve: magnesium powder: copper powder: iron powder is equal to 1:
1:0.5:1.
A kind of preparation method of Grille lamp lampshade composite material, mainly includes the following steps:
(1) it stocks up: by POE resin, polycarbonate resin, polystyrene, acrylate, nanometer anion powder, alumino-silicate, glimmering
Light powder, organosilicon light diffusing agent, antioxidant, light stabilizer, composite metal powder carry out ingredient according to quality proportioning；
(2) POE resin for one third of stocking up and whole organosilicon light diffusing agents light diffusion masterbatch preparation: are put into mixer
In, at 220~250 DEG C, the time is not less than 10 minutes for smelting temperature control, after, it is crushed through high speed disintegrator, obtains light
Spread masterbatch A；
(3) organic silicon original material preparation: the POE resin for one third of stocking up and alumino-silicate are put into mixer, smelting temperature
At 220~250 DEG C, the time is not less than 10 minutes for control, after, it is crushed through high speed disintegrator, obtains organic silicon original material B；
(4) prepared by auxiliary agent: the POE resin for one third of stocking up and nanometer anion powder being put into mixer, smelting temperature control
At 220~250 DEG C, the time is not less than 10 minutes system, after, it is crushed through high speed disintegrator, obtains aid master batches C；
(5) product: by above-mentioned (2) obtain light diffusion masterbatch A, polycarbonate resin, polystyrene, acrylate, fluorescent powder,
Antioxidant, composite metal powder and light stabilizer put into double screw extruder hopper, and the organic silicon original material B of step (3) (4), auxiliary agent are female
Material C feeds through side feed mouth, is melted, is blended, squeezes out, cools down, is granulated.
Embodiment 1
60 parts of POE resin, 35 parts of polycarbonate resin, 30 parts of polystyrene, 7 parts of acrylate, 1.5 parts of nanometer anion powder,
1 part of alumino-silicate, 5 parts of fluorescent powder, 0.5 part of organosilicon light diffusing agent, 0.3 part of antioxidant, 0.6 part of light stabilizer, composition metal
8 parts of powder.
Embodiment 2
80 parts of POE resin, 50 parts of polycarbonate resin, 45 parts of polystyrene, 9 parts of acrylate, 2.5 parts of nanometer anion powder,
1.2 parts of alumino-silicate, 8 parts of fluorescent powder, 1 part of organosilicon light diffusing agent, 0.9 part of antioxidant, 0.8 part of light stabilizer, composition metal
15 parts of powder.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (2)
1. a kind of Grille lamp lampshade composite material, which is characterized in that its main constituents and quality proportioning are as follows: POE resin 40-
80 parts, 35-50 parts of polycarbonate resin, 30-45 parts of polystyrene, 6-10 parts of acrylate, 1.5-3 parts of nanometer anion powder,
1-1.2 parts of alumino-silicate, 5-10 parts of fluorescent powder, 0.5-1.2 parts of organosilicon light diffusing agent, 0.3-1.2 parts of antioxidant, light stabilizer
0.3-1.2 parts, 5-20 parts of composite metal powder, the main composition of the composite metal powder and proportion are titanium valve: magnesium powder: copper powder:
Iron powder is equal to 1:1:0.5:1.
2. a kind of preparation method of Grille lamp lampshade composite material, which is characterized in that preparation method mainly includes the following steps:
(1) it stocks up: by POE resin, polycarbonate resin, polystyrene, acrylate, nanometer anion powder, alumino-silicate, glimmering
Light powder, organosilicon light diffusing agent, antioxidant, light stabilizer, composite metal powder carry out ingredient according to quality proportioning；
(2) POE resin for one third of stocking up and whole organosilicon light diffusing agents light diffusion masterbatch preparation: are put into mixer
In, at 220~250 DEG C, the time is not less than 10 minutes for smelting temperature control, after, it is crushed through high speed disintegrator, obtains light
Spread masterbatch A；
(3) organic silicon original material preparation: the POE resin for one third of stocking up and alumino-silicate are put into mixer, smelting temperature
At 220~250 DEG C, the time is not less than 10 minutes for control, after, it is crushed through high speed disintegrator, obtains organic silicon original material B；
(4) prepared by auxiliary agent: the POE resin for one third of stocking up and nanometer anion powder being put into mixer, smelting temperature control
At 220~250 DEG C, the time is not less than 10 minutes system, after, it is crushed through high speed disintegrator, obtains aid master batches C；
(5) product: by above-mentioned (2) obtain light diffusion masterbatch A, polycarbonate resin, polystyrene, acrylate, fluorescent powder,
Antioxidant, composite metal powder and light stabilizer put into double screw extruder hopper, and the organic silicon original material B of step (3) (4), auxiliary agent are female
Material C feeds through side feed mouth, is melted, is blended, squeezes out, cools down, is granulated.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810880404.2A CN109370021A (en) | 2018-08-03 | 2018-08-03 | A kind of Grille lamp lampshade composite material and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810880404.2A CN109370021A (en) | 2018-08-03 | 2018-08-03 | A kind of Grille lamp lampshade composite material and preparation method |
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| CN109370021A true CN109370021A (en) | 2019-02-22 |
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| CN201810880404.2A Pending CN109370021A (en) | 2018-08-03 | 2018-08-03 | A kind of Grille lamp lampshade composite material and preparation method |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643525A (en) * | 2012-04-06 | 2012-08-22 | 南京同辉新型材料科技有限公司 | Special polycarbonate light-diffusion material for outer cover of LED (light-emitting diode) lamp and preparation method for same |
| JP2013133349A (en) * | 2011-12-26 | 2013-07-08 | Mitsubishi Engineering Plastics Corp | Light diffusing member for led lighting |
| CN103724973A (en) * | 2014-01-03 | 2014-04-16 | 东莞市欣隆光电材料有限公司 | Composite material for LED (Light Emitting Diode) fluorescent lamp |
| CN106751659A (en) * | 2016-12-11 | 2017-05-31 | 安徽兆利光电科技有限公司 | A kind of LED outer cover |
| CN107245233A (en) * | 2016-04-26 | 2017-10-13 | 宁波浙铁大风化工有限公司 | LED illumination uses up diffusion flame-retardant polycarbonate material and preparation method thereof |
| CN107556678A (en) * | 2017-08-17 | 2018-01-09 | 芜湖晶鑫光电照明有限公司 | A kind of LED grille lamp lampshade composite |
| CN107573626A (en) * | 2017-08-17 | 2018-01-12 | 芜湖晶鑫光电照明有限公司 | A kind of LED lampshade composite |
| CN107914437A (en) * | 2017-11-24 | 2018-04-17 | 江苏瑞博光电科技有限公司 | Double-layer L ED desk lamp lampshade composite material |
-
2018
- 2018-08-03 CN CN201810880404.2A patent/CN109370021A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013133349A (en) * | 2011-12-26 | 2013-07-08 | Mitsubishi Engineering Plastics Corp | Light diffusing member for led lighting |
| CN102643525A (en) * | 2012-04-06 | 2012-08-22 | 南京同辉新型材料科技有限公司 | Special polycarbonate light-diffusion material for outer cover of LED (light-emitting diode) lamp and preparation method for same |
| CN103724973A (en) * | 2014-01-03 | 2014-04-16 | 东莞市欣隆光电材料有限公司 | Composite material for LED (Light Emitting Diode) fluorescent lamp |
| CN107245233A (en) * | 2016-04-26 | 2017-10-13 | 宁波浙铁大风化工有限公司 | LED illumination uses up diffusion flame-retardant polycarbonate material and preparation method thereof |
| CN106751659A (en) * | 2016-12-11 | 2017-05-31 | 安徽兆利光电科技有限公司 | A kind of LED outer cover |
| CN107556678A (en) * | 2017-08-17 | 2018-01-09 | 芜湖晶鑫光电照明有限公司 | A kind of LED grille lamp lampshade composite |
| CN107573626A (en) * | 2017-08-17 | 2018-01-12 | 芜湖晶鑫光电照明有限公司 | A kind of LED lampshade composite |
| CN107914437A (en) * | 2017-11-24 | 2018-04-17 | 江苏瑞博光电科技有限公司 | Double-layer L ED desk lamp lampshade composite material |
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Application publication date: 20190222 |