CN109354566A - A kind of fireworks and firecrackers pyrotechnic composition - Google Patents

A kind of fireworks and firecrackers pyrotechnic composition Download PDF

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Publication number
CN109354566A
CN109354566A CN201811508314.7A CN201811508314A CN109354566A CN 109354566 A CN109354566 A CN 109354566A CN 201811508314 A CN201811508314 A CN 201811508314A CN 109354566 A CN109354566 A CN 109354566A
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CN
China
Prior art keywords
powder
flame retardant
pyrotechnic composition
fireworks
mesh
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Pending
Application number
CN201811508314.7A
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Chinese (zh)
Inventor
王贤凤
郭建彪
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Individual
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Individual
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Priority to CN201811508314.7A priority Critical patent/CN109354566A/en
Publication of CN109354566A publication Critical patent/CN109354566A/en
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    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B23/00Compositions characterised by non-explosive or non-thermic constituents
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B31/00Compositions containing an inorganic nitrogen-oxygen salt
    • C06B31/02Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate
    • C06B31/04Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate with carbon or sulfur
    • C06B31/06Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate with carbon or sulfur with an organic non-explosive or an organic non-thermic component

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Medicines Containing Plant Substances (AREA)

Abstract

The present invention discloses a kind of fireworks and firecrackers pyrotechnic composition comprising propellant powder, polishes and flame retardant, the flame retardant account for the 8%-30% of pyrotechnic composition according to weight percent;The flame retardant its by weight include the component of following ratio: shellac powder: 15%-25%, glutinous rice flour: 5%-15%, charcoal powder: 3%-10%, surplus be -200 mesh of 120 mesh bamboo powder, wood powder or bamboo powder and wood powder mixture.Using flame retardant of the invention, delay the combustion efficiency of pyrotechnic composition more preferable, while there is preferable stability and be also possible that this product light for issuing in burning is more bright-coloured.

Description

A kind of fireworks and firecrackers pyrotechnic composition
Technical field
The present invention relates to fireworks pharmaceutical techniques field more particularly to a kind of fireworks and firecrackers pyrotechnic compositions.
Background technique
Fireworks medicine is usually made of propellant powder, fire-retardant medicine and colored-light composition.Wherein propellant powder is predominantly so that combustible Burning, is usually made of all kinds of oxidants and combustible.The effect of fire-retardant medicine be reduce propellant powder burning velocity, delay it is coloured The fluorescent lifetime of photo etching.
The Chinese patent of Publication No. CN1763470A discloses a kind of " application of the dicyandiamide in fireworks medicament ", uses Dicyandiamides more than 100 mesh is added in fireworks medicament as fire retardant, and playing reduces burning velocity, extends the colorful light-emitting time Effect.But the prior art, only with the medicament of single dicyandiamide, retarding action is not obvious, while it also can not be with The other components of fireworks medicament generate synergistic effect, are only capable of being purely by way of fire retardant use.In addition dicyandiamide is as chemical agent, Its use cost is also higher.
Summary of the invention
Technical problem to be solved by the present invention lies in, for the above-mentioned deficiency of the prior art, propose it is a kind of cost is relatively low, Good flame retardation effect and the more bright-coloured pyrotechnic composition of color when can make firework display.
The technical solution used to solve the technical problems of the present invention is that proposing a kind of fireworks and firecrackers pyrotechnic composition comprising Propellant powder, polishes and flame retardant, the flame retardant account for the 8%-30% of pyrotechnic composition according to weight percent;The flame retardant It includes the component of following ratio by weight:
Shellac powder: 15%-25%, glutinous rice flour: 5%-15%, charcoal powder: 3%-10%, surplus are -200 purpose of 120 mesh The mixture of bamboo powder, wood powder or bamboo powder and wood powder.
Bamboo powder and wood powder are oxidizers under normal particle sizes, but when bamboo powder, the granularity of wood powder reach 120 mesh with After upper, extremely difficult burning, becomes flame retardant.The present invention using the higher bamboo powder of granularity, wood powder as major ingredient, have it is lower at Sheet and preferable flame retardant effect, while being also possible to be that color is more bright-coloured to lure so that fireworks burn after using bamboo powder and wood powder Cause.
Shellac powder and glutinous rice flour are all preferable flame retardants.Find during the experiment, if only using bamboo powder and wood powder as Flame-proof material flame retardant effect is unsatisfactory.Flame retardant effect is very ideal after adding shellac powder and glutinous rice flour.
Glutinous rice flour also acts as the effect of adhesive simultaneously, and this product is enabled to make this in practical application to pyrotechnic composition The other components of product and pyrotechnic composition are preferably bonded together.Glutinous rice powder content must be suitable, if glutinous rice flour too high levels It may be that pyrotechnic composition sticks into one, pyrotechnic composition too disperses if content is too low, and pyrotechnic composition both cannot form desired Fountain or bright pearl effect.
Charcoal powder primarily serves toning effect in the present invention, so that entire product is in grey black.The product of grey black can It is mixed well with the other compositions with pyrotechnic composition.
Further, the flame retardant further includes the fragrance powder of parts by weight 1%-3%.
Fragrance powder primarily serves the effect for improving product odour in the present invention.Product process and with other groups of pyrotechnic composition The working environment of workers can be improved when dividing mixing.
Further, the parts by weight of the flame retardant of the fireworks medicine are as follows: shellac powder: 15%, glutinous rice flour: 5%, charcoal powder: 6%, surplus is the bamboo powder of 120 mesh and the mixture of wood powder.
Further, the parts by weight of the flame retardant of the fireworks medicine are as follows: shellac powder: 20%, glutinous rice flour: 8%, charcoal powder: 3%, surplus is the bamboo powder of 150 mesh.
Further, the parts by weight of the flame retardant of the fireworks medicine are as follows: shellac powder: 25%, glutinous rice flour: 15%, charcoal powder: 10%, surplus is the bamboo powder of 200 mesh and the mixture of wood powder.
The present invention has the following beneficial effects: compared with prior art
1, the virtuous phoenix chemical industry in Liuyang City manages Co., Ltd and the flame retardant of this product is entrusted Hunan Entry-Exit Inspection and Quarantine Bureau The detection of fireworks and firecrackers inspection center show that the burn rate of the flame retardant of this product is 0.0042mm/S, has very outstanding Flame retardant effect, while the ignition temperature of this product is 309.3 DEG C, it may not combustion on fire under normal storage, traffic condition It burns.
2, the light color that this product is issued when fireworks burn is more bright-coloured.
Specific embodiment
The following is specific embodiments of the present invention, and technical scheme of the present invention will be further described, but the present invention is simultaneously It is not limited to these embodiments.
Embodiment 1:
With ball mill be made 120 mesh bamboo powder and wood powder it is spare.
By weight score weigh 15% shellac powder, 5% glutinous rice flour, 6% charcoal powder;1% fragrance;Surplus is with bamboo Powder and wood powder polishing.
Flame retardant is made in above-mentioned powder after mixing.
Flame retardant, propellant powder, polishes are obtained into this product fireworks and firecrackers pyrotechnic composition after mixing.It is wherein fire-retardant The parts by weight accounting of object is 8%.Conventional fountain class fireworks use all can be used in propellant powder and polishes or bright pearl class fireworks are used Propellant powder and polishes, such as potassium nitrate, sulphur, as propellant powder, strontium nitrate, strontium carbonate, oxalic acid, barium nitrate, chloric acid etc. are made For polishes.
Embodiment 2:
The bamboo powder that 150 mesh are made with ball mill is spare.
By weight score weigh 20% shellac powder, 8% glutinous rice flour, 3% charcoal powder;3% fragrance;Surplus is with bamboo Powder polishing.
Above-mentioned powder is obtained into flame retardant after mixing.
Flame retardant, propellant powder, polishes are obtained into this product fireworks and firecrackers pyrotechnic composition after mixing.It is wherein fire-retardant The parts by weight accounting of object is 20%.
Embodiment 3:
With ball mill be made 200 mesh bamboo powder and wood powder it is spare.
By weight score weigh 25% shellac powder, 15% glutinous rice flour, 10% charcoal powder;Surplus is with bamboo powder and wood powder Polishing.
Above-mentioned powder is obtained into flame retardant after mixing.
Flame retardant, propellant powder, polishes are obtained into this product fireworks and firecrackers pyrotechnic composition after mixing.It is wherein fire-retardant The parts by weight accounting of object is 30%.
Specific embodiment described herein is only an example for the spirit of the invention.The neck of technology belonging to the present invention The technical staff in domain can make various modifications or additions to the described embodiments or replace by a similar method In generation, however, it does not deviate from the spirit of the invention or beyond the scope of the appended claims.

Claims (5)

1. a kind of fireworks and firecrackers pyrotechnic composition, which is characterized in that including propellant powder, polishes and flame retardant, the flame retardant The 8%-30% of pyrotechnic composition is accounted for according to weight percent;The flame retardant its by weight include the component of following ratio:
Shellac powder: 15%-25%, glutinous rice flour: 5%-15%, charcoal powder: 3%-10%, surplus be -200 mesh of 120 mesh bamboo powder, The mixture of wood powder or bamboo powder and wood powder.
2. pyrotechnic composition according to claim 1, it is characterised in that: the flame retardant further includes the perfume (or spice) of parts by weight 1%-3% Feed powder.
3. pyrotechnic composition according to claim 1 or 2, it is characterised in that: the parts by weight of the flame retardant are as follows: shellac powder: 15%, glutinous rice flour: 5%, charcoal powder: 6%, surplus is the bamboo powder of 120 mesh and the mixture of wood powder.
4. pyrotechnic composition according to claim 1 or 2, it is characterised in that: the parts by weight of the flame retardant are as follows: the flame retardant Parts by weight are as follows: shellac powder: 20%, glutinous rice flour: 8%, charcoal powder: 3%, surplus be 150 mesh bamboo powder.
5. pyrotechnic composition according to claim 1, it is characterised in that: the parts by weight of the flame retardant are as follows: shellac powder: 25%, Glutinous rice flour: 15%, charcoal powder: 10%, surplus is the bamboo powder of 200 mesh and the mixture of wood powder.
CN201811508314.7A 2018-12-11 2018-12-11 A kind of fireworks and firecrackers pyrotechnic composition Pending CN109354566A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811508314.7A CN109354566A (en) 2018-12-11 2018-12-11 A kind of fireworks and firecrackers pyrotechnic composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811508314.7A CN109354566A (en) 2018-12-11 2018-12-11 A kind of fireworks and firecrackers pyrotechnic composition

Publications (1)

Publication Number Publication Date
CN109354566A true CN109354566A (en) 2019-02-19

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101519333A (en) * 2009-01-25 2009-09-02 祁阳县顺发彩光氧化剂有限责任公司 Fireworks powder color light oxidant
EP3112333A1 (en) * 2015-06-30 2017-01-04 Fireworks Europe Innovation Sp. z o.o. Ecological fireworks, method of preparation thereof and method of reducing environmental contamination with heavy metal compounds from fireworks and use of fireworks and use of mineral additives in pyrotechnic materials

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101519333A (en) * 2009-01-25 2009-09-02 祁阳县顺发彩光氧化剂有限责任公司 Fireworks powder color light oxidant
EP3112333A1 (en) * 2015-06-30 2017-01-04 Fireworks Europe Innovation Sp. z o.o. Ecological fireworks, method of preparation thereof and method of reducing environmental contamination with heavy metal compounds from fireworks and use of fireworks and use of mineral additives in pyrotechnic materials

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
国家安全生产应急救援指挥中心: "《烟花爆竹企业安全生产应急管理》", 30 June 2009, 煤炭工业出版社 *
徐强国等: "《烟花爆竹安全管理技术》", 31 December 2005, 南京大学出版社 *
潘功配: "《烟火药材料手册》", 31 May 1983, 江苏省溧水县柘塘印刷厂 *

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Application publication date: 20190219