CN109342605A - Volatile organic matter (VOCs) on-line monitoring system - Google Patents
Volatile organic matter (VOCs) on-line monitoring system Download PDFInfo
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- CN109342605A CN109342605A CN201811454020.0A CN201811454020A CN109342605A CN 109342605 A CN109342605 A CN 109342605A CN 201811454020 A CN201811454020 A CN 201811454020A CN 109342605 A CN109342605 A CN 109342605A
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- 239000012855 volatile organic compound Substances 0.000 title claims abstract description 21
- 238000012544 monitoring process Methods 0.000 title claims abstract description 19
- 239000005416 organic matter Substances 0.000 title claims abstract description 19
- 239000007789 gas Substances 0.000 claims abstract description 63
- 239000001257 hydrogen Substances 0.000 claims abstract description 33
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 33
- 239000000523 sample Substances 0.000 claims abstract description 32
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000012159 carrier gas Substances 0.000 claims abstract description 22
- 238000005070 sampling Methods 0.000 claims abstract description 16
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003546 flue gas Substances 0.000 claims abstract description 15
- 238000007781 pre-processing Methods 0.000 claims abstract description 10
- 238000007405 data analysis Methods 0.000 claims abstract description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 25
- 150000002430 hydrocarbons Chemical class 0.000 claims description 25
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 24
- 239000004215 Carbon black (E152) Substances 0.000 claims description 24
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 239000002808 molecular sieve Substances 0.000 claims description 3
- 239000000741 silica gel Substances 0.000 claims description 3
- 229910002027 silica gel Inorganic materials 0.000 claims description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 230000005611 electricity Effects 0.000 claims description 2
- 238000004868 gas analysis Methods 0.000 claims description 2
- 238000001228 spectrum Methods 0.000 claims description 2
- 238000010183 spectrum analysis Methods 0.000 claims 2
- 239000003086 colorant Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 230000009977 dual effect Effects 0.000 abstract description 2
- 238000004458 analytical method Methods 0.000 description 12
- 238000010586 diagram Methods 0.000 description 6
- 238000001514 detection method Methods 0.000 description 4
- 230000004044 response Effects 0.000 description 4
- 238000004587 chromatography analysis Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010408 sweeping Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000003708 edge detection Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003012 network analysis Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
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- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
Abstract
The invention discloses a kind of volatile organic matter (VOCs) on-line monitoring systems, belong to volatile organic matter monitoring field.It mainly includes flue gas sampling probe, heat tracing pipe, pre-processing system, carrier gas device, electronic flow control system, Data Analysis Services system, host computer computer, gas chromatographicanalyzer and hydrogen zero level air generator all-in-one machine, flue gas sampling probe is connect by heat tracing pipe with the system of pre-processing and gas chromatographicanalyzer, host computer computer is controlled by signal and is connect with gas chromatographicanalyzer, and flue gas sampling probe, carrier gas device and hydrogen zero level air generator all-in-one machine pass through electronic flow control system respectively and connect with gas chromatographicanalyzer.Gas chromatographicanalyzer of the present invention has dual pre-processing effect, and is all added to blowback in every set switching valve and sweeps function, ensure that instrument analyzes data memory-less effect, reproducible, long service life.Present invention is mainly used for the monitorings of volatile organic matter.
Description
Technical field
The invention belongs to volatile organic matters to monitor field, specifically, more particularly to a kind of volatile organic matter
(VOCs) on-line monitoring system.
Background technique
Volatile organic matter (VOCs) be to be formed the secondary pollutions such as fine particle (PM2.5), ozone (O3) it is important before
Body object, and then cause the atmospheric environments problems such as gray haze, photochemical fog.With China's industrialization and urbanization it is fast-developing with
And the sustainable growth of energy-consuming, the compound atmosphere pollution of regionality characterized by PM2.5 become increasingly conspicuous, air weight in region
The frequency that contamination phenomenon occurs simultaneously on a large scale is increasing, and the serious sustainable development for restricting social economy threatens people group
Many healths.In order to solve the pollution problems such as PM2.5, O3 at all, improve atmosphere quality conscientiously.But China at present
VOCs prevention and cure of pollution basis is more weak, exist discharge radix it is unclear, statutory standard is unsound, control technology application lag, ring
Supervise the problems such as not in place in border.Simultaneously as VOCs discharge source is complicated, form of export is various, substance classes are various, lead
It is larger that VOCs prevention and cure of pollution system difficulty is established in cause.Existing VOCs on-line monitoring system, integrated complex, volume be big, instrument function
It can be with setting low, being at high cost, production efficiency is low, and can not separate the special gas factor, functional single.
Summary of the invention
It is an object of the invention to overcome drawbacks described above, a kind of volatile organic matter (VOCs) on-line monitoring system is provided,
Its integrated level is high, saves space, gas chromatographicanalyzer has dual pre-processing effect, and all adds in every set switching valve
Function is swept in blowback, ensure that instrument analyzes data memory-less effect, reproducible, long service life.
Described volatile organic matter (VOCs) on-line monitoring system, including flue gas sampling probe, heat tracing pipe, pre-processing
System, carrier gas device, electronic flow control system and data analysis process system, pre-processing system include particulate matter metal mistake
Filter and oil water separator；It further include host computer computer, gas chromatographicanalyzer and hydrogen zero level air generator all-in-one machine, cigarette
Gas sampling probe is connect by heat tracing pipe with the system of pre-processing and gas chromatographicanalyzer, and host computer computer is controlled by signal
It is connect with gas chromatographicanalyzer, flue gas sampling probe, carrier gas device and hydrogen zero level air generator all-in-one machine pass through respectively
Electronic flow control system is connect with gas chromatographicanalyzer, and gas chromatographicanalyzer is connect with Data Analysis Services system.
Further, the gas chromatographicanalyzer includes methane chromatographic column, total hydrocarbon chromatographic column, benzene homologues chromatographic column, ten
Port valve V1, six-way valve V2, ten-way valve V3 and flame ionization ditector, ten-way valve V1, six-way valve V2 and ten-way valve V3 difference
It is connect by quantitative loop with flue gas sampling probe, ten-way valve V1, six-way valve V2 and ten-way valve V3 are respectively equipped with blowback channel one, instead
It blows channel one to connect with carrier gas device, the blowback channel one of ten-way valve V1, six-way valve V2 and ten-way valve V3 pass through methane color respectively
Spectrum column, total hydrocarbon chromatographic column and benzene homologues chromatographic column are connect with flame ionization ditector.
Further, the gas chromatographicanalyzer further includes two pretreatment chromatographic columns, ten-way valve V1 and ten-way valve V3
It is equipped with blowback channel two, two pretreatment chromatographic columns are connect with the blowback channel two of ten-way valve V1 and ten-way valve V3 respectively.
Further, it is equipped with zero level air generator module in the hydrogen zero level air generator all-in-one machine, described zero
Grade air generator module includes compressor, air accumulator, Primary relief valve, drying tube and accurate pressure maintaining valve and hydrocarbon removing device, pressure
Contracting machine is connect by pipeline with air accumulator, air accumulator by pipeline be sequentially connected Primary relief valve, drying tube, precision pressure maintaining valve and
Hydrocarbon removing device, accurate pressure maintaining valve are connected with air outlet slit and the outlet of driving gas respectively, and hydrocarbon removing device is connected with hydrocarbon outlet is removed.
Further, the air accumulator is equipped with water, the oily delay controller for carrying out automatic-discharging in control air accumulator.
Further, the air accumulator is equipped with pressure switch and safety valve.
Further, described except hydrocarbon outlet connection filter device, filter device includes silica gel, molecular sieve, active carbon.
Further, hydrogen generator module, the hydrogen hair are equipped in the hydrogen zero level air generator all-in-one machine
Raw device module includes electrolytic cell and fluid level control device, and liquid reflux device is connect with electrolytic cell, electrolytic cell and Liquid level mould
Block connection, liquid level module are connect by small pump with water inlet pipe, and liquid level module is connect by shut-off valve with drainpipe,
Liquid level reflux unit is separately connected electronics pressure control module, pressure gauge and drying tube, drying tube by one-way water stop valve and goes out with hydrogen
Mouth connection.
Further, high pure nitrogen is equipped in the carrier gas device.
Compared with prior art, the beneficial effects of the present invention are:
1, gas chromatographicanalyzer adds pretreatment chromatographic column, and chemistry pre- place is added on the basis of former pre-processing system
Reason is introduced into pretreatment chromatographic column in advance by carrier gas and carries out preliminary analysis, heavy component and the useless factor are absorbed and filter, remained
Under gas respectively enter total hydrocarbon chromatographic column, methane chromatographic column, benzene homologues chromatographic column again, every set chromatographic column configures independent switching
Valve, so that the process step of gas analysis does not interfere with each other with independence；
2, blowback is all added in every set switching valve of gas chromatographicanalyzer and sweeps function, so that gas enters chromatographic column point
After analysis, switch valve events, carry out anti-scavenging pipeline with high pure nitrogen, ensure that instrument analyzes data memory-less effect, repeatability
It is good, substantially prolong service life；
3, the internal structure for improving hydrogen generator module and zero level air generator module, mentions hydrogen, aeroscope
It rises, improves the service life of industrial on-line instrument；
4, the present invention saves space, modularization peace using host computer computer instead of traditional relay and connection line
Dress, maintenance convenience, gas source pressure stabilizing use electronic flow control system (EPC), and electronic flow control system (EPC) is existing skill
Art, which solve tradition machinery pressure maintaining valves the shortcomings that can not reading accurate flow, ensure that the stabilization of bleed pressure, Er Qie electricity
Subflow amount control system (EPC) circuit main board carries diagnostic function, gas flow can be monitored in real time, if there is system mode
Abnormal, the output of electronic flow control system (EPC) gas source can be automatically closed in bleed pressure flowed fluctuation or reduction, system,
And alarm signal is issued, guarantee the safety of system.
Detailed description of the invention
Fig. 1 is the principle of the present invention figure；
Fig. 2 is the injection flow chart of gas chromatographicanalyzer；
Fig. 3 is the analysis flow chart diagram of gas chromatographicanalyzer；
Fig. 4 is the pneumatic diagram of zero level air generator module；
Fig. 5 is the circuit diagram of zero level air generator module；
Fig. 6 is the pneumatic diagram of hydrogen generator module；
Fig. 7 is the circuit diagram of hydrogen generator module；
Fig. 8 is the schematic diagram of liquid level module.
Specific embodiment
The present invention will be further explained below with reference to the attached drawings:
As shown in Figure 1, volatile organic matter (VOCs) on-line monitoring system, including flue gas sampling probe, heat tracing pipe, in advance
Processing system, carrier gas device, electronic flow control system, Data Analysis Services system, host computer computer, gas chromatographicanalyzer
With hydrogen zero level air generator all-in-one machine, flue gas sampling probe is by heat tracing pipe and pre-processes system and gas chromatographic analysis
Instrument connection, host computer computer are controlled by signal and are connect with gas chromatographicanalyzer, flue gas sampling probe, carrier gas device and hydrogen
Zero level air generator all-in-one machine passes through electronic flow control system respectively and connect with gas chromatographicanalyzer, gas chromatographic analysis
Instrument is connect with Data Analysis Services system.
As shown in Figures 2 and 3, the gas chromatographicanalyzer includes methane chromatographic column, total hydrocarbon chromatographic column, benzene homologues chromatography
Column, ten-way valve V1, six-way valve V2, ten-way valve V3 and flame ionization ditector, ten-way valve V1, six-way valve V2 and ten-way valve V3
It is connect respectively by quantitative loop with flue gas sampling probe, ten-way valve V1, six-way valve V2 and ten-way valve V3 are respectively equipped with blowback channel
One, blowback channel one is connect with carrier gas device, and the blowback channel one of ten-way valve V1, six-way valve V2 and ten-way valve V3 pass through first respectively
Alkane chromatographic column, total hydrocarbon chromatographic column and benzene homologues chromatographic column are connect with flame ionization ditector；Gas chromatographicanalyzer also wraps
Include two pretreatment chromatographic columns, ten-way valve V1 and ten-way valve V3 are equipped with blowback channel two, and two pretreatment chromatographic columns are respectively with ten
The blowback channel two of port valve V1 and ten-way valve V3 connects.
As shown in Figure 4 and Figure 5, zero level air generator module is equipped in the hydrogen zero level air generator all-in-one machine,
The zero level air generator module includes compressor, air accumulator, Primary relief valve, drying tube and accurate pressure maintaining valve and except hydrocarbon fills
It sets, compressor is connect by pipeline with air accumulator, and air accumulator is sequentially connected Primary relief valve, drying tube, precision surely by pipeline
Pressure valve and hydrocarbon removing device, accurate pressure maintaining valve are connected with air outlet slit and the outlet of driving gas respectively, and hydrocarbon removing device connects with hydrocarbon outlet is removed
It connects.
The air accumulator is equipped with water, the oily delay controller for carrying out automatic-discharging in control air accumulator；On air accumulator
Equipped with pressure switch and safety valve；Described to connect filter device except hydrocarbon exports, filter device includes silica gel, molecular sieve, activity
Charcoal.
As shown in Figure 6 to 8, hydrogen generator module is equipped in the hydrogen zero level air generator all-in-one machine, it is described
Hydrogen generator module includes electrolytic cell and fluid level control device, and liquid reflux device is connect with electrolytic cell, electrolytic cell and liquid level
Control module connection, liquid level module are connect by small pump with water inlet pipe, and liquid level module passes through shut-off valve and draining
Pipe connection, liquid level reflux unit are separately connected electronics pressure control module, pressure gauge and drying tube by one-way water stop valve, drying tube and
Hydrogen outlet connection；As shown in figure 8, K1 is lower water-level probe in liquid level module, K2 is upper water-level probe, during K3 and K4 be
Between relay.
The present invention during installation, according to the mountable air at the top of factory's circle edge detection station or is mounted on tested gas
Flue by；In use, being equipped with high pure nitrogen in carrier gas device.
As shown in Figure 1, when system is run, hydrogen zero level air generator all-in-one machine is to flame ionization ditector FID
Pure air and hydrogen are provided, for its sustained combustion, flame ionization ditector (FID) is that a kind of high sensitivity is universal
Detector, it almost has response to all organic matters, and to the substance etc. not dissociated in inorganic matter, inert gas or flame
Without response or response very little.The remolding sensitivity thermal conductivity detector (TCD) of FID is 100-10000 times high, and detection limit reaches 10-13g/s, to temperature
Insensitive, response is fast, is suitble to connection open tubular column to carry out the separation of complex sample, 7 powers that the range of linearity is 10, are gas chromatographs
A kind of means best to hydro carbons sensitivity in detector are widely used in volatile hydrocarbon and many carbon compounds
Detection, the operation of flame ionization ditector (FID) are needed using combustion of hydrogen, zero level air-breathing, it is therefore desirable to hydrogen
It is supplied with the gas source of zero level air-stable.
When work, the thief hatch in slave station roof as needed portion acquires the sample gas in air or directly extracts in flue
Sample gas is monitored, and sample gas enters pre-processing system by flue gas sampling probe under the whole heat tracing of heat tracing pipe and carries out
Particulate matter filtering and water-oil separating processing, subsequently enter gas chromatographicanalyzer and pass through ten-way valve V1, six-way valve V2, ten-way valve V3
Injection process enter each chromatographic column separated, be then fed into flame ionization ditector FID detection, hydrogen flame ion
Change detector is the prior art, after the signal of detection passes through Data Analysis Services network analysis, in the form of data in industrial personal computer
It has been shown that, the gas after measurement enter atmosphere.
As shown in Fig. 2, the first step is that gas chromatographicanalyzer injects process and anti-sweeping process, ten-way valve does not turn at this time
Dynamic, internal connection relationship is original state.
It is as follows to inject process: sample gas flows through quantitative loop 1 by the passway 1-9 that threeway respectively enters ten-way valve V1
(SAMPLE LOOP1) is finally discharged from No. 10 passways；The channel the 1-5 slogan of six-way valve V2 flows through 2 (SAMPLE of quantitative loop
LOOP2 it) is finally discharged from No. 6 passways；It is final that the passway 1-9 of ten-way valve V3 flows through quantitative loop 3 (SAMPLE LOOP2)
It is discharged from No. 10 passways, at this time to inject process, so that sample gas flows through each quantitative loop in real time, to make to infuse in quantitative loop
Penetrate full sample gas, the preparation before performing an analysis.
Anti- sweeping process is as follows: the carrier gas 1 of ten-way valve V1 is entered by No. 7 passways, carrier gas 2 by No. 4 passways into
Enter, methane chromatographic column and pretreatment chromatographic column are purged respectively；The carrier gas 3 of six-way valve V2 is entered by No. 3 passways, right
Total hydrocarbon chromatographic column is purged；The carrier gas 4 of ten-way valve V3 is entered by No. 7 passways, carrier gas 5 by 4 channel number passways into
Enter, benzene homologues chromatographic column and pretreatment chromatographic column are purged respectively, the carrier gas under the working condition is high pure nitrogen, high-purity
Nitrogen carries out blowback cleaning works as gas source is cleaned, to 5 sets of chromatographic columns, and remaining gas component is blown completely when will analyze last time
Sweep clean, the stability and accuracy of guarantee analysis next time data；
As shown in figure 3, second step is gas chromatographicanalyzer analysis process, gas source driving ten-way valve rotation is driven at this time,
Change internal connection relationship.
Analysis process is as follows:
Sample gas is switched to row's mouth state by the original annotation state of penetrating: sample gas enters from the passway 1-9 of ten-way valve V1, from
No. 10 passway discharges；The passway 1-5 of six-way valve V2 enters, and is discharged from No. 6 passways；The channel 1-9 of ten-way valve V3
Mouth enters, and is discharged from No. 10 passways；
Carrier gas is switched to driving sample gas by former blowback cleaning state and enters analysis process state: the carrier gas 1 of ten-way valve V1
Entered by No. 7 passways, flows through the sample gas in No. 8 passway driving quantitative loops 1 and sequentially enter pretreatment chromatographic column first mistake
Weight analysis substance and the impurity in air are filtered, is then left relatively pure methane gas and is again introduced into the progress of methane chromatographic column
Pure methane gas is finally entered flame ionization ditector FID and analyzed by adsorbing separation, and six-way valve V2 and ten is logical
Valve V3 working principle is same as above.After the completion of analysis, ten-way valve V1, six-way valve V2 and ten-way valve V3 are turned by the driving of driving gas source respectively
It is dynamic, be restored to first step injection process and anti-sweeping process from second step analysis state, so in cycles inject-it is anti-
Purging-analysis work.
Claims (9)
1. a kind of volatile organic matter (VOCs) on-line monitoring system, including flue gas sampling probe, heat tracing pipe, pre-processing system
System, carrier gas device, electronic flow control system and data analysis process system；It is characterized by also including host computer computers, gas
Analysis of hplc instrument and hydrogen zero level air generator all-in-one machine, flue gas sampling probe by heat tracing pipe and pre-process system and
Gas chromatographicanalyzer connection, host computer computer are controlled by signal and are connect with gas chromatographicanalyzer, flue gas sampling probe, load
Device of air and hydrogen zero level air generator all-in-one machine pass through electronic flow control system respectively and connect with gas chromatographicanalyzer,
Gas chromatographicanalyzer is connect with Data Analysis Services system.
2. volatile organic matter (VOCs) on-line monitoring system according to claim 1, it is characterised in that: the gas phase color
Spectrum analysis instrument includes methane chromatographic column, total hydrocarbon chromatographic column, benzene homologues chromatographic column, ten-way valve V1, six-way valve V2, ten-way valve V3 and hydrogen
Flame ionization detector, ten-way valve V1, six-way valve V2 and ten-way valve V3 pass through quantitative loop respectively and connect with flue gas sampling probe,
Ten-way valve V1, six-way valve V2 and ten-way valve V3 are respectively equipped with blowback channel one, and blowback channel one is connect with carrier gas device, ten-way valve
The blowback channel one of V1, six-way valve V2 and ten-way valve V3 pass through methane chromatographic column, total hydrocarbon chromatographic column and benzene homologues chromatographic column respectively
It is connect with flame ionization ditector.
3. volatile organic matter (VOCs) on-line monitoring system according to claim 2, it is characterised in that: the gas phase color
Spectrum analysis instrument further includes two pretreatment chromatographic columns, and ten-way valve V1 and ten-way valve V3 are equipped with blowback channel two, two pretreatment colors
Spectrum column is connect with the blowback channel two of ten-way valve V1 and ten-way valve V3 respectively.
4. volatile organic matter (VOCs) on-line monitoring system according to any one of claim 1 to 3, feature exist
In: zero level air generator module, the zero level air generator mould are equipped in the hydrogen zero level air generator all-in-one machine
Block includes compressor, air accumulator, Primary relief valve, drying tube and accurate pressure maintaining valve and hydrocarbon removing device, compressor by pipeline with
Air accumulator connection, air accumulator is sequentially connected Primary relief valve, drying tube, accurate pressure maintaining valve and hydrocarbon removing device by pipeline, accurate
Pressure maintaining valve is connected with air outlet slit and the outlet of driving gas respectively, and hydrocarbon removing device is connected with hydrocarbon outlet is removed.
5. volatile organic matter (VOCs) on-line monitoring system according to claim 4, it is characterised in that: the air accumulator
The water, the oil that are equipped in control air accumulator carry out the delay controller of automatic-discharging.
6. volatile organic matter (VOCs) on-line monitoring system according to claim 5, it is characterised in that: the air accumulator
It is equipped with pressure switch and safety valve.
7. volatile organic matter (VOCs) on-line monitoring system according to claim 6, it is characterised in that: described except hydrocarbon goes out
Mouth connection filter device, filter device includes silica gel, molecular sieve, active carbon.
8. volatile organic matter (VOCs) on-line monitoring system according to any one of claim 1 to 3, feature exist
In: hydrogen generator module is equipped in the hydrogen zero level air generator all-in-one machine, the hydrogen generator module includes electricity
Solution slot and fluid level control device, liquid reflux device are connect with electrolytic cell, and electrolytic cell is connect with liquid level module, Liquid level
Module is connect by water inlet pipe with small pump, and liquid level module is connect by shut-off valve with drainpipe, and liquid level reflux unit is logical
It crosses one-way water stop valve and is separately connected electronics pressure control module, pressure gauge and drying tube, drying tube and connect with hydrogen outlet.
9. volatile organic matter (VOCs) on-line monitoring system according to claim 1, it is characterised in that: the carrier gas dress
High pure nitrogen is equipped in setting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811454020.0A CN109342605A (en) | 2018-11-30 | 2018-11-30 | Volatile organic matter (VOCs) on-line monitoring system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811454020.0A CN109342605A (en) | 2018-11-30 | 2018-11-30 | Volatile organic matter (VOCs) on-line monitoring system |
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| CN110376324A (en) * | 2019-07-12 | 2019-10-25 | 北京雪迪龙科技股份有限公司 | Utilize the method and gas chromatograph of flame ionization ditector measurement oxygen concentration |
| CN110500504A (en) * | 2019-09-10 | 2019-11-26 | 青岛诺诚化学品安全科技有限公司 | A kind of two-way fuel gas feed system and its application |
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