CN109321343A - 一种矿用挤压抗磨剂 - Google Patents

一种矿用挤压抗磨剂 Download PDF

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CN109321343A
CN109321343A CN201811460610.4A CN201811460610A CN109321343A CN 109321343 A CN109321343 A CN 109321343A CN 201811460610 A CN201811460610 A CN 201811460610A CN 109321343 A CN109321343 A CN 109321343A
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oil
mining
antiwear additive
demulsifier
oleamide
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俞华元
黄威
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Xuzhou Sanheng Electromechanical Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/083—Dibenzyl sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

本发明是一种矿用挤压抗磨剂，配方中的原料按重量百分比组成分别是：硫化鲸鱼油5‑15%、硫化烯烃棉籽油1‑5%、硫化异丁烯1‑10%、二苄基二硫5‑15%、偏硼酸钾3‑9%、聚二甲硅氧烷2‑3%、油酰胺1‑5%、氯化石蜡11‑19%、抗氧防腐剂5‑7%、金属钝化剂3‑5%、防锈剂3‑5%、抗泡沫剂1‑5%、油性剂5‑10%、粘度指数改进剂1‑1.5%、破乳剂4‑5%、纳米金刚石2‑4%，此时齿轮油具有较强的极压抗磨性，且拥有较强的抗氧化性能。

Description

一种矿用挤压抗磨剂
技术领域
本发明是一种矿用挤压抗磨剂。
背景技术
在边界润滑中，当金属表面只承受中等负荷时，如有一种添加剂能被吸附在金属表面上或与金属表面剧烈磨损，这种添加剂称为抗磨添加剂，当金属表面承受很高的负荷时，大量的金属表面直接接触，产生大量的热，而抗磨剂形成的膜也被破坏，不再起保护金属表面的作用，如有一种添加剂能与金属表面起化学反应生成化学反应膜，起润滑作用，防止金属表面擦伤，甚至熔焊，通常把这种最苛刻的边界润滑叫做极压润滑，现有的极压抗磨剂中，器大多的挤压抗磨性能不理想，抗氧化性能不足。
发明内容
针对上述现有技术存在的问题，本发明提供一种矿用挤压抗磨剂，具有较强的极压抗磨性，且拥有较强的抗氧化性能。
为了实现上述目的，本发明通过以下技术方案实现：一种齿轮油，配方中的原料按重量百分比组成分别是：硫化鲸鱼油5-15%、硫化烯烃棉籽油1-5%、硫化异丁烯1-10%、二苄基二硫5-15%、偏硼酸钾3-9%、聚二甲硅氧烷2-3%、油酰胺1-5%、氯化石蜡11-19%、抗氧防腐剂5-7%、金属钝化剂3-5%、防锈剂3-5%、抗泡沫剂1-5%、油性剂5-10%、粘度指数改进剂1-1.5%、破乳剂4-5%、纳米金刚石2-4%。
有益效果：通过本方法制备齿轮油为纯中药配方，具有较强的极压抗磨性，且拥有较强的抗氧化性能。
具体实施方式
实施例1
一种矿用挤压抗磨剂，配方中的原料按重量百分比组成分别是：硫化鲸鱼油5%、硫化烯烃棉籽油1%、硫化异丁烯1%、二苄基二硫5%、偏硼酸钾3%、聚二甲硅氧烷2%、油酰胺1%、氯化石蜡11%、抗氧防腐剂5%、金属钝化剂3%、防锈剂3%、抗泡沫剂1%、油性剂5%、粘度指数改进剂1%、破乳剂4%、纳米金刚石2%，此时齿轮油具有较强的极压抗磨性，但是抗氧化性能较差。
实施例2
一种矿用挤压抗磨剂，配方中的原料按重量百分比组成分别是：硫化鲸鱼油15%、硫化烯烃棉籽油5%、硫化异丁烯10%、二苄基二硫15%、偏硼酸钾9%、聚二甲硅氧烷3%、油酰胺5%、氯化石蜡19%、抗氧防腐剂7%、金属钝化剂5%、防锈剂5%、抗泡沫剂5%、油性剂10%、粘度指数改进剂1.5%、破乳剂5%、纳米金刚石4%，此时齿轮油具有较强的抗氧化性能，但是其极压抗磨性能较差。
实施例3
一种矿用挤压抗磨剂，配方中的原料按重量百分比组成分别是：硫化鲸鱼油10%、硫化烯烃棉籽油3%、硫化异丁烯6%、二苄基二硫10%、偏硼酸钾6%、聚二甲硅氧烷2.3%、油酰胺1.5%、氯化石蜡11.9%、抗氧防腐剂5.7%、金属钝化剂3.5%、防锈剂3.5%、抗泡沫剂1.5%、油性剂8%、粘度指数改进剂1.28%、破乳剂4.5%、纳米金刚石2.4%，此时齿轮油具有较强的极压抗磨性，且拥有较强的抗氧化性能。

Claims (4)

1.一种矿用挤压抗磨剂，其特征在于，配方中的原料按重量百分比组成分别是：硫化鲸鱼油5-15%、硫化烯烃棉籽油1-5%、硫化异丁烯1-10%、二苄基二硫5-15%、偏硼酸钾3-9%、聚二甲硅氧烷2-3%、油酰胺1-5%、氯化石蜡11-19%、抗氧防腐剂5-7%、金属钝化剂3-5%、防锈剂3-5%、抗泡沫剂1-5%、油性剂5-10%、粘度指数改进剂1-1.5%、破乳剂4-5%、纳米金刚石2-4%。
2.根据权利要求1所述的矿用挤压抗磨剂，其特征在于，配方中的原料按重量百分比组成分别是：硫化鲸鱼油5%、硫化烯烃棉籽油1%、硫化异丁烯1%、二苄基二硫5%、偏硼酸钾3%、聚二甲硅氧烷2%、油酰胺1%、氯化石蜡11%、抗氧防腐剂5%、金属钝化剂3%、防锈剂3%、抗泡沫剂1%、油性剂5%、粘度指数改进剂1%、破乳剂4%、纳米金刚石2%。
3.根据权利要求1所述的矿用挤压抗磨剂，其特征在于，配方中的原料按重量百分比组成分别是：硫化鲸鱼油15%、硫化烯烃棉籽油5%、硫化异丁烯10%、二苄基二硫15%、偏硼酸钾9%、聚二甲硅氧烷3%、油酰胺5%、氯化石蜡19%、抗氧防腐剂7%、金属钝化剂5%、防锈剂5%、抗泡沫剂5%、油性剂10%、粘度指数改进剂1.5%、破乳剂5%、纳米金刚石4%。
4.根据权利要求1所述的矿用挤压抗磨剂，其特征在于，配方中的原料按重量百分比组成分别是：硫化鲸鱼油10%、硫化烯烃棉籽油3%、硫化异丁烯6%、二苄基二硫10%、偏硼酸钾6%、聚二甲硅氧烷2.3%、油酰胺1.5%、氯化石蜡11.9%、抗氧防腐剂5.7%、金属钝化剂3.5%、防锈剂3.5%、抗泡沫剂1.5%、油性剂8%、粘度指数改进剂1.28%、破乳剂4.5%、纳米金刚石2.4%。
CN201811460610.4A 2018-12-01 2018-12-01 一种矿用挤压抗磨剂 Withdrawn CN109321343A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114507513A (zh) * 2020-11-17 2022-05-17 中国石油化工股份有限公司 一种耐高温非水体系无固相隔离液及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114507513A (zh) * 2020-11-17 2022-05-17 中国石油化工股份有限公司 一种耐高温非水体系无固相隔离液及其制备方法

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Application publication date: 20190212