CN109321288A - 一种车用木醇汽油及其配制方法 - Google Patents
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- 239000003502 gasoline Substances 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 21
- 230000000996 additive effect Effects 0.000 claims abstract description 20
- 238000010025 steaming Methods 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000005642 Oleic acid Substances 0.000 abstract description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract description 4
- 238000002485 combustion reaction Methods 0.000 abstract description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract description 4
- 150000003973 alkyl amines Chemical class 0.000 abstract description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract description 3
- 239000012964 benzotriazole Substances 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 3
- -1 1.0-20.0% Chemical compound 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 239000003245 coal Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000446 fuel Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1608—Well defined compounds, e.g. hexane, benzene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1857—Aldehydes; Ketones
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
- C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/14—Organic compounds
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- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
- C10L1/233—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles
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- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
本发明公开了一种车用木醇汽油及其制备方法，其特征在于该车用木醇汽油以重量百分比为木醇16.0‑70.0％、汽油26.0‑80.0％、添加剂1.5‑3.5％组成。其添加剂以重量百分比为异丙醇8.0‑30.0％、丙酮、1.0‑20.0％、正戊烷17.0‑45.0％、S‑807.0‑20.0％、油酸10.0‑35.0％、邻苯二甲酸二甲酯1.0‑15.0％、苯并三氮唑0.1‑10.0％、烷基胺T5340.1‑10.0％组成。本发明在常温常压下操作，工艺流程简单，原料丰富、易得，生产成本低。不需要对现汽车的发动机等其它部件进行改造或更新，奌火性能好，易发动。储存使用中不分层，稳定性好，燃烧效果好。
Description
技术领域
发明涉及一种合成汽油，特别是一种车用木醇汽油及其配制方法。
背景技术
随着中国经济的快速增长、能源消耗的加大以及国际石油价格的不稳定，能源的短缺直接危及我国经济的可持续发展和国家能源战略安全，我国进口原油及成品油已超过消费总量的60％。今后我国石油对外依存度将继续上升。另一方面我国目前有丰富的煤炭资源，大部分煤炭是直接燃烧，能源利用率低，污染物排放严重，煤炭消费结构极为不合理。进入新世纪来国家鼓励煤制醇项目，目前煤制甲醇产能近一亿吨，由于没能解决好甲醇的利用问题，大量的产能没有释放出来，据不完全统计甲醇的消费量仅仅为30％左右。
同时随着经济的快速发展，尤其是机动车保有量的高速增长，导致我市城市污染日趋严重，空气污染指数优良天数明显减少，可吸入污染物占主要污染物的比例越来越大，近年来我市雾霾非常严重，给人民的正常生活造成了极大的困扰，PM2.5的控制显得非常紧迫。而机动车尾气排放是PM2.5的主要来源之一。因此，无论是出于能源安全考虑，还是出于节能减排的目的，发展替代能源，清洁能源、可再生能源已成为当务之急。
发明内容
本发明的目的在于提出一种用木醇、汽油、添加剂等合成的汽油，木醇参入量大，储存使用中不分层，可最大限度地减少汽车尾气污染，对汽车发动机无不良影响，燃烧效果好，可降低生产成本，在常温常压条件下合成的高标号车用木醇汽油。
本发明的内容是：一种合成车用木醇汽油，其特征之处是组成(重量％)为：
木醇 16.0-70.0％
汽油 26.0-80.0％
添加剂 1.5-3.5％
本发明所述的木醇是含量≥98％的木醇。
本发明所述的汽油是70号至120号汽油。
本发明所述的汽油可以是直馏汽油或凝析汽油或拨头汽油。
本发明所述的添加剂是由下述组份构成(重量％)：
车用木醇汽油的制造方法，以重量百分比计，由以下步骤制取的：
在常温常压条件下，将木醇、汽油、添加剂置于各自容器中，按照所述各组份按比例取量混合均匀即完成，密封存放；其中添加剂亦在常温常压条件下，将丙醇、异丙醇、正戊烷、S-80、油酸、邻苯二甲酸二甲酯、苯并三氮唑、烷基胺T534按照所述各组份按比例取量混合均匀后，再过滤即可。
本发明所述的木醇是本燃料的主燃剂，辛烷值一般高于汽油，蒸发热大，气化膨胀系数大，热利用率高；汽油作为奌火剂与主燃剂；添加剂主要由助溶剂(丙酮、异丙醇)、稳定剂(S-80、油酸)、抗腐剂(苯并三氮唑)、抗氧剂(烷基胺T534)、防橡胶溶胀剂(邻苯二甲酸二甲酯)等组成。组份中加入正戊烷后促进燃料完全燃烧，减少发动机排出的黑烟，实现污染防治、洁净能源、清洁环境的目的；加入S-80、油酸可以进一步促进各原料的互溶，解决了燃料的分层和起油团的问题。
本发明与现有技术相比，具有如下特奌：
1、本发明的车用木醇汽油在常温常压下操作，工艺流程简单，工艺过程可连续生产。
2、本发明的车用木醇汽油原料丰富、易得，生产成本低。
3、本发明的车用木醇汽油在使用时不需要对现汽车的发动机等其它部件进行改造或更新，奌火性能好，易发动。
4、本发明的车用木醇汽油中的木醇参入量大，具有较高的抗爆性和良好的蒸发性，储存使用中不分层，稳定性好，燃烧效果好。
5、本发明的车用木醇汽油可减少环境污染，汽车尾气排放少污染，在操作人员的大气环境中，木醇浓度低于我国居民区大气环境允许的平均浓度值，对人体健康不会产生不良影响。
6、本发明的车用木醇汽油具有节油效果。
下面通过实施例对本发明作进一步描述：
实施例一
木醇 51.0％
89号汽油 47.0％
添加剂 2.0％
其中添加剂按下列各成份的重量百分配比为
实施例二
甲醇 70.0％
89号汽油 27.0％
添加剂 3.0％
其中添加剂按下列各成份的重量百分配比为
实施例三
甲醇 25.0％
89号汽油 73.0％
添加剂 1.8％
其中添加剂按下列各成份的重量百分配比为
配制时，只需在常温常压条件下，将含量≥98％的木醇、89号汽油、添加剂按上述各实施例配比量投入容器中混合均匀即完成；其添加剂亦在常温常压条件下，按照上述各实施例添加剂配比量混合均匀后，再过滤即可。
注：木醇是甲醇的俗称。
Claims (5)
1.车用木醇汽油是由木醇、汽油、添加剂合成的，其特征在于该车用木醇汽油以重量百分比为木醇16.0-70.0％、汽油26.0-80.0％、添加剂1.5-3.5％组成。
2.根椐权利1所述的车用木醇汽油，其特征在于所述的木醇是含量≥98％的木醇。
3.根椐权利1所述的车用木醇汽油，其特征在于所述的汽油是70号至120号汽油。
4.根椐权利1和权利2所述的车用木醇汽油，其特征在于所述的汽油可以是直馏汽油或凝析汽油或拨头汽油。
5.根椐权利1所述的车用木醇汽油，其特征在于所述的添加剂以重量百分比为
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110317648A (zh) * | 2019-08-21 | 2019-10-11 | 章敏 | 一种柴油环保清净增效剂及配制方法 |
| CN110408441A (zh) * | 2019-08-21 | 2019-11-05 | 章敏 | 一种车用汽油环保清净增效剂及配制方法 |
Citations (5)
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| CN110408441A (zh) * | 2019-08-21 | 2019-11-05 | 章敏 | 一种车用汽油环保清净增效剂及配制方法 |
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