CN109306219A - Water super-thin expands fire-resistant coating for steel structure - Google Patents
Water super-thin expands fire-resistant coating for steel structure Download PDFInfo
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- CN109306219A CN109306219A CN201811231351.8A CN201811231351A CN109306219A CN 109306219 A CN109306219 A CN 109306219A CN 201811231351 A CN201811231351 A CN 201811231351A CN 109306219 A CN109306219 A CN 109306219A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention proposes a kind of water super-thins to expand fire-resistant coating for steel structure, according to parts by weight, including following components: 40~60 parts of acrylic emulsion, 10~30 parts of polyvinyl acetate emulsion, 4~8 parts of ammonium polyphosphate, 2~6 parts of dipentaerythritol, 8~16 parts of expanded perlite, 0.4~0.8 part of wetting dispersing agent, 0.3~0.6 part of levelling agent, 2~6 parts of coalescing agent and 20~30 parts of wastewaters with modified calcium sulfate whiskers；Wherein, the wastewaters with modified calcium sulfate whiskers is mainly prepared by calcium sulfate crystal whiskers, nano-titanium dioxide and aluminate coupling agent.The fireproof coating has the characteristics that coating is thin and heat-insulating, fire-preventing is had excellent performance.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of water super-thin expansion fire-resistant coating for steel structure.
Background technique
Relative to concrete, steel construction has apparent advantage in material property, economic benefit, environmental protection, wide
It is general to be applied to longspan structure, super high-rise building, ordinary residence and office building etc., just gradually become the mainstay material of building.So
And the fire protecting performance of steel construction is poor, largely constrains its development.Theoretically, steel construction can not be protected under full load
The critical-temperature for holding static balancing is 528 DEG C.Fire once occurs for building, and fire scene temperature just can reach 700 DEG C in 10 minutes
More than, exposed steel construction reaches critical-temperature in 10 minutes that fire occurs, will generate plastic deformation and lose and hold
Beijing South Maxpower Technology Co. Ltd's power, and then cause the rapid collapsing of steel building.Fireproof coating can play the role of effective flameproof protection to steel construction,
It can delay the heating of steel construction in a fire, extend its time for reaching critical-temperature, can be fire fighter's fire extinguishing and people
Escape is raced against time, and is had important practical significance.
Fire-resistant coating for steel structure has the characteristics that coating thickness is thin, facing type is good, is widely used in steel construction, is meeting
Under fiery heating condition can rapid expanding to more than ten times of original thickness even decades of times, it is fine and close at one layer of steel structure surface formation
Insulating prevents heat from transmitting to steel construction, plays the function of improving fire endurance.However, unexpansive relative to other
Type fireproof coating, existing fire-resistant coating for steel structure is lower in foaming and intumescing initial stage heat-insulating capability, causes steel construction in heat-insulated guarantor
Temperature rises larger before warm layer expands completely, and whole fire resisting effect is usually not so good as Non-expansive fireproof paint, and most coating
The weight bearing of steel construction is increased larger, application effect is undesirable, using being restricted.
Summary of the invention
The present invention proposes that a kind of water super-thin expansion fire-resistant coating for steel structure, the fireproof coating have coating thin and heat-insulated
The excellent feature of fire protecting performance.
The technical scheme of the present invention is realized as follows:
A kind of water super-thin expansion fire-resistant coating for steel structure, according to parts by weight, including following components:
40~60 parts of acrylic emulsion, 10~30 parts of polyvinyl acetate emulsion, 4~8 parts of ammonium polyphosphate, dipentaerythritol 2
~6 parts, 8~16 parts of expanded perlite, 0.4~0.8 part of wetting dispersing agent, 0.3~0.6 part of levelling agent, 2~6 parts of coalescing agent
And 20~30 parts of wastewaters with modified calcium sulfate whiskers；Wherein, the wastewaters with modified calcium sulfate whiskers is mainly by calcium sulfate crystal whiskers, nano-titanium dioxide
It is prepared with aluminate coupling agent.
Preferably, the wastewaters with modified calcium sulfate whiskers the preparation method comprises the following steps:
Calcium sulfate crystal whiskers are added in the maleic acid solution of 3~6wt% and carry out ultrasonic disperse, are warming up to 80 DEG C~90
DEG C, then add nano-titanium dioxide and aluminate coupling agent, be stirred to react 2~6h, after centrifugal vacuum it is dry.
Preferably, the mass ratio of the calcium sulfate crystal whiskers and the aluminate coupling agent is 25~35:1, the sulfuric acid
The mass ratio of calcium pyroborate and the nano-titanium dioxide is 2~6:1.
Preferably, the wetting dispersing agent is calgon wetting agent；The levelling agent selects water-and acrylate total
Polymers, fluorine richness polyacrylate copolymer or Siloxane-Oxyalkylene Copolymers polymer are one such.
Preferably, the coalescing agent be propylene glycol phenylate, dipropylene glycol n-butyl ether, Lauryl Alcohol ester, methoxybutanol,
At least one of ethylene glycol monobutyl ether and dipropylene glycol propyl ether.
The preparation method of water super-thin expansion fire-resistant coating for steel structure of the invention:
After mixing the above components evenly according to the proportion.
Beneficial effects of the present invention:
Water super-thin expansion fire-resistant coating for steel structure of the invention is added to mainly by calcium sulfate crystal whiskers, nanometer titanium dioxide
The wastewaters with modified calcium sulfate whiskers that titanium and aluminate coupling agent are prepared, it is high with matrix resin binding force, it is not easy to be precipitated, improve
The refractory heat-insulating performance of fireproof coating.
The present invention uses two kinds of lotions for base-material, has taken into account fire line, anticorrosive property and the dicoration of coating, has avoided list
One lotion makees base-material and bring certain paint film defect.
Specific embodiment
Embodiment 1
Wastewaters with modified calcium sulfate whiskers the preparation method comprises the following steps:
Calcium sulfate crystal whiskers are added in the maleic acid solution of 3wt% and carry out ultrasonic disperse, are warming up to 80 DEG C, are then added again
Enter nano-titanium dioxide and aluminate coupling agent, be stirred to react 10h, after centrifugal vacuum it is dry.
The mass ratio of calcium sulfate crystal whiskers and aluminate coupling agent is 25:1, the matter of calcium sulfate crystal whiskers and nano-titanium dioxide
The ratio between amount is 6:1.
Embodiment 2
Wastewaters with modified calcium sulfate whiskers the preparation method comprises the following steps:
Calcium sulfate crystal whiskers are added in the maleic acid solution of 6wt% and carry out ultrasonic disperse, are warming up to 90 DEG C, are then added again
Enter nano-titanium dioxide and aluminate coupling agent, be stirred to react 5h, after centrifugal vacuum it is dry.
The mass ratio of calcium sulfate crystal whiskers and aluminate coupling agent is 35:1, the matter of calcium sulfate crystal whiskers and nano-titanium dioxide
The ratio between amount is 2:1.
Embodiment 3
A kind of water super-thin expansion fire-resistant coating for steel structure, according to parts by weight, including following components:
50 parts of acrylic emulsion, 20 parts of polyvinyl acetate emulsion, 6 parts of ammonium polyphosphate, 7 parts of dipentaerythritol, expanded pearlite
12 parts of rock, 0.6 part of calgon wetting agent, 0.5 part of water-borne acrylate copolymer, 4 parts of propylene glycol phenylate and embodiment 1
26 parts of wastewaters with modified calcium sulfate whiskers.
Embodiment 4
A kind of water super-thin expansion fire-resistant coating for steel structure, according to parts by weight, including following components:
40 parts of acrylic emulsion, 30 parts of polyvinyl acetate emulsion, 4 parts of ammonium polyphosphate, 8 parts of dipentaerythritol, expanded pearlite
8 parts of rock, 0.4 part of calgon wetting agent, 0.3 part of Siloxane-Oxyalkylene Copolymers polymer, 3 parts of Lauryl Alcohol ester and embodiment
20 parts of 2 wastewaters with modified calcium sulfate whiskers.
Embodiment 5
A kind of water super-thin expansion fire-resistant coating for steel structure, according to parts by weight, including following components:
60 parts of acrylic emulsion, 10 parts of polyvinyl acetate emulsion, 8 parts of ammonium polyphosphate, 5 parts of dipentaerythritol, expanded pearlite
16 parts of rock, 0.5 part of calgon wetting agent, 0.6 part of Siloxane-Oxyalkylene Copolymers polymer, 2 parts of ethylene glycol monobutyl ether and reality
30 parts of wastewaters with modified calcium sulfate whiskers for applying example 1.
Embodiment 6
A kind of water super-thin expansion fire-resistant coating for steel structure, according to parts by weight, including following components:
45 parts of acrylic emulsion, 15 parts of polyvinyl acetate emulsion, 5 parts of ammonium polyphosphate, 10 parts of dipentaerythritol, expanded pearlite
14 parts of rock, 0.8 part of calgon wetting agent, 0.6 part of fluorine richness polyacrylate copolymer, 6 parts of dipropylene glycol propyl ether and reality
24 parts of wastewaters with modified calcium sulfate whiskers for applying example 2.
Test example
The water super-thin expansion fire-resistant coating for steel structure that embodiment 3~6 is obtained is according to GB14907-2002 progressive
It can test, the results are shown in Table 1:
The performance test results of the water super-thin expansion fire-resistant coating for steel structure of the invention of table 1
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (5)
1. a kind of water super-thin expands fire-resistant coating for steel structure, which is characterized in that according to parts by weight, including following components:
40~60 parts of acrylic emulsion, 10~30 parts of polyvinyl acetate emulsion, 4~8 parts of ammonium polyphosphate, dipentaerythritol 2~6
Part, 8~16 parts of expanded perlite, 0.4~0.8 part of wetting dispersing agent, 0.3~0.6 part of levelling agent, 2~6 parts of coalescing agent and change
20~30 parts of calcium sulfate crystal whiskers of property；Wherein, the wastewaters with modified calcium sulfate whiskers is mainly by calcium sulfate crystal whiskers, nano-titanium dioxide and aluminium
Acid esters coupling agent is prepared.
2. water super-thin according to claim 1 expands fire-resistant coating for steel structure, which is characterized in that the modified sulfuric acid
Calcium pyroborate the preparation method comprises the following steps:
Calcium sulfate crystal whiskers are added in the maleic acid solution of 3~6wt% and carry out ultrasonic disperse, are warming up to 80 DEG C~90 DEG C, so
After add nano-titanium dioxide and aluminate coupling agent, be stirred to react 2~6h, after centrifugal vacuum it is dry.
3. water super-thin according to claim 2 expands fire-resistant coating for steel structure, which is characterized in that the calcium sulfate is brilliant
It must be 25~35:1, the matter of the calcium sulfate crystal whiskers and the nano-titanium dioxide with the mass ratio of the aluminate coupling agent
The ratio between amount is 2~6:1.
4. water super-thin according to claim 1 expands fire-resistant coating for steel structure, which is characterized in that the wetting and dispersing
Agent is calgon wetting agent；The levelling agent selects water-borne acrylate copolymer, fluorine richness polyacrylate copolymer
Or Siloxane-Oxyalkylene Copolymers polymer is one such.
5. water super-thin according to claim 1 expands fire-resistant coating for steel structure, which is characterized in that the coalescing agent
For propylene glycol phenylate, dipropylene glycol n-butyl ether, Lauryl Alcohol ester, methoxybutanol, ethylene glycol monobutyl ether and dipropylene glycol propyl ether
At least one of.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811231351.8A CN109306219A (en) | 2018-10-22 | 2018-10-22 | Water super-thin expands fire-resistant coating for steel structure |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811231351.8A CN109306219A (en) | 2018-10-22 | 2018-10-22 | Water super-thin expands fire-resistant coating for steel structure |
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| CN109306219A true CN109306219A (en) | 2019-02-05 |
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| CN201811231351.8A Pending CN109306219A (en) | 2018-10-22 | 2018-10-22 | Water super-thin expands fire-resistant coating for steel structure |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112709353A (en) * | 2020-12-30 | 2021-04-27 | 宁波鼎翔消防技术有限公司 | Preparation method of fireproof coating and fireproof wall |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2577065B2 (en) * | 1988-08-31 | 1997-01-29 | 株式会社アイジー技術研究所 | Fire protection panel |
| CN102219930A (en) * | 2011-06-07 | 2011-10-19 | 刘立文 | Calcium sulfate whisker surface modification technology |
| CN104231805A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Water-based ultra-thin fire-retardant coating for steel structures and preparation method of fire-retardant coating |
| CN104559679A (en) * | 2015-02-05 | 2015-04-29 | 四川明鑫佳杰新材料有限责任公司 | Water-based waterproof coating added with calcium sulfate whiskers and preparation method of coating |
| CN107698838A (en) * | 2017-09-20 | 2018-02-16 | 无锡市永兴金属软管有限公司 | A kind of buried drain pipe masterbatch and preparation method thereof |
-
2018
- 2018-10-22 CN CN201811231351.8A patent/CN109306219A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2577065B2 (en) * | 1988-08-31 | 1997-01-29 | 株式会社アイジー技術研究所 | Fire protection panel |
| CN102219930A (en) * | 2011-06-07 | 2011-10-19 | 刘立文 | Calcium sulfate whisker surface modification technology |
| CN104231805A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Water-based ultra-thin fire-retardant coating for steel structures and preparation method of fire-retardant coating |
| CN104559679A (en) * | 2015-02-05 | 2015-04-29 | 四川明鑫佳杰新材料有限责任公司 | Water-based waterproof coating added with calcium sulfate whiskers and preparation method of coating |
| CN107698838A (en) * | 2017-09-20 | 2018-02-16 | 无锡市永兴金属软管有限公司 | A kind of buried drain pipe masterbatch and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112709353A (en) * | 2020-12-30 | 2021-04-27 | 宁波鼎翔消防技术有限公司 | Preparation method of fireproof coating and fireproof wall |
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