CN109294402A - A kind of wet structure solidifies solvent-free anticorrosive paint and preparation process - Google Patents
A kind of wet structure solidifies solvent-free anticorrosive paint and preparation process Download PDFInfo
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- CN109294402A CN109294402A CN201811255777.7A CN201811255777A CN109294402A CN 109294402 A CN109294402 A CN 109294402A CN 201811255777 A CN201811255777 A CN 201811255777A CN 109294402 A CN109294402 A CN 109294402A
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- anticorrosive paint
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- free anticorrosive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0881—Titanium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to anticorrosive paint technology fields, solidify solvent-free anticorrosive paint and preparation process more particularly, to a kind of wet structure.The coating is made of two kinds of components of first, second that mass parts ratio is 1~4: 1, first component is 20~50 parts of low viscosity epoxy resin by mass parts, 5~10 parts of Epoxy-Terminated Polydimethylsiloxane, 1~3 part of basalt fibre, 4~10 parts of basalt scale, 10~20 parts of reactive diluent, 1~35 part of ferrophosphorus powder, 1~30 part of titanium valve, 1~10 part of aluminium triphosphate, 5~25 parts of composite zinc phosphate, 1.5~10 parts of aluminium flake, 1~3 part of barium sulfate, 1~2 part of dispersing agent, the raw material composition that 5~20 parts of anatase titanium dioxide；Second component is 25~30 parts of Man Xini alkali curing agent by mass parts, and 5~10 parts of polyamines polyene, the raw material that 0.5~2 part of thixotropic agents forms.The coating is solvent free corrosion prevention coating, and has better weatherability, resistance to acid and alkali, wearability.
Description
Technical field
The present invention relates to anticorrosive paint technology field, more particularly, to a kind of wet structure solidify solvent-free anticorrosive paint and
Preparation process.
Background technique
Anticorrosive paint is in energy industry, large size industrial enterprise, Modern Traffic transport, emerging ocean engineering, port engineering etc.
It is widely applied on steel construction.World's offshore wind farm technology reaches its maturity, and comes into the large-scale development stage, and China possesses ten
Divide coastal waters wind-resources abundant, energy supply situation will be effectively improved by developing and using offshore wind energy resource abundant；Meanwhile it is close several
Year in order to more efficiently carry out it is long-distance transport in short-term, more bridge spanning the seas of China Reconstructs, but since sea is relatively high containing salinity,
Equipment is corroded quite serious, and currently used epoxy powder coating has the waste of energy that need to be heating and curing, damages in transportational process
It is bad to repair two such disadvantage, therefore high-performance corrosion-inhibiting coating is needed to meet current needs.
The glass flake anticorrosion paint deposited at present, glass flake neutral and alkali oxides silicon dioxide content is high, which deposits
Resistance to acid and alkali it is insufficient, weatherability is poor, wearability is insufficient the defects of cause coating short to the guard time of metallic matrix, reach not
To expected effect.For glass flake, iron oxide in Black Warrior scale, titanium dioxide, aluminium oxide, calcium oxide content compared with
Height, therefore basalt scale can substitute common glass flake applied to petrochemical industry, communications and transportation, ocean engineering and harbour
Engineering etc..
There are iron oxide, the ferrous oxide of high level in basalt fibre ingredient, making it not only has tensile strength height, bullet
The mechanical properties such as property modulus height, creep resistant, and basalt fibre items mechanical index is above simple glass fiber, resists compacted
The long-term mechanical properties such as change, antifatigue are better than glass, aramid fiber.Basalt is a kind of high performance volcanic rock component, this
Special silicate makes basalt fibre have excellent chemical resistance, especially has the advantages that alkali resistance, this makes basalt
Fiber has the performance of chloride ion corrosion in good resistance to ocean, therefore basalt fibre can be very good to be applied to instead of carbon fiber
Petrochemical industry, communications and transportation, ocean engineering and port engineering etc..
Contain organic solvent in common anticorrosive paint, during curing of coatings, the volatilization of solvent can be in coating table
Face leaves hole, and the performance of coating is caused to decline；And the volatilization of solvent also threatens the health of construction personnel, also brings to environment
Harm；National relevant policies also limit the development of coatings volatile organic compounds.
Summary of the invention
In order to solve the above problem, the present invention provides a kind of wet structures to solidify solvent-free anticorrosive paint and preparation process,
The dioxide-containing silica of basalt scale in the coating is 50 mass parts；Iron oxide in basalt fibre, ferrous oxide contain
Amount is higher, has excellent mechanical property；And the coating is solvent-free anticorrosive paint, therefore the coating has than common anti-corrosion
The better weatherability of coating, resistance to acid and alkali, wearability.
A kind of wet structure solidifies solvent-free anticorrosive paint, is made of two kinds of components of first component and second component, first component by
Raw material including following components is prepared, and the mass parts ratio of each component is 20~50 parts of low viscosity epoxy resin, epoxy terminated
5~10 parts of dimethyl silicone polymer, 1~3 part of basalt fibre, 4~10 parts of basalt scale, 10~20 parts of reactive diluent,
1~35 part of ferrophosphorus powder, 1~30 part of titanium valve, 1~10 part of aluminium triphosphate, 5~25 parts of composite zinc phosphate, 1.5~10 parts of aluminium flake,
1~3 part of barium sulfate, 1~2 part of dispersing agent, 5~20 parts of anatase titanium dioxide；Second component is by the raw material system including following components
Standby to form, the mass parts ratio of each component is 25~30 parts of Man Xini alkali curing agent, 5~10 parts of polyamines polyene, thixotropic agents 0.5~
2 parts；The mass parts ratio for forming a kind of two kinds of components of first, second that wet structure solidifies solvent-free anticorrosive paint is 1~4: 1.
The low viscosity epoxy resin is bisphenol-A, Bisphenol F, more phenolic tetraglycidel ether epoxy resins, aliphatic shrink
One of glycerin ether epoxy resin and a variety of；Viscosity is controlled in rotary viscosity are as follows: 50~2500mPa.s.
The Epoxy-Terminated Polydimethylsiloxane is with hydroxyl-terminated injecting two methyl siloxane and epoxychloropropane for original
Material, in molar ratio 1: 2~3 at 90~130 DEG C synthesizing organo-silicon glycol ethers intermediate, dechlorination closed loop is formed in the presence of alkali
Epoxy-Terminated Polydimethylsiloxane, structure are as follows:
The basaltic scale of the flakey is 100~1000 mesh, with a thickness of 1~10 μm；Threadiness is basaltic
For diameter less than 20 μm, major diameter ratio is greater than 10.
The reactive diluent is acrylic glycidol ether, phenyl glycidyl ether, benzyl glycidyl ether, second two
Alcohol bisglycidyl ether, 1,4-butanediol diglycidyl ether, 1,6- hexanediol diglycidyl ether or resorcinol are double to shrink
One of glycerin ether is a variety of.
The dispersing agent be one of fatty acid dispersing agent, aliphatic amide type dispersing agent, esters dispersing agent or
It is several.
The Man Xini alkali curing agent is with anacardol, m-xylene diamine and paraformaldehyde according to molar ratio for 3: (1~
1.5): (0.9~1.2) synthesis.
The polyamines polyene be diethylenetriamine, triethylene tetramine, tetraethylenepentamine it is one or more.Thixotropic agents
For fumed silica.
A kind of preparation method that wet structure solidifies solvent-free anticorrosive paint comprises the steps of:
(1) reactive diluent, dispersing agent are added in low viscosity epoxy resin, under 300~1000 revs/min of rates
Stirring 20~60 minutes, obtains mixed liquor；
(2) basalt scale, basalt fibre, epoxy terminated poly dimethyl are added in the mixed liquor that step (1) obtains
Siloxanes, ferrophosphorus powder, aluminium triphosphate, composite zinc phosphate, aluminium flake, titanium valve, barium sulfate, anatase titanium dioxide, 1400~
It is stirred 20~60 minutes under 1500 revs/min of rates, obtains first component；
(3) by Man Xini alkali, the polyamines polyene of proportion is added under thixotropic agent effect, obtains second component；
(4) by weight it is 1~4: 1 mixing by two kinds of components of first, second, stirs 10 under 300~1000 revs/min of rates
~20 minutes, obtain a kind of curable solvent-free anticorrosive paint of wet structure.
Compared with prior art, the present invention having the advantage that
(1) for glass flake, iron oxide in Black Warrior scale, titanium dioxide, aluminium oxide, calcium oxide content compared with
It is high；Iron oxide and ferrous oxide in basalt fibre containing high level, with tensile strength height, elasticity modulus is high, it is compacted to resist
The excellent mechanical property of change etc., so that basalt scale and basalt fibre have better weatherability, acid and alkali-resistance
Property, wearability, enhance corrosion resistance；
(2) compared with common coating, there are labyrinth effect due to being added to basalt scale in coating of the invention, from
And corrosion rate being reduced, while also added the basalt fibre with excellent mechanical performance, the addition of both components makes
Obtaining the coating has very strong resistance to acid and alkali, weatherability, and antiseptic property is very prominent, has in similar anticorrosive paint obvious
Advantage；
(3) coating of coating preparation of the invention is compared with related conventional coatings, and wearability improves 1.5~2.0 times, right
Metal and concrete have very high adhesion strength, and operational difference makes the cold resistance of concrete increase by 5~6 times up to 60 DEG C；
(4) coating of the invention is solventless coatings, in coating preparation process, so that the integrality of coating, construction peace
Quan Xing, economy get a promotion, and meet policy development trend.
Specific embodiment
The following is specific embodiments of the present invention, carries out specific detailed description to technical solution of the present invention, but originally
Invention is not limited to following embodiment；The chemical reagent that embodiment is mentioned is the chemical reagent that market possesses, special chemical examination
Agent can illustrate；Reactive diluent, the products such as dispersing agent can be carried out using coating industry engineer according to domain knowledge
Allotment, product are also commercial product simultaneously, and coating engineer can solve according to professional knowledge.The present invention provides a new skill
Art scheme, all within that scope of the present invention according to the synthesis step of patent of invention and main component and content.
Embodiment 1
First component includes: 30 mass parts of low viscosity bisphenol F epoxy resin, 7 mass parts of Epoxy-Terminated Polydimethylsiloxane,
2 mass parts of basalt fibre, 7 mass parts of basalt scale, 15 mass parts of reactive diluent acrylic glycidol ether, ferrophosphorus powder
5 mass parts, 15 mass parts of titanium valve, 1 mass parts of aluminium triphosphate, 5 mass parts of composite zinc phosphate, 1.5 mass parts of aluminium flake, barium sulfate
3 mass parts, Bi Ke company produce 1 mass parts of Disperbyk164 dispersing agent, 5 mass parts of anatase titanium dioxide.
Second component includes: 25 mass parts of Man Xini alkali curing agent, 10 mass parts of diethylenetriamine, thixotropic agents gas phase dioxy
2 mass parts of SiClx.
Preparation process is as follows:
(1) reactive diluent, dispersing agent are added in low viscosity epoxy resin, under 300~1000 revs/min of rates
Stirring 20~60 minutes, obtains mixed liquor；
(2) basalt scale, basalt fibre, epoxy terminated poly dimethyl are added in the mixed liquor that step (1) obtains
Siloxanes, ferrophosphorus powder, aluminium triphosphate, composite zinc phosphate, aluminium flake, titanium valve, barium sulfate, anatase titanium dioxide, 1400~
It is stirred 20~60 minutes under 1500 revs/min of rates, obtains first component；
(3) by Man Xini alkali, the polyamines polyene of proportion, as second component are added under thixotropic agent effect；
(4) by two kinds of components of first, second be in mass ratio 2: 1 mixing, under 300~1000 revs/min of rates stir 10~
20 minutes, obtain a kind of curable solvent-free anticorrosive paint of wet structure.
Embodiment 2
First component includes: 20 mass parts of low-viscosity bisphenol A epoxide resin, 10 mass of Epoxy-Terminated Polydimethylsiloxane
Part, 3 mass parts of basalt fibre, 10 mass parts of basalt scale, 20 mass parts of reactive diluent ethylene glycol bisglycidyl ether,
35 mass parts of ferrophosphorus powder, 30 mass parts of titanium valve, 10 mass parts of aluminium triphosphate, 15 mass parts of composite zinc phosphate, 5 mass of aluminium flake
Part, 2 mass parts of barium sulfate, Bi Ke company produces 2 mass parts of Disperbyk164 dispersing agent, 20 mass parts of anatase titanium dioxide.
Second component includes: 28 mass parts of Man Xini alkali curing agent, 7 mass parts of triethylene tetramine, thixotropic agents gas phase dioxy
1 mass parts of SiClx.
Preparation process is as follows:
(1) reactive diluent, dispersing agent are added in low viscosity epoxy resin, under 300~1000 revs/min of rates
Stirring 20~60 minutes, obtains mixed liquor；
(2) basalt scale, basalt fibre, epoxy terminated poly dimethyl are added in the mixed liquor that step (1) obtains
Siloxanes, ferrophosphorus powder, aluminium triphosphate, composite zinc phosphate, aluminium flake, titanium valve, barium sulfate, anatase titanium dioxide, 1400~
It is stirred 20~60 minutes under 1500 revs/min of rates, obtains first component；
(3) by Man Xini alkali, the polyamines polyene of proportion, as second component are added under thixotropic agent effect；
(4) by two kinds of components of first, second be in mass ratio 1: 1 mixing, under 300~1000 revs/min of rates stir 10~
20 minutes, obtain a kind of curable solvent-free anticorrosive paint of wet structure.
Embodiment 3
First component includes: 50 mass parts of more phenolic tetraglycidel ether epoxy resins, 5 matter of Epoxy-Terminated Polydimethylsiloxane
Measure part, 1 mass parts of basalt fibre, 4 mass parts of basalt scale, reactive diluent 1,10 matter of 6- hexanediol diglycidyl ether
Measure part, 20 mass parts of ferrophosphorus powder, 1 mass parts of titanium valve, 5 mass parts of aluminium triphosphate, 25 mass parts of composite zinc phosphate, 2 matter of aluminium flake
Part, 1 mass parts of barium sulfate are measured, Bi Ke company produces 1.5 mass parts of Disperbyk162 dispersing agent, 15 mass of anatase titanium dioxide
Part.
Second component includes: 30 mass parts of Man Xini alkali curing agent, 5 mass parts of tetraethylenepentamine, thixotropic agents gas phase dioxy
0.5 mass parts of SiClx.
Preparation process is as follows:
(1) reactive diluent, dispersing agent are added in low viscosity epoxy resin, under 300~1000 revs/min of rates
Stirring 20~60 minutes, obtains mixed liquor；
(2) basalt scale, basalt fibre, epoxy terminated poly dimethyl are added in the mixed liquor that step (1) obtains
Siloxanes, ferrophosphorus powder, aluminium triphosphate, composite zinc phosphate, aluminium flake, titanium valve, barium sulfate, anatase titanium dioxide, 1400~
It is stirred 20~60 minutes under 1500 revs/min of rates, obtains first component；
(3) by Man Xini alkali, the polyamines polyene of proportion, as second component are added under thixotropic agent effect；
(4) by two kinds of components of first, second be in mass ratio 4: 1 mixing, under 300~1000 revs/min of rates stir 10~
20 minutes, obtain a kind of curable solvent-free anticorrosive paint of wet structure.
Claims (10)
1. a kind of wet structure solidifies solvent-free anticorrosive paint, which is characterized in that it is made of two kinds of components of first component and second component,
For first component by including that the raw material of following components is prepared, the mass parts ratio of each component is 20~50 parts of low viscosity epoxy resin,
5~10 parts of Epoxy-Terminated Polydimethylsiloxane, 1~3 part of basalt fibre, 4~10 parts of basalt scale, reactive diluent 10
~20 parts, 1~35 part of ferrophosphorus powder, 1~30 part of titanium valve, 1~10 part of aluminium triphosphate, 5~25 parts of composite zinc phosphate, aluminium flake 1.5
~10 parts, 1~3 part of barium sulfate, 1~2 part of dispersing agent, 5~20 parts of anatase titanium dioxide；Second component is by including following components
Raw material is prepared, and the mass parts ratio of each component is 25~30 parts of Man Xini alkali curing agent, and 5~10 parts of polyamines polyene, thixotroping helps
0.5~2 part of agent；Forming a kind of wet structure to solidify the mass parts ratio of two kinds of components of first, second of solvent-free anticorrosive paint is 1~4:
1。
2. a kind of wet structure according to claim 1 solidifies solvent-free anticorrosive paint, which is characterized in that low described in it
Viscosity epoxy is bisphenol-A, in Bisphenol F, more phenolic tetraglycidel ether epoxy resins, aliphatic glycidyl ether epoxy resin
One kind and it is a variety of；Viscosity is controlled in rotary viscosity are as follows: 50~2500mPa.s.
3. a kind of wet structure according to claim 1 solidifies solvent-free anticorrosive paint, which is characterized in that the end described in it
Epoxy group dimethyl silicone polymer is 1:2~3 in molar ratio using hydroxyl-terminated injecting two methyl siloxane and epoxychloropropane as raw material
The synthesizing organo-silicon glycol ethers intermediate at 90~130 DEG C, dechlorination closed loop forms epoxy terminated poly dimethyl in the presence of alkali
Siloxanes, structure are as follows:
4. a kind of wet structure according to claim 1 solidifies solvent-free anticorrosive paint, which is characterized in that the squama described in it
The basaltic scale of sheet is 100~1000 mesh, with a thickness of 1~10 μm；The basaltic diameter of threadiness is less than 20 μm, major diameter
Ratio is greater than 10.
5. a kind of wet structure according to claim 1 solidifies solvent-free anticorrosive paint, which is characterized in that the work described in it
Property diluent be acrylic glycidol ether, phenyl glycidyl ether, benzyl glycidyl ether, ethylene glycol bisglycidyl ether,
One of 1,4-butanediol diglycidyl ether, 1,6- hexanediol diglycidyl ether or resorcinol bisglycidyl ether or
It is a variety of.
6. a kind of wet structure according to claim 1 solidifies solvent-free anticorrosive paint, which is characterized in that point described in it
Powder is one or more of fatty acid dispersing agent, aliphatic amide type dispersing agent, esters dispersing agent.
7. a kind of wet structure according to claim 1 solidifies solvent-free anticorrosive paint, which is characterized in that graceful described in it
Uncommon Buddhist nun's alkali curing agent is according to molar ratio with anacardol, m-xylene diamine and paraformaldehyde for 3: 1~1.5: 0.9~1.2 synthesis.
8. a kind of wet structure according to claim 1 solidifies solvent-free anticorrosive paint, which is characterized in that more described in it
Alkene polyamines be diethylenetriamine, triethylene tetramine, tetraethylenepentamine it is one or more.
9. a kind of wet structure according to claim 1 solidifies solvent-free anticorrosive paint, which is characterized in that the touching described in it
Change auxiliary agent is fumed silica.
10. a kind of described in any item wet structures solidify the preparation method of solvent-free anticorrosive paint according to claim 1~9,
It is characterized in that comprising the steps of:
(1) reactive diluent, dispersing agent are added in low viscosity epoxy resin, are stirred under 300~1000 revs/min of rates
20~60 minutes, obtain mixed liquor；
(2) basalt scale, basalt fibre, epoxy terminated polydimethylsiloxanes are added in the mixed liquor that step (1) obtains
Alkane, ferrophosphorus powder, aluminium triphosphate, composite zinc phosphate, aluminium flake, titanium valve, barium sulfate, anatase titanium dioxide, 1400~1500
It is stirred 20~60 minutes under rev/min rate, obtains first component；
(3) by Man Xini alkali under the action of thixotropic agent, the polyamines polyene of proportion is added, obtains second component；
(4) by weight it is 1~4: 1 mixing by two kinds of components of first, second, 10~20 is stirred under 300~1000 revs/min of rates
Minute, obtain scale containing basalt and the curable solvent-free anticorrosive paint of fiber wet structure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811255777.7A CN109294402A (en) | 2018-10-26 | 2018-10-26 | A kind of wet structure solidifies solvent-free anticorrosive paint and preparation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811255777.7A CN109294402A (en) | 2018-10-26 | 2018-10-26 | A kind of wet structure solidifies solvent-free anticorrosive paint and preparation process |
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| CN109294402A true CN109294402A (en) | 2019-02-01 |
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| CN201811255777.7A Pending CN109294402A (en) | 2018-10-26 | 2018-10-26 | A kind of wet structure solidifies solvent-free anticorrosive paint and preparation process |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112680012A (en) * | 2020-12-24 | 2021-04-20 | 海南大学 | Degradable antifouling coating containing basalt fiber, flake powder and copper metal powder and preparation process thereof |
| CN112694833A (en) * | 2020-12-26 | 2021-04-23 | 海南大学 | Composite low-surface-energy antifouling paint containing basalt fiber powder and scale powder and preparation method thereof |
| CN116285592A (en) * | 2023-04-25 | 2023-06-23 | 陕西科技大学 | Basalt nano-sheet-based high-performance insulating paint and preparation method thereof |
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| CN101319042A (en) * | 2007-06-08 | 2008-12-10 | 上海美东生物材料有限公司 | Low-viscosity cardanol solidifying agent of epoxy resin and preparation method thereof |
| CN106811004A (en) * | 2017-01-24 | 2017-06-09 | 东南大学 | A kind of heavy antisepsis non-solvent epoxy basalt flake paint and preparation method thereof |
| CN107868535A (en) * | 2017-12-21 | 2018-04-03 | 罗汉平 | A kind of basalt fibre crack resisting coating and preparation method thereof |
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2018
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| CN101319042A (en) * | 2007-06-08 | 2008-12-10 | 上海美东生物材料有限公司 | Low-viscosity cardanol solidifying agent of epoxy resin and preparation method thereof |
| CN106811004A (en) * | 2017-01-24 | 2017-06-09 | 东南大学 | A kind of heavy antisepsis non-solvent epoxy basalt flake paint and preparation method thereof |
| CN107868535A (en) * | 2017-12-21 | 2018-04-03 | 罗汉平 | A kind of basalt fibre crack resisting coating and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112680012A (en) * | 2020-12-24 | 2021-04-20 | 海南大学 | Degradable antifouling coating containing basalt fiber, flake powder and copper metal powder and preparation process thereof |
| CN112694833A (en) * | 2020-12-26 | 2021-04-23 | 海南大学 | Composite low-surface-energy antifouling paint containing basalt fiber powder and scale powder and preparation method thereof |
| CN116285592A (en) * | 2023-04-25 | 2023-06-23 | 陕西科技大学 | Basalt nano-sheet-based high-performance insulating paint and preparation method thereof |
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Application publication date: 20190201 |