CN109279665A - A kind of processing method of nickle cobalt lithium manganate ternary waste material - Google Patents
A kind of processing method of nickle cobalt lithium manganate ternary waste material Download PDFInfo
- Publication number
- CN109279665A CN109279665A CN201811066427.6A CN201811066427A CN109279665A CN 109279665 A CN109279665 A CN 109279665A CN 201811066427 A CN201811066427 A CN 201811066427A CN 109279665 A CN109279665 A CN 109279665A
- Authority
- CN
- China
- Prior art keywords
- cobalt
- solution
- nickel
- lithium
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002699 waste material Substances 0.000 title claims abstract description 36
- OVAQODDUFGFVPR-UHFFFAOYSA-N lithium cobalt(2+) dioxido(dioxo)manganese Chemical compound [Li+].[Mn](=O)(=O)([O-])[O-].[Co+2] OVAQODDUFGFVPR-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000003672 processing method Methods 0.000 title claims abstract description 17
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 68
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 56
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000011572 manganese Substances 0.000 claims abstract description 41
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 39
- 239000010941 cobalt Substances 0.000 claims abstract description 38
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 38
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000000463 material Substances 0.000 claims abstract description 32
- 238000000926 separation method Methods 0.000 claims abstract description 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000011084 recovery Methods 0.000 claims abstract description 26
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 24
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 230000009467 reduction Effects 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 17
- 230000001376 precipitating effect Effects 0.000 claims abstract description 17
- 239000002893 slag Substances 0.000 claims abstract description 16
- 230000008569 process Effects 0.000 claims abstract description 15
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000460 chlorine Substances 0.000 claims abstract description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 8
- 239000000706 filtrate Substances 0.000 claims description 42
- 238000005406 washing Methods 0.000 claims description 41
- 238000001816 cooling Methods 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 238000001914 filtration Methods 0.000 claims description 29
- ZGDWHDKHJKZZIQ-UHFFFAOYSA-N cobalt nickel Chemical compound [Co].[Ni].[Ni].[Ni] ZGDWHDKHJKZZIQ-UHFFFAOYSA-N 0.000 claims description 24
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 19
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 19
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 19
- 239000001099 ammonium carbonate Substances 0.000 claims description 19
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims description 18
- 229940044175 cobalt sulfate Drugs 0.000 claims description 16
- 229910000361 cobalt sulfate Inorganic materials 0.000 claims description 15
- 239000003638 chemical reducing agent Substances 0.000 claims description 14
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 13
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 13
- 238000002425 crystallisation Methods 0.000 claims description 13
- 230000008025 crystallization Effects 0.000 claims description 13
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 12
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 12
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 12
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 12
- 238000007885 magnetic separation Methods 0.000 claims description 12
- 229940099596 manganese sulfate Drugs 0.000 claims description 12
- 235000007079 manganese sulphate Nutrition 0.000 claims description 12
- 239000011702 manganese sulphate Substances 0.000 claims description 12
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 239000012452 mother liquor Substances 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 7
- 239000003337 fertilizer Substances 0.000 claims description 7
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 6
- 239000001569 carbon dioxide Substances 0.000 claims description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 6
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 6
- 238000012216 screening Methods 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000004411 aluminium Substances 0.000 abstract description 12
- 229910052751 metal Inorganic materials 0.000 abstract description 10
- 239000002184 metal Substances 0.000 abstract description 10
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 abstract description 9
- 239000002351 wastewater Substances 0.000 abstract description 7
- 150000002739 metals Chemical class 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- KFDQGLPGKXUTMZ-UHFFFAOYSA-N [Mn].[Co].[Ni] Chemical compound [Mn].[Co].[Ni] KFDQGLPGKXUTMZ-UHFFFAOYSA-N 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- 239000003513 alkali Substances 0.000 abstract description 2
- 229910001429 cobalt ion Inorganic materials 0.000 abstract description 2
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 abstract description 2
- 229910001947 lithium oxide Inorganic materials 0.000 abstract description 2
- 238000001514 detection method Methods 0.000 description 16
- 238000004064 recycling Methods 0.000 description 10
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 9
- 229910001416 lithium ion Inorganic materials 0.000 description 9
- 229910009378 Zn Ca Inorganic materials 0.000 description 7
- 239000002253 acid Substances 0.000 description 4
- HFCVPDYCRZVZDF-UHFFFAOYSA-N [Li+].[Co+2].[Ni+2].[O-][Mn]([O-])(=O)=O Chemical compound [Li+].[Co+2].[Ni+2].[O-][Mn]([O-])(=O)=O HFCVPDYCRZVZDF-UHFFFAOYSA-N 0.000 description 3
- 239000010405 anode material Substances 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 229910010707 LiFePO 4 Inorganic materials 0.000 description 1
- 229910015853 MSO4 Inorganic materials 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical class [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 229910001386 lithium phosphate Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/08—Halides
- C01G53/09—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/08—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/34—Preparation of aluminium hydroxide by precipitation from solutions containing aluminium salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/10—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Index | Main content | Fe | Mn | Zn | Ca | Mg | Na |
Numerical value | 99.63% | 2.5ppm | 21ppm | 4ppm | 31ppm | 21ppm | 25ppm |
K | Pb | Ni | As | Cu | Cd | Water-insoluble | Cl |
12ppm | 2ppm | 39ppm | 0.2ppm | 1.5ppm | 2.3ppm | 45ppm | 12ppm |
Index | Main content | Fe | Mn | Zn | Ca | Mg | Na |
Numerical value | 99.51% | 2.5ppm | 24ppm | 2ppm | 21ppm | 13ppm | 21ppm |
K | Pb | Co | As | Cu | Cd | Water-insoluble | pH |
12ppm | 1ppm | 42ppm | 0.3ppm | 2.1ppm | 2.1ppm | 35ppm | 4.6 |
Index | Main content | Fe | Mn | Zn | Ca | Mg | Na |
Numerical value | 99.61% | 4ppm | 18ppm | 3ppm | 25ppm | 20ppm | 21ppm |
K | Pb | Ni | As | Cu | Cd | Water-insoluble | Cl |
8ppm | 2ppm | 35ppm | 0.2ppm | 1.5ppm | 2.1ppm | 41ppm | 11ppm |
Index | Main content | Fe | Mn | Zn | Ca | Mg | Na |
Numerical value | 99.54% | 2.9ppm | 32ppm | 2ppm | 22ppm | 11ppm | 21ppm |
K | Pb | Co | As | Cu | Cd | Water-insoluble | pH |
11ppm | 1ppm | 41ppm | 0.3ppm | 2.4ppm | 2.6ppm | 39ppm | 4.5 |
Index | Mn | Fe | Ni | Zn | Ca | Mg | Na |
Numerical value | 32.2% | 4ppm | 23ppm | 1ppm | 13ppm | 15ppm | 21ppm |
K | Pb | Co | As | Cu | Cd | Water-insoluble | pH |
11ppm | 0.2ppm | 21ppm | 0.2ppm | 2ppm | 2.1ppm | 41ppm | 5.8 |
Index | Main content | Fe | Mn | Zn | Ca | Mg | Na |
Numerical value | 99.61% | 2ppm | 23ppm | 4ppm | 21ppm | 26ppm | 23ppm |
K | Pb | Ni | As | Cu | Cd | Water-insoluble | Cl |
21ppm | 1ppm | 34ppm | 0.3ppm | 1.4ppm | 2.1ppm | 43ppm | 12ppm |
Index | Mn | Fe | Ni | Zn | Ca | Mg | Na |
Numerical value | 32.3% | 4ppm | 20ppm | 1ppm | 8ppm | 11ppm | 27ppm |
K | Pb | Co | As | Cu | Cd | Water-insoluble | pH |
12ppm | 0.2ppm | 33ppm | 0.3ppm | 2.7ppm | 2.1ppm | 49ppm | 5.8 |
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811066427.6A CN109279665B (en) | 2018-09-13 | 2018-09-13 | Treatment method of nickel cobalt lithium manganate ternary waste |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811066427.6A CN109279665B (en) | 2018-09-13 | 2018-09-13 | Treatment method of nickel cobalt lithium manganate ternary waste |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109279665A true CN109279665A (en) | 2019-01-29 |
CN109279665B CN109279665B (en) | 2020-09-25 |
Family
ID=65181035
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201811066427.6A Active CN109279665B (en) | 2018-09-13 | 2018-09-13 | Treatment method of nickel cobalt lithium manganate ternary waste |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109279665B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111039312A (en) * | 2019-12-26 | 2020-04-21 | 甘肃睿思科新材料有限公司 | Treatment method of nickel cobalt lithium manganate positive electrode material |
CN111118311A (en) * | 2019-12-28 | 2020-05-08 | 湖南金源新材料股份有限公司 | Manganese-lithium separation method in comprehensive recovery of ternary battery waste |
CN112442597A (en) * | 2020-10-21 | 2021-03-05 | 荆门市格林美新材料有限公司 | Method for comprehensively treating materials in nickel-cobalt-manganese ternary precursor washing wastewater |
EP4194572A4 (en) * | 2020-08-25 | 2024-01-24 | Hunan Brunp Recycling Technology Co., Ltd. | Method for recycling iron and aluminum in nickel-cobalt-manganese solution |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6835228B1 (en) * | 2003-11-14 | 2004-12-28 | Industrial Technology Research Institute | Process of recovering valuable metals from waste secondary batteries |
CN101006190A (en) * | 2004-06-28 | 2007-07-25 | 斯凯资源有限公司 | Method for nickel and cobalt recovery from laterite ores by reaction with concentrated acid and water leaching |
CN101871048A (en) * | 2010-06-25 | 2010-10-27 | 浙江华友钴业股份有限公司 | Method for recovering cobalt, nickel and manganese from waste lithium cells |
CN103014346A (en) * | 2012-12-03 | 2013-04-03 | 河池市津泰资源再生有限公司 | Process method for separating zinc, iron and cobalt and nickel ore concentrates from cobalt and nickel slag |
CN103361483A (en) * | 2013-07-26 | 2013-10-23 | 浙江钛合仪器有限公司 | Technology for removing cobalt by dynamic wave chlorine oxidation |
JP5636688B2 (en) * | 2010-02-23 | 2014-12-10 | 住友大阪セメント株式会社 | Method for producing electrode material and method for recovering lithium phosphate |
CN107151739A (en) * | 2017-07-07 | 2017-09-12 | 金川集团股份有限公司 | A kind of full leaching method of nitric acid of the high iron alloy powder of low nickel |
CN107653378A (en) * | 2017-08-25 | 2018-02-02 | 金川集团股份有限公司 | The recovery method of valuable metal in a kind of waste and old nickel cobalt manganese lithium ion battery |
CN108265178A (en) * | 2018-03-08 | 2018-07-10 | 蒋央芳 | A kind of processing method of cobalt metallurgy of nickel waste water slag |
-
2018
- 2018-09-13 CN CN201811066427.6A patent/CN109279665B/en active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6835228B1 (en) * | 2003-11-14 | 2004-12-28 | Industrial Technology Research Institute | Process of recovering valuable metals from waste secondary batteries |
CN101006190A (en) * | 2004-06-28 | 2007-07-25 | 斯凯资源有限公司 | Method for nickel and cobalt recovery from laterite ores by reaction with concentrated acid and water leaching |
JP5636688B2 (en) * | 2010-02-23 | 2014-12-10 | 住友大阪セメント株式会社 | Method for producing electrode material and method for recovering lithium phosphate |
CN101871048A (en) * | 2010-06-25 | 2010-10-27 | 浙江华友钴业股份有限公司 | Method for recovering cobalt, nickel and manganese from waste lithium cells |
CN103014346A (en) * | 2012-12-03 | 2013-04-03 | 河池市津泰资源再生有限公司 | Process method for separating zinc, iron and cobalt and nickel ore concentrates from cobalt and nickel slag |
CN103361483A (en) * | 2013-07-26 | 2013-10-23 | 浙江钛合仪器有限公司 | Technology for removing cobalt by dynamic wave chlorine oxidation |
CN107151739A (en) * | 2017-07-07 | 2017-09-12 | 金川集团股份有限公司 | A kind of full leaching method of nitric acid of the high iron alloy powder of low nickel |
CN107653378A (en) * | 2017-08-25 | 2018-02-02 | 金川集团股份有限公司 | The recovery method of valuable metal in a kind of waste and old nickel cobalt manganese lithium ion battery |
CN108265178A (en) * | 2018-03-08 | 2018-07-10 | 蒋央芳 | A kind of processing method of cobalt metallurgy of nickel waste water slag |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111039312A (en) * | 2019-12-26 | 2020-04-21 | 甘肃睿思科新材料有限公司 | Treatment method of nickel cobalt lithium manganate positive electrode material |
CN111118311A (en) * | 2019-12-28 | 2020-05-08 | 湖南金源新材料股份有限公司 | Manganese-lithium separation method in comprehensive recovery of ternary battery waste |
CN111118311B (en) * | 2019-12-28 | 2021-10-22 | 湖南金源新材料股份有限公司 | Manganese-lithium separation method in comprehensive recovery of ternary battery waste |
EP4194572A4 (en) * | 2020-08-25 | 2024-01-24 | Hunan Brunp Recycling Technology Co., Ltd. | Method for recycling iron and aluminum in nickel-cobalt-manganese solution |
CN112442597A (en) * | 2020-10-21 | 2021-03-05 | 荆门市格林美新材料有限公司 | Method for comprehensively treating materials in nickel-cobalt-manganese ternary precursor washing wastewater |
Also Published As
Publication number | Publication date |
---|---|
CN109279665B (en) | 2020-09-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111206148B (en) | Method for recycling and preparing ternary cathode material by using waste ternary lithium battery | |
CN109279665A (en) | A kind of processing method of nickle cobalt lithium manganate ternary waste material | |
CN107267759B (en) | Comprehensive recovery method of lithium ion battery anode material | |
CA3066431A1 (en) | Process for the recovery of cobalt, lithium, and other metals from spent lithium-based batteries and other feeds | |
WO2012011205A1 (en) | Method for separating nikel and cobalt from active materials contained in spent nickel-hydrogen battery | |
US20130247721A1 (en) | Method for separating positive-pole active substance and method for recovering valuable metals from lithium ion battery | |
CN107437626B (en) | Method for preparing carbon-coated manganese phosphate from waste zinc-manganese battery | |
CN102088124A (en) | High-purity polymetallic-element solid mixed salt and preparation method and application thereof | |
JP2022507019A (en) | Process for extracting metal from lithium-ion batteries | |
KR20170061206A (en) | Collection method of precursor material using disposed lithum-ion battery | |
CN109574048B (en) | Treatment method of waste lithium iron phosphate cathode material | |
US20240055684A1 (en) | Preparation method of heterosite iron phosphate and application thereof | |
TW202221145A (en) | Method for separating cobalt and nickel | |
CN111498878A (en) | Resource utilization method of waste lithium hexafluorophosphate | |
CN108539308A (en) | A kind of recovery method of waste lithium manganese oxide positive electrode | |
CN113957264A (en) | Method for preparing nickel sulfate from low grade nickel matte | |
CN114249313A (en) | Method for recovering battery-grade iron phosphate from waste lithium iron phosphate powder | |
JP2023516191A (en) | Precursor material for positive electrode active material, method for producing positive electrode active material for lithium secondary battery, and positive electrode active material for lithium secondary battery produced by the method | |
CN115583640A (en) | Method for recycling waste lithium iron phosphate black powder with multiple impurities | |
KR102324910B1 (en) | Manufacturing method of precursor raw material from disposed cathode material of lithium secondary battery | |
KR101839460B1 (en) | High-purity lithium carbonate recovery method from solution Containing Lithium | |
US20230104094A1 (en) | A method for processing lithium iron phosphate batteries | |
KR20150075200A (en) | Method of preparing positive active material precursor | |
KR101372622B1 (en) | Method for preparing nmc(ni-co-mn) hydroxide from ni ore | |
CN112342383A (en) | Method for separating and recovering nickel, cobalt, manganese and lithium in ternary waste |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220616 Address after: Building 148000, South Building, Guangdong Province, Guangdong science and Technology Park Patentee after: Yuanbang JIAYE (Shenzhen) Industrial Co.,Ltd. Address before: No.2-4, shuikeng lane, Dongmen, Fuying street, Xianju County, Taizhou City, Zhejiang Province, 317399 Patentee before: Zheng Yiyi |
|
TR01 | Transfer of patent right |
Effective date of registration: 20220921 Address after: No. 2708-5, 27th Floor, International Trade Center, Building 1, Furao Center, No. 200, Changjiang Road, Yantai District, China (Shandong) Pilot Free Trade Zone, Yantai City, Shandong Province, 264001 Patentee after: China Lithium New Energy Technology (Yantai) Co.,Ltd. Address before: Building 148000, South Building, Guangdong Province, Guangdong science and Technology Park Patentee before: Yuanbang JIAYE (Shenzhen) Industrial Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230105 Address after: Room 01, 21/F, Xianglong Center, No. 7, Yanda Road, Laishan District, Yantai City, Shandong Province, 264000 Patentee after: China Combustion Energy Environmental Energy (Shandong) Co.,Ltd. Address before: No. 2708-5, 27th Floor, International Trade Center, Building 1, Furao Center, No. 200, Changjiang Road, Yantai District, China (Shandong) Pilot Free Trade Zone, Yantai City, Shandong Province, 264001 Patentee before: China Lithium New Energy Technology (Yantai) Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A Treatment Method for Nickel Cobalt Lithium Manganate Ternary Waste Effective date of registration: 20230331 Granted publication date: 20200925 Pledgee: Yantai Rural Commercial Bank Co.,Ltd. Zhifu District Branch Pledgor: China Combustion Energy Environmental Energy (Shandong) Co.,Ltd. Registration number: Y2023980037052 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right |