CN109265038A - A kind of modification regeneration coarse aggregate and its method for preparing regeneration concrete - Google Patents

A kind of modification regeneration coarse aggregate and its method for preparing regeneration concrete Download PDF

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Publication number
CN109265038A
CN109265038A CN201811354413.4A CN201811354413A CN109265038A CN 109265038 A CN109265038 A CN 109265038A CN 201811354413 A CN201811354413 A CN 201811354413A CN 109265038 A CN109265038 A CN 109265038A
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China
Prior art keywords
coarse aggregate
regeneration
partial size
aggregate
concrete
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Pending
Application number
CN201811354413.4A
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Chinese (zh)
Inventor
丁丽芳
姚志玉
张萌
冯冀平
张军会
姜山
张思雨
杨彩虹
孙志彬
郭万峰
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Hebei Construction Co Ltd
Hebei Construction Group Corp Ltd
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Hebei Construction Co Ltd
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Priority to CN201811354413.4A priority Critical patent/CN109265038A/en
Publication of CN109265038A publication Critical patent/CN109265038A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of modification regeneration coarse aggregates, are obtained by the regenerated coarse aggregate of grade 5-10mm and 10-20mm by being uniformly mixed again with the ratio of 35%-45% ︰ 55%-65% after the immersion treatment in the waste mud liquid that solid content is 1%-9%.By the method that it prepares regeneration concrete: the modification regeneration coarse aggregate that volume ratio is 5%-25% being substituted natural coarse aggregate in equal volume, then mixes coarse aggregate, 30.56~32.45 natural sands, 9.80~10.20 cement, 2.65~2.75 flyash, 3.92~4.08 ground granulated blast furnace slags, 0.29~0.31 water-reducing agent and 7.64~7.96 drinking water for 45.79~48.61 and is stirred and is made.Modification regeneration coarse aggregate surface roughness of the present invention is low, porosity is low, water absorption rate is low, and crush index is high, and the regeneration concrete slump of production is low, and elasticity modulus is high, and contract with dry rate and creep are low.

Description

A kind of modification regeneration coarse aggregate and its method for preparing regeneration concrete
Technical field
The invention belongs to the field of building materials coagulation great soil group, it is related to a kind of modification regeneration coarse aggregate and its manufactured is suitable for The regeneration concrete that concrete construction of the strength grade less than or equal to C40 pours.
Background technique
With rapid development of economy, in many big cities in China, the waste that building industry generates has been changed to public hazards.This A little wastes not only cause serious destruction to environment, but also the space of existence is fought for the mankind, and seriously affect country can Sustainable development.Therefore, exploitation reduces, recycles and utilize the new technology of waste material of buildings extremely urgent.
Waste material of buildings occurs mainly in the removal of old building and the building course of new building, therefore, reduces building Object must just remove and build in engineering, using advanced management technology and removal building technology.It is well known that waste material of buildings Generally it is made of broken concrete, clay brick and ceramic tile, sand and dust, sawdust, plastics and waste paper, old metal etc..Concrete is broken Block is usually the maximum component part of waste material of buildings, can be used in substitution concrete by the broken concrete of crushing and screening Natural aggregate or be used to do the basis of road.This type salvage material is just called recycled aggregates.Circular regeneration Aggregate has been applied successfully in the building industry of some European and American developed countries, but is mainly used in non-structural concrete and road On the basis of road, mainly due to recycled aggregate rough surface, porosity height, water absorption rate are high, crush index is low for this.Therefore, when again When raw aggregate is used to manufacture concrete, the slump of concrete can be brought to be difficult to control, intensity is low, elasticity modulus decline, drying shrinkage Rate and creep be high and the weakness such as durability difference, so as to cause recycled aggregate in structural concrete using very limited.Separately Outer ready-mixed concrete enterprise is every year because rinsing mixer truck, a large amount of waste sludge slurries of mixing plant generation, these waste sludge slurries row Generation large amount of sewage is run out, pollutes environment, and keep the sewage treatment in later period more difficult.
Summary of the invention
The object of the invention is to solve the above-mentioned problems in the prior art, provide a kind of modification regeneration coarse aggregate and It prepares the method for regeneration concrete;Modification regeneration coarse aggregate surface roughness is low, porosity is low, water absorption rate is low for this, and crushing refers to The regeneration concrete slump of absolute altitude, production is low, and intensity is high, and elasticity modulus is high, and contract with dry rate and creep are low, and durability becomes strong, Quality is stablized, and mixture is functional, and application range is more and more wider, can be suitably used for the concrete that strength grade is less than or equal to C40 Construction casting;Resource has been saved in application of the invention, is effectively reduced the generation of building waste, is reduced ready-mixed concrete enterprise Problem of environmental pollution.
First purpose to realize the present invention, the technical solution of the invention is as follows: a kind of modification regeneration coarse aggregate, It is made of following methods: the discarded concrete after hardening being broken into two kinds of grades of 5-10mm and 10-20mm again with sand making machine Raw coarse aggregate;Two kinds of regenerated coarse aggregates are soaked in respectively and rinse mixer truck, the useless mud that the solid content that mixing plant generates is 1%-9% In slurries, according to requirement circulation immersion 24 hours or more of 5 minutes of minimum stirring within an hour, with screening of being tiled, prevent The aggregate for being only wrapped with waste mud liquid is mutually bonded to the cement block of large volume, to dry tack free or first goes water removal again for screenings is cool It is cool to dry tack free;By treated partial size be 5-10mm modification regeneration coarse aggregate and partial size be 10-20mm modification regeneration Coarse aggregate is uniformly mixed with the ratio of 35%-45% ︰ 55%-65%, is mixed into the modification regeneration coarse aggregate that partial size is 5-20mm.
Second purpose to realize the present invention, the technical solution of the invention is as follows: a kind of thick with above-mentioned modification regeneration The method that aggregate prepares regeneration concrete, comprising the following steps:
(1) natural coarse aggregate is substituted in equal volume: the modification regeneration coarse aggregate is substituted in equal volume with the volume ratio of 5%-25% It is spare to be prepared into mixing coarse aggregate for natural coarse aggregate;The particle size content of natural coarse aggregate: partial size accounts for 0-5%, partial size for 0-5mm's 10-20% is accounted for for 5-10mm, partial size is that 10-20mm accounts for 40-80%, and partial size is that 20mm or more accounts for 0-10%;
(2) regeneration concrete is prepared, by weight calculating, is made of following material, 45.79~48.61 mixing is thick Aggregate, 30.56~32.45 natural sand, 9.80~10.20 cement, 2.65~2.75 flyash, 3.92~4.08 height Furnace slag powders, 0.29~0.31 water-reducing agent and 7.64~7.96 drinking water;The water-reducing agent of the amount is dissolved in the amount It is diluted in drinking water;Mixing coarse aggregate, natural sand, cement, flyash and the ground granulated blast furnace slag of the amount are poured into stirring It being stirred in machine, after mixing evenly, the diminishing agent solution diluted is added and continues to stir, mixing time is not less than 30s, It stirs evenly to get regeneration concrete.
It is further preferred that the water-reducing agent in the step (2) is poly carboxylic acid series water reducer.
The present invention impregnates the regenerated coarse aggregate of two kinds of grades with waste mud liquid respectively, is because regenerated coarse aggregate exists Because being generated a large amount of micro-cracks by external force in preparation process, micro-crack can be filled and be bonded to waste mud liquid, and it is thick to improve regeneration The disadvantages such as aggregate surface is coarse, corner angle are more, porosity is high, water absorption rate is big, crush index is low, partial size are the thick bone of regeneration of 5-10mm The hole of the regenerated coarse aggregate of material filling 10-20mm forms good gradation, and formation surface roughness reduces, corner angle are rounded cunning, Porosity reduces, water absorption rate reduces, the modification regeneration coarse aggregate that crush index is got higher.It is replaced in equal volume with the modification regeneration coarse aggregate For natural coarse aggregate, natural resources have on the one hand been saved, have reduced the soil occupied to disposed waste processing, it on the other hand can be with Guarantee the constancy of volume of regeneration concrete;Natural sand can fill the hole of coarse aggregate as fine aggregate;Cement is as inorganic glue Gel material, before concrete hardening, cement and water form cement slurry and play lubricating action, assign concrete mix certain flowing Property, cementation is played convenient for construction, after cement slurry hardening, sandstone aggregate is cementing integral, intensity is generated, hard water is become Mudstone;Flyash and ground granulated blast furnace slag substitute cement as admixture, can with save the cost, improve later strength, be effectively relieved The heat of hydration, and can reach waste utilization, protect the purpose of environment;Using poly carboxylic acid series water reducer as additive, can reduce Coagulation local prescription water consumption improves concrete strength, and can improve concrete mixing physical property to reduce water-binder ratio Energy.Cement, flyash, miberal powder and water form slurry, and natural sand formation cement mortar is filled and wrapped up before hydration reaction occurs, Mortar fills and wraps up coarse aggregate;Over time, hydration reaction gradually carries out, and cement slurry starts to generate intensity, by day Right sand is tightly bonded together with coarse aggregate.The regeneration concrete slump prepared with above-mentioned modification regeneration coarse aggregate is low, intensity Height, elasticity modulus is high, and contract with dry rate and creep are low, and durability becomes strong, and quality is stablized, and mixture is functional, and application range is more next It is wider, it can be suitably used for concrete construction of the strength grade less than or equal to C40 and pour.Resource has been saved in application of the invention, effectively The generation for reducing building waste reduces ready-mixed concrete corporate environment pollution problem, realizes that Concrete Industry green can be held Supervention exhibition.
Specific embodiment
The present invention will be further described combined with specific embodiments below.
Embodiment 1, the modification regeneration coarse aggregate of the present embodiment, is made of following methods: will be after hardening with sand making machine Discarded concrete is broken into the regenerated coarse aggregate of two kinds of grades of 5-10mm and 10-20mm.Two kinds of regenerated coarse aggregates are impregnated respectively In the waste mud liquid that the solid content for rinsing mixer truck, mixing plant generates is 5%, according to minimum stirring within an hour 5 minutes It is required that circulation immersion 24 hours or more, with screening of being tiled, the aggregate for being wrapped with waste mud liquid is prevented mutually to be bonded to substantially Long-pending cement block is cool to dry tack free by screenings.The modification regeneration coarse aggregate and partial size for being 5-10mm by treated partial size For 10-20mm modification regeneration coarse aggregate with the ratio of 40% ︰ 60% be uniformly mixed, be mixed into partial size be 5-20mm modification again Raw coarse aggregate.The method for preparing regeneration concrete with the modification regeneration coarse aggregate, comprising the following steps: (1) substitute day in equal volume Right coarse aggregate: substituting natural coarse aggregate for the modification regeneration coarse aggregate with 10% volume ratio in equal volume, and it is thick to be prepared into mixing Aggregate is spare.The particle size content of natural coarse aggregate: partial size is the arbitrary value of 0-5mm accounted in 0-5%, and partial size is that 5-10mm accounts for 10- Arbitrary value in 20%, partial size are that 10-20mm accounts for the arbitrary value in 40-80%, and partial size accounts for any in 0-10% for 20mm or more Value.(2) regeneration concrete is prepared, by weight calculating, is made of following material, the 46.25 mixing coarse aggregate, 30.87 natural sand, 9.90 cement, 2.67 flyash, 3.96 ground granulated blast furnace slag, 0.297 water-reducing agent and 7.72 Drinking water.The water-reducing agent of the amount is dissolved in the drinking water of the amount and being diluted;By the mixing coarse aggregate of the amount, naturally Sand, cement, flyash and ground granulated blast furnace slag, which pour into blender, to be stirred, and after mixing evenly, the water-reducing agent diluted is added Solution continues to stir, and mixing time is not less than 30s, stirs evenly to get regeneration concrete.Preferably, the step (2) In water-reducing agent be poly carboxylic acid series water reducer.
1 5-10mm and 10-20mm regenerated coarse aggregate of table impregnates forward and backward performance comparison, observes regenerated coarse aggregate surface, Before surface roughness after immersion is significantly better than immersion.As can be seen from the table: stacked area and apparent density all become after immersion Greatly, porosity increases, water absorption rate reduces, and crush values are got higher.
Embodiment 2, other features of the modification regeneration coarse aggregate of the present embodiment are with embodiment 1, and only waste mud liquid generates Solid content be 9%, the modification regeneration coarse aggregate that treated partial size is 5-10mm and the modification regeneration that partial size is 10-20mm are thick Aggregate mixed proportion is 45% ︰ 55%.The present embodiment prepares in the method for regeneration concrete that other features are with embodiment 1, only The volume ratio that modification regeneration coarse aggregate substitutes natural coarse aggregate in equal volume is 25;The mixing coarse aggregate accounts for 45.79, natural sand and accounts for 32.45, cement, which accounts for 10.00, flyash and accounts for 2.75, ground granulated blast furnace slag and account for 4.08, water-reducing agent and account for 0.31, drinking water, accounts for 7.96.
Embodiment 3, other features of the modification regeneration coarse aggregate of the present embodiment are with embodiment 1, and only waste mud liquid generates Solid content be 1%, the modification regeneration coarse aggregate that treated partial size is 5-10mm and the modification regeneration that partial size is 10-20mm are thick Aggregate mixed proportion is 35% ︰ 65%.The present embodiment prepares in the method for regeneration concrete that other features are with embodiment 1, only The volume ratio that modification regeneration coarse aggregate substitutes natural coarse aggregate in equal volume is 5;The mixing coarse aggregate accounts for 48.61, natural sand and accounts for 30.56, cement, which accounts for 9.8, flyash and accounts for 2.65, ground granulated blast furnace slag and account for 3.92, water-reducing agent and account for 0.29, drinking water, accounts for 7.64.
Embodiment 4, other features of the modification regeneration coarse aggregate of the present embodiment are with embodiment 1, and only waste mud liquid generates Solid content be 3%, the modification regeneration coarse aggregate that treated partial size is 5-10mm and the modification regeneration that partial size is 10-20mm are thick Aggregate mixed proportion is 43% ︰ 57%.The present embodiment prepares in the method for regeneration concrete that other features are with embodiment 1, only The volume ratio that modification regeneration coarse aggregate substitutes natural coarse aggregate in equal volume is 15;The mixing coarse aggregate accounts for 47.1, natural sand and accounts for 31.5, cement, which accounts for 10.2, flyash and accounts for 2.71, ground granulated blast furnace slag and account for 3.98, water-reducing agent and account for 0.298, drinking water, accounts for 7.80.
Embodiment 5, other features of the modification regeneration coarse aggregate of the present embodiment are with embodiment 1, and only waste mud liquid generates Solid content be 7%, the modification regeneration coarse aggregate that treated partial size is 5-10mm and the modification regeneration that partial size is 10-20mm are thick Aggregate mixed proportion is 38% ︰ 62%.The present embodiment prepares in the method for regeneration concrete that other features are with embodiment 1, only The volume ratio that modification regeneration coarse aggregate substitutes natural coarse aggregate in equal volume is 20;The mixing coarse aggregate accounts for 47.9, natural sand and accounts for 31.9, cement, which accounts for 9.5, flyash and accounts for 2.74, ground granulated blast furnace slag and account for 4.02, water-reducing agent and account for 0.30, drinking water, accounts for 7.90.
Above-described embodiment be only it is preferably good and illustrative, those skilled in the art can also retouching according to this patent It states, selection uses other equivalent technologies, these are all covered by the protection scope of this patent.

Claims (3)

1. a kind of modification regeneration coarse aggregate, it is characterised in that: it is made of following methods: will be discarded mixed after hardening with sand making machine Solidifying soil is broken into the regenerated coarse aggregate of two kinds of grades of 5-10mm and 10-20mm;Two kinds of regenerated coarse aggregates are soaked in flushing respectively The solid content that mixer truck, mixing plant generate is in the waste mud liquid of 1%-9%, according to the requirement of minimum stirring 5 minutes within an hour Circulation immersion 24 hours or more, with screening of being tiled, the aggregate for being wrapped with waste mud liquid is prevented mutually to be bonded to large volume Cement block to dry tack free or first goes water removal cool to dry tack free again for screenings is cool;By treated, partial size is 5-10mm's Modification regeneration coarse aggregate and partial size are that the modification regeneration coarse aggregate of 10-20mm is uniformly mixed with the ratio of 35%-45% ︰ 55%-65%, It is mixed into the modification regeneration coarse aggregate that partial size is 5-20mm.
2. a kind of method for preparing regeneration concrete with modification regeneration coarse aggregate described in claim 1, it is characterised in that: including Following steps:
(1) natural coarse aggregate is substituted in equal volume: the modification regeneration coarse aggregate is substituted in equal volume with the volume ratio of 5%-25% It is spare to be prepared into mixing coarse aggregate for natural coarse aggregate;The particle size content of natural coarse aggregate: partial size accounts for 0-5%, partial size for 0-5mm's 10-20% is accounted for for 5-10mm, partial size is that 10-20mm accounts for 40-80%, and partial size is that 20mm or more accounts for 0-10%;
(2) regeneration concrete is prepared, by weight calculating, is made of following material, 45.79~48.61 mixing is thick Aggregate, 30.56~32.45 natural sand, 9.80~10.20 cement, 2.65~2.75 flyash, 3.92~4.08 height Furnace slag powders, 0.29~0.31 water-reducing agent and 7.64~7.96 drinking water;The water-reducing agent of the amount is dissolved in the amount It is diluted in drinking water;Mixing coarse aggregate, natural sand, cement, flyash and the ground granulated blast furnace slag of the amount are poured into stirring It being stirred in machine, after mixing evenly, the diminishing agent solution diluted is added and continues to stir, mixing time is not less than 30s, It stirs evenly to get regeneration concrete.
3. the method according to claim 2 for preparing regeneration concrete, it is characterised in that: the diminishing in the step (2) Agent is poly carboxylic acid series water reducer.
CN201811354413.4A 2018-11-14 2018-11-14 A kind of modification regeneration coarse aggregate and its method for preparing regeneration concrete Pending CN109265038A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109879619A (en) * 2019-02-23 2019-06-14 陕西秦汉恒盛新型建材科技股份有限公司 The intensifying method of recycled aggregate pervious concrete and preparation method thereof and its used recycled aggregate
CN110922080A (en) * 2019-11-27 2020-03-27 长安大学 Modified recycled coarse aggregate, permeable water-storing concrete and preparation method thereof
CN110981244A (en) * 2019-12-30 2020-04-10 河北红墙新材料有限公司 Concrete residual slurry treatment process
CN111875309A (en) * 2020-06-22 2020-11-03 浙江二十冶建设有限公司 Recycled concrete and preparation method and application thereof
CN112239332A (en) * 2020-09-29 2021-01-19 江苏晨马建筑科技有限公司 Preparation process of recycled concrete aggregate

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CN101767960A (en) * 2008-12-29 2010-07-07 沈阳建筑大学 Recycled concrete coarse aggregate modified processing method
CN104829178A (en) * 2015-04-21 2015-08-12 江苏德丰建设集团有限公司 C30 grade steel-doped slag recycled aggregate self compacting concrete and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109879619A (en) * 2019-02-23 2019-06-14 陕西秦汉恒盛新型建材科技股份有限公司 The intensifying method of recycled aggregate pervious concrete and preparation method thereof and its used recycled aggregate
CN110922080A (en) * 2019-11-27 2020-03-27 长安大学 Modified recycled coarse aggregate, permeable water-storing concrete and preparation method thereof
CN110981244A (en) * 2019-12-30 2020-04-10 河北红墙新材料有限公司 Concrete residual slurry treatment process
CN111875309A (en) * 2020-06-22 2020-11-03 浙江二十冶建设有限公司 Recycled concrete and preparation method and application thereof
CN112239332A (en) * 2020-09-29 2021-01-19 江苏晨马建筑科技有限公司 Preparation process of recycled concrete aggregate

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