CN109265017A - A kind of intensifying method of glassware - Google Patents
A kind of intensifying method of glassware Download PDFInfo
- Publication number
- CN109265017A CN109265017A CN201811401492.XA CN201811401492A CN109265017A CN 109265017 A CN109265017 A CN 109265017A CN 201811401492 A CN201811401492 A CN 201811401492A CN 109265017 A CN109265017 A CN 109265017A
- Authority
- CN
- China
- Prior art keywords
- glassware
- soak
- intensifying method
- electrolyte
- preheating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/0095—Solution impregnating; Solution doping; Molecular stuffing, e.g. of porous glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/007—Other surface treatment of glass not in the form of fibres or filaments by thermal treatment
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/0075—Cleaning of glass
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Electrolytic Production Of Metals (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The invention discloses a kind of intensifying method of glassware, includes the following steps: for glassware to be placed in the preheating chamber of temperature constant state, be preheated；Vinyltriethoxysilane and ethylene glycol ether are chosen, and vinyltriethoxysilane is put into ethylene glycol ether and is dissolved, and obtains vinyltriethoxysilane solution, as soak；The mixed liquor and potassium glutamate collectively constituted to Klorvess Liquid, titanium tetrachloride and alcohols solvent is mixed, and ultimately forms electrolyte；Glassware after preheating is immersed in soak and is impregnated；Glassware after immersion is taken out, and puts into and is electrolysed into electrolyte, takes out glassware from electrolyte after electrolysis, uses clear water cleaning, naturally dry.The step of present invention can make glassware be not easy that fracture phenomena occurs because of the collision of exterior object during use, entire intensifying method, process are simple, are conducive to be executed and be operated.
Description
Technical field
The present invention relates to glassware technical field more particularly to a kind of intensifying methods of glassware.
Background technique
Glass is fused together and is formed by silica and other chemical substances.The earliest glass manufacturer in the world is
Ancient Egyptian, and with the development of science and technology, the progress of social productive forces, in today's society, the glass system made of glass
Product are widely used in our life, but the resistance to deflection and impact resistance of traditional glassware are poor, because
This ruptures glassware easily because of the collision of exterior object during use, and then leads to making for glassware
It is lower with the service life, and be unfavorable for glassware using safe.For this purpose, we have proposed a kind of intensifying methods of glassware.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of reinforcing of the glassware proposed
Method.
To achieve the goals above, present invention employs following technical solutions:
A kind of intensifying method of glassware, includes the following steps:
(1) preheating of glassware: glassware is placed in the preheating chamber of temperature constant state, carries out continuing 10-15 points
The preheating of clock；
(2) preparation of soak: choosing vinyltriethoxysilane and ethylene glycol ether, and by three ethoxy of vinyl
It is dissolved in base silane investment ethylene glycol ether, and obtains vinyltriethoxysilane solution, as soak；
(3) preparation of electrolyte: add its quality 0.2-0.4%'s into the Klorvess Liquid that mass fraction is 7-9%
Potassium glutamate, then add the titanium tetrachloride of Klorvess Liquid quality 8-12% and mixed liquor that alcohols solvent is collectively constituted, it is right
The mixed liquor and potassium glutamate that Klorvess Liquid, titanium tetrachloride and alcohols solvent are collectively constituted are mixed, and final
Form electrolyte；
(4) it macerates processing: the glassware after preheating in step 1 being immersed in soak and is impregnated, and was impregnated
Cheng Zhong, soak completely flood glassware, and entire soaking process continues 40-50 minutes；
(5) electrolysis is handled: the glassware after impregnating in step (4) is taken out, and puts into and is electrolysed into electrolyte,
Electrolytic process be specially continue three times, and each duration be 60-120 second, third time electrolysis after, by glassware from
It is taken out in electrolyte, uses clear water cleaning, naturally dry.
Further, in step (1), preheating indoor temperature is specially 150-180 degrees Celsius.
Further, in step (2), the prepared mass fraction for obtaining vinyltriethoxysilane solution is 6-
10%.
Further, in step (3), it is specially 20-30 degrees Celsius that locating temperature, which is mixed, and be mixed
Time continues 10-16 minutes.
Further, in step (3), in the mixed liquor that titanium tetrachloride and alcohols solvent are collectively constituted, titanium tetrachloride
Mass percentage be 50%-70%, the content of organic solvent is 50%-30%.
Further, in step (4), when soak is when impregnating glassware, the entire environment that impregnates is in
The vacuum degree of 0.030-0.036MPa.
Further, the glassware is by that need to carry out glassware clear after taking out in soak and before electrolyte
It washes, dry, and the cleaning of glassware specially uses clear water, and during drying, specially at 60-80 degrees Celsius
Hot wind is dried under brushing.
Further, in step (5), the interval time between electrolytic process is 5-9 minutes three times.
A kind of intensifying method of glassware proposed by the present invention, beneficial effect are: by the reinforcing side in this programme
Method is capable of the resistance to deflection and impact resistance of reinforcing glass product, so that glass after carrying out intensive treatment to glassware
Glass product is not easy that fracture phenomena occurs because of the collision of exterior object during use, that is, is conducive to improve glassware
Service life, and can further ensure glassware when in use using safe, the step of entire intensifying method, process
Simply, be conducive to be executed and operated, great application value.
Specific embodiment
Below in conjunction with embodiment, further description of the specific embodiments of the present invention, and following embodiment is only used for more
Add and clearly demonstrate technical solution of the present invention, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of intensifying method of glassware, includes the following steps:
(1) preheating of glassware: glassware is placed in the preheating chamber of temperature constant state, is carried out lasting 10 minutes
Preheating；
(2) preparation of soak: choosing vinyltriethoxysilane and ethylene glycol ether, and by three ethoxy of vinyl
It is dissolved in base silane investment ethylene glycol ether, and obtains vinyltriethoxysilane solution, as soak；
(3) glutamic acid of its quality 0.2% preparation of electrolyte: is added in the Klorvess Liquid for being 7% to mass fraction
Potassium, then add the titanium tetrachloride of Klorvess Liquid quality 8% and mixed liquor that alcohols solvent is collectively constituted, it is molten to potassium chloride
The mixed liquor and potassium glutamate that liquid, titanium tetrachloride and alcohols solvent are collectively constituted are mixed, and ultimately form electrolysis
Liquid；
(4) it macerates processing: the glassware after preheating in step 1 being immersed in soak and is impregnated, and was impregnated
Cheng Zhong, soak completely flood glassware, and entire soaking process continues 40 minutes；
(5) electrolysis is handled: the glassware after impregnating in step (4) is taken out, and puts into and is electrolysed into electrolyte,
Electrolytic process is specially to continue three times, and each duration is 60 seconds, after third time is electrolysed, by glassware from electrolysis
It is taken out in liquid, uses clear water cleaning, naturally dry.
In step (1), preheating indoor temperature is specially 150 degrees Celsius.
In step (2), the prepared mass fraction for obtaining vinyltriethoxysilane solution is 6%.
In step (3), it is specially 20 degrees Celsius that locating temperature, which is mixed, and the time being mixed continues 10 points
Clock.
In step (3), in the mixed liquor that titanium tetrachloride and alcohols solvent are collectively constituted, the quality percentage of titanium tetrachloride
Content is 50%, and the content of organic solvent is 50%.
In step (4), when soak is when impregnating glassware, entire immersion environment is in the vacuum of 0.030MPa
Degree.
The glassware by soak take out after and before electrolyte, glassware need to be cleaned, be dried, and
The cleaning of glassware is specially to use clear water, and during drying, specially in the case where 60 degrees Celsius of hot wind is brushed into
Row drying.
In step (5), the interval time between electrolytic process is 5 minutes three times.
Embodiment 2
A kind of intensifying method of glassware, includes the following steps:
(1) preheating of glassware: glassware is placed in the preheating chamber of temperature constant state, is carried out lasting 13 minutes
Preheating；
(2) preparation of soak: choosing vinyltriethoxysilane and ethylene glycol ether, and by three ethoxy of vinyl
It is dissolved in base silane investment ethylene glycol ether, and obtains vinyltriethoxysilane solution, as soak；
(3) glutamic acid of its quality 0.3% preparation of electrolyte: is added in the Klorvess Liquid for being 8% to mass fraction
Potassium, then add the titanium tetrachloride of Klorvess Liquid quality 10% and mixed liquor that alcohols solvent is collectively constituted, it is molten to potassium chloride
The mixed liquor and potassium glutamate that liquid, titanium tetrachloride and alcohols solvent are collectively constituted are mixed, and ultimately form electrolysis
Liquid；
(4) it macerates processing: the glassware after preheating in step 1 being immersed in soak and is impregnated, and was impregnated
Cheng Zhong, soak completely flood glassware, and entire soaking process continues 45 minutes；
(5) electrolysis is handled: the glassware after impregnating in step (4) is taken out, and puts into and is electrolysed into electrolyte,
Electrolytic process is specially to continue three times, and each duration is 90 seconds, after third time is electrolysed, by glassware from electrolysis
It is taken out in liquid, uses clear water cleaning, naturally dry.
In step (1), preheating indoor temperature is specially 165 degrees Celsius.
In step (2), the prepared mass fraction for obtaining vinyltriethoxysilane solution is 8%.
In step (3), it is specially 25 degrees Celsius that locating temperature, which is mixed, and the time being mixed continues 13 points
Clock.
In step (3), in the mixed liquor that titanium tetrachloride and alcohols solvent are collectively constituted, the quality percentage of titanium tetrachloride
Content is 60%, and the content of organic solvent is 40%.
In step (4), when soak is when impregnating glassware, entire immersion environment is in the vacuum of 0.033MPa
Degree.
The glassware by soak take out after and before electrolyte, glassware need to be cleaned, be dried, and
The cleaning of glassware is specially to use clear water, and during drying, specially in the case where 70 degrees Celsius of hot wind is brushed into
Row drying.
In step (5), the interval time between electrolytic process is 7 minutes three times.
Embodiment 3
A kind of intensifying method of glassware, includes the following steps:
(1) preheating of glassware: glassware is placed in the preheating chamber of temperature constant state, is carried out lasting 15 minutes
Preheating；
(2) preparation of soak: choosing vinyltriethoxysilane and ethylene glycol ether, and by three ethoxy of vinyl
It is dissolved in base silane investment ethylene glycol ether, and obtains vinyltriethoxysilane solution, as soak；
(3) glutamic acid of its quality 0.4% preparation of electrolyte: is added in the Klorvess Liquid for being 9% to mass fraction
Potassium, then add the titanium tetrachloride of Klorvess Liquid quality 12% and mixed liquor that alcohols solvent is collectively constituted, it is molten to potassium chloride
The mixed liquor and potassium glutamate that liquid, titanium tetrachloride and alcohols solvent are collectively constituted are mixed, and ultimately form electrolysis
Liquid；
(4) it macerates processing: the glassware after preheating in step 1 being immersed in soak and is impregnated, and was impregnated
Cheng Zhong, soak completely flood glassware, and entire soaking process continues 50 minutes；
(5) electrolysis is handled: the glassware after impregnating in step (4) is taken out, and puts into and is electrolysed into electrolyte,
Electrolytic process is specially to continue three times, and each duration is 120 seconds, after third time is electrolysed, by glassware from electricity
It is taken out in solution liquid, uses clear water cleaning, naturally dry.
In step (1), preheating indoor temperature is specially 180 degrees Celsius.
In step (2), the prepared mass fraction for obtaining vinyltriethoxysilane solution is 10%.
In step (3), it is specially 30 degrees Celsius that locating temperature, which is mixed, and the time being mixed continues 16 points
Clock.
In step (3), in the mixed liquor that titanium tetrachloride and alcohols solvent are collectively constituted, the quality percentage of titanium tetrachloride
Content is 70%, and the content of organic solvent is 30%.
In step (4), when soak is when impregnating glassware, entire immersion environment is in the vacuum of 0.036MPa
Degree.
The glassware by soak take out after and before electrolyte, glassware need to be cleaned, be dried, and
The cleaning of glassware is specially to use clear water, and during drying, specially in the case where 80 degrees Celsius of hot wind is brushed into
Row drying.
In step (5), the interval time between electrolytic process is 9 minutes three times.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of intensifying method of glassware, which comprises the steps of:
(1) preheating of glassware: glassware is placed in the preheating chamber of temperature constant state, carries out continuing 10-15 minutes
Preheating；
(2) preparation of soak: choosing vinyltriethoxysilane and ethylene glycol ether, and by vinyl triethoxyl silicon
It is dissolved in alkane investment ethylene glycol ether, and obtains vinyltriethoxysilane solution, as soak；
(3) the paddy ammonia of its quality 0.2-0.4% the preparation of electrolyte: is added into the Klorvess Liquid that mass fraction is 7-9%
Sour potassium, then add the titanium tetrachloride of Klorvess Liquid quality 8-12% and mixed liquor that alcohols solvent is collectively constituted, to chlorination
The mixed liquor and potassium glutamate that potassium solution, titanium tetrachloride and alcohols solvent are collectively constituted are mixed, and are ultimately formed
Electrolyte；
(4) it macerates processing: the glassware after preheating in step 1 being immersed in soak and is impregnated, and in soaking process,
Soak completely floods glassware, and entire soaking process continues 40-50 minutes；
(5) electrolysis is handled: the glassware after impregnating in step (4) being taken out, and puts into and is electrolysed into electrolyte, is electrolysed
Process is specially to continue three times, and each duration is 60-120 second, after third time electrolysis, by glassware from electrolysis
It is taken out in liquid, uses clear water cleaning, naturally dry.
2. a kind of intensifying method of glassware according to claim 1, which is characterized in that in step (1), preheating chamber
Interior temperature is specially 150-180 degrees Celsius.
3. a kind of intensifying method of glassware according to claim 1, which is characterized in that in step (2), prepared
Vinyltriethoxysilane solution mass fraction be 6-10%.
4. a kind of intensifying method of glassware according to claim 1, which is characterized in that in step (3), mixing is stirred
Mixing locating temperature is specially 20-30 degrees Celsius, and the time being mixed continues 10-16 minutes.
5. a kind of intensifying method of glassware according to claim 1, which is characterized in that in step (3), four chlorinations
In the mixed liquor that titanium and alcohols solvent are collectively constituted, the mass percentage of titanium tetrachloride is 50%-70%, organic solvent
Content is 50%-30%.
6. a kind of intensifying method of glassware according to claim 1, which is characterized in that in step (4), work as immersion
Liquid is when impregnating glassware, the entire vacuum degree impregnated environment and be in 0.030-0.036MPa.
7. a kind of intensifying method of glassware according to claim 1, which is characterized in that the glassware is by impregnating
After being taken out in liquid and before electrolyte, glassware need to be cleaned, be dried, and the cleaning of glassware is specially using clear
Water, and during drying is specially dried in the case where 60-80 degrees Celsius of hot wind brushes.
8. a kind of intensifying method of glassware according to claim 1, which is characterized in that electric three times in step (5)
Interval time between solution preocess is 5-9 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811401492.XA CN109265017A (en) | 2018-11-22 | 2018-11-22 | A kind of intensifying method of glassware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811401492.XA CN109265017A (en) | 2018-11-22 | 2018-11-22 | A kind of intensifying method of glassware |
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| Publication Number | Publication Date |
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| CN109265017A true CN109265017A (en) | 2019-01-25 |
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| CN201811401492.XA Pending CN109265017A (en) | 2018-11-22 | 2018-11-22 | A kind of intensifying method of glassware |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035651A (en) * | 1988-03-12 | 1989-09-20 | 余华 | Improved float glass surface treatment method and device |
| CN101888905A (en) * | 2007-11-06 | 2010-11-17 | 罗迪亚公司 | Articles having an interface between a polymer surface and a modified glass surface |
| CN102653456A (en) * | 2012-05-15 | 2012-09-05 | 江苏大学 | Superhydrophobic glass and preparation method thereof |
| CN104877290A (en) * | 2015-06-08 | 2015-09-02 | 西安钧盛新材料科技有限公司 | Preparation method for anti-glare material and anti-glare glass product |
| CN108017285A (en) * | 2017-12-27 | 2018-05-11 | 安徽凤阳亚欧玻璃工艺品有限公司 | A kind of method that glassware is strengthened |
-
2018
- 2018-11-22 CN CN201811401492.XA patent/CN109265017A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035651A (en) * | 1988-03-12 | 1989-09-20 | 余华 | Improved float glass surface treatment method and device |
| CN101888905A (en) * | 2007-11-06 | 2010-11-17 | 罗迪亚公司 | Articles having an interface between a polymer surface and a modified glass surface |
| CN102653456A (en) * | 2012-05-15 | 2012-09-05 | 江苏大学 | Superhydrophobic glass and preparation method thereof |
| CN104877290A (en) * | 2015-06-08 | 2015-09-02 | 西安钧盛新材料科技有限公司 | Preparation method for anti-glare material and anti-glare glass product |
| CN108017285A (en) * | 2017-12-27 | 2018-05-11 | 安徽凤阳亚欧玻璃工艺品有限公司 | A kind of method that glassware is strengthened |
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Application publication date: 20190125 |
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