CN109251562A - Enhance the manufacture craft of environmentally friendly diatom ooze coating - Google Patents
Enhance the manufacture craft of environmentally friendly diatom ooze coating Download PDFInfo
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- CN109251562A CN109251562A CN201810939846.XA CN201810939846A CN109251562A CN 109251562 A CN109251562 A CN 109251562A CN 201810939846 A CN201810939846 A CN 201810939846A CN 109251562 A CN109251562 A CN 109251562A
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- diatom ooze
- environmentally friendly
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- 239000011248 coating agent Substances 0.000 title claims abstract description 34
- 238000000576 coating method Methods 0.000 title claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000000843 powder Substances 0.000 claims abstract description 44
- 230000004913 activation Effects 0.000 claims abstract description 43
- 239000000463 material Substances 0.000 claims abstract description 34
- 229920000728 polyester Polymers 0.000 claims abstract description 32
- 229920005610 lignin Polymers 0.000 claims abstract description 27
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 18
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 18
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 18
- 230000002708 enhancing effect Effects 0.000 claims abstract description 16
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000002500 ions Chemical class 0.000 claims abstract description 12
- -1 oxygen ion Chemical class 0.000 claims abstract description 12
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 10
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 9
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 44
- 239000002002 slurry Substances 0.000 claims description 43
- 239000007787 solid Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 claims description 27
- 235000014676 Phragmites communis Nutrition 0.000 claims description 24
- 239000002131 composite material Substances 0.000 claims description 24
- 239000008187 granular material Substances 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 23
- 238000002156 mixing Methods 0.000 claims description 23
- 238000002360 preparation method Methods 0.000 claims description 23
- 150000001450 anions Chemical class 0.000 claims description 22
- 239000002518 antifoaming agent Substances 0.000 claims description 22
- 239000002270 dispersing agent Substances 0.000 claims description 22
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 238000000498 ball milling Methods 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 239000011159 matrix material Substances 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 21
- 239000010453 quartz Substances 0.000 claims description 19
- 241000589517 Pseudomonas aeruginosa Species 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 239000002893 slag Substances 0.000 claims description 17
- 235000001674 Agaricus brunnescens Nutrition 0.000 claims description 16
- 238000000227 grinding Methods 0.000 claims description 16
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 14
- 239000000919 ceramic Substances 0.000 claims description 14
- 239000000835 fiber Substances 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- UUAGPGQUHZVJBQ-UHFFFAOYSA-N Bisphenol A bis(2-hydroxyethyl)ether Chemical compound C=1C=C(OCCO)C=CC=1C(C)(C)C1=CC=C(OCCO)C=C1 UUAGPGQUHZVJBQ-UHFFFAOYSA-N 0.000 claims description 7
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 7
- 241000233805 Phoenix Species 0.000 claims description 7
- 240000008042 Zea mays Species 0.000 claims description 7
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 7
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 7
- 239000001110 calcium chloride Substances 0.000 claims description 7
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 7
- 235000005822 corn Nutrition 0.000 claims description 7
- 229910000396 dipotassium phosphate Inorganic materials 0.000 claims description 7
- 239000000284 extract Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000011081 inoculation Methods 0.000 claims description 7
- 239000002054 inoculum Substances 0.000 claims description 7
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 7
- 235000019198 oils Nutrition 0.000 claims description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 7
- 229920000053 polysorbate 80 Polymers 0.000 claims description 7
- 229910052573 porcelain Inorganic materials 0.000 claims description 7
- 239000002244 precipitate Substances 0.000 claims description 7
- 239000001294 propane Substances 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 7
- 238000004062 sedimentation Methods 0.000 claims description 7
- 239000011780 sodium chloride Substances 0.000 claims description 7
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 7
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 7
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 7
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 238000001238 wet grinding Methods 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 6
- 239000013049 sediment Substances 0.000 claims description 2
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 20
- 239000001301 oxygen Substances 0.000 abstract description 8
- 229910052760 oxygen Inorganic materials 0.000 abstract description 8
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- 235000013312 flour Nutrition 0.000 abstract description 3
- 238000005299 abrasion Methods 0.000 abstract description 2
- 238000000855 fermentation Methods 0.000 abstract description 2
- 230000004151 fermentation Effects 0.000 abstract description 2
- 238000004887 air purification Methods 0.000 abstract 1
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 230000000813 microbial effect Effects 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 230000006872 improvement Effects 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 235000019256 formaldehyde Nutrition 0.000 description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 229920001568 phenolic resin Polymers 0.000 description 5
- 239000005011 phenolic resin Substances 0.000 description 5
- 230000001376 precipitating effect Effects 0.000 description 5
- 239000004575 stone Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000004005 microsphere Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- FCBUKWWQSZQDDI-UHFFFAOYSA-N rhamnolipid Chemical compound CCCCCCCC(CC(O)=O)OC(=O)CC(CCCCCCC)OC1OC(C)C(O)C(O)C1OC1C(O)C(O)C(O)C(C)O1 FCBUKWWQSZQDDI-UHFFFAOYSA-N 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- 239000011032 tourmaline Substances 0.000 description 2
- 229940070527 tourmaline Drugs 0.000 description 2
- 229910052613 tourmaline Inorganic materials 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- YIFFAEJYCUTZAO-UHFFFAOYSA-N 2-(4-propylphenoxy)ethanol Chemical compound CCCC1=CC=C(OCCO)C=C1 YIFFAEJYCUTZAO-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 108010029541 Laccase Proteins 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- 239000012675 alcoholic extract Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229960004424 carbon dioxide Drugs 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical compound C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 230000013632 homeostatic process Effects 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 229920006150 hyperbranched polyester Polymers 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000479 mixture part Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000008104 plant cellulose Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000010563 solid-state fermentation Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- General Preparation And Processing Of Foods (AREA)
Abstract
The present invention provides the manufacture craft for enhancing environmentally friendly diatom ooze coating, by preparing activation lignin and phenol reactant part fortified phenol with microbial fermentation, using hyper-branched polyester as medium, using porous material silica flour load negative ion powder and lignin fortified phenol and formaldehyde, then it is mixed with and obtains under high speed with diatomite, hydroxyethyl cellulose, inorganic pigment, calcium hydroxide.The environmentally friendly diatom ooze coating abrasion resistance of enhancing prepared by the present invention is high, and curing rate is fast, while the burst size of harmful substance formaldehyde is few, energy releasing negative oxygen ion is contacted with air, with good air purification ability, belong to environment-friendly type macromolecule material, has outstanding development potentiality.
Description
The application is the divisional application of following application: the applying date is on November 28th, 2017, application No. is 201711213094.0,
A kind of entitled preparation method for enhancing environmentally friendly diatom ooze coating.
Technical field
The invention belongs to chemical field of polymer material preparing technology, in particular to enhance the production of environmentally friendly diatom ooze coating
Technique.
Background technique
With the continuous improvement of people's living standards, the requirement to domestic environment is also increasingly paid attention to, for the dress in house
Effect after repairing and fitting up also is paid close attention to.Diatom ooze is a kind of using diatomite as the green inner wall decoration wall material of main raw material(s).
It, which has, eliminates formaldehyde, purification air, adjusts the function such as humidity, releasing negative oxygen ion, fire protection flame retarding, the self-cleaning, deodorization and sterilization of metope
Energy.But the aggregate that the production of existing diatom ooze decorative wall material uses is quartz or dolomite, and specific surface area is small, absorb-discharge humid
Energy and air cleaning performance are all very low.For the anti-crack fiber of existing product since plasticity is big, intensity is insufficient, is coated on wall over time
It will crack.And cellulose fibre mould easy to breed, the antibacterial agent used is calcium hydroxide, calcium hydroxide and two in air
Carbonoxide slow reaction generates calcium carbonate, anti-microbial property will be lost after a certain period of time, although the vapor partial pressure of organic antibacterial agent
It is smaller, but also have certain toxicity, it will affect indoor air quality.There are also be exactly to show product merely using diatomite as formaldehyde catching
Agent, kieselguhr adsorption are the homeostasis processes of desorption and absorption, are also being discharged while absorption.Therefore it says at present in reality
The diatom ooze decorative wall material of middle application is less desirable.
Patent of invention CN201310628130.5, a kind of Ecological diatom ooze decorative wall material, by diatomite, inorganic pigment,
Calcined zeolite, ethene-vinyl acetate redispersible rubber powder, attapulgite powder, tourmaline load nano-titanium dioxide, polyester are fine
Dimension, adipic dihydrazide etc. mix.The primary functional components of the invention are diatomite, because diatomite has porous knot
Structure has heat insulation function, the relative humidity of the interior space can be made to be automatically adjusted in 40%~70%；The tourmaline of use
The anion that load nano-titanium dioxide generates has sterilizing function, adsorbable resolving harmful gas, using calcined zeolite conduct
Aggregate is the characteristics of large specific surface area, to improve moisture adsorption and releasing because it is with porous structure and purify the function of air；Using
Polyester fiber increases intensity as anti-crack fiber, improves anti-crack ability, and will not go mouldy；Use calcium perborate for
Fungicide is long-acting nontoxic.Solve the problems, such as that existing decoration wall material exists, and method is simple, it is easy to implement.
Patent of invention CN201510888573.7, a kind of novel liquid diatom ooze wall material and preparation method thereof, the wall material
It is by following mass fraction at being grouped as: diatomite 35~45%, mesohole nano-titanium dioxide 15~20%, new sustained release
Glass microsphere 5~8%, Paris white 3.5~10%, plant cellulose 2~3%, defoaming agent 0.1~0.3%, more than deionized water
Amount.Modification of the preparation method using sodium alginate to sustained release glass microsphere surface, so that microballoon has well in the base
Dispersibility, and sodium alginate also acts as the effect of dispersing agent and binder in wall material, be not necessarily to another bonus point powder and binder,
Not only environmental protection is also energy saving；Also, it is sustained the release fragrance that glass microsphere can be permanent, makes wall material that there is long-term sterilization to press down
Bacterium, Vermins-proof mildew-proof and other effects, solve that diatom ooze wall material hygroscopicity is big, easily mouldy drawback.In addition, made from the preparation method
Novel liquid diatom ooze wall material, not stratified in Storage period with permanent storage stability, gelatinization is convenient for storage and transport.
Patent of invention CN201510574339.7, a kind of environmental protection diatom ooze composite material and preparation method, by diatomite
30~50%, dicalcium powder 3~12%, quartz sand 8~20%, pH adjusting agent 10~15%, calcined kaolin 6~10%, talcum
Powder 4~10%, sepiolite 5~10%, pigment 2~5%, pre-gelatinized starch 2~4%, hydroxypropyl methyl cellulose 1~3%, can
Dispersed latex 1~2%, starch ether 1~2%, sodium tripolyphosphate 0.5~2%, calgon 0.5~2%, polyvinyl alcohol
0.5~1%, guar gum 0.1~0.5% and nano-titanium dioxide 0.1~3% form.The invention preparation method is simple, and construction is held
Easily, diatomite is porous mass, can adsorb with the harmful substances such as decomposing formaldehyde, toluene, while there is humidity conditioning function, remove different
Function of odor.
In the prior art, the diatom ooze of preparation has miscellaneous function, but it is low still to there is wearability, harmful
The disadvantages of gas formaldehyde burst size is more, and detergent power is weak.
Summary of the invention
For deficiency existing for the diatom ooze coating prepared in the prior art, the present invention, which provides, enhances environmentally friendly diatom ooze coating
Manufacture craft.
The present invention is achieved by the following technical solutions:
The manufacture craft for enhancing environmentally friendly diatom ooze coating, is prepared by the following steps and obtains:
One, preparation activation lignin
(1) reed stems and leaves are taken, reed slag is ground into, it is 60~70% that watering, which moistens it to water content, adds reed slag
The Tween-80 of quality 0.05~0.15%, packs after mixing, and inoculation pseudomonas aeruginosa carries out sterile solid culture 2~3
After it, cultivation matrix is obtained, then in being inoculated with phoenix tail mushroom on cultivation matrix, is persistently cultivated 12~16 days, cultivation temperature is kept
At 37~45 DEG C；
(2) it takes culture mature and extracts the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3~3.5, room temperature
45~60min of lower reaction, is then filtered to remove solid residue, obtains activation lignin；
Two, quartz-anion composite granule is prepared
(1) 40~50 parts of water, 0.5~0.7 part of dispersing agent, 5040,0.2~0.3 parts of defoaming agent A10 are mixed by ratio of weight and the number of copies,
First dispersion stirs and evenly mixs, and adds powder quartz ore and carries out ball milling into porcelain mill, control solid-to-liquid ratio is (2~5): 1, it chooses
Ratio of grinding media to material is (3~5): 1 Ceramic Balls, sequentially adds 0.3% dispersing agent and 0.1% defoaming agent, and revolving speed is 70 revs/min
Clock, Ball-milling Time are 3.0~4.0h, prepare konilite slurry, hydroxyethyl cellulose is then added, prevent konilite slurry
Sedimentation, obtained konilite slurry；
(2) 40~50 parts of water, 5~10 parts of hydroxy ethyl fiber solution mixing are taken by ratio of weight and the number of copies, by negative ion powder according to solid-liquid
Than the ratio addition for 1:1, it is then transferred to vertical mixing mill, ratio of grinding media to material is (3~5): 1 Ceramic Balls sequentially add 0.3%
The defoaming agent A10 of dispersing agent 5040 and 0.1%, 1~2h of ball milling obtain anion agent slurry；
(3) be (12~25) according to mass ratio by konilite slurry and anion slurry: 1 mixing is added to sand mill, ratio of grinding media to material
It is fitted into centrifuge tube, is washed with deionized 3~4 times, room temperature leeward for (3~5): 1 zirconium ball 30~60min of wet grinding
It is dry, obtain quartz-anion composite granule；
Three, hyper-branched polyester is prepared
By mass parts ratio, 20~30 parts of propane of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] is taken, constant temperature is molten in 210 DEG C of oil baths
Melt, trimesic acid is added, with 0.1~0.5 part of stannous octoate；After 3.0~5.0h of heating stirring, vacuumizes and strength is kept to stir
1.0~2.0h of reaction is mixed, pours into methanol precipitate while hot after reaction, tetrahydrofuran is dissolved in after filtering and is sunk in methanol again
It forms sediment, 40~60h is dried at 100 DEG C, obtains hyper-branched polyester solid；
Four, preparation enhances environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, 10~15 parts of lignin of activation, quartz -12~24 parts of anion composite granule, hyper-branched polyester are taken
It 1~3 part of solid, 6~10 parts of phenol, 1~4 part of sodium hydroxide, 10~12 parts of formaldehyde, 10~24 parts of water, is uniformly mixed and is added instead
It answers in device, is warming up to 80~100 DEG C, 1~2h of isothermal reaction obtains mixture, and diatomite 20~46 is then added in mixture
Part, 2~5 parts of hydroxyethyl cellulose, 5~10 parts of inorganic pigment, 2~5 parts of calcium hydroxide, at 800~1000rpm mix 60~
The environmentally friendly diatom ooze coating of enhancing can be obtained in 100min.
Pseudomonas aeruginosa and phoenix-tail mushroom solid state fermentation reed slag can effectively decompose cellulose in reed slag and wooden
Element；The rhamnolipid that pseudomonas aeruginosa fermentation generates can promote decomposition of the phoenix-tail mushroom secretion laccase to reed slag lignin, living
Change and improve methylol, phenolic hydroxyl group, alcoholic extract hydroxyl group content on lignin molecule, to improve lignin and the phenolic resin degree of polymerization.
Quartzy main component is silica, has porous performance, can load more negative oxygen ions, adsorbs free formaldehyde
And phenol, while negative ion powder is contacted with moisture in air or oxygen, releasing negative oxygen ion after ionizing, and improves air matter
Amount；The many combination hyper-branched polyesters of the porous structure energy of quartz, further increase the degree of polymerization of phenolic resin adhesive.Bear from
When sub- additional amount is between 4~8%, purifying formaldehyde rate is small more than the variation of 8% after-purification rate between 91~94%, still
The Percentage bound of negative ion powder and silica flour reduces with the increase of negative ion powder additional amount, therefore is best with 4~8%.
Hyper-branched polyester has highly branched molecular structure, and radical species are more, and solubility high viscosity is low, can effectively mention
The polymerization speed of high phenolic resin improves the intensity of resin glue；Feature more than its radical species simultaneously can be combined more free
Phenol and formaldehyde, reduce the release of phenol and formaldehyde to improve Environmental security；On the other hand, phenolic resin is due to lignin
With the addition of silicon powder complex, gel-forming property is influenced, this influence can be eliminated using hyper-branched polyester.
As a further improvement of the present invention, pseudomonas aeruginosa described in step 1 (1) fills liquid prior to activation medium
Amount is in 20% conical flask, inoculum concentration 5%, 37 DEG C, 12~16h of activation culture under 200rpm.
As a further improvement of the present invention, the activation medium is prepared by following density component substance: vegetable seed
Oily 30g/L, Dried Corn Steep Liquor Powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L,
CaCl20.05g/L, NaCl 1.5g/L adjust pH to 6.5~7.0.
In best medium, the rhamnolipid average product that pseudomonas aeruginosa is fermented is 30.41~34.52g/L.
As a further improvement of the present invention, powder quartz ore fineness described in step 2 (1) is 200~300 mesh.
The granule size of konilite determines its dispersion performance and absorption property, the better but adsorption capacity of the smaller dispersion of granularity
It is low, therefore in order to preferably disperse to adsorb negative ion powder simultaneously, the silica flour using 200~300 mesh is best.
As a further improvement of the present invention, bis- [4- (2- hydroxy ethoxy) phenyl] propane of 2,2- described in step 3 and
The molar ratio of benzenetricarboxylic acid is (2~4): 1.
The mol ratio of two kinds of monomers influences the dissaving polymer of hyper-branched polyester molecular weight and terminal groups, and 2,2- is bis-
To obtain when 2:1, terminal groups dispersibility is big to gather the molar ratio of [4- (2- hydroxy ethoxy) phenyl] propane and trimesic acid
Ester has more binding sites (group), to promote the intensity of resin reaction polymerization speed and resin, wear-resisting property.
As a further improvement of the present invention, quartz described in step 4-anion composite granule and hyper-branched polyester are solid
Body amount ratio is (8~15): 1.
The content of hyper-branched polyester influences resin integrally curing conversion ratio, and content high resin solidification conversion ratio is low, and content is low
Resin bonding strength and wear-resisting property are low, and when hyperbranched poly ester content is 5~15%, the solidification conversion ratio of phenolic resin is 95
~98%, wear-resisting property and bond strength change rate are small, influence on whole resin property little.
As a further improvement of the present invention, the viscosity of hydroxyethyl cellulose described in step 4 is 5000~8000.
The smear that hydroxyethyl cellulose can play thickening, protection hydrate colloid, strengthen adhesive force, improve slurry
Effect, while the wear-resisting property of coating can be improved in conjunction with hyper-branched polyester, viscosity is excessively high to accelerate paint adhesion speed.
Beneficial effects of the present invention:
1, preparation process of the present invention requires low, does not need high capital equipment and raw material, has good economic benefit；
2, the diatom ooze coating that is prepared into of the present invention is safe and reliable, and burst size of methanal is low, at the same can also discharge beneficial negative oxygen from
Son, environmental pollution is low, meets demand of the people to environment-friendly materials；
3, diatom ooze coating abrasion resistance prepared by the present invention is high, and curing rate is fast, and bonding strength is high, with excellent water-fast resistance to
Climate performance.
Specific embodiment
Below with reference to embodiment, the present invention is further described.
Embodiment 1
One, preparation activation lignin
(1) reed stems and leaves are taken, reed slag is ground into, it is 60% that watering, which moistens it to water content, adds reed slag quality
0.05% Tween-80, packs after mixing, after inoculation pseudomonas aeruginosa carries out sterile solid culture 2 days, is cultivated
Matrix is persistently cultivated 12 days, cultivation temperature is maintained at 37 DEG C then in being inoculated with phoenix tail mushroom on cultivation matrix；
In the conical flask that the pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
Activation culture 12h under 200rpm；The activation medium is prepared by following density component substance: rapeseed oil 30g/L, corn
Paste dry powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L,
NaCl 1.5g/L adjusts pH to 6.5；
(2) it takes culture mature and extracts the cultivation matrix after phoenix-tail mushroom, be milled to powder, it is 3 that acetic acid, which is added, to pH, is reacted under room temperature
Then 45min is filtered to remove solid residue, obtain activation lignin；
Two, quartz-anion composite granule is prepared
(1) 40 parts of water, 0.5 part of dispersing agent, 5040,0.2 parts of defoaming agent A10 are mixed by ratio of weight and the number of copies, first dispersion stirring is mixed
It is even, it adds the powder quartz ore that fineness is 200 mesh and carries out ball milling into porcelain mill, control solid-to-liquid ratio is 2:1, chooses ball material
Than the Ceramic Balls for 3:1,0.3% dispersing agent and 0.1% defoaming agent are sequentially added, revolving speed is 70 revs/min, Ball-milling Time
For 3.0h, konilite slurry is prepared, hydroxyethyl cellulose is then added, prevents the sedimentation of konilite slurry, obtained powder stone
English slurry；
(2) 40 parts of water, the mixing of 5 parts of hydroxy ethyl fiber solution are taken by ratio of weight and the number of copies, according to solid-to-liquid ratio are 1:1's by negative ion powder
Ratio is added, and is then transferred to vertical mixing mill, and ratio of grinding media to material is the Ceramic Balls of 3:1, sequentially adds 0.3% 5040 He of dispersing agent
0.1% defoaming agent A10, ball milling 1h obtain anion agent slurry；
(3) konilite slurry and anion slurry are mixed according to mass ratio for 12:1, is added to sand mill, ratio of grinding media to material 3:1
Zirconium ball wet grinding 30min, be fitted into centrifuge tube, be washed with deionized 3~4 times, air-dried under room temperature, it is negative to obtain quartz-
Ion composite granule；
Three, hyper-branched polyester is prepared
By mass parts ratio, 20 parts of propane of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] is taken, constant temperature melts in 210 DEG C of oil baths,
Trimesic acid (molar ratio of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] propane and trimesic acid is 2:1) is added, with 0.1
Part stannous octoate；After heating stirring 3.0h, vacuumizes and strong stirring is kept to react 1.0h, pour into methanol while hot after reaction
Middle precipitating is dissolved in tetrahydrofuran and precipitates in methanol again, dries 40h at 100 DEG C after filtering, it is solid to obtain hyper-branched polyester
Body；
Four, preparation enhances environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, take activation 10 parts of lignin, quartz -12 parts of anion composite granule, 1 part of hyper-branched polyester solid,
It 6 parts of phenol, 1 part of sodium hydroxide, 10 parts of formaldehyde, 10 parts of water, is uniformly mixed and is added in reactor, be warming up to 80~100 DEG C, constant temperature
Reaction 1h obtains mixture, and 20 parts of diatomite, 2 parts of hydroxyethyl cellulose, 5 parts of inorganic pigment, hydrogen are then added in mixture
2 parts of calcium oxide, 60min is mixed at 800 rpm, and the environmentally friendly diatom ooze coating of enhancing can be obtained.
Embodiment 2
One, preparation activation lignin
(1) reed stems and leaves are taken, reed slag is ground into, it is 70% that watering, which moistens it to water content, adds reed slag quality
0.15% Tween-80, packs after mixing, after inoculation pseudomonas aeruginosa carries out sterile solid culture 3 days, is cultivated
Matrix is persistently cultivated 16 days, cultivation temperature is maintained at 45 DEG C then in being inoculated with phoenix tail mushroom on cultivation matrix；
In the conical flask that the pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
Activation culture 16h under 200rpm；The activation medium is prepared by following density component substance: rapeseed oil 30g/L, corn
Paste dry powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L,
NaCl 1.5g/L adjusts pH to 7.0
(2) it takes culture mature and extracts the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3.5, anti-under room temperature
60min is answered, solid residue is then filtered to remove, obtains activation lignin；
Two, quartz-anion composite granule is prepared
(1) 50 parts of water, 0.7 part of dispersing agent, 5040,0.3 parts of defoaming agent A10 are mixed by ratio of weight and the number of copies, first dispersion stirring is mixed
It is even, it adds the powder quartz ore that fineness is 300 mesh and carries out ball milling into porcelain mill, control solid-to-liquid ratio is 5:1, chooses ball material
Than the Ceramic Balls for 5:1,0.3% dispersing agent and 0.1% defoaming agent are sequentially added, revolving speed is 70 revs/min, Ball-milling Time
For 4.0h, konilite slurry is prepared, hydroxyethyl cellulose is then added, prevents the sedimentation of konilite slurry, obtained powder stone
English slurry；
(2) 50 parts of water, the mixing of 10 parts of hydroxy ethyl fiber solution are taken by ratio of weight and the number of copies, according to solid-to-liquid ratio are 1:1 by negative ion powder
Ratio be added, be then transferred to vertical mixing mill, ratio of grinding media to material is the Ceramic Balls of 5:1, sequentially adds 0.3% 5040 He of dispersing agent
0.1% defoaming agent A10, ball milling 2h obtain anion agent slurry；
(3) konilite slurry and anion slurry are mixed according to mass ratio for 25:1, is added to sand mill, ratio of grinding media to material 5:1
Zirconium ball wet grinding 60min, be fitted into centrifuge tube, be washed with deionized 3~4 times, air-dried under room temperature, it is negative to obtain quartz-
Ion composite granule；
Three, hyper-branched polyester is prepared
By mass parts ratio, 30 parts of propane of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] is taken, constant temperature melts in 210 DEG C of oil baths,
Trimesic acid (molar ratio of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] propane and trimesic acid is 2:1) is added, with 0.5
Part stannous octoate；After heating stirring 5.0h, vacuumizes and strong stirring is kept to react 2.0h, pour into methanol while hot after reaction
Middle precipitating is dissolved in tetrahydrofuran and precipitates in methanol again, dries 60h at 100 DEG C after filtering, it is solid to obtain hyper-branched polyester
Body；
Four, preparation enhances environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, take activation 15 parts of lignin, quartz -24 parts of anion composite granule, 3 parts of hyper-branched polyester solid,
It 10 parts of phenol, 4 parts of sodium hydroxide, 12 parts of formaldehyde, 24 parts of water, is uniformly mixed and is added in reactor, be warming up to 100 DEG C, constant temperature is anti-
It answers 2h to obtain mixture, 46 parts of diatomite, 5 parts of hydroxyethyl cellulose, 10 parts of inorganic pigment, hydrogen-oxygen is then added in mixture
Change 5 parts of calcium, mix 100min at 1000rpm, the environmentally friendly diatom ooze coating of enhancing can be obtained.
Embodiment 3
One, preparation activation lignin
(1) reed stems and leaves are taken, reed slag is ground into, it is 65% that watering, which moistens it to water content, adds reed slag quality
0.1% Tween-80, packs after mixing, after inoculation pseudomonas aeruginosa carries out sterile solid culture 3 days, is cultivated
Matrix is persistently cultivated 14 days, cultivation temperature is maintained at 40 DEG C then in being inoculated with phoenix tail mushroom on cultivation matrix；
In the conical flask that the pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
Activation culture 14h under 200rpm；The activation medium is prepared by following density component substance: rapeseed oil 30g/L, corn
Paste dry powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L,
NaCl 1.5g/L adjusts pH to 6.5~7.0
(2) it takes culture mature and extracts the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3.3, anti-under room temperature
50min is answered, solid residue is then filtered to remove, obtains activation lignin；
Two, quartz-anion composite granule is prepared
(1) 45 parts of water, 0.6 part of dispersing agent, 5040,0.25 parts of defoaming agent A10 are mixed by ratio of weight and the number of copies, first dispersion stirring is mixed
It is even, it adds the powder quartz ore that fineness is 220 mesh and carries out ball milling into porcelain mill, control solid-to-liquid ratio is 3:1, chooses ball material
Than the Ceramic Balls for 4:1,0.3% dispersing agent and 0.1% defoaming agent are sequentially added, revolving speed is 70 revs/min, Ball-milling Time
For 3.5h, konilite slurry is prepared, hydroxyethyl cellulose is then added, prevents the sedimentation of konilite slurry, obtained powder stone
English slurry；
(2) 45 parts of water, the mixing of 8 parts of hydroxy ethyl fiber solution are taken by ratio of weight and the number of copies, according to solid-to-liquid ratio are 1:1's by negative ion powder
Ratio is added, and is then transferred to vertical mixing mill, and ratio of grinding media to material is the Ceramic Balls of 4:1, sequentially adds 0.3% 5040 He of dispersing agent
0.1% defoaming agent A10, ball milling 1.5h obtain anion agent slurry；
(3) konilite slurry and anion slurry are mixed according to mass ratio for 20:1, is added to sand mill, ratio of grinding media to material 4:1
Zirconium ball wet grinding 50min, be fitted into centrifuge tube, be washed with deionized 3~4 times, air-dried under room temperature, it is negative to obtain quartz-
Ion composite granule；
Three, hyper-branched polyester is prepared
By mass parts ratio, 25 parts of propane of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] is taken, constant temperature melts in 210 DEG C of oil baths,
Trimesic acid (molar ratio of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] propane and trimesic acid is 2:1) is added, with 0.4
Part stannous octoate；After heating stirring 4.0h, vacuumizes and strong stirring is kept to react 1.5h, pour into methanol while hot after reaction
Middle precipitating is dissolved in tetrahydrofuran and precipitates in methanol again, dries 50h at 100 DEG C after filtering, it is solid to obtain hyper-branched polyester
Body；
Four, preparation enhances environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, take activation 12 parts of lignin, quartz -18 parts of anion composite granule, 2 parts of hyper-branched polyester solid,
It 8 parts of phenol, 2 parts of sodium hydroxide, 11 parts of formaldehyde, 17 parts of water, is uniformly mixed and is added in reactor, be warming up to 80~100 DEG C, constant temperature
Reaction 2h obtains mixture, and 22 parts of diatomite, 3 parts of hydroxyethyl cellulose, 5 parts of inorganic pigment, hydrogen are then added in mixture
3 parts of calcium oxide, 80min is mixed at 900rpm, the environmentally friendly diatom ooze coating of enhancing can be obtained.
Embodiment 4
One, preparation activation lignin
(1) reed stems and leaves are taken, reed slag is ground into, it is 62% that watering, which moistens it to water content, adds reed slag quality
0.15% Tween-80, packs after mixing, after inoculation pseudomonas aeruginosa carries out sterile solid culture 2 days, is cultivated
Matrix is persistently cultivated 16 days, cultivation temperature is maintained at 40 DEG C then in being inoculated with phoenix tail mushroom on cultivation matrix；
In the conical flask that the pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
Activation culture 12h under 200rpm；The activation medium is prepared by following density component substance: rapeseed oil 30g/L, corn
Paste dry powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L,
NaCl 1.5g/L adjusts pH to 6.5~7.0
(2) it takes culture mature and extracts the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3.3, anti-under room temperature
50min is answered, solid residue is then filtered to remove, obtains activation lignin；
Two, quartz-anion composite granule is prepared
(1) 42 parts of water, 0.5 part of dispersing agent, 5040,0.3 parts of defoaming agent A10 are mixed by ratio of weight and the number of copies, first dispersion stirring is mixed
It is even, it adds the powder quartz ore that fineness is 220 mesh and carries out ball milling into porcelain mill, control solid-to-liquid ratio is 2:1, chooses ball material
Than the Ceramic Balls for 5:1,0.3% dispersing agent and 0.1% defoaming agent are sequentially added, revolving speed is 70 revs/min, Ball-milling Time
For 3.0h, konilite slurry is prepared, hydroxyethyl cellulose is then added, prevents the sedimentation of konilite slurry, obtained powder stone
English slurry；
(2) 40 parts of water, the mixing of 10 parts of hydroxy ethyl fiber solution are taken by ratio of weight and the number of copies, according to solid-to-liquid ratio are 1:1 by negative ion powder
Ratio be added, be then transferred to vertical mixing mill, ratio of grinding media to material is the Ceramic Balls of 5:1, sequentially adds 0.3% 5040 He of dispersing agent
0.1% defoaming agent A10, ball milling 2.0h obtain anion agent slurry；
(3) konilite slurry and anion slurry are mixed according to mass ratio for 15:1, is added to sand mill, ratio of grinding media to material 5:1
Zirconium ball wet grinding 60min, be fitted into centrifuge tube, be washed with deionized 3~4 times, air-dried under room temperature, it is negative to obtain quartz-
Ion composite granule；
Three, hyper-branched polyester is prepared
By mass parts ratio, 25 parts of propane of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] is taken, constant temperature melts in 210 DEG C of oil baths,
Trimesic acid (molar ratio of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] propane and trimesic acid is 2:1) is added, with 0.4
Part stannous octoate；After heating stirring 5.0h, vacuumizes and strong stirring is kept to react 1.0h, pour into methanol while hot after reaction
Middle precipitating is dissolved in tetrahydrofuran and precipitates in methanol again, dries 40h at 100 DEG C after filtering, it is solid to obtain hyper-branched polyester
Body；
Four, preparation enhances environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, take activation 12 parts of lignin, quartz -20 parts of anion composite granule, 2 parts of hyper-branched polyester solid,
8 parts of phenol, 2 parts of sodium hydroxide, 10 parts of formaldehyde, water 15 is uniformly mixed and is added in reactor, is warming up to 80~100 DEG C, constant temperature is anti-
It answers 1.5h to obtain mixture, 22 parts of diatomite, 3 parts of hydroxyethyl cellulose, 10 parts of inorganic pigment, hydrogen is then added in mixture
5 parts of calcium oxide, 100min is mixed at 1000rpm, the environmentally friendly diatom ooze coating of enhancing can be obtained.
Embodiment 5
One, preparation activation lignin
(1) reed stems and leaves are taken, reed slag is ground into, it is 65% that watering, which moistens it to water content, adds reed slag quality
0.15% Tween-80, packs after mixing, after inoculation pseudomonas aeruginosa carries out sterile solid culture 3 days, is cultivated
Matrix is persistently cultivated 16 days, cultivation temperature is maintained at 40 DEG C then in being inoculated with phoenix tail mushroom on cultivation matrix；
In the conical flask that the pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
Activation culture 12h under 200rpm；The activation medium is prepared by following density component substance: rapeseed oil 30g/L, corn
Paste dry powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L,
NaCl 1.5g/L adjusts pH to 6.5；
(2) it takes culture mature and extracts the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3.5, anti-under room temperature
60min is answered, solid residue is then filtered to remove, obtains activation lignin；
Two, quartz-anion composite granule is prepared
(1) 45 parts of water, 0.7 part of dispersing agent, 5040,0.3 parts of defoaming agent A10 are mixed by ratio of weight and the number of copies, first dispersion stirring is mixed
It is even, it adds the powder quartz ore that fineness is 300 mesh and carries out ball milling into porcelain mill, control solid-to-liquid ratio is 4:1, chooses ball material
Than the Ceramic Balls for 4:1,0.3% dispersing agent and 0.1% defoaming agent are sequentially added, revolving speed is 70 revs/min, Ball-milling Time
For 4.0h, konilite slurry is prepared, hydroxyethyl cellulose is then added, prevents the sedimentation of konilite slurry, obtained powder stone
English slurry；
(2) 45 parts of water, the mixing of 10 parts of hydroxy ethyl fiber solution are taken by ratio of weight and the number of copies, according to solid-to-liquid ratio are 1:1 by negative ion powder
Ratio be added, be then transferred to vertical mixing mill, ratio of grinding media to material is the Ceramic Balls of 5:1, sequentially adds 0.3% 5040 He of dispersing agent
0.1% defoaming agent A10, ball milling 2h obtain anion agent slurry；
(3) konilite slurry and anion slurry are mixed according to mass ratio for 15:1, is added to sand mill, ratio of grinding media to material 3:1
Zirconium ball wet grinding 50min, be fitted into centrifuge tube, be washed with deionized 3~4 times, air-dried under room temperature, it is negative to obtain quartz-
Ion composite granule；
Three, hyper-branched polyester is prepared
By mass parts ratio, 30 parts of propane of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] is taken, constant temperature melts in 210 DEG C of oil baths,
Trimesic acid (molar ratio of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] propane and trimesic acid is 2:1) is added, with 0.5
Part stannous octoate；After heating stirring 4.0h, vacuumizes and strong stirring is kept to react 2.0h, pour into methanol while hot after reaction
Middle precipitating is dissolved in tetrahydrofuran and precipitates in methanol again, dries 48h at 100 DEG C after filtering, it is solid to obtain hyper-branched polyester
Body；
Four, preparation enhances environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, take activation 15 parts of lignin, quartz -18 parts of anion composite granule, 2 parts of hyper-branched polyester solid,
It 8 parts of phenol, 2 parts of sodium hydroxide, 12 parts of formaldehyde, 22 parts of water, is uniformly mixed and is added in reactor, be warming up to 90 DEG C, isothermal reaction
1.5h obtains mixture, and 44 parts of diatomite, 4 parts of hydroxyethyl cellulose, 8 parts of inorganic pigment, hydrogen-oxygen are then added in mixture
Change 5 parts of calcium, mix 100min at 1000rpm, the environmentally friendly diatom ooze coating of enhancing can be obtained.
The diatom ooze coating of comprehensive detection Examples 1 to 5 preparation, performance such as table 1.
Table 1 enhances environmentally friendly diatom ooze coating performance table
As shown in Table 1, environmentally friendly diatom ooze coating prepared by the present invention meets safe mark, has good performance and air cleaning
Ability.
Above embodiments are only exemplary embodiment of the present invention, are not used in the limitation present invention, protection scope of the present invention
It is defined by the claims.Those skilled in the art can make various repair to the present invention within the spirit and scope of the present invention
Change or equivalent replacement, this modification or equivalent replacement also should be regarded as being within the scope of the present invention.
Claims (5)
1. enhancing the manufacture craft of environmentally friendly diatom ooze coating, which is characterized in that be prepared by the following steps and obtain:
One, preparation activation lignin
(1) reed stems and leaves are taken, reed slag is ground into, it is 60~70% that watering, which moistens it to water content, adds reed slag
The Tween-80 of quality 0.05~0.15%, packs after mixing, and inoculation pseudomonas aeruginosa carries out sterile solid culture 2~3
After it, cultivation matrix is obtained, then in being inoculated with phoenix tail mushroom on cultivation matrix, is persistently cultivated 12~16 days, cultivation temperature is kept
At 37~45 DEG C；
(2) it takes culture mature and extracts the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3~3.5, room temperature
45~60min of lower reaction, is then filtered to remove solid residue, obtains activation lignin；
Two, quartz-anion composite granule is prepared
(1) 40~50 parts of water, 0.5~0.7 part of dispersing agent, 5040,0.2~0.3 parts of defoaming agent A10 are mixed by ratio of weight and the number of copies,
First dispersion stirs and evenly mixs, and adds powder quartz ore and carries out ball milling into porcelain mill, control solid-to-liquid ratio is (2~5): 1, it chooses
Ratio of grinding media to material is (3~5): 1 Ceramic Balls, sequentially adds 0.3% dispersing agent and 0.1% defoaming agent, and revolving speed is 70 revs/min
Clock, Ball-milling Time are 3.0~4.0h, prepare konilite slurry, hydroxyethyl cellulose is then added, prevent konilite slurry
Sedimentation, obtained konilite slurry；
(2) 40~50 parts of water, 5~10 parts of hydroxy ethyl fiber solution mixing are taken by ratio of weight and the number of copies, by negative ion powder according to solid-liquid
Than the ratio addition for 1:1, it is then transferred to vertical mixing mill, ratio of grinding media to material is (3~5): 1 Ceramic Balls sequentially add 0.3%
The defoaming agent A10 of dispersing agent 5040 and 0.1%, 1~2h of ball milling obtain anion agent slurry；
(3) be (12~25) according to mass ratio by konilite slurry and anion slurry: 1 mixing is added to sand mill, ratio of grinding media to material
It is fitted into centrifuge tube, is washed with deionized 3~4 times, room temperature leeward for (3~5): 1 zirconium ball 30~60min of wet grinding
It is dry, obtain quartz-anion composite granule；
Three, hyper-branched polyester is prepared
By mass parts ratio, 20~30 parts of propane of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] is taken, constant temperature is molten in 210 DEG C of oil baths
Melt, trimesic acid is added, with 0.1~0.5 part of stannous octoate；After 3.0~5.0h of heating stirring, vacuumizes and strength is kept to stir
1.0~2.0h of reaction is mixed, pours into methanol precipitate while hot after reaction, tetrahydrofuran is dissolved in after filtering and is sunk in methanol again
It forms sediment, 40~60h is dried at 100 DEG C, obtains hyper-branched polyester solid；
Four, preparation enhances environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, 10~15 parts of lignin of activation, quartz -12~24 parts of anion composite granule, hyper-branched polyester are taken
1~3 part of solid, the quartz-anion composite granule and hyper-branched polyester solid amount ratio are (8~15): 1, phenol 6~
It 10 parts, 1~4 part of sodium hydroxide, 10~12 parts of formaldehyde, 10~24 parts of water, is uniformly mixed and is added in reactor, it is warming up to 80~
100 DEG C, 1~2h of isothermal reaction obtains mixture, and 20~46 parts of diatomite, hydroxyethyl cellulose 2 are then added in mixture
~5 parts, the viscosity of the hydroxyethyl cellulose is 5000~8000,5~10 parts of inorganic pigment, 2~5 parts of calcium hydroxide,
60~100min is mixed under 800~1000rpm, and the environmentally friendly diatom ooze coating of enhancing can be obtained.
2. the manufacture craft according to claim 1 for enhancing environmentally friendly diatom ooze coating, it is characterised in that: step 1 (1) institute
In the conical flask that the pseudomonas aeruginosa stated is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C, 200rpm
12~16h of lower activation culture.
3. the manufacture craft according to claim 1 for enhancing environmentally friendly diatom ooze coating, it is characterised in that: step 2 (1) institute
The powder quartz ore fineness stated is 200~300 mesh.
4. the manufacture craft according to claim 1 for enhancing environmentally friendly diatom ooze coating, it is characterised in that: described in step 3
The molar ratio of 2,2- bis- [4- (2- hydroxy ethoxy) phenyl] propane and trimesic acid is (2~4): 1.
5. the manufacture craft according to claim 2 for enhancing environmentally friendly diatom ooze coating, it is characterised in that: the activation culture
Base is prepared by following density component substance: rapeseed oil 30g/L, Dried Corn Steep Liquor Powder 6g/L, NaNO36g/L, K2HPO4
0.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L, NaCl 1.5g/L adjust pH to 6.5~7.0
?.
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| CN201810939846.XA CN109251562B (en) | 2017-11-28 | 2017-11-28 | Preparation process of reinforced environment-friendly diatom ooze coating |
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| CN201810940858.4A Active CN108659587B (en) | 2017-11-28 | 2017-11-28 | Preparation process of reinforced environment-friendly diatom ooze coating |
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| CN109127076A (en) * | 2017-09-01 | 2019-01-04 | 江西理工大学 | A kind of super low energy consumption grinding process of nonferrous metals ore |
| CN109722099A (en) * | 2018-12-28 | 2019-05-07 | 徐州众恒淀粉科技有限公司 | A kind of preparation method of the environmentally friendly diatom ooze coating compound by converted starch |
| CN112794664A (en) * | 2021-01-13 | 2021-05-14 | 爱上佳环保新材料有限公司 | Long-acting dual-purification material added into diatom ooze and preparation method thereof |
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| CN103613321A (en) * | 2013-11-18 | 2014-03-05 | 贵州联和新型建材有限公司 | Konilite wet ball milling-paint integrated preparation method |
| CN104877427A (en) * | 2015-05-29 | 2015-09-02 | 桐城市慧琦工贸有限公司 | Diatom ooze coating and preparation method thereof |
| CN105131739A (en) * | 2015-09-01 | 2015-12-09 | 天长市银狐漆业有限公司 | Environment-friendly humidifying diatom ooze coating |
| CN105153766A (en) * | 2015-10-24 | 2015-12-16 | 洪其祥 | Quick-dry diatom ooze paint |
| CN105542630A (en) * | 2016-01-22 | 2016-05-04 | 立邦工业涂料(上海)有限公司 | Waterborne coil coating polyester rear face paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105524528A (en) * | 2016-02-02 | 2016-04-27 | 贵州联和新型建材有限公司 | Ecological and environment-friendly coating and preparation method thereof |
| CN106542773A (en) * | 2016-11-02 | 2017-03-29 | 东莞市爱乐居环保科技有限公司 | A kind of polyester fiber strengthens resistance and splits type diatom mud material and preparation method thereof |
| CN106673595A (en) * | 2016-12-29 | 2017-05-17 | 欧亚绿邦（北京）科技有限公司 | Water-based diatom ooze coating and preparation method thereof |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103613321A (en) * | 2013-11-18 | 2014-03-05 | 贵州联和新型建材有限公司 | Konilite wet ball milling-paint integrated preparation method |
| CN104877427A (en) * | 2015-05-29 | 2015-09-02 | 桐城市慧琦工贸有限公司 | Diatom ooze coating and preparation method thereof |
| CN105131739A (en) * | 2015-09-01 | 2015-12-09 | 天长市银狐漆业有限公司 | Environment-friendly humidifying diatom ooze coating |
| CN105153766A (en) * | 2015-10-24 | 2015-12-16 | 洪其祥 | Quick-dry diatom ooze paint |
| CN105542630A (en) * | 2016-01-22 | 2016-05-04 | 立邦工业涂料(上海)有限公司 | Waterborne coil coating polyester rear face paint and preparation method thereof |
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| Publication number | Publication date |
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| CN109251562B (en) | 2020-09-25 |
| WO2019104816A1 (en) | 2019-06-06 |
| CN107674465A (en) | 2018-02-09 |
| CN108659587B (en) | 2020-10-02 |
| CN107674465B (en) | 2018-10-09 |
| CN108659587A (en) | 2018-10-16 |
| CN109082147B (en) | 2020-10-02 |
| CN109082147A (en) | 2018-12-25 |
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