CN109244500A - Anode of solid oxide fuel cell sulfur poisoning recovery device and regeneration method - Google Patents
Anode of solid oxide fuel cell sulfur poisoning recovery device and regeneration method Download PDFInfo
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- CN109244500A CN109244500A CN201811044273.0A CN201811044273A CN109244500A CN 109244500 A CN109244500 A CN 109244500A CN 201811044273 A CN201811044273 A CN 201811044273A CN 109244500 A CN109244500 A CN 109244500A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/008—Disposal or recycling of fuel cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
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Abstract
Anode of solid oxide fuel cell sulfur poisoning recovery device and regeneration method, the invention belongs to solid oxide fuel cell sulfur poisoning recovery fields, in order to solve the problems, such as that existing anode of solid oxide fuel cell sulfur poisoning recovery method efficiency is lower, unsafe.Anode of solid oxide fuel cell sulfur poisoning recovery method of the present invention is after sulfur poisoning occurs for anode, it removes fuel and is passed through inert gas, applied simultaneously by electrochemical workstation to battery and electrochemical pump oxygen process, the O that pump oxygen process generates are carried out by the pump oxygen electric current that cathode flows to anode2‑And O2Redox reaction can occur with sulfur poisoning product and effectively remove sulfur poisoning product.This electrochemical pump oxygen oxidized regenerating method is easy to operate, safety, time-consuming short, high-efficient, suitable for the regeneration of hybrid ionic conductivity type anode sulfur poisoning, reduces SOFC operation and regeneration cost, and accelerate the commercialization process of SOFC.
Description
Technical field
The invention belongs to solid oxide fuel cell sulfur poisoning recovery fields, and in particular to a kind of electrochemical pump oxygen oxidation
Regenerating unit and regeneration method.
Background technique
Solid oxide fuel cell (Solid Oxide Fuel Cell, SOFC) generation technology is to solve high efficiency of energy
Using one of the approach with the difficult problem of environmental protection, chemical energy directly can be converted to electric energy and thermal energy by electrochemical reaction by SOFC, tool
There are pollution-free, high efficiency, high fuel tolerance.But cheap fuel is in use, chemistry occurs for anode and sulfur-containing impurities instead
This sulfur poisoning phenomenon that sulfur poisoning product (absorption sulphur simple substance, metal sulfide etc.) should be generated is to restrict the commercialized master of SOFC
One of reason is wanted, is to need key problems-solving in SOFC commercialization process.Currently, researcher is by finding substituted type anode
Material, Humidified fuel, promotes the methods of operating temperature to inhibit anode sulfur poisoning at installation desulfurizer, but metal anode material
Material (Ni, Au, Pt, Pd etc.) is transitioned into perovskite oxide anode material (La0.75Sr0.25Cr0.5Mn0.5O3(LSCrM)、La1- xSrxVO3(LSV)、Sr1-xLaxTiO3(LST) etc.) be only capable of promoting anode sulfur poisoning threshold value, desulfurizer higher cost and desulfurization energy
Power is limited, and Humidified fuel can't change final sulfur poisoning product types, and the work longevity of SOFC can be reduced by promoting operating temperature
Life, therefore above method cannot make anode thoroughly avoid sulfur poisoning, will not fundamentally solve the problems, such as anode sulfur poisoning, and
It is solution that the regeneration method of anodic composition, structure and chemical property can utmostly be restored by, which finding after the failure of anode sulfur poisoning,
The certainly key point of anode sulfur poisoning problem.
In pure H2In fuel, under larger discharge current density, for a long time (hour tens of or up to a hundred) it is multiple to sulfur poisoning Ni base
Heyang pole (Ni/YSZ, Ni/GDC) carries out constant-current discharge can restore its chemical property, the recovery of chemical property to a certain degree
The O that anode is transported to by cathode is generated in the process2-, a large amount of O2-It can be with fuel H2Redox reaction, O occurs2-It can't participate in
Removing sulfur poisoning product, and H2It may be that sulfur poisoning anode performance realizes that part is extensive that redox reaction, which occurs, with sulfur poisoning product
The main reason for multiple, but this process is extremely slow, even hour up to a hundred can not restore the electrification of sulfur poisoning anode completely
Performance is learned, and in expensive, explosive H2In by long-time constant-current discharge make anode obtain regeneration method be SOFC business
It is unacceptable to change institute, and developing time-consuming short, high-efficient anode regeneration method is a good problem to study.Whether can shield
Cover fuel H2To the regenerated contribution of anode, and by transporting O from cathode to anode2-To realize sulfur poisoning anode performance and microcosmic
The recovery of pattern is based on this, and the present invention proposes the regeneration method and device that carry out the oxidation of electrochemical pump oxygen under an inert gas, and
It is successfully applied to the LSCrM anode of sulfur poisoning.
Summary of the invention
That the purpose of the present invention is to solve existing solid oxide fuel cell sulfur poisoning recovery method efficiency is lower, no
The problem of safety, the present invention provide a kind of anode of solid oxide fuel cell sulfur poisoning recovery device and regeneration method.
Anode of solid oxide fuel cell sulfur poisoning recovery device of the present invention includes solid oxide fuel cell, air inlet
Pipe, escape pipe, battery fixing pipe, anode current lead, cathode current leads, electrochemical workstation, mass spectrometer and H2S inhales
Receives pond, solid oxide fuel cell are fixed in one end tube body of battery fixing pipe, press from both sides between galvanic anode and cell cathode
Equipped with electrolyte, the other end of battery fixing pipe is by seal cap sealing, and galvanic anode is in battery fixing pipe and sealing cover is close
It seals in the anode gas chamber formed, cell cathode is in cathode air chamber, and cathode air chamber is provided with air inlet, air inlet pipe and anode gas chamber
It is connected and extends in battery fixing pipe, one end of escape pipe is connected with anode gas chamber, the other end and H of escape pipe2S inhales
The air inlet of receives pond is connected, and one end of mass spectrometer branch pipe is connected with escape pipe, and the other end of mass spectrometer branch pipe connects
It connects on the air inlet of mass spectrometer, galvanic anode passes through the working electrode end phase of anode current lead and electrochemical workstation
Even, cell cathode being connected to electrode tip by cathode current leads and electrochemical workstation.
Anode of solid oxide fuel cell sulfur poisoning recovery method of the present invention follows these steps to realize:
One, the flow of inert gas in the anode gas chamber of solid oxide fuel cell is gradually increased, and gradually decreases sun
The flow of pole gas chamber fuel gas until be zero, then by electrochemical workstation be applied to solid oxide fuel cell by
Cell cathode flows to the pump oxygen electric current of galvanic anode, and the oxygen on cathode of solid oxide fuel cell surface is reduced at this time
O2-, O2-Galvanic anode is transported to by electrolyte and removes sulfur poisoning product, and the gas in anode gas chamber flows into matter by escape pipe
SO is analyzed in spectrum analysis instrument2Signal or O2Signal works as O2Signal increases or SO2Stop pump oxygen electric current when signal reduces to terminate
Electrochemical pump oxygen regenerative process；
Two, after electrochemical pump oxygen oxidation regeneration, the fuel gas flow in anode gas chamber is gradually increased, and gradually drop
The flow of low inert gas is until be zero, solid oxide fuel cell resumes work and continues to power to external circuit at this time.
Battery fixing pipe in the present invention is used for fixed solid oxide fuel cell, and is in anode and cathode respectively
In independent gas chamber.Snorkel is for transporting fuel gas or inert gas.After sulfur poisoning occurs for anode, stop fuel gas
Be passed through, and be passed through inert gas, applied using electrochemical workstation to solid oxide fuel cell and anode is flowed to by cathode
Electric current (electrochemical pump oxygen process), this electrochemical pump oxygen process can transport a large amount of O to anode2-, while generating a certain amount of O2。
O at anode2-And O2The efficient oxidation and sulfur poisoning product (oxidative regeneration process) can be removed.After sulfur poisoning anode realizes regeneration,
Being passed through for inert gas is closed, being passed through fuel gas again makes battery recovery work.
The present invention provides the device and regeneration method of a kind of achievable hybrid ionic conductivity type anode sulfur poisoning recovery, institutes
The electrochemical pump oxygen oxidized regenerating method stated is easy to operate, safety, time-consuming short (up to 15min or so), high-efficient, can be applicable in
In the regeneration of the hybrid ionic conductivity type anode of sulfur poisoning, SOFC operation and regeneration cost can be reduced, and accelerates the quotient of SOFC
Industry process.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of anode of solid oxide fuel cell sulfur poisoning recovery device of the present invention；
Fig. 2 is O at LSCrM anode in electrochemical pump oxygen oxidative regeneration process in embodiment2The variation diagram of signal；
Fig. 3 is SO at LSCrM anode in electrochemical pump oxygen oxidative regeneration process in embodiment2The variation diagram of signal；
Fig. 4 is before sulphur poisons in embodiment, sulphur poisons the output performance of monocell after rear and electrochemical pump oxygen oxidation regeneration
Curve graph, wherein ■ is represented before sulphur poisons, ● represent after sulphur poisons, ▲ represent oxidation regeneration after.
Specific embodiment
Specific embodiment 1: present embodiment anode of solid oxide fuel cell sulfur poisoning recovery device includes solid
Oxide fuel cell 1, air inlet pipe 2, escape pipe 3, battery fixing pipe 4, anode current lead 5, cathode current leads 6, electrification
Learn work station 7, mass spectrometer 8 and H2S absorption cell 10, solid oxide fuel cell 1 are fixed on one end of battery fixing pipe 4
In tube body, electrolyte 1-2 is folded between galvanic anode 1-1 and cell cathode 1-3, the other end of battery fixing pipe 4 passes through close
4-1 sealing is covered, galvanic anode 1-1 is in battery fixing pipe 4 and sealing cover 4-1 is sealed in the anode gas chamber to be formed, battery yin
Pole 1-3 is in cathode air chamber, and cathode air chamber is provided with air inlet, and air inlet pipe 2, which is connected with anode gas chamber and extends to battery, to be consolidated
Determine in pipe 4, one end of escape pipe 3 is connected with anode gas chamber, the other end and H of escape pipe 32The air inlet phase of S absorption cell 10
Even, one end of mass spectrometer branch pipe 8-1 is connected with escape pipe 3, and the other end of mass spectrometer branch pipe 8-1 is connected to mass spectrum
On the air inlet of analyzer 8, galvanic anode 1-1 passes through the working electrode end phase of anode current lead 5 and electrochemical workstation 7
Even, cell cathode 1-3 being connected to electrode tip by cathode current leads 6 and electrochemical workstation 7.
Present embodiment is analyzed and processed by the partial pressure signal that computer 9 obtains mass spectrometer.This reality
The mode of applying can be suitable for the anode sulfur poisoning recovery of monocell or battery pack.
The material of present embodiment anode of solid oxide fuel cell 1-1 is the oxide for having electronic and ionic conductivity
Anode material, thuliums and alkali earth metal are compound including La, Sr, Ba, Ca, Cr, Ti, Mg, Mo, Fe, Mn, Co etc.
Oxide anode material, or the above oxide anode material and electrolyte (doped zirconia or doped cerium oxide
Deng) composition composite anode materials.The material of solid-oxide fuel battery electrolyte 1-2 is doped zirconia, doping oxidation
Cerium, doped lanthanum gallate solid electrolyte or other oxygen ion conduction type electrolytes.Cathode of solid oxide fuel cell
The material of 1-3 is usually to have ABO3Or A2BO4The composite oxide material (O is oxygen element) of general formula, or there is ABO3Or
A2BO4The composite cathode material of general formula oxide material and a certain amount of electrolyte composition.
Present embodiment shields fuel H2It is regenerated to anode to contribute and transport O using from cathode to anode2-In turn
It realizes the regenerated principle of sulfur poisoning anode, proposes method-electrification suitable for hybrid ionic conductivity type anode sulfur poisoning recovery
Pump oxygen oxidized regenerating method is learned, and is initially applied to the LSCrM anode of sulfur poisoning.
Specific embodiment 2: the present embodiment is different from the first embodiment in that the solid oxide fuel
Battery 1 is anode support type, electrolyte-supporting type or cathode support type.
Specific embodiment 3: the present embodiment is different from the first and the second embodiment in that the soild oxide
The cross sectional shape of fuel cell 1 is round or square.
Specific embodiment 4: air inlet pipe 2 unlike one of present embodiment and specific embodiment one to three and sun
Pole gas chamber is connected and extends in battery fixing pipe 4, protrudes into the nozzle and galvanic anode of the air inlet pipe 2 in battery fixing pipe 4
1-1 is at a distance of 1~3cm.
Specific embodiment 5: H unlike one of present embodiment and specific embodiment one to four2S absorption cell 10
Middle filling is sodium hydroxide solution.
Specific embodiment 6: present embodiment anode of solid oxide fuel cell sulfur poisoning recovery method presses following step
It is rapid to implement:
One, the flow of inert gas in the anode gas chamber of solid oxide fuel cell 1 is gradually increased, and gradually decreases sun
Then the flow of pole gas chamber fuel gas is applied to solid oxide fuel cell 1 by electrochemical workstation 7 up to being zero
The pump oxygen electric current of galvanic anode 1-1 is flowed to by cell cathode 1-3, at this time the oxygen on the surface cathode of solid oxide fuel cell 1-3
Gas is reduced to O2-, O2-Galvanic anode 1-1, which is transported to, by electrolyte 1-2 removes sulfur poisoning product, the gas in anode gas chamber
It is flowed into mass spectrometer by escape pipe 3 and analyzes SO2Signal or O2Signal works as O2Signal increases or SO2Signal stops when reducing
Pump oxygen electric current only to terminate electrochemical pump oxygen regenerative process；
Two, after electrochemical pump oxygen oxidation regeneration, the fuel gas flow in anode gas chamber is gradually increased, and gradually drop
The flow of low inert gas is until be zero, solid oxide fuel cell 1 resumes work and continues to power to external circuit at this time.
Pump oxygen process is carried out under present embodiment inert gas atmosphere can generate O at cathode2-, O2-It is defeated by electrolyte
It is transported to anode and enters sulfur poisoning product lattice, the element sulphur in sulfur poisoning product (metal sulfide) may be replaced, and generate
Metal oxide.In addition to this, O2-Also generation O can be oxidized by betatopic at anode2,O2Can further with sulfur poisoning product
(metal sulfide and sulphur simple substance) occurs redox reaction and generates SO2With metal oxide.Above procedure can be achieved in sulphur
The regeneration of malicious anode, reproduction time are 10min or shorter.It can also be in yin although being large current discharge under fuel atmosphere
O is generated at pole2-, but it is transported to most of O of anode2-Redox reaction can occur with fuel, almost without O2-Participate in sulphur
The removing of poisoning product, this is also that can't also thoroughly remove sulfur poisoning by up to a hundred hours heavy-current discharges under fuel atmosphere
The reason of product and thoroughly recovery battery performance.
Specific embodiment 7: present embodiment indifferent gas described in step 1 unlike specific embodiment six
Body is Ar, N2Or He.
Specific embodiment 8: present embodiment air inlet pipe 2 in step 1 unlike specific embodiment six or seven
Material with escape pipe 3 is ceramics, quartz glass or stainless steel.
Specific embodiment 9: battery fixing pipe 4 unlike one of present embodiment and specific embodiment six to eight
Material be ceramics or quartz glass.
Specific embodiment 10: pumping oxygen in step 1 unlike one of present embodiment and specific embodiment six to nine
The size of electric current is 100~140mAcm-2。
Embodiment: the present embodiment anode of solid oxide fuel cell sulfur poisoning recovery method follows these steps to implement:
One, the flow of inert gas Ar in anode gas chamber is gradually increased, and gradually decreases solid oxide fuel cell 1
The flow of anode gas chamber fuel gas is until be zero, it is electric to be then applied to solid oxide fuel by electrochemical workstation 7
Pond 1 is flowed to the pump oxygen electric current of galvanic anode 1-1 by cell cathode 1-3, at this time at the surface cathode of solid oxide fuel cell 1-3
Oxygen be reduced to O2-, O2-Galvanic anode 1-1 is transported to by electrolyte 1-2 and removes sulfur poisoning product, in anode gas chamber
Gas is flowed into mass spectrometer by escape pipe 3 and analyzes SO2Signal or O2Signal works as O2Signal increases or SO2Signal reduces
When stop pump oxygen electric current with terminate electrochemical pump oxygen regeneration；
Two, after electrochemical pump oxygen oxidation regeneration, the fuel gas flow in anode gas chamber is gradually increased, and gradually drop
The flow of low inert gas is until be zero, solid oxide fuel cell 1 resumes work and continues to power to external circuit at this time.
The present embodiment solid oxide fuel cell 1 is electrolyte-supporting type monocell, is yin by anode, LSM of LSCrM
Pole, YSZ are electrolyte.Cell active area is 0.13cm-2.Battery is in sulfurous fuels (H2+50ppm(v)H2S 5h is run in),
Fuel flow rate is 50mL/min, and electrochemical pump oxygen oxidative regeneration process carries out in inert gas Ar, and Ar flow is 10mL/min,
Pump oxygen electric current is 120mAcm-2, reproduction time 10min, cathode is in air.Fig. 2 and Fig. 3 is the oxidation of electrochemical pump oxygen
O at sulfur poisoning anode in regenerative process2And SO2The situation of change of signal.It can be seen that electrochemical pump oxygen process is produced from Fig. 2 and Fig. 3
A certain amount of O is given birth to2, sulfur poisoning product is oxidized and generates SO2.Fig. 3 be sulfur poisoning before, after sulfur poisoning, electrochemical pump oxygen oxygen
The output characteristics of monocell after change.As can be seen from the figure electrochemical pump oxygen energy of oxidation restores and is promoted the performance of battery, this is again
Generation method is shown good application prospect.
Claims (10)
1. anode of solid oxide fuel cell sulfur poisoning recovery device, it is characterised in that the anode of solid oxide fuel cell
Sulfur poisoning recovery device includes solid oxide fuel cell (1), air inlet pipe (2), escape pipe (3), battery fixing pipe (4), sun
Electrode current lead (5), cathode current leads (6), electrochemical workstation (7), mass spectrometer (8) and H2S absorption cell (10), Gu
Oxide body fuel cell (1) is fixed in one end tube body of battery fixing pipe (4), galvanic anode (1-1) and cell cathode (1-
3) it is folded between electrolyte (1-2), the other end of battery fixing pipe (4) is sealed by sealing cover (4-1), galvanic anode (1-
1) it is in battery fixing pipe (4) and the anode gas chamber of sealing cover (4-1) sealing formation, cell cathode (1-3) is in cathode gas
Interior, cathode air chamber are provided with air inlet, and air inlet pipe (2) is connected with anode gas chamber and extends in battery fixing pipe (4), outlet
One end of pipe (3) is connected with anode gas chamber, the other end and H of escape pipe (3)2The air inlet of S absorption cell (10) is connected, mass spectrum
One end of analyzer branch pipe (8-1) is connected with escape pipe (3), and the other end of mass spectrometer branch pipe (8-1) is connected to mass spectrum
On the air inlet of analyzer (8), galvanic anode (1-1) is electric by the work of anode current lead (5) and electrochemical workstation (7)
Extreme to be connected, cell cathode (1-3) is connected to electrode tip by cathode current leads (6) and electrochemical workstation (7).
2. anode of solid oxide fuel cell sulfur poisoning recovery device according to claim 1, it is characterised in that described
Solid oxide fuel cell (1) be anode support type, electrolyte-supporting type or cathode support type.
3. anode of solid oxide fuel cell sulfur poisoning recovery device according to claim 1, it is characterised in that described
The cross sectional shape of solid oxide fuel cell (1) be round or square.
4. anode of solid oxide fuel cell sulfur poisoning recovery device according to claim 1, it is characterised in that air inlet
Pipe (2) is connected with anode gas chamber and extends in battery fixing pipe (4), protrudes into the air inlet pipe (2) in battery fixing pipe (4)
Nozzle and galvanic anode (1-1) are at a distance of 1~3cm.
5. anode of solid oxide fuel cell sulfur poisoning recovery device according to claim 1, it is characterised in that H2S inhales
What is filled in receives pond (10) is sodium hydroxide solution.
6. anode of solid oxide fuel cell sulfur poisoning recovery method, it is characterised in that this method is to follow these steps to realize:
One, the flow of inert gas in the anode gas chamber of solid oxide fuel cell (1) is gradually increased, and gradually decreases anode
Then the flow of gas chamber fuel gas is applied to solid oxide fuel cell by electrochemical workstation (7) up to being zero
(1) the pump oxygen electric current of galvanic anode (1-1) is flowed to by cell cathode (1-3), at this time cathode of solid oxide fuel cell (1-3)
The oxygen on surface is reduced to O2-, O2-Galvanic anode (1-1), which is transported to, by electrolyte (1-2) removes sulfur poisoning product, anode
The indoor gas of gas is flowed into mass spectrometer by escape pipe (3) and analyzes SO2Signal or O2Signal works as O2Signal increase or
SO2Stop pump oxygen electric current when signal reduces to terminate electrochemical pump oxygen regenerative process；
Two, after electrochemical pump oxygen oxidation regeneration, the fuel gas flow in anode gas chamber is gradually increased, and gradually decrease lazy
Property gas flow until be zero, solid oxide fuel cell (1) resumes work and continues to power to external circuit at this time.
7. anode of solid oxide fuel cell sulfur poisoning recovery method according to claim 6, it is characterised in that step
Inert gas described in one is Ar, N2Or He.
8. anode of solid oxide fuel cell sulfur poisoning recovery method according to claim 6, it is characterised in that step
Air inlet pipe (2) and the material of escape pipe (3) are ceramics, quartz glass or stainless steel in one.
9. anode of solid oxide fuel cell sulfur poisoning recovery method according to claim 6, it is characterised in that battery
The material of fixing pipe (4) is ceramics or quartz glass.
10. anode of solid oxide fuel cell sulfur poisoning recovery method according to claim 6, it is characterised in that step
The size that oxygen electric current is pumped in one is 100~140mAcm-2。
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| CN201811044273.0A CN109244500A (en) | 2018-09-07 | 2018-09-07 | Anode of solid oxide fuel cell sulfur poisoning recovery device and regeneration method |
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| CN201811044273.0A CN109244500A (en) | 2018-09-07 | 2018-09-07 | Anode of solid oxide fuel cell sulfur poisoning recovery device and regeneration method |
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| CN110146576A (en) * | 2019-06-13 | 2019-08-20 | 东北大学 | A kind of electrochemical testing device for solid electrolyte |
| CN112246289A (en) * | 2020-10-22 | 2021-01-22 | 哈尔滨工业大学 | Regeneration device and regeneration method for eliminating toxic influence of air impurities on oxygen electrode electrocatalyst |
| CN113049653A (en) * | 2021-04-01 | 2021-06-29 | 南京理工大学 | Integrated evaluation device and method for gas impurity poisoning of fuel cell material |
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| CN113049653A (en) * | 2021-04-01 | 2021-06-29 | 南京理工大学 | Integrated evaluation device and method for gas impurity poisoning of fuel cell material |
| CN113049653B (en) * | 2021-04-01 | 2023-10-31 | 南京理工大学 | Integrated evaluation device and method for fuel cell material gas impurity poisoning |
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Application publication date: 20190118 |