CN109228778A - The vertex-gluing graph method of silicate cultural relic - Google Patents
The vertex-gluing graph method of silicate cultural relic Download PDFInfo
- Publication number
- CN109228778A CN109228778A CN201811044914.2A CN201811044914A CN109228778A CN 109228778 A CN109228778 A CN 109228778A CN 201811044914 A CN201811044914 A CN 201811044914A CN 109228778 A CN109228778 A CN 109228778A
- Authority
- CN
- China
- Prior art keywords
- cultural relic
- vertex
- adhesives
- silicate cultural
- section
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The vertex-gluing graph method of silicate cultural relic of the present invention, comprising: beat connecting hole in the section to be bonded of silicate cultural relic；Adhesives is injected in the connecting hole and/or coats adhesives on siliceous fibrous column surface；And adhesives is coated in the section to be bonded of silicate cultural relic, and siliceous fibrous column is inserted into connecting hole, silicate cultural relic section to be bonded is docked, the bonding of section is carried out.
Description
Technical field
The present invention relates to historical relic's protection field, the novel reparation more particularly, to a kind of silicate cultural relic is bonded skill
Art, it is specific main using the siliceous fibrous material with silicate cultural relic similar performance as connecting column, while applying bonding material
Material carries out the repairing technique of section bonding.
Background technique
Silicate cultural relic be history, culture, art, all sectors of society important carrier, witnessed the hair of Chinese civilization
Exhibition course reflects the invention and progress of technology, has agglomerated the intelligence and wisdom of the Chinese nation, has irreplaceable important work
With.Silicate cultural relic is the important component of China's cultural heritage, mainly includes stone cultural artifact, soil property historical relic, brick and tile, pottery
Porcelain and coloured glaze etc., enormous amount, distribution is extensive, famous Shaanxi lifesize terracotta soldiers and horses in Chin tomb, Dunhuang, Gansu Province Mogao Grottoes, Henan
The China such as the Luoyang the Longmen Grottoes, Hubei Province's ancient buildings world cultural heritage is related to this.
Wherein it is poor to resist environmental attack ability for fragility silicate cultural relic, be subjected to buried soil, environment weathering etc. because
The continuous destruction of element is corroded, and easily changes or various change easily occurs, protect situation very severe.With regard to silicate cultural relic
Fracture the most typical is cracked for this lesion, is with the ceramic relics that world cultural heritage First Emperor, Emperor Chin mound museum is unearthed
Example, it is deep to be covered pressure and destruction by heavy soil etc. and be branch when unearthed since Qin's figurines ceramic relics are imbedded in underground for many years
From broken relic, loses original elegance and affect the values such as its high art and science, so necessary in view of this
It could restore to restore its original pattern by effective, scientific vertex-gluing graph.
In the bonding and repairing research for including the silicate cultural relics such as ware historical relic, stone cultural artifact, brick and tile, coloured glaze,
In a large amount of research and development and update for reporting the selection for being concentrated mainly on adhesives, Performance Evaluation and material, novel organic bonding
Material continues to bring out, including the organic siliconresins such as neo-epoxy resin, acrylic resin, organo-fluorine polymer and polysiloxanes with
And all kinds of composite materials etc., the resistance to ag(e)ing of these organic bonding materials are its fatal defects, are being applied to phyllosilicate
After the vertex-gluing graph of historical relic, adhesive failure can not estimate become be difficult to overcome the problems, such as at present.
Summary of the invention
In view of the above-mentioned problems, the present invention is directed to prevent from using adhesives aging to cause adhesive failure at present, lead to text
The destruction of the fracture cracking of object again etc. provides new method.
A kind of vertex-gluing graph method of silicate cultural relic is provided herein, comprising: in the disconnected wait be bonded of silicate cultural relic
Connecting hole is beaten in face；Adhesives is injected in the connecting hole and/or coats adhesives on siliceous fibrous column surface；And
The section to be bonded of silicate cultural relic coats adhesives, and siliceous fibrous column is inserted into connecting hole, by phyllosilicate text
Object section docking to be bonded, carries out the bonding of section.
According to the present invention, using the siliceous fibrous material with silicate cultural relic similar performance as section connecting column, together
Shi Caiyong adhesives carries out section bonding can prevent from using adhesives old at present under the action of dual bonding effect
Change and the fracture cracking etc. of adhesive failure, silicate cultural relic again is caused to lead to the inestimable destruction of historical relic.Moreover, adopting
With the siliceous fibrous column material with silicate cultural relic similar performance, can delay after removing or solving vertex-gluing graph in varying environment item
Fibre columns and the unmatched problem of historical relic ontology dilatancy under part.
Preferably, the quantity of the connecting hole on each section is two or more.
Preferably, the shape of the connecting hole is cylindric, shape of threads, inverted cone shape etc., wherein preferably inverted cone shape.
In the present invention, the material of the siliceous fibrous column can be glass or quartz etc..
Preferably, the surface of the siliceous fibrous column is coated with coupling agent, preferably silane coupling agent.
Preferably, the adhesives is organic and inorganic or Organic-inorganic composite adhesives, it preferably is selected from organic bonding
At least one of material acroleic acid resin, epoxy resin.
Preferably, before coating adhesives, phosphoric acid solution using concentration lower than 35% to connection hole surface and/or
Historical relic section to be bonded is surface-treated.
In the present invention, the silicate cultural relic can be stone cultural artifact, pottery historical relic, brick and tile or ancient building coloured glaze etc..
Detailed description of the invention
Fig. 1 is the structural schematic diagram that sample block vertex-gluing graph is simulated according to the fracture ceramic of an implementation form of the invention.
Fig. 2 is the adhesive effect schematic diagram and comparison diagram in implementation form shown in Fig. 1.
Symbol description:
1. wait be bonded simulation ceramic sample；
2. sample section to be bonded；
3. connecting hole；
4. connecting column.
Specific embodiment
The present invention is further illustrated below by way of following embodiments, it should be appreciated that following embodiments are merely to illustrate this
Invention, is not intended to limit the present invention.
The first technical problem to be solved by the present invention is to provide a kind of novel reparation bonding skill of silicate cultural relic
Art, it is specific using the siliceous fibrous material with silicate cultural relic similar performance as section connecting column, while using bonding material
Material carries out the repairing technique of section bonding, under the action of dual bonding effect, to prevent from using adhesives aging to draw at present
Playing the fracture cracking etc. of adhesive failure, silicate cultural relic again causes the inestimable destruction of historical relic to provide new side
Method.
In the present invention, the silicate cultural relic as vertex-gluing graph object includes but is not limited to stone cultural artifact, pottery text
Object, brick and tile and ancient building coloured glaze etc..
It first can the silicate cultural relic removing surface of required bonding is clean, drying drying.Removing surface method
It may be, for example, water cleaning, laser cleaning, ultrasonic cleaning, high-pressure steam-cleaning etc..
Divided in silicate cultural relic section part and need the connecting column position that connects, and carry out the quantity of connecting hole, position,
The determination of hole shape, depth etc..
The quantity of connecting hole and position can be selected according to historical relic type, weight etc..In general, on each section
Connecting hole quantity can for two or more, can be bonded in this way by two or more connecting columns, keep bonding force stronger.
The position of connecting hole may be, for example, symmetrical bikini, four-point, six point types etc..
The shape of connecting hole may be, for example, cylindric, shape of threads, inverted cone shape etc., wherein preferably inverted cone shape, this small
Big structure can make the combination between connecting hole and connecting column more firm down.
The depth of connecting hole, maximum gauge with not excess destruction silicate cultural relic and enable connecting column to be effectively inserted as
Preferably, it can be selected according to historical relic type, weight etc..In one embodiment, in permissible range, the depth of connecting hole
Deeper bonding stability is better.
According to determining connecting hole, the section part being bonded is needed to be punched each.Drilling method may be, for example, using tooth
Section's round bur etc..After punching, in cleaning eye and break surface.
In hole after cleaning and break surface, it can be surface-treated using solution such as low concentration phosphoric acid, to thick
Roughening connecting hole and historical relic section to be bonded, the combination being respectively increased between siliceous fibrous column material and adhesives are strong
Degree.
Connecting column removes or solves to glue using the siliceous fibrous column material with silicate cultural relic similar performance thus, it is possible to slow
Connect after reparation fibre columns and the unmatched problem of historical relic ontology dilatancy under difficult environmental conditions.Siliceous fibrous column material refers to
Rich silica containing fibrous material.Siliceous fibrous column material ingredient can be glass or quartz etc..
The shapes and sizes of connecting column must be consistent with connecting hole, and ensures the male structure and connecting hole of connecting column
Female structural integrity is agreed with, and guarantees the adaptation that the two combines.
The siliceous fibrous column material of connecting column and the adhesives such as acrylic resin being often used at present etc. are more difficult to be formed altogether
Coalescence is closed, in order to improve retention, connecting column surface can coated with coupling agent, so as to improve siliceous fibrous and historical relic ontology with
And the bond properties of adhesives, greatly improve adhesive strength.Coupling agent can be silane coupling agent, may be, for example, vinyl silicon
Alkane, methacryloxypropyl silane etc..
Before connecting column is inserted into connecting hole, adhesives can be injected in connecting hole.Alternatively or additionally,
Adhesives can be coated on connecting column surface.Adhesives can be selected from epoxy resin, acrylic resin, organo-fluorine polymer,
The organic siliconresins such as polysiloxanes and all kinds of composite materials etc..
Adhesives is coated in silicate cultural relic fracture bonding plane.In silicate cultural relic fracture bonding plane coating bonding
Material carries out before being inserted into connecting column.The adhesives of the coating can be selected according to the height of silicate cultural relic bulk strength
It selects, such as can choose the materials such as acrylate, epoxy resin, the principle of selection is to be bonded the intensity and historical relic ontology of the plane of disruption
It is close or consistent.
Then, connecting column is inserted into simultaneously in the connecting hole of two historical relics to be bonded, while by two planes of disruption to be bonded
It is connected to each other, it is ensured that can fill complete between connecting column and hole wall and the plane of disruption and be firmly combined.
Extra adhesives around removing, to avoid the influence to other positions.
Resulting convered structure has excellent flexural strength, toughness, ageing-resistant performance, such as under the conditions of 200 DEG C of temperature
Flexural strength, which has no, after heat ageing 14 days and in the UV lamp irradiation 20 days is decreased obviously.
Using the novel reparation adhesive technology of silicate cultural relic of the present invention, efficiently solves and use adhesives mistake merely
Cheng Zhong, the problem reduced by the brought adhesive strength of material aging.
According to following specific embodiments and with reference to attached drawing with the present invention will be described in detail.It will similarly be understood that following embodiment
It is served only for that invention is further explained, should not be understood as limiting the scope of the invention, those skilled in the art
Some nonessential modifications and adaptations that member's above content according to the present invention is made all belong to the scope of protection of the present invention.It is following
Specific technological parameter of example etc. is also only an example in OK range, i.e. those skilled in the art can pass through this paper's
Illustrate to do selection in suitable range, and does not really want to be defined in hereafter exemplary specific value.
Embodiment 1
As shown in Figure 1, the ceramic simulation sample block 1 that cutting is voluntarily fired, having a size of 40*20*20mm, removing surface is completely simultaneously
Dried for standby.
It divides and needs the position for two sections, 2 four connecting holes 3 being bonded, determines hole depth about 8mm, hole shape is in back taper
Maximum gauge about 3mm.
It is ground using the brill that dental round bur is attached hole on demand at cross section place, and uses high-pressure jet head by hole
The interior ceramic powder for boring mill is removed.
3 surface of connecting hole and historical relic section 2 to be bonded are carried out at surface using phosphoric acid solution of the concentration lower than 35%
Reason, improves the roughness of contacting surface waiting.
Using fine, soft fur brush by the brushing of silane coupling agent vinyl triethoxysilane consistent in shape and size with connecting hole
The surface glass fiber pellets 4 (German DMG) selects ultraviolet light irradiation 20 seconds to accelerate to solidify.
Using instillation syringe needle, by adhesives acrylic resin, (methyl methacrylate and ethyl methacrylate are copolymerized
Object) it injects in connecting hole 3, and quickly in 2 brushing adhesives acrylic resin of ceramic sample break surface.
Fibre columns 4 after coupling agent treatment are inserted into hole 3, and ceramic sample break surface 2 is completely docked, it is ensured that is fine
It can fill complete between dimension column 4 and hole wall and the plane of disruption 2 and be firmly combined.
Around removing after extra adhesives, the fixed bonding plane of disruption, completion of cure for 24 hours.
Using universal mechanical intensity meter (U.S. Instron5566) test there is section connecting column and adhesives to break
The ceramic sample of face bonding, the flexural strength of sample is 6.34MPa after bonding, while toughness enhancing (see curve 1 in attached drawing 2).
The heat ageing 14 days and flexural strength has no and is decreased obviously (see attached after irradiating 20 days in the UV lamp under the conditions of 200 DEG C of temperature
Curve 2 in Fig. 2).
Comparative example 1
The ceramic simulation sample block voluntarily fired is cut, having a size of 40*20*20mm, the clean simultaneously dried for standby of removing surface.
Phosphoric acid solution using concentration lower than 35% is treated bonding historical relic section and is surface-treated, and contacting surface waiting is improved
Roughness.
Quickly in ceramic sample break surface brushing adhesives acrylic resin (methyl methacrylate and metering system
Acetoacetic ester copolymer), remove around after extra adhesives, the fixed bonding plane of disruption, completion of cure for 24 hours.
The ceramic that using universal mechanical intensity meter (U.S. Instron5566) test there is adhesives to carry out section bonding
Sample, the flexural strength of sample is 4.32MPa after bonding (see curve 3 in attached drawing 2).The heat ageing 14 under the conditions of 200 DEG C of temperature
It and in the UV lamp irradiate 20 days after flexural strength be decreased obviously, be 1.21MPa (see curve 4 in attached drawing 2).
Industrial applicability
The novel reparation adhesive technology of silicate cultural relic through the invention, using with silicate cultural relic similar performance
Siliceous material uses the repairing technique of adhesives progress section bonding as section connecting column, in dual bonding effect
Under the action of, it solves and causes the fracture of adhesive failure, silicate cultural relic again using adhesives aging merely at present
Cracking etc. leads to the problem of the inestimable destruction of historical relic.
Claims (8)
1. a kind of vertex-gluing graph method of silicate cultural relic characterized by comprising
Connecting hole is beaten in the section to be bonded of silicate cultural relic；
Adhesives is injected in the connecting hole and/or coats adhesives on siliceous fibrous column surface；And
Adhesives is coated in the section to be bonded of silicate cultural relic, and siliceous fibrous column is inserted into connecting hole, by silicic acid
The section docking to be bonded of salt matter historical relic, carries out the bonding of section.
2. the vertex-gluing graph method of silicate cultural relic according to claim 1, which is characterized in that the company on each section
The quantity in hole is connect as two or more.
3. the vertex-gluing graph method of silicate cultural relic according to claim 1 or 2, which is characterized in that the connecting hole
Shape be inverted cone shape.
4. the vertex-gluing graph method of silicate cultural relic according to any one of claim 1 to 3, which is characterized in that institute
The material for stating siliceous fibrous column is glass or quartz.
5. the vertex-gluing graph method of silicate cultural relic according to any one of claim 1 to 4, which is characterized in that institute
The surface for stating siliceous fibrous column is coated with coupling agent, preferably silane coupling agent.
6. the vertex-gluing graph method of silicate cultural relic according to any one of claim 1 to 5, which is characterized in that institute
Stating adhesives is organic and inorganic or Organic-inorganic composite adhesives, preferably is selected from organic bonding material acroleic acid resin, ring
At least one of oxygen resin.
7. the vertex-gluing graph method of silicate cultural relic according to any one of claim 1 to 6, which is characterized in that
Before coating adhesives, the phosphoric acid solution using concentration lower than 35% carries out connection hole surface and/or historical relic section to be bonded
Surface treatment.
8. the vertex-gluing graph method of silicate cultural relic according to any one of claim 1 to 7, which is characterized in that institute
Stating silicate cultural relic is stone cultural artifact, pottery historical relic, brick and tile or ancient building coloured glaze.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811044914.2A CN109228778B (en) | 2018-09-07 | 2018-09-07 | Method for bonding and repairing silicate cultural relics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811044914.2A CN109228778B (en) | 2018-09-07 | 2018-09-07 | Method for bonding and repairing silicate cultural relics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109228778A true CN109228778A (en) | 2019-01-18 |
| CN109228778B CN109228778B (en) | 2020-12-11 |
Family
ID=65060167
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811044914.2A Active CN109228778B (en) | 2018-09-07 | 2018-09-07 | Method for bonding and repairing silicate cultural relics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109228778B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112480339A (en) * | 2020-11-13 | 2021-03-12 | 西安交通大学 | Preparation method of graphene-based epoxy copolymer for protecting silicate cultural relics |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003335584A (en) * | 2002-05-16 | 2003-11-25 | Aida Kagaku Kogyo Kk | Process for joining heat-resistant substrates, ornament and its manufacturing process |
| CN102108256A (en) * | 2010-12-31 | 2011-06-29 | 哈尔滨工业大学深圳研究生院 | Inorganic-organic superhydrophobic nanocomposite for stone historical relics and preparation method thereof |
| CN102391013A (en) * | 2011-08-02 | 2012-03-28 | 中国科学院上海硅酸盐研究所 | Method for reinforcing silicate cultural relic |
| CN203583751U (en) * | 2013-09-01 | 2014-05-07 | 张人益 | Brick |
| CN107956495B (en) * | 2017-11-21 | 2019-05-31 | 浙江双林古建园林工程有限公司 | A kind of stone cultural artifact anchoring process |
-
2018
- 2018-09-07 CN CN201811044914.2A patent/CN109228778B/en active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112480339A (en) * | 2020-11-13 | 2021-03-12 | 西安交通大学 | Preparation method of graphene-based epoxy copolymer for protecting silicate cultural relics |
| CN112480339B (en) * | 2020-11-13 | 2022-05-20 | 西安交通大学 | Preparation method of graphene-based epoxy copolymer for protecting silicate cultural relics |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109228778B (en) | 2020-12-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Brentel et al. | Microtensile bond strength of a resin cement to feldpathic ceramic after different etching and silanization regimens in dry and aged conditions | |
| Snethlage et al. | Stone conservation | |
| Posritong et al. | The impact of hydrofluoric acid etching followed by unfilled resin on the biaxial strength of a glass-ceramic | |
| CN108104502A (en) | Ancient building brick wall surface protection and crack repairing method based on structural integrity | |
| CN103304263B (en) | Restoration method of lacquer ceramic fragment | |
| Mendes Tribst et al. | Fatigue Failure Load of Resin-bonded Simplified Lithium Disilicate Glass-Ceramic Restorations: Effect of Ceramic Conditioning Methods. | |
| CN109228778A (en) | The vertex-gluing graph method of silicate cultural relic | |
| CN109057385A (en) | Engineering method is repaired in the fixed pin part slip casting of inlet of a kind of hollowing inner-outer wall ceramic tile, stone material | |
| AL‐Turki et al. | Repair bond strength of dental computer‐aided design/computer‐aided manufactured ceramics after different surface treatments | |
| RU2018132002A (en) | COMPOSITE FIBER COATED WITH SILICON DIOXIDE FOR REINFORCING CONCRETE | |
| Alves et al. | Conservation of stony materials in the built environment | |
| CN104032972A (en) | Method for repairing cracks of thermal mortar of outer wall | |
| KR100502277B1 (en) | Composition of mortar that is mixed suface modified fiber for repair and renovation of concrete structures and its manufacturing process | |
| CN108484018A (en) | A kind of light mortar and its processing method for traditional earth kiln local-style dwelling houses wall coating | |
| CN108193862A (en) | Building wall plastering construction method | |
| CN105503259B (en) | Brick stone cultural artifact compound desalination closure material and its preparation method and application | |
| CN103590557B (en) | A kind of method preventing vitrified tile from inlaying hollowing and coming off | |
| DE60137902D1 (en) | High-strength steam turbine rotor with low susceptibility to stress corrosion cracking and its method of production | |
| CN105619185B (en) | Using sweet wormwood cellulose crystal to the method for ceramic material local polishing | |
| CN104893627B (en) | Renewable restoration method for ancient ceramic microcracks | |
| CN107269020B (en) | A kind of method for repairing and mending of ancient city wall brick | |
| CN108585532A (en) | A kind of preparation method of selfreparing multifunctional glass | |
| CN209723073U (en) | A kind of concrete repair structure | |
| CN105908933A (en) | Building porcelain tile with conical holes and copper wires for enhancing bonding and pasting construction method of building porcelain tile | |
| CN207597699U (en) | A kind of precast concrete external wall panel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |