CN109228563B - Flame-retardant anti-static composite material plate and preparation method thereof - Google Patents
Flame-retardant anti-static composite material plate and preparation method thereof Download PDFInfo
- Publication number
- CN109228563B CN109228563B CN201810838567.4A CN201810838567A CN109228563B CN 109228563 B CN109228563 B CN 109228563B CN 201810838567 A CN201810838567 A CN 201810838567A CN 109228563 B CN109228563 B CN 109228563B
- Authority
- CN
- China
- Prior art keywords
- glue
- flame
- retardant
- antistatic
- structure layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/1845—Aromatic mono- or polycarboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
- D06M13/453—Phosphates or phosphites containing nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
- D06M15/51—Unsaturated polymerisable polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/21—Anti-static
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Abstract
A flame-retardant antistatic composite material plate is composed of an upper antistatic surface layer, a lower antistatic surface layer, a flame-retardant structure layer and an impermeable structure layer, wherein the antistatic surface layer is formed by compounding unsaturated resin, a surface felt, graphene and nano silver powder; the flame-retardant structure layer is formed by compounding unsaturated resin, glass fiber cloth, a flame retardant, whiskers and graphene; the anti-seepage structure layer is formed by compounding unsaturated resin, glass fiber felt, crystal whisker and graphene; the accelerant is cobalt naphthanate, and the initiator is methyl ethyl ketone peroxide. The invention has the advantages of convenient production and manufacture, high mechanization degree of the production process and low production cost. Compared with the common polymer matrix composite material, the flame retardant antistatic polyester composite material has good flame retardant and antistatic performance, low shrinkage rate, more excellent strength, modulus and the like of subsequent products and longer service life; compared with metal and ceramic materials, the invention has the advantages of light weight, high specific strength, low cost, convenient transportation and installation, and the like. The flame-retardant antistatic floor can be used for manufacturing flame-retardant antistatic floors, partition boards, wall boards and the like in places such as machine rooms, storehouses, factory buildings and the like.
Description
Technical Field
The invention relates to a flame-retardant antistatic composite material plate and a preparation method thereof, which can be used for manufacturing flame-retardant antistatic floors, partition boards, wall boards and the like in places such as machine rooms, storehouses, factory buildings and the like, and belongs to the technical field of composite materials.
Background
In some special places such as machine rooms, storehouses, factory buildings and the like, the used floors, partition boards, wall boards and the like are often required to have flame retardant and antistatic effects so as to prevent fire or explosion caused by sparks generated by static electricity and prevent fire and the like caused by sparks generated in the operation process. Conventionally, in order to eliminate static electricity, an antistatic agent may be added to the material; in order to achieve the flame retardant effect, a non-combustible material such as a metal material, a ceramic material and the like can be selected, or a combustible material is selected, and a flame retardant is added into the combustible material to achieve the flame retardant effect. These traditional methods all have certain limitations, and often cannot solve the problems of static electricity prevention and flame retardance at the same time. In addition, the metal material and the ceramic material are heavy and inconvenient to transport and install.
The polymer-based composite material is a novel material obtained by compounding a polymer serving as a matrix and fibers serving as a reinforcement through a certain process, has the characteristics of light weight, high specific strength, convenience in molding and processing, corrosion resistance and the like, and is widely applied to the fields of petroleum, chemical industry, building, transportation and the like at present. However, the traditional polymer matrix composite material does not have an antistatic effect and is not flame-retardant, so that great potential safety hazards exist in places such as special machine rooms, storehouses and factory buildings.
In order to overcome the defects and further play the role of the polymer matrix composite, the invention of the flame-retardant antistatic composite plate is necessary.
Disclosure of Invention
The invention aims at the above purpose and provides a flame-retardant antistatic composite material plate and a preparation method thereof.
The purpose of the invention is realized by the following technical scheme:
a flame-retardant antistatic composite material plate is composed of an upper antistatic surface layer, an upper flame-retardant structure layer, an impermeable structure layer, a lower flame-retardant structure layer and a lower antistatic surface layer, wherein the upper flame-retardant structure layer is positioned between the upper antistatic surface layer and the impermeable structure layer; the anti-seepage structure layer is positioned between the upper flame-retardant structure layer and the lower flame-retardant structure layer; the lower flame-retardant structural layer is positioned between the seepage-proofing structural layer and the lower antistatic surface layer.
The upper anti-static surface layer and the lower anti-static surface layer are compounded by unsaturated polyester resin, polyester surface felt, graphene oxide and nano silver powder, the adopted accelerant is cobalt naphthanate, and the initiator is methyl ethyl ketone peroxide; the upper flame-retardant structure layer and the lower flame-retardant structure layer are compounded by unsaturated polyester resin, alkali-free glass fiber cloth, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker and graphene oxide, the adopted accelerant is cobalt naphthanate, and the initiator is methyl ethyl ketone peroxide; the anti-seepage structure layer is formed by compounding unsaturated polyester resin, a glass fiber felt, basic magnesium sulfate whisker and graphene oxide, the adopted accelerant is cobalt naphthanate, and the initiator is methyl ethyl ketone peroxide.
The single weight of the polyester surface felt is 30g/m2Or 45g/m2One kind of (1).
The graphene oxide is multilayer graphene, and the number of layers is 3-11.
The particle size of the nano silver powder is 20-80 nm.
The single weight of the alkali-free glass fiber cloth is 225g/m2、300g/m2、450g/m2One kind of (1).
The nitrogen-phosphorus compound flame retardant is prepared from phosphoric acid, pentaerythritol and aniline.
The length-diameter ratio of the basic magnesium sulfate whisker is 40-80.
The single weight of the glass fiber felt is 450g/m2、600g/m2Or 900g/m2One kind of (1).
A flame-retardant antistatic composite material plate and a preparation method thereof are disclosed, wherein the preparation process comprises the following steps:
(1) weighing phosphoric acid, pentaerythritol and aniline according to the following parts by weight:
15-25% of phosphoric acid
13-16 parts of pentaerythritol
7-11 parts of aniline;
placing phosphoric acid into a reaction container, preheating for 10-20 min at 100 ℃, slowly adding pentaerythritol, reacting for 2-3 h at 100 ℃, adding 20-40 parts by weight of aqueous solution, slowly adding aniline, continuously reacting for 3-5 h at 100 ℃, cooling to room temperature, filtering, removing filtrate to obtain solid filtrate, washing the solid filtrate for 2-4 times with 50-100 parts by weight of ethanol, washing off redundant aniline and pentaerythritol, performing suction filtration and drying again, and crushing to obtain the nitrogen-phosphorus compound flame retardant with the particle size of 0.5-1.5 mu m.
(2) Weighing unsaturated polyester resin, polyester surface felt, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide according to the following parts by weight:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide into a container, and mixing for 10-20 min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank A;
enabling the polyester surface felt to pass through a glue dipping tank A at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain an upper antistatic surface layer substrate;
(3) weighing unsaturated polyester resin, polyester surface felt, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide according to the following parts by weight:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide into a container, and mixing for 10-20 min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank B;
enabling the polyester surface felt to pass through a glue dipping tank B at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a lower antistatic surface layer substrate;
(4) weighing unsaturated polyester resin, alkali-free glass fiber cloth, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide in parts by weight as follows:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered materials into a container, and mixing the materials for 10-20 min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank C;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank C at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue by a glue scraping device, and adjusting the tension of the scraped glue to obtain an upper flame retardant structure layer substrate;
(5) weighing unsaturated polyester resin, alkali-free glass fiber cloth, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide in parts by weight as follows:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered materials into a container, and mixing the materials for 10-20 min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank D;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank D at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue through a glue scraping device, and adjusting the tension of the scraped glue to obtain a lower flame retardant structure layer substrate;
(6) weighing unsaturated polyester resin, a glass fiber felt, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide in parts by weight as follows:
metering unsaturated polyester resin, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 10-20 min by using an electric stirrer to prepare an anti-seepage adhesive;
adding the anti-seepage glue into a glue dipping tank E;
enabling the glass fiber mat to pass through a glue dipping tank E at a certain speed, dipping the glass fiber mat in anti-seepage glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a base material of the anti-seepage structure layer;
(7) taking a PE film, laying the PE film on an operation table, laying a lower anti-static surface layer substrate on the film, laying a lower flame-retardant structure layer substrate on the lower anti-static surface layer substrate, laying an anti-seepage structure layer substrate on the lower flame-retardant structure layer substrate, laying a flame-retardant structure layer substrate on the anti-seepage structure layer substrate, laying an anti-static surface layer substrate on the upper flame-retardant structure layer substrate, slightly rolling by using a compression roller in each laying process to form a composite material plate, and covering another PE film on the composite material plate;
(9) placing the composite material plate with the upper surface and the lower surface both covered with the PE films on a press, performing die pressing at room temperature for 10-20 min under the pressure of 0.8-1.2 MPa, then heating to 80 ℃, performing die pressing for 10-30 min under the pressure of 2-4 MPa, heating to 100 ℃, and performing die pressing for 30-60 min under the pressure of 8-12 MPa;
(10) and opening the press, and uncovering the PE films on the upper surface and the lower surface of the composite material plate to obtain the flame-retardant anti-static composite material plate.
The flame-retardant antistatic composite material plate is convenient to produce and manufacture, the traditional glass fiber reinforced plastic production process can be used for production and processing without improvement, the degree of mechanization in the production process is high, the required labor force is low, and the production cost is low. Compared with the common polymer-based composite material, the flame-retardant antistatic composite material plate has the advantages of good flame-retardant property and antistatic property, low shrinkage rate, more excellent mechanical properties such as strength and modulus of subsequent products and longer service life; compared with metal materials and ceramic materials, the flame-retardant antistatic composite material plate has the advantages of light weight, high specific strength, low cost, very convenient transportation and installation and the like.
Detailed Description
A flame-retardant antistatic composite material plate is composed of an upper antistatic surface layer, an upper flame-retardant structure layer, an impermeable structure layer, a lower flame-retardant structure layer and a lower antistatic surface layer, wherein the upper flame-retardant structure layer is positioned between the upper antistatic surface layer and the impermeable structure layer; the anti-seepage structure layer is positioned between the upper flame-retardant structure layer and the lower flame-retardant structure layer; the lower flame-retardant structural layer is positioned between the seepage-proofing structural layer and the lower antistatic surface layer.
The upper anti-static surface layer and the lower anti-static surface layer are compounded by unsaturated polyester resin, polyester surface felt, graphene oxide and nano silver powder, the adopted accelerant is cobalt naphthanate, and the initiator is methyl ethyl ketone peroxide; the upper flame-retardant structure layer and the lower flame-retardant structure layer are compounded by unsaturated polyester resin, alkali-free glass fiber cloth, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker and graphene oxide, the adopted accelerant is cobalt naphthanate, and the initiator is methyl ethyl ketone peroxide; the anti-seepage structure layer is formed by compounding unsaturated polyester resin, a glass fiber felt, basic magnesium sulfate whisker and graphene oxide, the adopted accelerant is cobalt naphthanate, and the initiator is methyl ethyl ketone peroxide.
The following examples are used to specifically illustrate a flame-retardant antistatic composite plate and a preparation method thereof.
Example 1:
(1) weighing phosphoric acid, pentaerythritol and aniline according to the following parts by weight:
phosphoric acid 20
Pentaerythritol 14.5
Aniline 9;
placing phosphoric acid into a reaction vessel, preheating for 15min at 100 ℃, slowly adding pentaerythritol, reacting for 2.5h at 100 ℃, adding 30 parts by weight of aqueous solution, slowly adding aniline, continuing to react for 4h at 100 ℃, cooling to room temperature, filtering, removing filtrate to obtain solid filtrate, washing the solid filtrate for 3 times by using 75 parts by weight of ethanol, washing off redundant aniline and pentaerythritol, performing suction filtration again, drying, and crushing to obtain the nitrogen-phosphorus compound flame retardant with the particle size of 1 micron.
(2) Weighing unsaturated polyester resin and polyester surface felt (the single weight is 30 g/m)2) Graphene oxide (7 layers), silver nanopowder (50 nm in particle size), cobalt naphthoate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 15min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank A;
enabling the polyester surface felt to pass through a glue dipping tank A at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain an upper antistatic surface layer substrate;
(3) weighing unsaturated polyester resin and polyester surface felt (the single weight is 30 g/m)2) Graphene oxide (7 layers), nano silver powder (50 nm in particle size), and naphthoic acidCobalt and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 15min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank B;
enabling the polyester surface felt to pass through a glue dipping tank B at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a lower antistatic surface layer substrate;
(4) weighing unsaturated polyester resin and alkali-free glass fiber cloth (the single weight is 300 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 60), graphene oxide (the number of layers is 7), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered substances into a container, and mixing the substances for 15min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank C;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank C at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue by a glue scraping device, and adjusting the tension of the scraped glue to obtain an upper flame retardant structure layer substrate;
(5) weighing unsaturated polyester resin and alkali-free glass fiber cloth (the single weight is 300 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 60), graphene oxide (the number of layers is 7), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered substances into a container, and mixing the substances for 15min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank D;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank D at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue through a glue scraping device, and adjusting the tension of the scraped glue to obtain a lower flame retardant structure layer substrate;
(6) weighing unsaturated polyester resin and glass fiber felt (the single weight is 600 g/m)2) Basic magnesium sulfate whisker (length-diameter ratio is 60), graphene oxide (the number of layers is 7), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 15min by using an electric stirrer to prepare an anti-seepage adhesive;
adding the anti-seepage glue into a glue dipping tank E;
enabling the glass fiber mat to pass through a glue dipping tank E at a certain speed, dipping the glass fiber mat in anti-seepage glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a base material of the anti-seepage structure layer;
(7) taking a PE film, laying the PE film on an operation table, laying a lower anti-static surface layer substrate on the film, laying a lower flame-retardant structure layer substrate on the lower anti-static surface layer substrate, laying an anti-seepage structure layer substrate on the lower flame-retardant structure layer substrate, laying a flame-retardant structure layer substrate on the anti-seepage structure layer substrate, laying an anti-static surface layer substrate on the upper flame-retardant structure layer substrate, slightly rolling by using a compression roller in each laying process to form a composite material plate, and covering another PE film on the composite material plate;
(9) placing the composite material plate with the upper surface and the lower surface both covered with the PE films on a press, and carrying out die pressing for 15min at room temperature by adopting the pressure of 1 MPa; then heating to 80 ℃, adopting 3MPa pressure to mold for 20min, heating to 100 ℃, adopting 10MPa pressure to mold for 45 min;
(10) and opening the press, and uncovering the PE films on the upper surface and the lower surface of the composite material plate to obtain the flame-retardant anti-static composite material plate.
Example 2:
(1) weighing phosphoric acid, pentaerythritol and aniline according to the following parts by weight:
phosphoric acid 15
Pentaerythritol 13
Aniline 7;
placing phosphoric acid into a reaction vessel, preheating for 10min at 100 ℃, slowly adding pentaerythritol, reacting for 2h at 100 ℃, adding 20 parts by weight of aqueous solution, slowly adding aniline, continuing to react for 3h at 100 ℃, cooling to room temperature, filtering, removing filtrate to obtain solid filtrate, washing the solid filtrate for 2 times by using 50 parts by weight of ethanol, washing off redundant aniline and pentaerythritol, performing suction filtration again, drying, and crushing to obtain the nitrogen-phosphorus compound flame retardant with the particle size of 0.5 mu m.
(2) Weighing unsaturated polyester resin and polyester surface felt (the single weight is 30 g/m)2) Graphene oxide (the number of layers is 3), nano silver powder (the particle size is 20nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 10min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank A;
enabling the polyester surface felt to pass through a glue dipping tank A at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain an upper antistatic surface layer substrate;
(3) weighing unsaturated polyester resin and polyester surface felt (the single weight is 30 g/m)2) Graphene oxide (the number of layers is 3), nano silver powder (the particle size is 20nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 10min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank B;
enabling the polyester surface felt to pass through a glue dipping tank B at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a lower antistatic surface layer substrate;
(4) weighing unsaturated polyester resin and alkali-free glass fiber cloth (the single weight is 225 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 40), graphene oxide (the number of layers is 3), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 10min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank C;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank C at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue by a glue scraping device, and adjusting the tension of the scraped glue to obtain an upper flame retardant structure layer substrate;
(5) weighing unsaturated polyester resin and alkali-free glass fiber cloth (the single weight is 225 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 40), graphene oxide (the number of layers is 3), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 10min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank D;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank D at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue through a glue scraping device, and adjusting the tension of the scraped glue to obtain a lower flame retardant structure layer substrate;
(6) weighing unsaturated polyester resin and glass fiber felt (the single weight is 450 g/m)2) Basic magnesium sulfate whisker (length-diameter ratio is 40), graphene oxide (the number of layers is 3), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 10min by using an electric stirrer to prepare an anti-seepage adhesive;
adding the anti-seepage glue into a glue dipping tank E;
enabling the glass fiber mat to pass through a glue dipping tank E at a certain speed, dipping the glass fiber mat in anti-seepage glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a base material of the anti-seepage structure layer;
(7) taking a PE film, laying the PE film on an operation table, laying a lower anti-static surface layer substrate on the film, laying a lower flame-retardant structure layer substrate on the lower anti-static surface layer substrate, laying an anti-seepage structure layer substrate on the lower flame-retardant structure layer substrate, laying a flame-retardant structure layer substrate on the anti-seepage structure layer substrate, laying an anti-static surface layer substrate on the upper flame-retardant structure layer substrate, slightly rolling by using a compression roller in each laying process to form a composite material plate, and covering another PE film on the composite material plate;
(9) placing the composite material plate with the upper surface and the lower surface both covered with the PE films on a press, adopting the pressure of 0.8MPa to mold for 10min at room temperature, then heating to 80 ℃, adopting the pressure of 2MPa to mold for 10min, then heating to 100 ℃, and adopting the pressure of 8MPa to mold for 30 min;
(10) and opening the press, and uncovering the PE films on the upper surface and the lower surface of the composite material plate to obtain the flame-retardant anti-static composite material plate.
Example 3:
(1) weighing phosphoric acid, pentaerythritol and aniline according to the following parts by weight:
phosphoric acid 25
Pentaerythritol 16
Aniline 11;
placing phosphoric acid into a reaction vessel, preheating for 20min at 100 ℃, slowly adding pentaerythritol, reacting for 3h at 100 ℃, adding 40 parts by weight of aqueous solution, slowly adding aniline, continuing to react for 5h at 100 ℃, cooling to room temperature, filtering, removing filtrate to obtain solid filtrate, washing the solid filtrate for 4 times by using 100 parts by weight of ethanol, washing off redundant aniline and pentaerythritol, performing suction filtration again, drying, and crushing to obtain the nitrogen-phosphorus compound flame retardant with the particle size of 1.5 mu m.
(2) Weighing unsaturated polyester resin and polyester surface felt (the single weight is 45 g/m)2) Graphene oxide (the number of layers is 11), silver nanopowder (the particle size is 80nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 20min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank A;
enabling the polyester surface felt to pass through a glue dipping tank A at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain an upper antistatic surface layer substrate;
(3) weighing unsaturated polyester resin and polyester surface felt (the single weight is 45 g/m)2) Graphene oxide (the number of layers is 11), silver nanopowder (the particle size is 80nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 20min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank B;
enabling the polyester surface felt to pass through a glue dipping tank B at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a lower antistatic surface layer substrate;
(4) weighing the unsaturated polyester resin and the alkali-free glass fiber cloth according to the following parts by weight (the single weight is 450 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 80), graphene oxide (the number of layers is 11), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered substances into a container, and mixing the substances for 20min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank C;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank C at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue by a glue scraping device, and adjusting the tension of the scraped glue to obtain an upper flame retardant structure layer substrate;
(5) weighing the unsaturated polyester resin and the alkali-free glass fiber cloth according to the following parts by weight (the single weight is 450 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 80), graphene oxide (the number of layers is 11), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered substances into a container, and mixing the substances for 20min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank D;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank D at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue through a glue scraping device, and adjusting the tension of the scraped glue to obtain a lower flame retardant structure layer substrate;
(6) weighing unsaturated polyester resin and glass fiber felt (the single weight is 900 g/m)2) Basic magnesium sulfate whisker (length-diameter ratio is 80), graphene oxide (the number of layers is 11), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 20min by using an electric stirrer to prepare an anti-seepage adhesive;
adding the anti-seepage glue into a glue dipping tank E;
enabling the glass fiber mat to pass through a glue dipping tank E at a certain speed, dipping the glass fiber mat in anti-seepage glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a base material of the anti-seepage structure layer;
(7) taking a PE film, laying the PE film on an operation table, laying a lower anti-static surface layer substrate on the film, laying a lower flame-retardant structure layer substrate on the lower anti-static surface layer substrate, laying an anti-seepage structure layer substrate on the lower flame-retardant structure layer substrate, laying a flame-retardant structure layer substrate on the anti-seepage structure layer substrate, laying an anti-static surface layer substrate on the upper flame-retardant structure layer substrate, slightly rolling by using a compression roller in each laying process to form a composite material plate, and covering another PE film on the composite material plate;
(9) placing the composite material plate with the upper surface and the lower surface both covered with the PE films on a press, carrying out die pressing at room temperature for 20min under the pressure of 1.2MPa, then heating to 80 ℃, carrying out die pressing for 30min under the pressure of 4MPa, heating to 100 ℃, and carrying out die pressing for 60min under the pressure of 12 MPa;
(10) and opening the press, and uncovering the PE films on the upper surface and the lower surface of the composite material plate to obtain the flame-retardant anti-static composite material plate.
Example 4:
(1) weighing phosphoric acid, pentaerythritol and aniline according to the following parts by weight:
phosphoric acid 15
Pentaerythritol 14.5
Aniline 11;
placing phosphoric acid into a reaction vessel, preheating for 10min at 100 ℃, slowly adding pentaerythritol, reacting for 2.5h at 100 ℃, adding 40 parts by weight of aqueous solution, slowly adding aniline, continuing to react for 3h at 100 ℃, cooling to room temperature, filtering, removing filtrate to obtain solid filtrate, washing the solid filtrate 4 times with 75 parts by weight of ethanol, washing off redundant aniline and pentaerythritol, performing suction filtration again, drying, and crushing to obtain the nitrogen-phosphorus compound flame retardant with the particle size of 0.5 mu m.
(2) Weighing unsaturated polyester resin and polyester surface felt (the single weight is 45 g/m)2) Graphene oxide (the number of layers is 11), silver nanopowder (the particle size is 20nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 10min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank A;
enabling the polyester surface felt to pass through a glue dipping tank A at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain an upper antistatic surface layer substrate;
(3) weighing unsaturated polyester resin and polyester surface felt (the single weight is 30 g/m)2) Graphene oxide (the number of layers is 11), silver nanopowder (the particle size is 20nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 10min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank B;
enabling the polyester surface felt to pass through a glue dipping tank B at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a lower antistatic surface layer substrate;
(4) weighing unsaturated polyester resin and alkali-free glass fiber cloth (the single weight is 300 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 80), graphene oxide (the number of layers is 3), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered substances into a container, and mixing the substances for 15min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank C;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank C at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue by a glue scraping device, and adjusting the tension of the scraped glue to obtain an upper flame retardant structure layer substrate;
(5) weighing the unsaturated polyester resin and the alkali-free glass fiber cloth according to the following parts by weight (the single weight is 450 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 40), graphene oxide (the number of layers is 7), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 10min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank D;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank D at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue through a glue scraping device, and adjusting the tension of the scraped glue to obtain a lower flame retardant structure layer substrate;
(6) weighing unsaturated polyester resin and glass fiber felt (the single weight is 600 g/m)2) Basic magnesium sulfate whisker (length-diameter ratio is 80), graphene oxide (the number of layers is 3), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 10min by using an electric stirrer to prepare an anti-seepage adhesive;
adding the anti-seepage glue into a glue dipping tank E;
enabling the glass fiber mat to pass through a glue dipping tank E at a certain speed, dipping the glass fiber mat in anti-seepage glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a base material of the anti-seepage structure layer;
(7) taking a PE film, laying the PE film on an operation table, laying a lower anti-static surface layer substrate on the film, laying a lower flame-retardant structure layer substrate on the lower anti-static surface layer substrate, laying an anti-seepage structure layer substrate on the lower flame-retardant structure layer substrate, laying a flame-retardant structure layer substrate on the anti-seepage structure layer substrate, laying an anti-static surface layer substrate on the upper flame-retardant structure layer substrate, slightly rolling by using a compression roller in each laying process to form a composite material plate, and covering another PE film on the composite material plate;
(9) placing the composite material plate with the upper surface and the lower surface both covered with the PE films on a press, carrying out die pressing at room temperature for 20min under the pressure of 1MPa, then heating to 80 ℃, carrying out die pressing under the pressure of 2MPa for 20min, heating to 100 ℃, and carrying out die pressing under the pressure of 8MPa for 60 min;
(10) and opening the press, and uncovering the PE films on the upper surface and the lower surface of the composite material plate to obtain the flame-retardant anti-static composite material plate.
Example 5:
(1) weighing phosphoric acid, pentaerythritol and aniline according to the following parts by weight:
phosphoric acid 20
Pentaerythritol 16
Aniline 7;
placing phosphoric acid into a reaction vessel, preheating for 15min at 100 ℃, slowly adding pentaerythritol, reacting for 3h at 100 ℃, adding 20 parts by weight of aqueous solution, slowly adding aniline, continuously reacting for 4h at 100 ℃, cooling to room temperature, filtering, removing filtrate to obtain solid filtrate, washing the solid filtrate for 2 times by using 100 parts by weight of ethanol, washing off redundant aniline and pentaerythritol, performing suction filtration again, drying, and crushing to obtain the nitrogen-phosphorus compound flame retardant, wherein the particle size of the solid filtrate is 1 mu m.
(2) Weighing unsaturated polyester resin and polyester surface felt (the single weight is 45 g/m)2) Graphene oxide (the number of layers is 3), silver nanopowder (the particle size is 50nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 15min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank A;
enabling the polyester surface felt to pass through a glue dipping tank A at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain an upper antistatic surface layer substrate;
(3) weighing unsaturated polyester resin and polyester surface felt (the single weight is 45 g/m)2) Graphene oxide (the number of layers is 3), silver nanopowder (the particle size is 50nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 15min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank B;
enabling the polyester surface felt to pass through a glue dipping tank B at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a lower antistatic surface layer substrate;
(4) weighing the unsaturated polyester resin and the alkali-free glass fiber cloth according to the following parts by weight (the single weight is 450 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 40), graphene oxide (the number of layers is 7), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered substances into a container, and mixing the substances for 20min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank C;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank C at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue by a glue scraping device, and adjusting the tension of the scraped glue to obtain an upper flame retardant structure layer substrate;
(5) weighing unsaturated polyester resin and alkali-free glass fiber cloth (the single weight is 225 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 60), graphene oxide (the number of layers is 11), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 10min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank D;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank D at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue through a glue scraping device, and adjusting the tension of the scraped glue to obtain a lower flame retardant structure layer substrate;
(6) weighing unsaturated polyester resin and glass fiber felt (the single weight is 600 g/m)2) Basic magnesium sulfate whisker (length-diameter ratio is 80), graphene oxide (the number of layers is 3), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 10min by using an electric stirrer to prepare an anti-seepage adhesive;
adding the anti-seepage glue into a glue dipping tank E;
enabling the glass fiber mat to pass through a glue dipping tank E at a certain speed, dipping the glass fiber mat in anti-seepage glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a base material of the anti-seepage structure layer;
(7) taking a PE film, laying the PE film on an operation table, laying a lower anti-static surface layer substrate on the film, laying a lower flame-retardant structure layer substrate on the lower anti-static surface layer substrate, laying an anti-seepage structure layer substrate on the lower flame-retardant structure layer substrate, laying a flame-retardant structure layer substrate on the anti-seepage structure layer substrate, laying an anti-static surface layer substrate on the upper flame-retardant structure layer substrate, slightly rolling by using a compression roller in each laying process to form a composite material plate, and covering another PE film on the composite material plate;
(9) placing the composite material plate with the upper surface and the lower surface both covered with the PE films on a press, carrying out die pressing at room temperature for 20min under the pressure of 1MPa, then heating to 80 ℃, carrying out die pressing under the pressure of 2MPa for 20min, heating to 100 ℃, and carrying out die pressing under the pressure of 10MPa for 60 min;
(10) and opening the press, and uncovering the PE films on the upper surface and the lower surface of the composite material plate to obtain the flame-retardant anti-static composite material plate.
Example 6:
(1) weighing phosphoric acid, pentaerythritol and aniline according to the following parts by weight:
phosphoric acid 15
Pentaerythritol 13
Aniline 9;
placing phosphoric acid into a reaction vessel, preheating for 15min at 100 ℃, slowly adding pentaerythritol, reacting for 3h at 100 ℃, adding 30 parts by weight of aqueous solution, slowly adding aniline, continuing to react for 5h at 100 ℃, cooling to room temperature, filtering, removing filtrate to obtain solid filtrate, washing the solid filtrate for 3 times by using 50 parts by weight of ethanol, washing off redundant aniline and pentaerythritol, performing suction filtration again, drying, and crushing to obtain the nitrogen-phosphorus compound flame retardant with the particle size of 1.5 mu m.
(2) Weighing unsaturated polyester resin and polyester surface felt (the single weight is 30 g/m)2) Graphene oxide (the number of layers is 3), nano silver powder (the particle size is 80nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 15min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank A;
enabling the polyester surface felt to pass through a glue dipping tank A at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain an upper antistatic surface layer substrate;
(3) weighing unsaturated polyester resin and polyester surface felt (the single weight is 30 g/m)2) Graphene oxide (7 layers), silver nanopowder (50 nm in particle size), cobalt naphthoate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing for 20min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank B;
enabling the polyester surface felt to pass through a glue dipping tank B at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a lower antistatic surface layer substrate;
(4) weighing unsaturated polyester resin and alkali-free glass fiber cloth (the single weight is 225 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 60), graphene oxide (the number of layers is 11), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 10min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank C;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank C at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue by a glue scraping device, and adjusting the tension of the scraped glue to obtain an upper flame retardant structure layer substrate;
(5) weighing unsaturated polyester resin and alkali-free glass fiber cloth (the single weight is 300 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 60), graphene oxide (the number of layers is 3), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered substances into a container, and mixing the substances for 20min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank D;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank D at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue through a glue scraping device, and adjusting the tension of the scraped glue to obtain a lower flame retardant structure layer substrate;
(6) weighing unsaturated polyester resin and glass fiber felt (the single weight is 900 g/m)2) Basic magnesium sulfate whisker (length-diameter ratio is 60), graphene oxide (the number of layers is 11), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 15min by using an electric stirrer to prepare an anti-seepage adhesive;
adding the anti-seepage glue into a glue dipping tank E;
enabling the glass fiber mat to pass through a glue dipping tank E at a certain speed, dipping the glass fiber mat in anti-seepage glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a base material of the anti-seepage structure layer;
(7) taking a PE film, laying the PE film on an operation table, laying a lower anti-static surface layer substrate on the film, laying a lower flame-retardant structure layer substrate on the lower anti-static surface layer substrate, laying an anti-seepage structure layer substrate on the lower flame-retardant structure layer substrate, laying a flame-retardant structure layer substrate on the anti-seepage structure layer substrate, laying an anti-static surface layer substrate on the upper flame-retardant structure layer substrate, slightly rolling by using a compression roller in each laying process to form a composite material plate, and covering another PE film on the composite material plate;
(9) placing the composite material plate with the upper surface and the lower surface both covered with the PE films on a press, adopting the pressure of 0.8MPa to mold for 10min at room temperature, then heating to 80 ℃, adopting the pressure of 3MPa to mold for 10min, then heating to 100 ℃, and adopting the pressure of 12MPa to mold for 45 min;
(10) and opening the press, and uncovering the PE films on the upper surface and the lower surface of the composite material plate to obtain the flame-retardant anti-static composite material plate.
Example 7:
(1) weighing phosphoric acid, pentaerythritol and aniline according to the following parts by weight:
phosphoric acid 18
Pentaerythritol 15
Aniline 10;
placing phosphoric acid into a reaction vessel, preheating for 12min at 100 ℃, slowly adding pentaerythritol, reacting for 2.3h at 100 ℃, adding 24 parts by weight of aqueous solution, slowly adding aniline, continuing to react for 3.5h at 100 ℃, cooling to room temperature, filtering, removing filtrate to obtain solid filtrate, washing the solid filtrate 3 times with 60 parts by weight of ethanol, washing off redundant aniline and pentaerythritol, performing suction filtration again, drying, and crushing to obtain the nitrogen-phosphorus compound flame retardant with the particle size of 0.8 mu m.
(2) Weighing unsaturated polyester resin and polyester surface felt (the single weight is 30 g/m)2) Graphene oxide (6 layers), silver nanopowder (particle size of 60nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing the materials for 17min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank A;
enabling the polyester surface felt to pass through a glue dipping tank A at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain an upper antistatic surface layer substrate;
(3) weighing unsaturated polyester resin and polyester surface felt (the single weight is 45 g/m)2) Graphene oxide (the number of layers is 4), silver nanopowder (the particle size is 30nm), cobalt naphthanate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthanate and methyl ethyl ketone peroxide into a container, and mixing the materials for 13min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank B;
enabling the polyester surface felt to pass through a glue dipping tank B at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a lower antistatic surface layer substrate;
(4) weighing unsaturated polyester resin and alkali-free glass fiber cloth (the single weight is 225 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 45), graphene oxide (the number of layers is 9), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered substances into a container, and mixing the substances for 16min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank C;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank C at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue by a glue scraping device, and adjusting the tension of the scraped glue to obtain an upper flame retardant structure layer substrate;
(5) weighing unsaturated polyester resin and alkali-free glass fiber cloth (the single weight is 300 g/m)2) The flame retardant comprises a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whiskers (the length-diameter ratio is 70), graphene oxide (the number of layers is 10), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 14min by using an electric stirrer to prepare a flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank D;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank D at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue through a glue scraping device, and adjusting the tension of the scraped glue to obtain a lower flame retardant structure layer substrate;
(6) weighing unsaturated polyester resin and glass fiber felt (the single weight is 900 g/m)2) Basic magnesium sulfate whisker (length-diameter ratio is 70), graphene oxide (the number of layers is 5), cobalt naphthenate and methyl ethyl ketone peroxide:
metering unsaturated polyester resin, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 13min by using an electric stirrer to prepare an anti-seepage adhesive;
adding the anti-seepage glue into a glue dipping tank E;
enabling the glass fiber mat to pass through a glue dipping tank E at a certain speed, dipping the glass fiber mat in anti-seepage glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a base material of the anti-seepage structure layer;
(7) taking a PE film, laying the PE film on an operation table, laying a lower anti-static surface layer substrate on the film, laying a lower flame-retardant structure layer substrate on the lower anti-static surface layer substrate, laying an anti-seepage structure layer substrate on the lower flame-retardant structure layer substrate, laying a flame-retardant structure layer substrate on the anti-seepage structure layer substrate, laying an anti-static surface layer substrate on the upper flame-retardant structure layer substrate, slightly rolling by using a compression roller in each laying process to form a composite material plate, and covering another PE film on the composite material plate;
(9) placing the composite material plate with the upper surface and the lower surface both covered with the PE films on a press, carrying out die pressing at room temperature for 17min under the pressure of 0.9MPa, then heating to 80 ℃, carrying out die pressing for 13min under the pressure of 2.4MPa, heating to 100 ℃, and carrying out die pressing for 50min under the pressure of 11 MPa;
(10) and opening the press, and uncovering the PE films on the upper surface and the lower surface of the composite material plate to obtain the flame-retardant anti-static composite material plate.
The following tests prove the effect of example 1 of the present invention, and the test results are as follows:
tensile strength: 48.12MPa, flexural Strength: 78.65MPa, LOI value: 27.2 (%), surface resistivity: 1.35X 108Ω;
The detection results of the other formulas of the graphene oxide, the basic magnesium sulfate whisker, the nitrogen-phosphorus compound flame retardant and the nano silver powder which are not added are the same as those of the plastic-wood composite material plate in the embodiment 1 of the invention:
tensile strength: 51.10MPa, flexural Strength: 76.62MPa, LOI value: 19.8 (%), surface resistivity: 4.77X 1010Ω。
The results show that the mechanical properties of the sample of the invention in example 1 are basically similar to those of the comparative sample, but the surface resistivity is reduced by 2 orders of magnitude compared with the comparative sample, the antistatic property is obviously improved, the limiting oxygen index LOI is improved from 19.8 (%) to 27.2 (%), and the flame retardant property is obviously improved.
Claims (9)
1. A flame-retardant antistatic composite material plate is characterized by comprising an upper antistatic surface layer, an upper flame-retardant structure layer, an impermeable structure layer, a lower flame-retardant structure layer and a lower antistatic surface layer, wherein the upper flame-retardant structure layer is positioned between the upper antistatic surface layer and the impermeable structure layer; the anti-seepage structure layer is positioned between the upper flame-retardant structure layer and the lower flame-retardant structure layer; the lower flame-retardant structural layer is positioned between the anti-seepage structural layer and the lower anti-static surface layer; the upper anti-static surface layer and the lower anti-static surface layer are compounded by unsaturated polyester resin, polyester surface felt, graphene oxide and nano silver powder, the adopted accelerant is cobalt naphthanate, and the initiator is methyl ethyl ketone peroxide; the upper flame-retardant structure layer and the lower flame-retardant structure layer are compounded by unsaturated polyester resin, alkali-free glass fiber cloth, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker and graphene oxide, the adopted accelerant is cobalt naphthanate, and the initiator is methyl ethyl ketone peroxide; the anti-seepage structure layer is formed by compounding unsaturated polyester resin, a glass fiber felt, basic magnesium sulfate whisker and graphene oxide, the adopted accelerant is cobalt naphthanate, and the initiator is methyl ethyl ketone peroxide.
2. The flame retardant antistatic composite material sheet as claimed in claim 1, wherein the polyester surfacing mat has a basis weight of 30g/m2Or 45g/m2One kind of (1).
3. The flame-retardant antistatic composite material plate as claimed in claim 1, wherein the graphene oxide is multilayer graphene, and the number of layers is 3-11.
4. The flame-retardant antistatic composite material plate as claimed in claim 1, wherein the nano silver powder has a particle size of 20 to 80 nm.
5. The flame-retardant antistatic composite material plate as claimed in claim 1, wherein the alkali-free glass fiber cloth has a basis weight of 225g/m2、300g/m2、450g/m2One kind of (1).
6. The flame-retardant antistatic composite material plate as claimed in claim 1, wherein the nitrogen-phosphorus compound flame retardant is prepared from phosphoric acid, pentaerythritol and aniline.
7. The flame-retardant antistatic composite material plate as claimed in claim 1, wherein the length-diameter ratio of the basic magnesium sulfate whiskers is 40-80.
8. The flame retardant antistatic composite material sheet as claimed in claim 1, wherein the glass fiber mat has a basis weight of 450g/m2、600g/m2Or 900g/m2One kind of (1).
9. The preparation method of the flame-retardant antistatic composite material plate as claimed in claim 1, which is characterized in that the preparation process comprises the following steps:
(1) weighing phosphoric acid, pentaerythritol and aniline according to the following parts by weight:
15-25% of phosphoric acid
13-16 parts of pentaerythritol
7-11 parts of aniline;
placing phosphoric acid into a reaction container, preheating for 10-20 min at 100 ℃, slowly adding pentaerythritol, reacting for 2-3 h at 100 ℃, adding 20-40 parts by weight of aqueous solution, slowly adding aniline, continuously reacting for 3-5 h at 100 ℃, cooling to room temperature, filtering, removing filtrate to obtain solid filtrate, washing the solid filtrate for 2-4 times with 50-100 parts by weight of ethanol, washing off redundant aniline and pentaerythritol, performing suction filtration and drying again, and crushing to obtain a nitrogen-phosphorus compound flame retardant with the particle size of 0.5-1.5 mu m;
(2) weighing unsaturated polyester resin, polyester surface felt, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide according to the following parts by weight:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide into a container, and mixing for 10-20 min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank A;
enabling the polyester surface felt to pass through a glue dipping tank A at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain an upper antistatic surface layer substrate;
(3) weighing unsaturated polyester resin, polyester surface felt, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide according to the following parts by weight:
metering unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide, adding the metered unsaturated polyester resin, graphene oxide, nano silver powder, cobalt naphthoate and methyl ethyl ketone peroxide into a container, and mixing for 10-20 min by using an electric stirrer to prepare the antistatic adhesive;
adding the antistatic adhesive into the impregnation tank B;
enabling the polyester surface felt to pass through a glue dipping tank B at a certain speed, dipping the polyester surface felt in antistatic glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a lower antistatic surface layer substrate;
(4) weighing unsaturated polyester resin, alkali-free glass fiber cloth, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide in parts by weight as follows:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered materials into a container, and mixing the materials for 10-20 min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank C;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank C at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue by a glue scraping device, and adjusting the tension of the scraped glue to obtain an upper flame retardant structure layer substrate;
(5) weighing unsaturated polyester resin, alkali-free glass fiber cloth, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide in parts by weight as follows:
metering unsaturated polyester resin, a nitrogen-phosphorus compound flame retardant, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding the metered materials into a container, and mixing the materials for 10-20 min by using an electric stirrer to prepare flame-retardant adhesive;
adding the flame-retardant glue into a glue dipping tank D;
enabling the alkali-free glass fiber cloth to pass through a glue dipping tank D at a certain speed, dipping the alkali-free glass fiber cloth in flame retardant glue, scraping the glue through a glue scraping device, and adjusting the tension of the scraped glue to obtain a lower flame retardant structure layer substrate;
(6) weighing unsaturated polyester resin, a glass fiber felt, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide in parts by weight as follows:
metering unsaturated polyester resin, basic magnesium sulfate whisker, graphene oxide, cobalt naphthenate and methyl ethyl ketone peroxide, adding into a container, and mixing for 10-20 min by using an electric stirrer to prepare an anti-seepage adhesive;
adding the anti-seepage glue into a glue dipping tank E;
enabling the glass fiber mat to pass through a glue dipping tank E at a certain speed, dipping the glass fiber mat in anti-seepage glue, scraping the glue by a glue scraping device, and adjusting the tension of the glue scraping to obtain a base material of the anti-seepage structure layer;
(7) taking a PE film, laying the PE film on an operation table, laying a lower anti-static surface layer substrate on the film, laying a lower flame-retardant structure layer substrate on the lower anti-static surface layer substrate, laying an anti-seepage structure layer substrate on the lower flame-retardant structure layer substrate, laying a flame-retardant structure layer substrate on the anti-seepage structure layer substrate, laying an anti-static surface layer substrate on the upper flame-retardant structure layer substrate, slightly rolling by using a compression roller in each laying process to form a composite material plate, and covering another PE film on the composite material plate;
(9) placing the composite material plate with the upper surface and the lower surface both covered with the PE films on a press, performing die pressing at room temperature for 10-20 min under the pressure of 0.8-1.2 MPa, then heating to 80 ℃, performing die pressing for 10-30 min under the pressure of 2-4 MPa, heating to 100 ℃, and performing die pressing for 30-60 min under the pressure of 8-12 MPa;
(10) and opening the press, and uncovering the PE films on the upper surface and the lower surface of the composite material plate to obtain the flame-retardant anti-static composite material plate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810838567.4A CN109228563B (en) | 2018-07-25 | 2018-07-25 | Flame-retardant anti-static composite material plate and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810838567.4A CN109228563B (en) | 2018-07-25 | 2018-07-25 | Flame-retardant anti-static composite material plate and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109228563A CN109228563A (en) | 2019-01-18 |
CN109228563B true CN109228563B (en) | 2021-03-02 |
Family
ID=65073084
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810838567.4A Active CN109228563B (en) | 2018-07-25 | 2018-07-25 | Flame-retardant anti-static composite material plate and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109228563B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110903746A (en) * | 2019-05-10 | 2020-03-24 | 扬州润友复合材料有限公司 | Graphene modified unsaturated polyester resin adhesive and preparation method thereof |
CN111560160A (en) * | 2019-06-11 | 2020-08-21 | 南京林业大学 | Antibacterial unsaturated polyester resin adhesive and preparation method thereof |
CN111734077B (en) * | 2020-07-02 | 2021-07-30 | 安徽可尔海思塑业有限公司 | Waterproof floor capable of preventing harmful free substances from diffusing and production process thereof |
CN112339300A (en) * | 2020-10-19 | 2021-02-09 | 天长市蓝天复合材料有限公司 | Continuous molding method for multi-cavity hollow plate |
CN114439186B (en) * | 2022-02-21 | 2023-07-18 | 南京林业大学 | Surface non-inflammable composite material plate and manufacturing method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201460138U (en) * | 2009-07-03 | 2010-05-12 | 北京中铁长龙新型复合材料有限公司 | Moveable sandwich anti-static floorboard of composite material |
CN101792674A (en) * | 2010-03-19 | 2010-08-04 | 大连理工大学 | Method for preparing nitrogen-phosphorus-magnesium compound fire retardant |
CN106084705A (en) * | 2016-06-09 | 2016-11-09 | 扬州润友复合材料有限公司 | A kind of high intensity antistatic composite material sheet material and preparation method thereof |
CN106827735A (en) * | 2017-02-06 | 2017-06-13 | 北京邦维高科特种纺织品有限责任公司 | A kind of fire-retardant electromagnetic shielding composite material of gas defence, preparation method and product |
-
2018
- 2018-07-25 CN CN201810838567.4A patent/CN109228563B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201460138U (en) * | 2009-07-03 | 2010-05-12 | 北京中铁长龙新型复合材料有限公司 | Moveable sandwich anti-static floorboard of composite material |
CN101792674A (en) * | 2010-03-19 | 2010-08-04 | 大连理工大学 | Method for preparing nitrogen-phosphorus-magnesium compound fire retardant |
CN106084705A (en) * | 2016-06-09 | 2016-11-09 | 扬州润友复合材料有限公司 | A kind of high intensity antistatic composite material sheet material and preparation method thereof |
CN106827735A (en) * | 2017-02-06 | 2017-06-13 | 北京邦维高科特种纺织品有限责任公司 | A kind of fire-retardant electromagnetic shielding composite material of gas defence, preparation method and product |
Also Published As
Publication number | Publication date |
---|---|
CN109228563A (en) | 2019-01-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN109228563B (en) | Flame-retardant anti-static composite material plate and preparation method thereof | |
EP1318907B1 (en) | Layered composite material comprising various pre-hardened resin layers | |
US3637578A (en) | Polyester-polyphenylene ether mixed resins | |
US3684616A (en) | Method of producing laminates from mixed thermosetting resin compositions containing polyphenylene ethers | |
CN103320041A (en) | Environmentally-friendly adhesive tape for gypsum boards | |
CN109593297A (en) | A kind of co-extrusion halogen-free flame-retardant wood moulding material and preparation method thereof | |
CN111635181B (en) | Fiber cement board for floor and preparation method and application thereof | |
KR101947743B1 (en) | Method for Manufacturing Incombustible Fiberglass Reinforced Plastic for outlet duct and pipe of in factory of manufacturing semiconductor | |
WO2019211862A1 (en) | High performance glossy finish green hybrid composites with variable density and an improved process for making thereof | |
CN105367008A (en) | Emulsifier-free styrene-acrylic emulsion polymer concrete and preparation method thereof | |
JPH07117027A (en) | Manufacture of inorganic multilayered molded matter | |
Zhu et al. | Filter‐through method of making highly efficient polymer‐clay nanocomposite membranes | |
CN1978189A (en) | Polymer composite material board and preparing method | |
CN107662253A (en) | A kind of fiber reinforcement orients wood-plastic composite particleboard | |
CN108752034B (en) | Preparation method of fiber-reinforced modified foaming cement insulation board | |
CN113174233B (en) | Anti-static aldehyde-free adhesive and preparation method and application thereof | |
KR101838848B1 (en) | Epoxy Resin Compositions for Bulk Mold Compound Dispersed Carbon Nano Tube | |
TW201934332A (en) | Intermediate film for laminated glass, rolled body, and laminated glass | |
JP7425732B2 (en) | Carbon fiber sheet material, prepreg, molded body, method for manufacturing carbon fiber sheet material, method for manufacturing prepreg, and method for manufacturing molded body | |
CN112094490B (en) | Carbon dioxide-cyclohexene oxide copolymer composite material and preparation method thereof | |
JPS61256955A (en) | Lightweight composite material composition | |
CN219583674U (en) | Fireproof core material with gridding cloth | |
Rout | Fabrication of transesterified cured coir reinforced composites and evaluation of their properties | |
CN115637825A (en) | Glass magnesium polymer composite board and preparation method thereof | |
WO2012040932A1 (en) | Board made from powders of waste electronic circuit board and manufacturing process thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210526 Address after: 225811 west head of Erqiao, Chengxi industrial concentration area, Baoying County, Yangzhou City, Jiangsu Province Patentee after: YANGZHOU RUNYOU COMPOSITE MATERIAL Co.,Ltd. Address before: College of science, Nanjing Forestry University, 159 Longpan Road, Nanjing, Jiangsu, 210037 Patentee before: NANJING FORESTRY University |