CN109207214A - A kind of gasoline additive of environment-friendly type and preparation method thereof - Google Patents
A kind of gasoline additive of environment-friendly type and preparation method thereof Download PDFInfo
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- CN109207214A CN109207214A CN201811321078.8A CN201811321078A CN109207214A CN 109207214 A CN109207214 A CN 109207214A CN 201811321078 A CN201811321078 A CN 201811321078A CN 109207214 A CN109207214 A CN 109207214A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
- C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/301—Organic compounds compounds not mentioned before (complexes) derived from metals
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
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- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention belongs to chemical technology fields, and in particular to a kind of gasoline additive of environment-friendly type and preparation method thereof, the raw material including following parts by weight: 40-45 parts of methanol；40-45 parts of ethyl alcohol；5-8 parts of cosolvent；0.3-0.6 parts of ferrocene；0.2-0.4 parts of rare earth metal salt；0.01-0.05 parts of ethoxylated dodecyl alcohol；0.5-1.0 parts of corrosion inhibitor；0.5-1.0 parts of triethanolamine；3-7 parts of vegetable oil.The gasoline additive of the environment-friendly type being prepared of the invention, the gasoline additive has good Cress effect, it can promote full combustion of fuel, improve gasoline combustion efficiency, reduce oil consumption, the significant discharge for reducing black smoke and particulate matter, it effectively saves gas and oil and reduces exhaust emissions, reduce exhaust emission pollution, promote environmental protection, and it joined more methanol and ethyl alcohol in the gasoline additive, gasoline additive obtained, which is added in gasoline, can replace the fuel of a part to use, and not only can be reduced the cost of fuel, but also reduce the pollution to environment.
Description
Technical field
The invention belongs to chemical technology fields, and in particular to a kind of gasoline additive of environment-friendly type and preparation method thereof.
Background technique
Gasoline, appearance is transparency liquid, flammable, boiling range be 30 DEG C to 220 DEG C, main component be C5~C12 aliphatic hydrocarbon and
Cycloalkane and a certain amount of aromatic hydrocarbon.Direct steaming gasoline component that gasoline is obtained by petroleum refining, is urged at catalytically cracked gasoline component
Change the different gasoline components such as Reformed Gasoline component to be made with gasoline additive through reconciling after refining, is mainly used as automobile spark ignition type
The fuel of internal combustion engine.
It is a large amount of long-term studies have shown that fuel such as gasoline or diesel oil, are burnt in engine combustion room with extremely short moment,
It is discharged, not fully, remaining fuel is with the intermediate product that burns or even unburned is arranged for such fuel combustion
Out, not only making the utilization rate of fuel in this way reduces, and can also make a large amount of pernicious gas, as hydrocarbon and fuel oil are incomplete
The intermediate product of burning is discharged into air, pollutes environment.And additive is introduced in fuel oil and is drawn with improving fuel oil in internal combustion engine
The method for holding up efficiency of combustion in combustion chamber has been widely developed and has applied." the combustion of gasoline additive i.e. commercial type
Oily treasured ", also referred to as fuel oil additive, economizing additive, gasoline cleaning agent etc..Briefly, gasoline additive is for " energy conservation
A kind of substance that the purpose of emission reduction " is added into vehicle fuel." energy conservation " saves the consumption of gasoline, improves the flammability of gasoline
Can, so that the mileage number for consuming a certain amount of gasoline traveling under automobile square one increases." emission reduction " reduces harmful substance
Discharge, be still through gasoline additive and reduce the burn incompletely of fuel oil so that in carbon distribution, tail gas harmful substance content
It is reduced Deng corresponding.Some development tests show that automobile after using fuel oil additive, can accordingly reduce one in its service life
Ton or more related exhaust gas (hydrocarbon oxide, carbon monoxide and nitrogen oxides etc.).
The main function of gasoline additive includes: decarbonizing, clean fuel oil system；Enhance power performance；Improve atomization,
Save fuel oil；Anti-corrosion, antirust, lubrication protect engine；Noise is reduced, abrasion is reduced, extends engine life；Eliminate black smoke, drop
Low emission etc..But it is some studies have shown that certain gasoline additives may stability to gasoline, combustion heat value cause it is bad
It influences.Although having a plurality of types of fuel oil additives on the market to exist, existing fuel oil additive effect is relatively simple, though
The combustibility of fuel oil can so be improved to a certain extent, but imitated in terms of the discharge for improving engine power, reduction exhaust gas
Fruit is unobvious, and the practical rate of economizing gasoline of appearance is not high, and removing black smoke is undesirable, is promoting oil quality and is improving the function of efficiency of combustion
Situations such as aspect is undesirable；Existing gasoline additive contains more toxic component, after gasoline combustion, still there is a large amount of pernicious gases
Discharge, and oil-saving effect is unobvious.Therefore the energy saving and environment friendly fuel oil additive of exploitation high-efficiency and economic is still that market is badly in need of
's.
Summary of the invention
The object of the present invention is to provide gasoline additive of a kind of environment-friendly type and preparation method thereof, which has
Good Cress effect, can promote full combustion of fuel, improve gasoline combustion efficiency, and reduction oil consumption, significant reduction are black
The discharge of cigarette and particulate matter effectively saves gas and oil and reduces exhaust emissions, reduce exhaust emission pollution, promotes environmental protection, and
It joined more methanol and ethyl alcohol in the gasoline additive, gasoline additive obtained, which is added in gasoline, can replace a part
Fuel use, not only can be reduced fuel cost, but also reduce the pollution to environment.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of gasoline additive of environment-friendly type, the raw material including following parts by weight:
40-45 parts of methanol；
40-45 parts of ethyl alcohol；
5-8 parts of cosolvent；
0.3-0.6 parts of ferrocene；
0.2-0.4 parts of rare earth metal salt；
0.01-0.05 parts of ethoxylated dodecyl alcohol；
0.5-1.0 parts of corrosion inhibitor；
0.5-1.0 parts of triethanolamine；
3-7 parts of vegetable oil.
In the gasoline additive of above-mentioned environment-friendly type, the cosolvent is one of petroleum ether, ether and hexamethylene
Or it is a variety of.
In the gasoline additive of above-mentioned environment-friendly type, the rare earth metal salt is cerium naphthenate, cerium stearate or cycloalkanes
The mixture of sour cerium and cerium stearate.
In the gasoline additive of above-mentioned environment-friendly type, the corrosion inhibitor is methyl benzoate, methyl isobutyrate, 2,4
One or both of diisopropyl phenol, cyclohexylamine and inositol hexaphosphate.
In the gasoline additive of above-mentioned environment-friendly type, the vegetable oil be rapeseed oil, peanut oil, eucalyptus citriodora oil, corn oil,
One of coconut oil, castor oil, cottonseed oil, tea-seed oil and soybean oil are a variety of.
The gasoline additive of the environment-friendly type, preparation method are as follows: according to parts by weight by methanol, ethyl alcohol, cosolvent
, ferrocene, rare earth metal salt, ethoxylated dodecyl alcohol, corrosion inhibitor, triethanolamine and vegetable oil be uniformly mixed, with stirring
Mix device high shear agitation 15 minutes~20 minutes gasoline additives to get environment-friendly type.
The gasoline additive for the environment-friendly type that the present invention is prepared, the gasoline additive are added in gasoline, gasoline addition
Agent: the volume ratio of gasoline is 5-6:4.
Used ferrocene is a kind of organo-transition metal compound with aromatic nature in the present invention, has height
Degree thermal stability, chemical stability and radiation resistance, ferrocene can be used as the anti-knock agent and rubber of rocket fuel additive, gasoline
And the curing agent of silicone resin, ultraviolet absorbing agent can also be made.Ferrocene and its derivative is added to solid, liquid or gas combustion
In material, can play that its is combustion-supporting, eliminates smoke and the effects of antiknock, especially to burning when generate the hydro carbons of volume of smoke, effect is more
It is significant.Ferrocene is added in boiler oil, can reduce generation and the carbon trumpet of cigarette, can also mix make in coal dust it is combustion-supporting
Subtract fumicants use.In addition, ferrocene is added in motive power machine fuel, the carbon deposit of combustion chamber can be made to reduce, to reduce flue dust
Pollution to atmosphere.The ferrocene being added in the present invention can improve the anti-knock properties of gasoline, and can play and reduce nozzle product
Carbon and combustion-supporting effect.
Rare earth metal salt used in the present invention is the mixed of cerium naphthenate, cerium stearate or cerium naphthenate and cerium stearate
Close object.Rare earth element has energy level abundant and special 4f outer shell structure, by the way that rare earth metal salt is added, can reduce
The activation energy of fuel molecule C-H bond is allowed to accelerate full combustion, to be significantly reduced carbon monoxide, nitrogen oxides and black
The discharge of cigarette especially has more obvious effect to the full combustion of heavy oil.
Corrosion inhibitor used in the present invention be methyl benzoate, methyl isobutyrate, 2,4 diisopropyl phenols, cyclohexylamine and
One or both of inositol hexaphosphate.These substances all have an effect of corrosion inhibition, and there are substances to starting in gasoline
Many metal protections of machine fuel system can corrode copper, iron, aluminium, lead, magnesium and their many alloys, and corrosion is added
Inhibitor and metal surface strong effect generate chemically and physically suction-operated, form good protective film, to a certain extent
Contact of the corrosive deposit with metalwork has been isolated, has achieved the purpose that inhibit corrosion, protects engine fuel system, extend and use the longevity
Life.
On the one hand the lubricity and abrasion resistance of gasoline can be greatly improved in the vegetable oil being added in the present invention, improve
Viscosity and enhancing activity, achieve the purpose that save fuel oil.
Ethoxylated dodecyl alcohol used in the present invention, molecular formula are C58H118O24, have excellent washing, emulsification,
The functions such as dispersion, wetting, solubilising, and foaming power is strong, easily rinses, detergency is excellent；It is in surfactant to skin irritation
One of minimum kind.It can reduce their irritation, improve the performance of product with various surfactant compounds.This hair
It is added with ethoxylated dodecyl alcohol in bright, the carbon distribution formed after gasoline combustion can be removed, extend the service life of engine.
Used triethanolamine in the present invention, to be colourless to pale yellow transparent thick liquid, micro- have an ammonia taste, when low temperature at
For colourless to faint yellow cubic system crystal.Color deepens gradually when being placed in air, can absorbing carbon dioxide and hydrogen sulfide
Equal sour gas.Triethanolamine can be used as fibre finish, anticorrosive additive, plasticizer, photographic process solution additive, engine
Carbon distribution preventing agent etc..Also serve as point of plasticizer, neutralizer, lubricant additive or anticorrosive and dyestuff, resin etc.
Powder and synthetic surfactant, stabilizer etc..Triethanolamine is added in the present invention can reduce the nitrogen oxygen in exhaust emission
Compound guarantees the cleaning of oil piping system, removes carbon on engine.
The primary raw material of methanol and ethyl alcohol as gasoline additive is used in the present invention, it being capable of generation after being added in gasoline
For the Fuel Petroleum of part, so as to effectively save raw material, and methanol and ethyl alcohol source are very extensive, can use coal, natural
Gas or other raw materials produce；Oxygen content is higher, and burning is abundant, the pernicious gas that can be effectively reduced in tail gas, while
The carbon deposit for effectively reducing fuel system extends the service life of engine；Have the function of more satisfactory oil circuit dredging, it can
Reduce the use of cleaning oil piping system additive.With splendid cooling effect, high antiknock when methanol is used as fuel
Ability with burning thoroughly, the advantages such as volatility is low, engine temperature can be reduced, will not be overheated, premium can be higher than
The combusting under pressure allowed is without pinking, this is just being suitble to high compression ratio, high performance engine to need, and institute after burning
The pernicious gases such as hydrocarbon, nitrogen oxide and the carbon monoxide of discharge are few.And also add in additive prepared by the present invention
Cosolvent is entered, the cosolvent of addition can be improved intersolubility and swellability between methanol, ethyl alcohol and gasoline, can effectively promote
Into dissolving each other for gasoline and alcohols material, the gasoline additive of addition and the intersolubility of gasoline are good, will not generate gasoline and methanol
Lamination.
The invention has the benefit that
1, the corrosion that the gasoline additive that the present invention is prepared can reduce gasoline to engine metal after being added in gasoline
Property, the present invention is added in Fuel Petroleum, can replace the Fuel Petroleum of part, so as to effectively save raw material, reduce
Cost, and the efficiency of combustion of fuel can be improved, mitigate environmental pollution.The additive is added in gasoline, with dissolving each other for gasoline
Property is good, will not generate the lamination of gasoline and methanol.
2, the gasoline additive for the environment-friendly type that the present invention is prepared, preparation process is simple, at low cost, vapour of the present invention
Each component used in oil additive cooperates, and mutually cooperates with, and can significantly improve the octane number of gasoline, and it is anti-to improve gasoline
Quick-fried performance, which, which is added in gasoline, can effectively promote gasoline quality, improve gasoline combustion efficiency, promote fuel
Full combustion reduces oil consumption, reduces carbon deposit in engine cylinder body, improves engine power performance, extends the service life of gasoline engine,
The discharge for reducing motor exhaust harmful substance, substantially reduces the discharge of black smoke and particulate matter, effectively saves gasoline and reduces tail
Gas discharge reduces exhaust emission pollution, reduces discharge of poisonous waste amount, promotes environmental protection.It is added using the energy-saving environmental-protection petrol
The rear vehicle of agent is easy in starting up, and speed-raising performance is good, and tail gas black smoke significantly reduces, and oil-saving effect is obvious, has apparent economic effect
Benefit and social benefit.
Specific embodiment
Embodiment 1
A kind of gasoline additive of environment-friendly type, the raw material including following parts by weight:
40 parts of methanol；40 parts of ethyl alcohol；5 parts of cosolvent petroleum ether；0.3 part of ferrocene；0.2 part of cerium naphthenate；Laruyl alcohol polyoxy second
0.01 part of alkene ether；0.5 part of corrosion inhibitor methyl benzoate；0.5 part of triethanolamine；3 parts of rapeseed oil；
The gasoline additive of the environment-friendly type, preparation method are as follows: according to parts by weight by methanol, ethyl alcohol, cosolvent petroleum
Ether, ferrocene, cerium naphthenate, ethoxylated dodecyl alcohol, corrosion inhibitor methyl benzoate, triethanolamine and rapeseed oil are mixed
It closes uniformly, with the blender high shear agitation 15 minutes gasoline additives to get environment-friendly type.
Embodiment 2
A kind of gasoline additive of environment-friendly type, the raw material including following parts by weight:
42 parts of methanol；43 parts of ethyl alcohol；6 parts of cosolvent ether；0.4 part of ferrocene；0.3 part of cerium stearate；Lauryl alcohol polyethylene glycol oxide
0.03 part of ether；0.7 part of methyl isobutyrate；0.7 part of triethanolamine；5 parts of castor oil；
The gasoline additive of the environment-friendly type, preparation method are as follows: according to parts by weight by methanol, ethyl alcohol, cosolvent ether
, ferrocene, cerium stearate, ethoxylated dodecyl alcohol, methyl isobutyrate, triethanolamine and castor oil be uniformly mixed, with stirring
Mix the device high shear agitation 18 minutes gasoline additives to get environment-friendly type.
Embodiment 3
A kind of gasoline additive of environment-friendly type, the raw material including following parts by weight:
45 parts of methanol；45 parts of ethyl alcohol；8 parts of cosolvent hexamethylene；0.6 part of ferrocene；0.4 part of rare earth metal salt；Laruyl alcohol polyoxy
0.05 part of vinethene；1.0 parts of corrosion inhibitor；1.0 parts of triethanolamine；7 parts of vegetable oil；The rare earth metal salt be cerium naphthenate and
The mixture of cerium stearate；The corrosion inhibitor is the mixture of 2,4 diisopropyl phenols and inositol hexaphosphate；The plant
Object oil is the mixture of peanut oil and eucalyptus citriodora oil；
The gasoline additive of the environment-friendly type, preparation method are as follows: according to parts by weight by methanol, ethyl alcohol, cosolvent hexamethylene
Alkane, ferrocene, rare earth metal salt, ethoxylated dodecyl alcohol, corrosion inhibitor, triethanolamine and vegetable oil are uniformly mixed, and are used
The blender high shear agitation 20 minutes gasoline additives to get environment-friendly type.
Embodiment 4
A kind of gasoline additive of environment-friendly type, the raw material including following parts by weight:
40 parts of methanol；45 parts of ethyl alcohol；5 parts of cosolvent；0.6 part of ferrocene；0.2 part of rare earth metal salt；Ethoxylated dodecyl alcohol
0.05 part；0.5 part of corrosion inhibitor；1.0 parts of triethanolamine；3 parts of vegetable oil；The cosolvent is the mixed of petroleum ether and ether
Close object；The rare earth metal salt is cerium naphthenate；The corrosion inhibitor is the mixture of methyl benzoate and cyclohexylamine；It is described
Vegetable oil is the mixture of corn oil, coconut oil and castor oil；
The gasoline additive of the environment-friendly type, preparation method are as follows: according to parts by weight by methanol, ethyl alcohol, cosolvent, two cyclopentadienyls
Iron, rare earth metal salt, ethoxylated dodecyl alcohol, corrosion inhibitor, triethanolamine and vegetable oil are uniformly mixed, and use blender
The high shear agitation 15 minutes gasoline additives to get environment-friendly type.
Embodiment 5
A kind of gasoline additive of environment-friendly type, the raw material including following parts by weight:
45 parts of methanol；40 parts of ethyl alcohol；8 parts of cosolvent；0.3 part of ferrocene；0.4 part of rare earth metal salt；Ethoxylated dodecyl alcohol
0.01 part；1.0 parts of corrosion inhibitor；0.5 part of triethanolamine；7 parts of vegetable oil；The cosolvent is petroleum ether, ether and hexamethylene
The mixture of alkane；The rare earth metal salt is cerium stearate；The corrosion inhibitor is the mixed of cyclohexylamine and inositol hexaphosphate
Close object；The vegetable oil is the mixture of cottonseed oil, tea-seed oil and soybean oil；
The gasoline additive of the environment-friendly type, preparation method are as follows: according to parts by weight by methanol, ethyl alcohol, cosolvent, two cyclopentadienyls
Iron, rare earth metal salt, ethoxylated dodecyl alcohol, corrosion inhibitor, triethanolamine and vegetable oil are uniformly mixed, and use blender
The high shear agitation 17 minutes gasoline additives to get environment-friendly type.
Embodiment 6
A kind of gasoline additive of environment-friendly type, the raw material including following parts by weight:
43 parts of methanol；42 parts of ethyl alcohol；6 parts of cosolvent petroleum ether；0.4 part of ferrocene；0.3 part of rare earth metal salt；Laruyl alcohol polyoxy
0.04 part of vinethene；0.8 part of corrosion inhibitor；0.8 part of triethanolamine；6 parts of vegetable oil；
The rare earth metal salt is the mixture of cerium naphthenate and cerium stearate；The corrosion inhibitor be methyl isobutyrate and 2,
The mixture of 4 diisopropyl phenols；The vegetable oil be rapeseed oil, peanut oil, eucalyptus citriodora oil, corn oil, coconut oil, castor oil,
One of cottonseed oil, tea-seed oil and soybean oil are a variety of.
The gasoline additive of the environment-friendly type, preparation method are as follows: according to parts by weight by methanol, ethyl alcohol, cosolvent,
Ferrocene, rare earth metal salt, ethoxylated dodecyl alcohol, corrosion inhibitor, triethanolamine and vegetable oil are uniformly mixed, with stirring
Mix the device high shear agitation 20 minutes gasoline additives to get environment-friendly type.
Effect test:
(1) according to standard GB18285-2005 spark-ignition engine automobile exhaust pollutant discharge limit value and measurement method, to making
It is detected with gasoline additive of the present invention and the automobile that gasoline additive of the invention is not used,
(2) specifically: automobile 1.: use regular gasoline；Automobile is 2.: using the vapour for being added to the embodiment of the present invention 3 and being prepared
The gasoline of oil additive, the gasoline additive are added in gasoline, gasoline additive: the volume ratio of gasoline is 6:4；Automobile 1. and
The other conditions of automobile 2. are the same.
(3) environmental parameter when detecting: detection temperature: 23.6 DEG C, atmospheric pressure (kpa): 100.2；Relative humidity (%):
59.7%。
(4) survey result is connect:
The spark-ignition engine automobile Double idle state method exhaust contaminant examining report result of automobile 1. is as shown in table 1 below:
The spark-ignition engine automobile Double idle state method exhaust contaminant examining report result of automobile 2. is as shown in table 2 below:
From in the result of above-mentioned Tables 1 and 2 it is found that in all identical situation of other conditions, with the automobile for using regular gasoline
It compares, has passed through detection using the automobile for the gasoline for being added to gasoline additive of the present invention, it is seen then that the vapour that the present invention is prepared
Oil additive can be efficiently modified the quality of gasoline, reduce the discharge of motor exhaust harmful substance, significant reduction black smoke and particle
The discharge of object effectively saves gasoline and reduces exhaust emissions, reduces exhaust emission pollution, promote environmental protection.
Claims (7)
1. a kind of gasoline additive of environment-friendly type, which is characterized in that the raw material including following parts by weight:
40-45 parts of methanol；
40-45 parts of ethyl alcohol；
5-8 parts of cosolvent；
0.3-0.6 parts of ferrocene；
0.2-0.4 parts of rare earth metal salt；
0.01-0.05 parts of ethoxylated dodecyl alcohol；
0.5-1.0 parts of corrosion inhibitor；
0.5-1.0 parts of triethanolamine；
3-7 parts of vegetable oil.
2. the gasoline additive of environment-friendly type according to claim 1, which is characterized in that the cosolvent be petroleum ether,
One of ether and hexamethylene are a variety of.
3. the gasoline additive of environment-friendly type according to claim 1, which is characterized in that the rare earth metal salt is aphthenic acids
The mixture of cerium, cerium stearate or cerium naphthenate and cerium stearate.
4. the gasoline additive of environment-friendly type according to claim 1, which is characterized in that the corrosion inhibitor is benzoic acid
Methyl esters, methyl isobutyrate, 2, one or both of 4 diisopropyl phenols, cyclohexylamine and inositol hexaphosphate.
5. the gasoline additive of environment-friendly type according to claim 1, which is characterized in that the vegetable oil is rapeseed oil, flower
One of oil generation, eucalyptus citriodora oil, corn oil, coconut oil, castor oil, cottonseed oil, tea-seed oil and soybean oil are a variety of.
6. the gasoline additive of environment-friendly type according to claim 1, which is characterized in that preparation method are as follows: according to weight
Number is by methanol, ethyl alcohol, cosolvent, ferrocene, rare earth metal salt, ethoxylated dodecyl alcohol, corrosion inhibitor, triethanolamine
And vegetable oil is uniformly mixed, with 15 minutes~20 minutes gasoline additives to get environment-friendly type of blender high shear agitation.
7. the gasoline additive of environment-friendly type according to claim 1, which is characterized in that the gasoline additive is added to gasoline
In, gasoline additive: the volume ratio of gasoline is 6:4.
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| CN201811321078.8A CN109207214A (en) | 2018-11-07 | 2018-11-07 | A kind of gasoline additive of environment-friendly type and preparation method thereof |
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| CN201811321078.8A CN109207214A (en) | 2018-11-07 | 2018-11-07 | A kind of gasoline additive of environment-friendly type and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN111298841A (en) * | 2020-02-28 | 2020-06-19 | 威县厚德汽车配件有限公司 | Catalyst for water decomposition on board and method of using the same |
| CN111635794A (en) * | 2020-05-27 | 2020-09-08 | 上海中太行之光能源有限公司 | Cleaning agent for diesel fuel system and preparation method thereof |
| CN113088348A (en) * | 2021-04-09 | 2021-07-09 | 重庆邑丰新能源有限公司 | Industrial modified methanol fuel and preparation method thereof |
| CN114058414A (en) * | 2021-11-22 | 2022-02-18 | 上海中尖实业(集团)有限公司 | Environment-friendly gasoline additive and preparation method thereof |
| CN115558531A (en) * | 2022-10-17 | 2023-01-03 | 湖北省中垚新能源科技有限公司 | Petroleum additive |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396438A (en) * | 2019-08-16 | 2019-11-01 | 鸿源新能源科技(广州)有限公司 | A kind of emission reduction type additive for diesel and gasoline and preparation method thereof |
| CN111298841A (en) * | 2020-02-28 | 2020-06-19 | 威县厚德汽车配件有限公司 | Catalyst for water decomposition on board and method of using the same |
| CN111635794A (en) * | 2020-05-27 | 2020-09-08 | 上海中太行之光能源有限公司 | Cleaning agent for diesel fuel system and preparation method thereof |
| CN113088348A (en) * | 2021-04-09 | 2021-07-09 | 重庆邑丰新能源有限公司 | Industrial modified methanol fuel and preparation method thereof |
| CN114058414A (en) * | 2021-11-22 | 2022-02-18 | 上海中尖实业(集团)有限公司 | Environment-friendly gasoline additive and preparation method thereof |
| CN115558531A (en) * | 2022-10-17 | 2023-01-03 | 湖北省中垚新能源科技有限公司 | Petroleum additive |
| CN115558531B (en) * | 2022-10-17 | 2023-11-10 | 西尼尔(山东)新材料科技有限公司 | Petroleum aid |
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