CN109206767A - A kind of TPR flexible glue insole and its manufacturing method - Google Patents

A kind of TPR flexible glue insole and its manufacturing method Download PDF

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Publication number
CN109206767A
CN109206767A CN201810950285.3A CN201810950285A CN109206767A CN 109206767 A CN109206767 A CN 109206767A CN 201810950285 A CN201810950285 A CN 201810950285A CN 109206767 A CN109206767 A CN 109206767A
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China
Prior art keywords
parts
insole
layer
raw material
flexible glue
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CN201810950285.3A
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Chinese (zh)
Inventor
沈德山
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Yangzhou Lang Jin Plastic Industry Co Ltd
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Yangzhou Lang Jin Plastic Industry Co Ltd
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Priority to CN201810950285.3A priority Critical patent/CN109206767A/en
Publication of CN109206767A publication Critical patent/CN109206767A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
    • A43B17/003—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
    • A43B17/006—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material multilayered
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
    • A43B17/02—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined wedge-like or resilient
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B32B5/20—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material foamed in situ
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0221—Vinyl resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0242—Acrylic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/56—Damping, energy absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/758—Odour absorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • B32B2437/02—Gloves, shoes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The invention discloses a kind of TPR flexible glue insole and its manufacturing methods, including insole body layer, deodorization antibiotic layer and buffer layer, the insole body layer includes the raw material of following parts by weight: styrene-butadiene-copolymer, phenolic resin, ethylene-vinyl acetate copolymer, polystyrene, 2,6- three-level butyl -4- methylphenols, copper 8-quinolinolate etc., deodorization antibiotic layer includes the raw material of following parts by weight: film-forming resin etc., manufacturing method the following steps are included: S1, insole body layer processing；The processing of S2, deodorization antibiotic layer；The processing of S3, buffer layer；S4, the upper end that deodorization antibiotic layer is pasted onto insole body layer using adhesive, and buffer layer is pasted onto the lower end of insole body layer, TPR flexible glue insole can be obtained, the present invention is by being arranged deodorization antibiotic layer and lower end setting buffer layer in the upper end of TPR flexible glue insole, the deodorization antibacterial effect of TPR flexible glue insole and the function of damping can be improved, so that the using effect of TPR flexible glue insole is good.

Description

A kind of TPR flexible glue insole and its manufacturing method
Technical field
The present invention relates to insole production technical field more particularly to a kind of TPR flexible glue insole and its manufacturing methods.
Background technique
TPR material is widely used in everyday articles, Mature Audiences, hardware tool, luggage wheel, sports equipment, toy system Product, automobile parts, medical article, wire cable, electronic apparatus communicate instrument and footwear material product etc..Wherein footwear material and object for appreciation Have an industry, the mainly application field of the TPR of SBS substrate, be mainly used in using SEBS as the modified material of substrate it is ageing-resistant, it is resistance to Hou Xing, material property tensile strength require high, the ultralow products application of material hardness.People can usually generate during wearing shoes A large amount of foot sweat, and foot sweat is deposited in shoes, can generate foot odour, existing TPR flexible glue insole does not have suction in the market Sweat, degerming and the effect of damping, therefore, we have proposed a kind of TPR flexible glue insoles and its manufacturing method for solving above-mentioned ask Topic.
Summary of the invention
The purpose of the present invention is to solve TPR flexible glue insole exists in the prior art not have absorbing sweat, degerming The shortcomings that with the effect of damping, and a kind of TPR flexible glue insole and its manufacturing method proposed.
To achieve the goals above, present invention employs following technical solutions:
A kind of TPR flexible glue insole and its manufacturing method, including insole body layer, deodorization antibiotic layer and buffer layer, the insole Body layer includes the raw material of following parts by weight: 40-50 parts of styrene-butadiene-copolymer, 15-20 parts of phenolic resin, and ethyl vinyl acetate 12-16 parts of ethylene copolymer, 70-85 parts of polystyrene, 2,6- 3-8 parts of -4- methylphenol of three-level butyl, copper 8-quinolinolate 5- 7 parts, 2-3 parts of thioether of bis- (3,5- three-level butyl -4- hydroxy phenyls), 3-4 parts of dimethyl silicone polymer, 5-6 parts of fatty acid amide, 5-7 parts of zinc stearate, 1-2 parts of colorant, 3-5 parts of pigment dispersing agent, the deodorization antibiotic layer includes the raw material of following parts by weight: 32-35 parts of film-forming resin, 3-5 parts of macroporous absorbent resin, 2-3 parts of hydroxypropyl cellulose, 5-7 parts of 4- chloro- 3,5- dimethyl phenol, 1, 3-5 parts of 2- benzisothiazole-3-ketone, 4-7 parts of active carbon, 2-3 parts of zinc oxide, 3-4 parts of propandiol butyl ether, propylene glycol monomethyl ether vinegar 4-5 parts of acid esters, 1-2 parts of triethyltin chloride, 1-2 parts of phenyl mercury oleate, 2-3 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, The buffer layer is ethylene n-butyl acrylate polymer composition.
Preferably, the insole body layer includes the raw material of following parts by weight: 45 parts of styrene-butadiene-copolymer, phenolic aldehyde tree 18 parts of rouge, 14 parts of ethylene-vinyl acetate copolymer, 78 parts of polystyrene, 2,6- 5 parts of methylphenol of three-level butyl -4-, 8- hydroxyl 6 parts of copper 8-hydroxyquinolinate, 2 parts of thioether of bis- (3,5- three-level butyl -4- hydroxy phenyls), 4 parts of dimethyl silicone polymer, 5 parts of fatty acid amide, 6 parts of zinc stearate, 1 part of colorant, 4 parts of pigment dispersing agent.
Preferably, the colorant is one in chrome yellow, barba hispanica, toluidines river, chrome green, carbon black, lithopone and titanium dioxide Kind, the pigment dispersing agent is sodium pyrophosphate, calgon, maleic anhydride multipolymer and trimethyl stearyl amide chlorination One of object.
Preferably, the deodorization antibiotic layer includes the raw material of following parts by weight: 33 parts of film-forming resin, macroporous absorbent resin 4 Part, 2 parts of hydroxypropyl cellulose, 6 parts of chloro- 3, the 5- dimethyl phenol of 4-, 4 parts of 1,2-benzisothiazolin-3-one, 5 parts of active carbon, oxygen 2 parts of zinc of change, 4 parts of propandiol butyl ether, 4 parts of propylene glycol methyl ether acetate, 2 parts of triethyltin chloride, 1 part of phenyl mercury oleate, polyoxy 3 parts of ether of ethylene polyoxypropylene pentaerythrite.
Preferably, the film-forming resin is one of phenolic resin, polyester resin and acrylic resin.
The invention also provides a kind of manufacturing methods of TPR flexible glue insole, comprising the following steps:
The processing of S1, insole body layer: proportionally weighing the raw material of insole body layer, and the raw material of plate body layer is being pulverized It is crushed in machine, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, it will be under molten condition The raw material of insole body layer be placed in sole shaped mold, obtain molding flexible glue body, as insole body layer after cooling；
The processing of S2, deodorization antibiotic layer: proportionally weighing the raw material of deodorization antibiotic layer, and the raw material of deodorization antibiotic layer is existed It is crushed in micronizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, will melt The raw material for melting the deodorization antibiotic layer under state is placed in sole shaped mold, obtains molding flexible glue body after cooling, as anti- Smelly antibiotic layer；
The processing of S3, buffer layer: ethylene n-butyl acrylate polymer is foamed under the action of polyurethane foams To buffer layer, and the width of buffer layer cut of same size with insole body layer, is insole body layer by the wide length of buffer layer Length 1/5；
S4, the upper end that deodorization antibiotic layer is pasted onto insole body layer using adhesive, and buffer layer is pasted onto insole body The lower end of layer, can be obtained TPR flexible glue insole.
The beneficial effects of the present invention are:
1, of the invention, by the way that deodorization antibiotic layer and lower end setting buffer layer, Ke Yiti is arranged in the upper end of TPR flexible glue insole The deodorization antibacterial effect of high TPR flexible glue insole and the function of damping, so that the using effect of TPR flexible glue insole is good.
2, of the invention, by adding 2,6- three-level butyl -4- methylphenol and bis- (3,5- three-level fourths in insole body layer Base -4- hydroxy phenyl) thioether is antioxidant, so that insole body layer has the function of preventing oxidation, so as to extend insole The service life of body layer is lubricant by addition fatty acid amide and zinc stearate, and the lubrication effect of insole body layer can be improved Fruit improves its usability.
3, of the invention, by adding active carbon and zinc oxide in deodorization antibiotic layer as antibacterial agent, passes through addition macropore and inhale Chloro- 3, the 5- dimethyl phenol of attached resin, 4-, 1,2-benzisothiazolin-3-one, hydroxypropyl cellulose and active carbon are odour adsorbent, The deodorization antibiotic layer being prepared is allowed to adsorb the effect of peculiar smell and antibacterial, triethyltin chloride and phenyl mercury oleate have Mould proof effect, so that the TPR flexible glue insole of preparation has the effect of adsorbing stink and sterilization, it is ensured that TPR flexible glue insole Using effect it is good.
4, of the invention, production method is simple, and raw material sources are extensive, and production cost is low, convenient for promoting and using on a large scale.
Detailed description of the invention
Fig. 1 is the side structure schematic view of a kind of TPR flexible glue insole proposed by the present invention and its manufacturing method.
In figure: 1 insole body layer, 2 deodorization antibiotic layers, 3 buffer layers.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.
Embodiment one: referring to Fig.1, a kind of TPR flexible glue insole, including insole body layer 1, deodorization antibiotic layer 2 and buffer layer 3, Insole body layer 1 includes the raw material of following parts by weight: 40 parts of styrene-butadiene-copolymer, 15 parts of phenolic resin, and ethyl vinyl acetate second 12 parts of alkene copolymer, 70 parts of polystyrene, 2,6- 3 parts of methylphenol of three-level butyl -4-, 5 parts of copper 8-quinolinolate, bis- (3,5- Three-level butyl -4- hydroxy phenyl) 2 parts of thioether, 3 parts of dimethyl silicone polymer, 5 parts of fatty acid amide, 5 parts of zinc stearate, toluene 1 part of amine river, 3 parts of calgon, deodorization antibiotic layer 2 includes the raw material of following parts by weight: 32 parts of polyester resin, macroporous absorption tree 3 parts of rouge, 2 parts of hydroxypropyl cellulose, 5 parts of chloro- 3, the 5- dimethyl phenol of 4-, 3 parts of 1,2-benzisothiazolin-3-one, active carbon 4 Part, 2 parts of zinc oxide, 3 parts of propandiol butyl ether, 4 parts of propylene glycol methyl ether acetate, 1 part of triethyltin chloride, 1 part of phenyl mercury oleate, 2 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, buffer layer 3 are ethylene n-butyl acrylate polymer composition；
Manufacturing method the following steps are included:
The processing of S1, insole body layer 1: proportionally weighing the raw material of insole body layer 1, by the raw material of plate body layer 1 in ultra micro It is crushed in pulverizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, by molten The raw material of insole body layer 1 under state is placed in sole shaped mold, obtains molding flexible glue body, as insole body layer after cooling 1；
The processing of S2, deodorization antibiotic layer 2: proportionally weighing the raw material of deodorization antibiotic layer 2, by the original of deodorization antibiotic layer 2 Material crushes in micronizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, The raw material of deodorization antibiotic layer 2 under molten condition is placed in sole shaped mold, obtains molding flexible glue body after cooling, i.e., For deodorization antibiotic layer 2；
The processing of S3, buffer layer 3: ethylene n-butyl acrylate polymer is foamed under the action of polyurethane foams To buffer layer 3, and the width of buffer layer 3 cut of same size with insole body layer 1, is insole by the wide length of buffer layer 3 The 1/5 of the length of body layer 1；
S4, the upper end that deodorization antibiotic layer 2 is pasted onto insole body layer 1 using adhesive, and buffer layer 3 is pasted onto insole TPR flexible glue insole can be obtained in the lower end of body layer 1.
Embodiment two: referring to Fig.1, a kind of TPR flexible glue insole, including insole body layer 1, deodorization antibiotic layer 2 and buffer layer 3, Insole body layer 1 includes the raw material of following parts by weight: 42 parts of styrene-butadiene-copolymer, 16 parts of phenolic resin, and ethyl vinyl acetate second 13 parts of alkene copolymer, 74 parts of polystyrene, 2,6- 5 parts of methylphenol of three-level butyl -4-, 6 parts of copper 8-quinolinolate, bis- (3,5- Three-level butyl -4- hydroxy phenyl) 2 parts of thioether, 3 parts of dimethyl silicone polymer, 5 parts of fatty acid amide, 6 parts of zinc stearate, toluene 1 part of amine river, 4 parts of calgon, deodorization antibiotic layer 2 includes the raw material of following parts by weight: 33 parts of polyester resin, macroporous absorption tree 4 parts of rouge, 2 parts of hydroxypropyl cellulose, 6 parts of chloro- 3, the 5- dimethyl phenol of 4-, 4 parts of 1,2-benzisothiazolin-3-one, active carbon 5 Part, 2 parts of zinc oxide, 3 parts of propandiol butyl ether, 4 parts of propylene glycol methyl ether acetate, 1 part of triethyltin chloride, 1 part of phenyl mercury oleate, 2 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, buffer layer 3 are ethylene n-butyl acrylate polymer composition；
Manufacturing method the following steps are included:
The processing of S1, insole body layer 1: proportionally weighing the raw material of insole body layer 1, by the raw material of plate body layer 1 in ultra micro It is crushed in pulverizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, by molten The raw material of insole body layer 1 under state is placed in sole shaped mold, obtains molding flexible glue body, as insole body layer after cooling 1；
The processing of S2, deodorization antibiotic layer 2: proportionally weighing the raw material of deodorization antibiotic layer 2, by the original of deodorization antibiotic layer 2 Material crushes in micronizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, The raw material of deodorization antibiotic layer 2 under molten condition is placed in sole shaped mold, obtains molding flexible glue body after cooling, i.e., For deodorization antibiotic layer 2；
The processing of S3, buffer layer 3: ethylene n-butyl acrylate polymer is foamed under the action of polyurethane foams To buffer layer 3, and the width of buffer layer 3 cut of same size with insole body layer 1, is insole by the wide length of buffer layer 3 The 1/5 of the length of body layer 1；
S4, the upper end that deodorization antibiotic layer 2 is pasted onto insole body layer 1 using adhesive, and buffer layer 3 is pasted onto insole TPR flexible glue insole can be obtained in the lower end of body layer 1.
Embodiment three: referring to Fig.1, a kind of TPR flexible glue insole, including insole body layer 1, deodorization antibiotic layer 2 and buffer layer 3, Insole body layer 1 includes the raw material of following parts by weight: 45 parts of styrene-butadiene-copolymer, 18 parts of phenolic resin, and ethyl vinyl acetate second 14 parts of alkene copolymer, 78 parts of polystyrene, 2,6- 5 parts of methylphenol of three-level butyl -4-, 6 parts of copper 8-quinolinolate, bis- (3,5- Three-level butyl -4- hydroxy phenyl) 2 parts of thioether, 4 parts of dimethyl silicone polymer, 5 parts of fatty acid amide, 6 parts of zinc stearate, toluene 1 part of amine river, 4 parts of calgon, deodorization antibiotic layer 2 includes the raw material of following parts by weight: 33 parts of polyester resin, macroporous absorption tree 4 parts of rouge, 2 parts of hydroxypropyl cellulose, 6 parts of chloro- 3, the 5- dimethyl phenol of 4-, 4 parts of 1,2-benzisothiazolin-3-one, active carbon 5 Part, 2 parts of zinc oxide, 4 parts of propandiol butyl ether, 4 parts of propylene glycol methyl ether acetate, 2 parts of triethyltin chloride, 1 part of phenyl mercury oleate, 3 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, buffer layer 3 are ethylene n-butyl acrylate polymer composition；
Manufacturing method the following steps are included:
The processing of S1, insole body layer 1: proportionally weighing the raw material of insole body layer 1, by the raw material of plate body layer 1 in ultra micro It is crushed in pulverizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, by molten The raw material of insole body layer 1 under state is placed in sole shaped mold, obtains molding flexible glue body, as insole body layer after cooling 1；
The processing of S2, deodorization antibiotic layer 2: proportionally weighing the raw material of deodorization antibiotic layer 2, by the original of deodorization antibiotic layer 2 Material crushes in micronizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, The raw material of deodorization antibiotic layer 2 under molten condition is placed in sole shaped mold, obtains molding flexible glue body after cooling, i.e., For deodorization antibiotic layer 2；
The processing of S3, buffer layer 3: ethylene n-butyl acrylate polymer is foamed under the action of polyurethane foams To buffer layer 3, and the width of buffer layer 3 cut of same size with insole body layer 1, is insole by the wide length of buffer layer 3 The 1/5 of the length of body layer 1；
S4, the upper end that deodorization antibiotic layer 2 is pasted onto insole body layer 1 using adhesive, and buffer layer 3 is pasted onto insole TPR flexible glue insole can be obtained in the lower end of body layer 1.
Example IV: referring to Fig.1, a kind of TPR flexible glue insole, including insole body layer 1, deodorization antibiotic layer 2 and buffer layer 3, Insole body layer 1 includes the raw material of following parts by weight: 48 parts of styrene-butadiene-copolymer, 18 parts of phenolic resin, and ethyl vinyl acetate second 15 parts of alkene copolymer, 82 parts of polystyrene, 2,6- 7 parts of methylphenol of three-level butyl -4-, 6 parts of copper 8-quinolinolate, bis- (3,5- Three-level butyl -4- hydroxy phenyl) 3 parts of thioether, 4 parts of dimethyl silicone polymer, 6 parts of fatty acid amide, 7 parts of zinc stearate, toluene 2 parts of amine river, 4 parts of calgon, deodorization antibiotic layer 2 includes the raw material of following parts by weight: 34 parts of polyester resin, macroporous absorption tree 4 parts of rouge, 3 parts of hydroxypropyl cellulose, 6 parts of chloro- 3, the 5- dimethyl phenol of 4-, 4 parts of 1,2-benzisothiazolin-3-one, active carbon 6 Part, 3 parts of zinc oxide, 4 parts of propandiol butyl ether, 5 parts of propylene glycol methyl ether acetate, 2 parts of triethyltin chloride, 2 parts of phenyl mercury oleate, 3 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, buffer layer 3 are ethylene n-butyl acrylate polymer composition；
Manufacturing method the following steps are included:
The processing of S1, insole body layer 1: proportionally weighing the raw material of insole body layer 1, by the raw material of plate body layer 1 in ultra micro It is crushed in pulverizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, by molten The raw material of insole body layer 1 under state is placed in sole shaped mold, obtains molding flexible glue body, as insole body layer after cooling 1；
The processing of S2, deodorization antibiotic layer 2: proportionally weighing the raw material of deodorization antibiotic layer 2, by the original of deodorization antibiotic layer 2 Material crushes in micronizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, The raw material of deodorization antibiotic layer 2 under molten condition is placed in sole shaped mold, obtains molding flexible glue body after cooling, i.e., For deodorization antibiotic layer 2；
The processing of S3, buffer layer 3: ethylene n-butyl acrylate polymer is foamed under the action of polyurethane foams To buffer layer 3, and the width of buffer layer 3 cut of same size with insole body layer 1, is insole by the wide length of buffer layer 3 The 1/5 of the length of body layer 1；
S4, the upper end that deodorization antibiotic layer 2 is pasted onto insole body layer 1 using adhesive, and buffer layer 3 is pasted onto insole TPR flexible glue insole can be obtained in the lower end of body layer 1.
Embodiment five: referring to Fig.1, a kind of TPR flexible glue insole, including insole body layer 1, deodorization antibiotic layer 2 and buffer layer 3, Insole body layer 1 includes the raw material of following parts by weight: 50 parts of styrene-butadiene-copolymer, 20 parts of phenolic resin, and ethyl vinyl acetate second 16 parts of alkene copolymer, 85 parts of polystyrene, 2,6- 8 parts of methylphenol of three-level butyl -4-, 7 parts of copper 8-quinolinolate, bis- (3,5- Three-level butyl -4- hydroxy phenyl) 3 parts of thioether, 4 parts of dimethyl silicone polymer, 6 parts of fatty acid amide, 7 parts of zinc stearate, toluene 2 parts of amine river, 5 parts of calgon, deodorization antibiotic layer 2 includes the raw material of following parts by weight: 35 parts of polyester resin, macroporous absorption tree 5 parts of rouge, 3 parts of hydroxypropyl cellulose, 7 parts of chloro- 3, the 5- dimethyl phenol of 4-, 5 parts of 1,2-benzisothiazolin-3-one, active carbon 7 Part, 3 parts of zinc oxide, 4 parts of propandiol butyl ether, 5 parts of propylene glycol methyl ether acetate, 2 parts of triethyltin chloride, 2 parts of phenyl mercury oleate, 3 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, buffer layer 3 are ethylene n-butyl acrylate polymer composition；
Manufacturing method the following steps are included:
The processing of S1, insole body layer 1: proportionally weighing the raw material of insole body layer 1, by the raw material of plate body layer 1 in ultra micro It is crushed in pulverizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, by molten The raw material of insole body layer 1 under state is placed in sole shaped mold, obtains molding flexible glue body, as insole body layer after cooling 1；
The processing of S2, deodorization antibiotic layer 2: proportionally weighing the raw material of deodorization antibiotic layer 2, by the original of deodorization antibiotic layer 2 Material crushes in micronizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, The raw material of deodorization antibiotic layer 2 under molten condition is placed in sole shaped mold, obtains molding flexible glue body after cooling, i.e., For deodorization antibiotic layer 2；
The processing of S3, buffer layer 3: ethylene n-butyl acrylate polymer is foamed under the action of polyurethane foams To buffer layer 3, and the width of buffer layer 3 cut of same size with insole body layer 1, is insole by the wide length of buffer layer 3 The 1/5 of the length of body layer 1；
S4, the upper end that deodorization antibiotic layer 2 is pasted onto insole body layer 1 using adhesive, and buffer layer 3 is pasted onto insole TPR flexible glue insole can be obtained in the lower end of body layer 1.
By embodiment one, embodiment two, embodiment three, TPR flexible glue insole made of example IV and embodiment five impregnates In bacterium solution, and contain staphylococcus aureus and Candida albicans in bacterium solution, is taken out after 3h, detect embodiment one, embodiment Two, embodiment three, the strain content on TPR flexible glue insole made of example IV and embodiment five, testing result is as follows:
By above-mentioned experimental result it is found that good anti-bacterial effect on TPR flexible glue insole proposed by the present invention.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (6)

1. a kind of TPR flexible glue insole, which is characterized in that including insole body layer (1), deodorization antibiotic layer (2) and buffer layer (3), institute State the raw material that insole body layer (1) includes following parts by weight: 40-50 parts of styrene-butadiene-copolymer, 15-20 parts of phenolic resin, 12-16 parts of ethylene-vinyl acetate copolymer, 70-85 parts of polystyrene, 2,6- 3-8 parts of -4- methylphenol of three-level butyl, 8- hydroxyl 5-7 parts of base copper 8-hydroxyquinolinate, 2-3 parts of thioether of bis- (3,5- three-level butyl -4- hydroxy phenyls), 3-4 parts of dimethyl silicone polymer, fatty acid 5-6 parts of amide, 5-7 parts of zinc stearate, 1-2 parts of colorant, 3-5 parts of pigment dispersing agent, the deodorization antibiotic layer (2) includes following The raw material of parts by weight: 32-35 parts of film-forming resin, 3-5 parts of macroporous absorbent resin, 2-3 parts of hydroxypropyl cellulose, chloro- 3, the 5- bis- of 4- 5-7 parts of sylvan, 3-5 parts of 1,2-benzisothiazolin-3-one, 4-7 parts of active carbon, 2-3 parts of zinc oxide, propandiol butyl ether 3-4 Part, 4-5 parts of propylene glycol methyl ether acetate, 1-2 parts of triethyltin chloride, 1-2 parts of phenyl mercury oleate, polyoxyethylene polyoxypropylene season Penta 4 2-3 parts of alcohol ethers, the buffer layer (3) are ethylene n-butyl acrylate polymer composition.
2. a kind of TPR flexible glue insole according to claim 1, which is characterized in that the insole body layer (1) includes following heavy The raw material of amount part: 45 parts of styrene-butadiene-copolymer, 18 parts of phenolic resin, 14 parts of ethylene-vinyl acetate copolymer, polyphenyl second It is 78 parts of alkene, 2,6- 5 parts of methylphenol of three-level butyl -4-, 6 parts of copper 8-quinolinolate, bis- (3,5- three-level butyl -4- hydroxy phenyl) 2 parts of thioether, 4 parts of dimethyl silicone polymer, 5 parts of fatty acid amide, 6 parts of zinc stearate, 1 part of colorant, 4 parts of pigment dispersing agent.
3. a kind of TPR flexible glue insole according to claim 1, which is characterized in that the colorant is chrome yellow, barba hispanica, first One of aniline river, chrome green, carbon black, lithopone and titanium dioxide, the pigment dispersing agent be sodium pyrophosphate, calgon, One of maleic anhydride multipolymer and trimethyl stearyl amide chloride.
4. a kind of TPR flexible glue insole according to claim 1, which is characterized in that the deodorization antibiotic layer (2) includes following The raw material of parts by weight: 33 parts of film-forming resin, 4 parts of macroporous absorbent resin, 2 parts of hydroxypropyl cellulose, chloro- 3, the 5- dimethyl phenol 6 of 4- Part, 4 parts of 1,2-benzisothiazolin-3-one, 5 parts of active carbon, 2 parts of zinc oxide, 4 parts of propandiol butyl ether, propylene glycol monomethyl ether acetic acid 4 parts of ester, 2 parts of triethyltin chloride, 1 part of phenyl mercury oleate, 3 parts of polyoxyethylene polyoxypropylene pentaerythrite ether.
5. a kind of TPR flexible glue insole according to claim 1, which is characterized in that the film-forming resin is phenolic resin, gathers One of ester resin and acrylic resin.
6. a kind of manufacturing method of TPR flexible glue insole, which comprises the following steps:
The processing of S1, insole body layer (1): proportionally weighing the raw material of insole body layer (1), by the raw material of plate body layer (1) super It is crushed in atomizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting state after mixing, will melt The raw material of insole body layer (1) under state is placed in sole shaped mold, obtains molding flexible glue body, as insole after cooling Body layer (1)；
The processing of S2, deodorization antibiotic layer (2): proportionally weighing the raw material of deodorization antibiotic layer (2), by deodorization antibiotic layer (2) Raw material crushes in micronizer, and its whole is passed through to the sieve of 140 mesh, and raw material is heated to melting shape after mixing The raw material of deodorization antibiotic layer (2) under molten condition is placed in sole shaped mold by state, obtains molding flexible glue after cooling Body, as deodorization antibiotic layer (2)；
The processing of S3, buffer layer (3): ethylene n-butyl acrylate polymer is foamed under the action of polyurethane foams and is obtained Buffer layer (3), and the width of buffer layer (3) cut it is of same size with insole body layer (1), by the wide length of buffer layer (3) It is the 1/5 of the length of insole body layer (1)；
S4, the upper end that deodorization antibiotic layer (2) is pasted onto insole body layer (1) using adhesive, and buffer layer (3) is pasted onto shoes TPR flexible glue insole can be obtained in the lower end of pad layer (1).
CN201810950285.3A 2018-08-20 2018-08-20 A kind of TPR flexible glue insole and its manufacturing method Pending CN109206767A (en)

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CN112602984A (en) * 2020-12-11 2021-04-06 重庆电子工程职业学院 3D orthopedic insole customization process

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112602984A (en) * 2020-12-11 2021-04-06 重庆电子工程职业学院 3D orthopedic insole customization process
CN112602984B (en) * 2020-12-11 2022-04-22 重庆电子工程职业学院 3D orthopedic insole customization process

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