CN109199921A - A kind of gel water-in-oil emulsion composition and its preparation method and application - Google Patents
A kind of gel water-in-oil emulsion composition and its preparation method and application Download PDFInfo
- Publication number
- CN109199921A CN109199921A CN201811158656.0A CN201811158656A CN109199921A CN 109199921 A CN109199921 A CN 109199921A CN 201811158656 A CN201811158656 A CN 201811158656A CN 109199921 A CN109199921 A CN 109199921A
- Authority
- CN
- China
- Prior art keywords
- oil
- water
- emulsion composition
- oil emulsion
- gel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Gerontology & Geriatric Medicine (AREA)
- Cosmetics (AREA)
Abstract
The present invention provides a kind of gel water-in-oil emulsion compositions and its preparation method and application.A kind of gel water-in-oil emulsion composition provided by the present invention is made by following methods: the grease of the trimethylolpropane tris caprylate of 60-80%, 1-20% being added in oily phase pot, stirs evenly, obtains mixed liquor A；Where mixed liquor A is added in the emulsifier of 1-10% in oily phase pot, stirs evenly, obtain oil-phase solution；The aqueous phase solution of 1-10% is slowly pumped into above-mentioned oil-phase solution, stirs at low speed and a kind of gel water-in-oil emulsion composition is prepared.A kind of gel water-in-oil emulsion composition provided by the invention and human sebaceous's structure are closely similar, safe and non-stimulating, are not easy sensitization.Its excellent in stability also has effects that moist moisturizing, repairs skin.
Description
Technical field
The invention belongs to cosmetic fields, and in particular to a kind of gel water-in-oil emulsion composition and preparation method thereof
And application.
Background technique
Currently, when manufacturing the product of the personal nursings classes such as hair washing product, cosmetics and medicine skin care item, it is often necessary to
The ingredient containing conditioning effect is added, has the function of conditioning skin.Substance of this kind is that conditioning is really played in personal nursing
The ingredient of effect and the key component of skin-protection product.Many functional components be it is oil-soluble, when by unstable, low water
When the functional mass of dissolubility is mixed with water-soluble products, it is necessary to by this transmission system of emulsion.
Emulsion is to be formed by multiphase dispersion by two or more immiscible liquid.Traditional emulsion
It is middle using more mainly oil-in-water (O/W) type emulsion, it is with good stability and transparent.And Water-In-Oil (W/
O) type emulsion has good skin-friendly, but WO emulsion own physical stability is low, in heating, cooling, cold
Demulsification phenomenon easily occurs under the conditions of jelly, dry etc., thus its use is subject to certain restrictions.
It is often used poly- hydrocarbon monomer in the prior art as the webbed cross-linked structure of crosslinking agent shape, or uses synthesis rheology
Regulator, to improve stability, the rheological characteristic of emulsion.However substance of this kind has certain irritation to skin, for skin
The problems such as being easy to cause allergy for the highly sensitive crowd of skin, and the biological degradability of substance of this kind is poor, be easy accumulation and
It pollutes the environment.As people pay attention to the Safety and Environmental Protection of product further in recent years, also to develop a kind of stabilization
And environmentally friendly non-stimulated water-in-oil emulsion composition and preparation method thereof is laid a good foundation.
Trimethylolpropane tris caprylate (3T) is a kind of moisturizer similar with human sebaceous's structure of plant origin,
In personal care product, the moisture content retentivity of skin and hair can be improved rapidly, activated cell vigor has and skin is kept to grow
Moisten, is smooth, preventing dry effect.Also, it has good gas permeability, not will cause clogging of pores while moisturizing,
Skin refreshing can be made ventilative.Aiming at the problem that water-in-oil emulsion composition in the prior art, the present invention provides a kind of main
Non-stimulated, moisturizing excellent using trimethylolpropane tris caprylate and natural grease emulsifying synthesising stability, mild is grown
Support the gel water-in-oil emulsion composition and its preparation method and application of skin.
Summary of the invention
To realize that foregoing invention, the embodiment that the present invention uses are as follows:
In a first aspect, be the present invention provides a kind of preparation method of gel water-in-oil emulsion composition, it is described
The preparation method comprises the following steps:
(1) grease of the trimethylolpropane tris caprylate of 60-80%, 1-20% are added in oily phase pot, are stirred evenly,
Obtain mixed liquor A；
(2) it where mixed liquor A being added in the emulsifier of 1-10% in oily phase pot, stirs evenly, obtains oil-phase solution；
(3) aqueous phase solution of 1-10% is slowly pumped into above-mentioned oil-phase solution, stirs at low speed and a kind of gel is prepared
Shape water-in-oil emulsion composition.
Preferably, the grease includes one of vegetable fat, animal fat and Synthetic Oil or a variety of.
It is further preferred that the grease is thorn A Gan tree benevolence oil, isononyl isononanoate, shea butter, Queensland nut
Oil, olive oil, apricot kernel oil, coconut oil avocado oil, jojoba oil, Butyrospermum parkii fatty oil, grape seed oil, rice bran oil, wheat-germ oil, angle
One of shark alkane is a variety of.
Most preferably, the grease be pierce A Gan tree benevolence oil and saualane composition, wherein thorn A Gan tree benevolence oil and
The weight ratio of saualane is 1:1-10.
By adopting the above technical scheme, piercing A Gan tree benevolence oil and saualane has the function of nourishing, maintenance skin.Saualane is
A kind of extraordinary grease of emollient, the mild not sensitization of property, the sebum height that can be secreted with skin mix, in skin surface
One layer of ventilative protective film is formed, the effect of moisturizing, moisturizing is played.Saualane can also inhibit the peroxidating of skin lipid, can have
Effect infiltrates through skin, and promotes the proliferation of skin base cell, delay skin aging.A Gan tree benevolence oil and saualane two are pierced simultaneously
Person is conducive to maintaining skin rich in nutritional ingredients such as vitamin E abundant, unsaturated fatty acid and alpha-tocopherols.Especially pierce
A Gan tree benevolence oil has the battalion such as vitamin Es more more than aloe and olive content and abundant fatty acid, alcohol steroid, phenolic compound
It forms point.The dry tree benevolence oil of Ci A has outstanding oxidation resistance to human body, repairs the lipid barrier of skin, has to sensibility skin
There is good maintenance effect.It, which also has, resists chafing, reduces acne, helps softening skin, stimulates pore toxin expelling, restores
The effect of natural lipid barrier.
Preferably, the emulsifier includes but is not limited to fatty acid mono glycidol, polyglyceryl fatty acid ester, lecithin
Class, alkyl glycosides, -10/1 dimethyl silica alkanol of cetyl polyethylene/polypropylene glycol, in sorbitan fatty acid ester
It is one or more.
It is further preferred that the emulsifier is polyglyceryl fatty acid ester.
Most preferably, the emulsifier is three isostearate of polyglycereol -2.
By adopting the above technical scheme, three isostearate of polyglycereol -2 safety with higher is conducive to improve safety
Effect.Three isostearate of polyglycereol -2 has oxidation stability more better than nonionic polyoxyethylene surfactant and pH
Stability, and there is thermal stability more better than sucrose, glycerol, sorbitan ester etc..It is different by the way that polyglycereol -2 three is added
Stearate is conducive to further increase the stablizing effect of emulsion as emulsifier.
Compared with nonionic polyoxyethylene surfactant, there is better oxidation stability and pH stability.Gather sweet
Oily -2 three isostearates have better thermal stability compared with sucrose, glycerol, sorbitan ester etc..
Preferably, the aqueous phase solution includes but is not limited to one of deionized water, pure water, distilled water or more
Kind.
Second aspect is that the present invention also provides using a kind of gel made from preparation method as described in relation to the first aspect
Shape water-in-oil emulsion composition.Wherein a kind of gel water-in-oil emulsion composition produced by the present invention is free of cross-linked polymeric
Object, and contain the trimethylolpropane tris caprylate of salubrious moisturizing in raw material components of the invention.One kind that the present invention synthesizes
Gel water-in-oil emulsion composition has the characteristics that safety and environmental protection, mild not sensitization, moistens and repair skin.
The present invention provides a kind of gel water-in-oil emulsion compositions, by weight percentage, raw material composition packet
It includes:
The trimethylolpropane tris caprylate of 60-80%；
The grease of 1-20%；
The emulsifier of 1-10%；
The aqueous phase solution of 1-10%.
Preferably, a kind of gel water-in-oil emulsion composition, by weight percentage, raw material composition packet
It includes:
The trimethylolpropane tris caprylate of 60-80%；
The saualane of 1-10%；
The thorn A Gan tree benevolence oil of 1-10%；
- 2 three isostearate of 1-10% polyglycereol；
The water of 1-10%.
It is further preferred that a kind of gel water-in-oil emulsion composition, by weight percentage, raw material
Component is as follows:
70% trimethylolpropane tris caprylate；
5% saualane；
5% thorn A Gan tree benevolence oil；
- 2 three isostearate of 10% polyglycereol；
10% water.
The third aspect, a kind of gel water-in-oil emulsion composition are preparing hair shampoo article, cosmetics and medicine shield
Application in skin product.
Compared with prior art, the beneficial effects of the invention are that: a kind of gel water-in-oil emulsion provided by the invention
Composition and human sebaceous's structure are closely similar, safe and non-stimulating to be not easy sensitization.Its excellent in stability, also have moisten moisturizing,
The effect of repairing skin.Gel water-in-oil emulsion composition Environmental compatibility provided by the invention is good, meets environmentally protective
Trend.A kind of preparation method of gel water-in-oil emulsion composition provided by the invention, preparation process is simple to operation,
Be conducive to save production cost.
Detailed description of the invention
Fig. 1: being that the gel water-in-oil emulsion composition that the present invention is prepared according to embodiment 2 is aobvious in ordinary optical
Amplify 400 times of microscope photo figure under micro mirror；
Fig. 2: being the gel water-in-oil emulsion composition of the invention being prepared according to embodiment 2 in petrographic microscope
The microscope photo figure of lower 400 times of amplification.
Specific embodiment
The present invention is further described With reference to embodiment, the embodiment provided is only for illustrating this
Invention, the range being not intended to be limiting of the invention, because without departing from the spirit and scope of the present invention, it can be right
The present invention carries out many changes.It is understood that those skilled in the art are after reading this specification according to conventional needs
That makes does not have creative modification, but as long as all by the protection of Patent Law in scope of the presently claimed invention.
Constituent content in following embodiments is unless otherwise specified mass percent.It is as used in the following examples
Raw material, reagent material etc. can be commercially available unless otherwise specified from conventional distributors.
The component information of embodiment 1-8
Embodiment 1-8 is a kind of gel water-in-oil emulsion composition prepared according to inventive formulation, contained group
Divide information as shown in table 1.
A kind of preparation of gel water-in-oil emulsion composition
A kind of preparation method of gel water-in-oil emulsion composition, includes the following steps: in embodiment 1-4
(1) trimethylolpropane tris caprylate centainly matched, saualane, thorn A Gan tree benevolence oil are weighed, oily phase pot is put into
It is interior, it stirs evenly, obtains mixed liquor A；
(2) it weighs in oily phase pot where mixed liquor A is added in three isostearate of polyglycereol -2 centainly matched, stirring is equal
It is even, obtain oil-phase solution；
(3) aqueous phase solution is slowly pumped into above-mentioned oil-phase solution, is stirred at low speed, a kind of gel oil packet is prepared
Water emulsion composition.
The preparation method of embodiment 5 is identical as the preparation method of embodiment 1-4, only replaces saualane, thorn A Gan tree benevolence oil
Change isononyl isononanoate, shea butter into.
The preparation method of embodiment 6 is identical as the preparation method of embodiment 1-4, only replaces saualane, thorn A Gan tree benevolence oil
Change PEG-7 olive grease, PEG-6 caprylic/capric glyceride into.
The preparation method of embodiment 7 is identical as the preparation method of embodiment 1-4, only replaces saualane, thorn A Gan tree benevolence oil
It changes isononyl isononanoate, shea butter into, three isostearate of polyglycereol -2 is substituted for cetyl polyethylene glycol/poly- the third two
- 10/1 dimethyl silica alkanol of alcohol.
The preparation method of embodiment 8 is identical as the preparation method of embodiment 1-4, only replaces saualane, thorn A Gan tree benevolence oil
It changes PEG-7 olive grease, PEG-6 caprylic/capric glyceride into, three isostearate of polyglycereol -2 is substituted for the poly- second of cetyl
- 10/1 dimethyl silica alkanol of glycol/polypropylene glycol.
The component information table of 1 embodiment 1-8 of table
The characteristic of embodiment 1-8
After a kind of gel water-in-oil emulsion composition preparation for being formulated preparation according to the present invention within 3 days, observation
Its appearance, color, smell, uniformity coefficient, observation result are as shown in the following Table 2.
The property list of 2 embodiment 1-8 of table
| Embodiment | 1 | 2 | 3 | 4 |
| Appearance | Translucent gels | Translucent gels | Translucent gels | Translucent gels |
| Color | It is yellowish | It is colourless | It is yellowish | It is yellowish |
| Smell | Characteristic odor | Characteristic odor | Characteristic odor | Characteristic odor |
| Uniformity coefficient | Uniformly | Uniformly | It is generally uniform | Uniformly |
| Embodiment | 5 | 6 | 7 | 8 |
| Appearance | Translucent gels | Translucent gels | Translucent gels | Translucent gels |
| Color | It is yellowish | It is yellowish | It is yellowish | It is yellowish |
| Smell | Characteristic odor | Characteristic odor | Characteristic odor | Characteristic odor |
| Uniformity coefficient | Uniformly | Uniformly | Uniformly | Uniformly |
According to 2 result of table it is found that translucent gels shape can be presented in the water-in-oil emulsion that the present invention prepares, color is nothing
Color is generally uniform to yellowish.This illustrates a kind of emulsification effect of gel water-in-oil emulsion composition produced by the present invention
Fruit is good, stability is excellent.
PH measurement
(1) laboratory apparatus: pH meter (minimum scale 0.1pH unit)；Glass electrode；Reference electrode (calomel/potassium chloride saturation
Solution-type)；Combination electrode (to replace glass electrode and reference electrode)；Magnetic stirring apparatus；Beaker (50ml)；Volumetric flask
(1000ml)；Thermometer (0-100 DEG C)；Water-bath.
(2) test condition: 25 DEG C of room temperature, sample is made in embodiment 1 to embodiment 8.
(3) it test method: at 25 DEG C of room temperature, weighs sample 10.0g and is placed in a beaker, weigh to 0.001g, use distilled water
Dissolution moves into and is diluted to scale in volumetric flask and shakes up；Above-mentioned solution is poured into beaker, magnetic stirrer 30s is placed in,
It is inserted into electrode, after pH meter stablizes 1min, reading.Same sample is measured in parallel 2 times, and the difference of measurement is counted no more than 0.1pH.
(4) test result: the gel accessed into embodiment 8 to embodiment 1 oil under the conditions of 25 DEG C of temperature
Water-in type emulsion compositions carry out pH measurement, measurement result 7.0-9.5.
Performance evaluation
Comparative example 1, PEG-7 glyceryl cocoate (HE) are purchased from Corning chemical industry (China) Co., Ltd.
Comparative example 2, PPG-3 Octyl Ether (GP-1) are purchased from Kao Corp.
The obtained sample of embodiment 2,5,6,7,8.
Performance (1): water solubility/hydrophily
HE, GP-1 of equivalent, the obtained gel water-in-oil emulsion composition of embodiment 2,5,6,7,8 are made an addition to respectively
It in equivalent pure water and is stirred, is tested respectively, observe each substance situation soluble in water.Test result is as shown in table 5.
The benchmark of evaluation is as described below:
● ● ● ● ●: dissolution degree 100%；
● ● ● ● zero: dissolution degree 80%；
● ● ● 00: dissolution degree 60%；
● ● 000: dissolution degree 40%；
● 0000: dissolution degree 20%；
00000: dissolution degree 0%.
Performance (2): the final transparency of table living body system
3 table living body system component table of table
| AES | 24% |
| K12 | 16 |
| AOS (α-sodium olefin sulfonate) | 20% |
| CAB | 39% |
| Composition/HE/GP-1 of embodiment 2,5,6,7,8 | 1% |
HE, GP-1, the obtained gel water-in-oil emulsion composition of embodiment 2,5,6,7,8 are made an addition into 3 institute of table respectively
It states in table living body system, is stirred, observe the final transparency in each comfortable table living body system.Test result is as shown in table 5.
The benchmark of evaluation is as described below:
● ● ● ● ●: transparency 100%；
● ● ● ● zero: transparency 80%；
● ● ● 00: transparency 60%；
● ● 000: transparency 40%；
● 0000: transparency 20%；
00000: transparency 0%.
Performance (3): residual/hair conditioning and scalp sebum structural similarity after wet hair improves, is dry
HE, GP-1, the obtained gel water-in-oil emulsion composition of embodiment 2,5,6,7,8 are made an addition into table 4 respectively
In aqueous systems of having one's hair wash, shampoo a, b, c, d, e, f, g are made respectively.
(1) test equipment: combing force tester.
(2) test sample: shampoo a, b, c, d, e, f, g, import topknot (30 ± 1cm of length, 10 ± 1g of weight).
(3) test method: first surveying the dry and wet carding force of blank topknot, after handling hair with 2g shampoo, test shampoo processing
The dry and wet carding force of topknot afterwards, the relatively variation of front and back carding force.Flushing period 30S, resistance unit are newton.
(4) test result: the conditioning of wet hair, it is dry after residual/hair conditioning, as shown in table 5 with scalp sebum structural similarity.
The benchmark of evaluation is as described below:
● ● ● ● ●: the impact of performance 100%；
● ● ● ● zero: the impact of performance 80%；
● ● ● 00: the impact of performance 60%；
● ● 000: the impact of performance 40%；
● 0000: the impact of performance 20%；
00000: the impact of performance 0%.
4 shampoo component table of table
The performance comparison of table 5HE, GP-1 and gel water-in-oil emulsion composition
The above results demonstrate a kind of gel water-in-oil emulsion composition of the invention produced than the prior art
Product HE, GP-1 are more similar to scalp sebum structure, are not easy to skin irritant.A kind of gel oil produced by the present invention
Residual/hair conditioning after water-in type emulsion compositions have more excellent wet hair conditioning, do.
Application Example
The Formulation Example of the cosmetics of inventive gel shape water-in-oil emulsion composition is listed below, but the present invention is not
It is defined in this.The cosmetics emulsion stability obtained by formula as below example is high, skin irritation is low, use feeling is excellent.
Application Example 1 nurses frost
The ingredient for nursing frost produced according to 2 composition of embodiment is as shown in table 6 below.By the material investment in the A of table 6
70 DEG C are heated to after mutually mixing into container, then the material use homogenizer in input table 6B carries out 5 with homogeneous 4000rpm
Minute emulsification treatment is carried out at emulsification in 3 minutes after material using homogenizer with homogeneous 4000rpm in the C of following input table 6
Reason produces above-mentioned nursing frost, and manufactured nursing frost is white, creams type.
Table 6 nurses the component list of frost
2 shampoo of Application Example
Shampoo (a)
The ingredient of the shampoo (a) produced according to 2 composition of embodiment is as shown in table 7 below.
(1) material in A, B, C of table 7 is mixed respectively in different vessels, solution where A is warming up to 75 DEG C；
(2) then the material in table 7D is put into the container where A, stirring is to forming transparent clear solution, temperature
Degree is maintained at 75 DEG C；
(3) material in table 7E is put into the mixed solution in step (2) with the B material mixed, is stirred at 75 DEG C
It mixes, keeps the temperature 30min；
(4) 45 DEG C are cooled to, citric acid, Kathon CG, the C-material mixed, color are added in the mixed liquor in step (3)
Element stirs evenly, and is eventually adding sodium chloride and obtains above-mentioned shampoo.
Manufactured shampoo is transparent no silicone oil shampoo, belongs to gel-type, excellent in stability.
The component list of 7 shampoo (a) of table
Shampoo comparative formula: shampoo (b)
The ingredient of the shampoo (b) produced according to 2 composition of embodiment is as shown in table 8 below.
(1) material in A, B, C of table 8 is mixed respectively in different vessels, solution where A is warming up to 75 DEG C；
(2) then the material in table 8D is put into the container where A, stirring is to forming transparent clear solution, temperature
Degree is maintained at 75 DEG C；
(3) material in table 8E is put into the mixed solution in step (2) with the B material mixed, is stirred at 75 DEG C
It mixes, keeps the temperature 30min；
(4) 45 DEG C are cooled to, citric acid, Kathon CG, the C-material mixed, color are added in the mixed liquor in step (3)
Element stirs evenly, and is eventually adding sodium chloride and obtains above-mentioned shampoo.
Compare shampoo formula manufactured by it is opaque without silicone oil shampoo muddiness, stability is poor.
The component list of 8 shampoo (b) of table
In conclusion a kind of gel water-in-oil emulsion composition provided by the invention and human sebaceous's structure very phase
Seemingly, safe and non-stimulating to be not easy sensitization, addition can then provide a kind of stability in suitable shampoo formula and use feeling is excellent
Different gel water-in-oil type composition.A kind of preparation method of gel water-in-oil emulsion composition provided by the invention,
Preparation process is simple to operation, is conducive to save production cost.
Claims (10)
1. a kind of preparation method of gel water-in-oil emulsion composition, it is characterized in that, using following steps:
(1) grease of the trimethylolpropane tris caprylate of 60-80%, 1-20% are added in oily phase pot, stir evenly, obtains
Mixed liquor A；
(2) it where mixed liquor A being added in the emulsifier of 1-10% in oily phase pot, stirs evenly, obtains oil-phase solution；
(3) aqueous phase solution of 1-10% is slowly pumped into above-mentioned oil-phase solution, stirs at low speed and a kind of gel oil is prepared
Water-in type emulsion compositions.
2. preparation method as described in claim 1, it is characterized in that, the grease include vegetable fat, animal fat,
One of Synthetic Oil is a variety of.
3. preparation method as described in claim 1, it is characterized in that, the grease is thorn A Gan tree benevolence oil and saualane
Composition, wherein the weight ratio of thorn A Gan tree benevolence oil and saualane is 1:1-10.
4. preparation method as described in claim 1, it is characterized in that, the emulsifier include fatty acid mono glycidol,
Polyglyceryl fatty acid ester, lecithin esters, alkyl glycosides, -10/1 dimethyl silica alkanol of cetyl polyethylene/polypropylene glycol,
One of sorbitan fatty acid ester is a variety of.
5. preparation method as described in claim 1, it is characterized in that, the emulsifier is three isostearic acid of polyglycereol -2
Ester.
6. preparation method as described in claim 1, it is characterized in that, the aqueous phase solution include deionized water, it is pure
One of water, distilled water are a variety of.
7. a kind of gel water-in-oil emulsion composition, which is characterized in that the gel water-in-oil emulsion composition
To be made using a kind of method described in claim 1 for preparing gel water-in-oil emulsion composition.
8. a kind of gel water-in-oil emulsion composition as claimed in claim 7, which is characterized in that a kind of gel
Shape water-in-oil emulsion composition, by weight percentage, material component includes:
The trimethylolpropane tris caprylate of 60-80%；
The saualane of 1-10%；
The thorn A Gan tree benevolence oil of 1-10%；
- 2 three isostearate of 1-10% polyglycereol；
The aqueous phase solution of 1-10%.
9. a kind of gel water-in-oil emulsion composition as claimed in claim 7, which is characterized in that a kind of gel
Shape water-in-oil emulsion composition, by weight percentage, material component is as follows:
70% trimethylolpropane tris caprylate；
5% saualane；
5% thorn A Gan tree benevolence oil；
- 2 three isostearate of 10% polyglycereol；
10% water.
10. a kind of gel water-in-oil emulsion composition as claimed in claim 7, prepare washing product, cosmetics with
And the application in medicine skin care item.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811158656.0A CN109199921A (en) | 2018-09-30 | 2018-09-30 | A kind of gel water-in-oil emulsion composition and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811158656.0A CN109199921A (en) | 2018-09-30 | 2018-09-30 | A kind of gel water-in-oil emulsion composition and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109199921A true CN109199921A (en) | 2019-01-15 |
Family
ID=64982713
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811158656.0A Pending CN109199921A (en) | 2018-09-30 | 2018-09-30 | A kind of gel water-in-oil emulsion composition and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109199921A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110755315A (en) * | 2019-08-12 | 2020-02-07 | 天津市康婷生物工程集团有限公司 | Water-in-oil gel pigment cream and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5946123A (en) * | 1982-09-05 | 1984-03-15 | Pola Chem Ind Inc | Preparation of gel like emulsion and oil in water type emulsion |
| JPH09104613A (en) * | 1995-10-06 | 1997-04-22 | Nisshin Oil Mills Ltd:The | Water-in-oil type gelatinous emulsion composition and emulsion cosmetic or external preparation using the same |
| CN1578654A (en) * | 2001-11-09 | 2005-02-09 | 日清奥利友株式会社 | Gel-form composition |
| CN103547251A (en) * | 2011-06-01 | 2014-01-29 | 株式会社大赛璐 | Oily gel composition |
| CN107007480A (en) * | 2015-11-30 | 2017-08-04 | 富士胶片株式会社 | The manufacture method of gel O/W emulsion composition, skin preparations for extenal use and O/W emulsion composition |
-
2018
- 2018-09-30 CN CN201811158656.0A patent/CN109199921A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5946123A (en) * | 1982-09-05 | 1984-03-15 | Pola Chem Ind Inc | Preparation of gel like emulsion and oil in water type emulsion |
| JPH09104613A (en) * | 1995-10-06 | 1997-04-22 | Nisshin Oil Mills Ltd:The | Water-in-oil type gelatinous emulsion composition and emulsion cosmetic or external preparation using the same |
| CN1578654A (en) * | 2001-11-09 | 2005-02-09 | 日清奥利友株式会社 | Gel-form composition |
| CN103547251A (en) * | 2011-06-01 | 2014-01-29 | 株式会社大赛璐 | Oily gel composition |
| CN107007480A (en) * | 2015-11-30 | 2017-08-04 | 富士胶片株式会社 | The manufacture method of gel O/W emulsion composition, skin preparations for extenal use and O/W emulsion composition |
Non-Patent Citations (1)
| Title |
|---|
| 李仲华等: "三羟甲基丙烷三辛酸酯/三癸酸酯在洗发香波中的应用", 《中国洗涤用品工业》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110755315A (en) * | 2019-08-12 | 2020-02-07 | 天津市康婷生物工程集团有限公司 | Water-in-oil gel pigment cream and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104693031B (en) | Polyglycerol partial ester, its preparation and use | |
| DE60107982T2 (en) | TRANSPARENT AQUEOUS COMPOSITIONS WITH HYDROPHOBIC SILICONE OILS | |
| CN107693433B (en) | Moisturizing essence and preparation method thereof | |
| CN108938439B (en) | Liquid crystal type emulsified composition and preparation method and application thereof | |
| CN101068528B (en) | Personal care compositions that deposit sunless tanning benefit agents | |
| EA032175B1 (en) | LOW pH COMPOSITION COMPRISING SPECIFIC PRESERVATIVE SYSTEMS | |
| CN111568782B (en) | Nanoemulsion composition capable of improving skin barrier and application thereof | |
| CN109922786A (en) | Emulsion oil-in-water with excellent stability and the cosmetic composition comprising it | |
| EA032136B1 (en) | Personal care cleansing composition comprising salt of acyl glutamate as primary anionic surfactant | |
| CN102370605A (en) | Smoothening and moisturizing lotion composition and preparation method thereof | |
| BR102015024850A2 (en) | cleaning compositions | |
| CN111888277B (en) | Plant sterol composition for cosmetics and preparation method and application thereof | |
| CN108578253A (en) | A kind of moisturizing cream and preparation method thereof with good liquid crystal structure | |
| CN106551819B (en) | microemulsified composition with high oil content, preparation method and application thereof | |
| CN110448483B (en) | Phase inversion emulsion and preparation method thereof | |
| CN106109275B (en) | A kind of foaming bath oil and preparation method thereof rich in vegetable oil | |
| CN102686281A (en) | Liquid personal cleansing composition | |
| TR201807715T4 (en) | Enhanced moisturizing blend | |
| CN109181907A (en) | A kind of high hair conditioning natural liquid essential oil soap and preparation method thereof | |
| CN109199921A (en) | A kind of gel water-in-oil emulsion composition and its preparation method and application | |
| JP2003055128A (en) | Transparent cosmetic composition | |
| CN108451783A (en) | A kind of skin care compositions and methods and preparation method thereof | |
| CN107822928B (en) | Face cream and preparation method thereof | |
| EP3849506A1 (en) | Opacifiers based on natural-based components | |
| CN109576072A (en) | A kind of environmental protection leather cleaning frost and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190115 |