CN109195577A - aqueous surfactant compositions - Google Patents
aqueous surfactant compositions Download PDFInfo
- Publication number
- CN109195577A CN109195577A CN201780030454.5A CN201780030454A CN109195577A CN 109195577 A CN109195577 A CN 109195577A CN 201780030454 A CN201780030454 A CN 201780030454A CN 109195577 A CN109195577 A CN 109195577A
- Authority
- CN
- China
- Prior art keywords
- group
- compound
- straight chain
- carbon atom
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 30
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 30
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 29
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 26
- 239000006260 foam Substances 0.000 claims abstract description 22
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 20
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 18
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 18
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 18
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 13
- 239000003599 detergent Substances 0.000 claims abstract description 12
- 239000002537 cosmetic Substances 0.000 claims abstract description 9
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910006146 SO3M1 Inorganic materials 0.000 claims abstract description 4
- 150000002148 esters Chemical class 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 87
- 239000011734 sodium Substances 0.000 claims description 33
- 239000000047 product Substances 0.000 claims description 11
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 6
- 239000000499 gel Substances 0.000 claims description 6
- -1 sulfo group ketone Chemical class 0.000 claims description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000002453 shampoo Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 239000006071 cream Substances 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims description 2
- POPRCUFMXZJTQI-UHFFFAOYSA-N oxomethanedisulfonic acid Chemical compound OS(=O)(=O)C(=O)S(O)(=O)=O POPRCUFMXZJTQI-UHFFFAOYSA-N 0.000 claims description 2
- 239000008257 shaving cream Substances 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- 239000000271 synthetic detergent Substances 0.000 claims description 2
- 238000005187 foaming Methods 0.000 abstract description 15
- 230000001953 sensory effect Effects 0.000 abstract description 3
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 20
- 150000001721 carbon Chemical group 0.000 description 14
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 150000004665 fatty acids Chemical class 0.000 description 10
- 238000005259 measurement Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000011149 active material Substances 0.000 description 6
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 5
- 229940043237 diethanolamine Drugs 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 210000000697 sensory organ Anatomy 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000006277 sulfonation reaction Methods 0.000 description 2
- MRTWZIXSCCETHN-UHFFFAOYSA-N 2-sulfododecanoic acid Chemical compound CCCCCCCCCCC(C(O)=O)S(O)(=O)=O MRTWZIXSCCETHN-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002324 mouth wash Substances 0.000 description 1
- 229940051866 mouthwash Drugs 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical class [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q9/00—Preparations for removing hair or for aiding hair removal
- A61Q9/02—Shaving preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to include following aqueous surfactant compositions: the α-sulfofattyacidsaltb (A) of one or more logical formula (I)s: R1CH(SO3M1)COOM2(I), wherein group R1It is that there is the straight chain or branched-alkyl or alkenyl of 6-18 carbon atom, and group M1And M2It is independently selected from the group by forming as follows: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine, the sulfosuccinate (B) of one or more logical formula (II)s: R31‑O‑CO‑CH(SO3M16)‑CH2‑COOM17(II), wherein group R31It is that there is the straight chain or branched-alkyl or alkenyl or alkoxylate straight chain or branched-alkyl or alkenyl with 6-22 carbon atom of 6-22 carbon atom, and group M16And M17It is independently selected from comprising following group: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine and water, wherein for so-called sulfonated ester, it is necessary to meet the terminal conditions further described in Patent right requirement.These compositions have the tactile sensory of pleasant with good foaming capacity and good skin-friendliness and foam, they are suitable for cosmetic agent and detergent and detergent.
Description
Invention field
The present invention relates to the aqueous surfactant compositions containing α-sulfofattyacidsaltb and sulfosuccinate.
The prior art
Anionic surfactant is some most common interfacial activity compounds, in addition to being used for detergent and detergent
Outside, it is also used to the various uses of cosmetic field.As the especially common anionic surfactants used in cosmetics are
The salt of alkyl ether sulfate (alkyl, polyether sulfate, poly alkyl alcohol ether sulfates go back abbreviation ether sulfate).Their spy
Sign is strong foaming capacity, high cleaning capability, to the hyposensitivity of hardness and grease, and is widely used in production cosmetic product, example
Such as shampoo, foam or shower bath and detergent for washing dishware with hand.
Many current applications also propose anionic surfactant other than good interface active function
Other are required.High skin-friendliness is especially required in cosmetics.In addition, usually requiring that good foaming capacity and pleasant
Foam tactile sensory.Furthermore, it is necessary to can be at least partly by biological source, the especially anionic surface of renewable raw materials preparation
Activating agent.
Invention description
The object of the present invention is to provide aqueous surfactant compositions, it is characterised in that performance described below:
Good foaming capacity.
The foam tactile sensory of pleasant.
Good skin-friendliness.
Firstly, it includes following aqueous surfactant compositions that the present invention, which provides:
The α-sulfofattyacidsaltb (A) of one or more logical formula (I)s,
R1CH(SO3M1)COOM2 (I)
Wherein group R1It is that there is the straight chain or branched-alkyl or alkenyl of 6-18 carbon atom, and group M1And M2Phase
Mutually independently selected from including following group: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine,
The sulfosuccinate (B) of one or more logical formula (II)s,
R31-O-CO-CH(SO3M16)-CH2-COOM17 (II)
Wherein group R31It is the straight chain or branched-alkyl or alkenyl or former with 6-22 carbon with 6-22 carbon atom
The alkoxylate straight chain or branched-alkyl or alkenyl of son, and group M16And M17It is independently selected from comprising following group:
H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine,
Water,
Wherein it is applicable in the following conditions:
If aqueous surfactant compositions include the sulfonated ester (E) of one or more logical formula (V)s,
R2CH(SO3M7)COOR3 (V)
Wherein group R2It is that there is the straight chain or branched-alkyl or alkenyl of 6-18 carbon atom, and group R3It is to have
The straight chain or branched-alkyl or alkenyl of 1-20 carbon atom, wherein group R3Logically only more than 3 carbon atoms when can
To be alkenyl or branching, and group M7Selected from including following group: Li, Na, K, Ca/2, Mg/2, ammonium and alkanol
Amine, then situation is that compound (A) must be with 50 weight % or more, especially 90 weights based on the total amount of compound (A) and (E)
The degree for measuring % or more exists.
Aqueous surfactant compositions of the present invention are characterized in that following advantageous property:
The foam sense organ sense of touch of good foaming capacity and pleasant.In this regard, it is to be noted that especially making up
In product field, foaming capacity can be taken to mean that different aspect, such as in order to assess foam, any foams can be used
Product, foam stability, the optical signature of foamed elastic, the water content of foam and foam, such as pore size.The present composition
There is macrofoam volume during foaming.In practice, initial foaming carries out for (several seconds to one minute) within the relatively short time.
Usually during initial foaming, bath gels or shampoo are smeared by rubbing between hand, skin and/or hair and makes its hair
Bubble.In the lab, it can be estimated that the foaming behavior of aqueous surfactant solution, such as by by stirring, shake, pumping,
It is bubbled through air-flow or otherwise stirs solution within the relatively short time.The subjective evaluation of foam sense organ sense of touch can be by
Test object carries out.For this purpose, it can be estimated that such as creaming of emulsion, elasticity, foam mouldability aspect.
Good skin and mucous membrane compatibility.These can pass through in-vitro method (example well known by persons skilled in the art
Such as RBC or HET-CAM) and by test object (such as patch test) detection.
To the outstanding care benefits of skin and hair.This can be for example in test object by reference to subjective skin sense
(smoothness, aridity etc.) or tactile and the feeling of processed hair are felt to assess.Also mechanical measuring means can be used such as
Hair can cardability.
Good storage stability.Situation be Aquo-composition do not show it is any it is visible (such as it is muddy, become
Color mutually separates) or measurable (such as pH, viscosity, activity substance content) variation.
Good applicability and processability.The composition can quickly and without providing heat be dissolved when introducing water.
Good obvious dissolubility and transparency.Aqueous surfactant compositions do not have precipitating or muddiness incline
To.
Sufficiently high viscosity, this is understood to mean that 1000mPas or higher value (make in the context of the present invention
With Brookfield RV laboratory rheometer at 23 DEG C, 12rpm, spindle sets RV 02 to 07 and (depends on range of viscosities to select
Spindle) under measure).As is known, " mPas " indicates mpas.
Good clean-up performance.Aqueous surfactant compositions are suitable for being removed by solid or fabric surface and emulsification
Dirt, especially fat contain oil foulant.
Compound (A)
The compound (A) for being known as α-sulfofattyacidsaltb in the context of the present invention is living containing water surface for the present invention
Property agent composition is necessary.They have above-mentioned formula (I):
R1CH(SO3M1)COOM2(I),
Wherein group R1It is that there is the straight chain or branched-alkyl or alkenyl of 6-18 carbon atom, and group M1And M2Phase
Mutually independently selected from including following group: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine.In this regard, particularly preferred
Alkanolamine is monoethanolamine, diethanol amine, triethanolamine and monoisopropanolamine.
In one embodiment, applicable condition is wherein group R1It is the compound (A) of alkenyl containing water surface
Ratio in surfactant composition is based on the total amount of compound (A) as 3 weight % or less.
In a preferred embodiment, the group R in formula (I)1It is the saturated straight chain alkane with 10-16 carbon atom
Base, wherein for compound (A), situation is wherein group R1It is the ratio base of the compound (A) of decyl and/or dodecyl
In the total amount of compound (A) be 70 weight % or more, preferably 90 weight % or more.
Preferably, the group M in formula (I)1And M2Selected from the group comprising H (hydrogen) and Na (sodium).
Compound (A) can be prepared by all appropriate methods well known by persons skilled in the art.Here particularly preferred
Preparation method is the sulphation of corresponding carboxylic acid.Here making corresponding carboxylic acid, especially corresponding fatty acid is reacted with gaseous sulfur trioxide,
Wherein the dosage of sulfur trioxide is preferably so that SO3Molar ratio with fatty acid is 1.0:1-1.1:1.Then it will obtain in this way
To crude product (its be acid sulfating product) partially or completely neutralize, wherein it is preferred that with NaOH aqueous solution complete neutralization.Such as
Fruit needs, and can also carry out purification step and/or bleaching (for light product needed for adjusting).
In an especially preferred embodiment, compound (A) is used in the form of technical grade.This means corresponding carboxylic
Thus acid, especially natural acid gaseous sulfur trioxide sulphation produce in partially or completely with gained acidity sulphation
After object, the mixture of compound (A), (C) and (D) are obtained.By accordingly adjusting response parameter (especially carboxylic acid and sulfur trioxide
Molar ratio and reaction temperature), can control the ratio of compound (A), (C) and (D).Compound (C) and (D) are below
Chapters and sections " preferred embodiment " in description.
In the context of the present invention, preferably with the technical grade mixing of those of consisting of α-sulfofattyacidsaltb
Object:
(A) content is 60-100 weight %,
(C) content is 0-20 weight %,
(D) content is 0-20 weight %,
Condition is that the summation of the component (A), (C) and (D) in the mixture is 100 weight %.
Compound (B)
It is known as the compound (B) of sulfosuccinate in the context of the present invention for aqueous surfactant of the present invention
Composition is necessary.They have above-mentioned formula (II)
R31-O-CO-CH(SO3M16)-CH2-COOM17 (II)
Wherein group R31It is the straight chain or branched-alkyl or alkenyl or former with 6-22 carbon with 6-22 carbon atom
The alkoxylate straight chain or branched-alkyl or alkenyl of son, and group M16And M17It is independently selected from comprising following group:
H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine.
Compound (B) can be prepared by all correlation techniques well known by persons skilled in the art.The weight of prepare compound (B)
Want method as follows: in two-step method, with alcohol or alcohol alkoxylates, (this addition for being interpreted as ethylene oxide and alcohol is produced first
Object) make maleic anhydride esterification.Then make the maleate obtained in this case sulfonation in aqueous solution of sodium bisulfite.
In one embodiment, applicable condition is the wherein group R in aqueous surfactant compound31It is alkene
The ratio of the compound (B) of base is based on the total amount of compound (B) as 3 weight % or less.
In one embodiment, the group R in formula (II)31It is the straight chain saturated alkyl with 12-18 carbon atom,
In for compound (B), situation is wherein group R31It is the ratio base of the compound (B) of dodecyl and/or myristyl
In the total amount of compound (B) be 70 weight % or more, preferably 90 weight % or more.
In one embodiment, the group R in formula (II)31Be with 8-18, especially 12-18 carbon atom it is straight
Alkyl group.
In another preferred embodiment of the present, the group R in formula (II)31It is-(CH2-CH2-O)p-R5Group, wherein p is 1-4
Number, and group R5It is the straight chained alkyl with 12-18 carbon atom.
The change of particularly preferred INCI entitled lauryl polyethers disodium sulfosuccinate and lauryl disodium sulfosuccinate
It closes object (B).
Group M in formula (II)16And M17It is preferably selected from comprising following group: H (hydrogen) and Na (sodium).Preferred embodiment
In one embodiment, aqueous surfactant compositions of the present invention go back volume in addition to compound (A), (B) and water
Outside include the compound (C) of one or more logical formula (III)s:
R4COOM5(III)。
In formula (III), group R4It is that there is the straight chain or branched-alkyl or alkenyl of 7-19 carbon atom, and group M5
Selected from including following group: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine.In this regard, particularly preferred alkanolamine
It is monoethanolamine, diethanol amine, triethanolamine and monoisopropanolamine.
In one embodiment, aqueous surfactant compositions of the present invention go back volume in addition to compound (A), (B) and water
Outside include the inorganic salts (D) of the sulfuric acid of one or more logical formula (IV)s:
(M6)2SO4(IV)
Wherein M6Selected from including following group: Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine.In this regard, especially excellent
The alkanolamine of choosing is monoethanolamine, diethanol amine, triethanolamine and monoisopropanolamine.
In a preferred embodiment, aqueous surfactant compositions of the present invention include compound (A), (B), (C)
(D).The group M of particularly preferred compound (A) in this case1And M2, compound (B) group M16And M17, compound
(C) group M5With the group M of compound (D)6Selected from the group comprising H (hydrogen) and Na (sodium).
In one embodiment, aqueous surfactant compositions of the present invention go back volume in addition to compound (A), (B) and water
Outside include the compound (F) of one or more logical formula (VI)s:
R6CH2-CO-CHR7(SO3M8) (VI),
Wherein group R6And R7It is that there is the straight chain or branched-alkyl of 6-18 carbon atom independently of each other, and group M8
Selected from including following group: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine.In this regard, particularly preferred alkanolamine
It is monoethanolamine, diethanol amine, triethanolamine and monoisopropanolamine.
In the context of the present invention, compound (F) is referred to as single sulfo group ketone.
In a preferred embodiment, the group R in formula (VI)6And R7It is with 10-16 carbon atom independently of each other
Straight chain saturated alkyl, wherein for compound (F), situation is wherein group R6And R7For the change of decyl and/or dodecyl
It is 70 weight % or more, preferably 90 weight % or more that the ratio for closing object (F), which is based on the total amount of compound (F),.In formula (VI)
Group M8It is preferably selected from the group comprising H and Na.
In one embodiment, aqueous surfactant compositions of the present invention go back volume in addition to compound (A), (B) and water
Outside include the compound (G) of one or more logical formula (VII)s:
(SO3M9)R8CH-CO-CHR9(SO3M10) (VII),
Wherein group R8And R9It is that there is the straight chain or branched-alkyl of 6-18 carbon atom independently of each other, and group M9
And M10It is independently selected from comprising following group: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine.In this regard, especially
Preferred alkanolamine is monoethanolamine, diethanol amine, triethanolamine and monoisopropanolamine.
In the context of the present invention, compound (G) is referred to as disulfo ketone.
In a preferred embodiment, the group R in formula (VII)8And R9It is former with 10-16 carbon independently of each other
The saturated straight chain group of son, wherein for compound (G), situation is wherein group R8And R9For decyl and/or dodecyl
The total amount that the ratio of compound (G) is based on compound (G) is 70 weight % or more, preferably 90 weight % or more.Formula (VII)
In group M9And M10It is preferably selected from the group comprising H and Na.
The preparation of compound (F) and (G) is not any particular limitation, and they can be by known to those skilled in the art
All methods preparation.
In one embodiment, compound (F) and (G) with the corresponding ketone of gaseous sulfur trioxide sulfonation by being prepared, such as
Described in German Prospectus DE-A-42,20,580.
In another embodiment, the preparation of compound (F) and (G) are by fatty acid.In this case, gaseous state is used
Sulfur trioxide makes the carrying out so that in addition to disalt (A) of liquid fatty acid sulphation, also formation compound (F) and (G), this can be with
Carry out due to carrying out sulphation as follows: adjusting raw material of fatty acid, (it can also be with the mixture shape of the fatty acid of different chain length
Formula uses) make every moles of fatty acids use 1.0-1.5mol, especially 1.0-1.25mol SO with the ratio of sulfur trioxide3。
Fatty acid is introduced into reactor under 70-100 DEG C of tank temperature.After sulphation, gained liquid sulfur acidizing product is kept
And aging 5-20 minutes at such a temperature in the rear reaction coil pipe of controlled temperature.Then use aqueous bases, preferably sodium hydroxide into
Row neutralizes, usually within the scope of the pH of 5-10, especially 5-7.Then, pH value is adjusted to 7 or lower here by acid bleaching-
Value-can be carried out with hydrogen peroxide.
In one embodiment, aqueous surfactant compositions of the present invention include compound (A), (B) and (F).?
In this case the group M of particularly preferred compound (A)1And M2And the group M of compound (B)16And M17Selected from including H (hydrogen)
With the group of Na (sodium).In this case, applicable condition is that the amount of compound (A) has to be larger than the amount of compound (F).
In one embodiment, aqueous surfactant compositions of the present invention include compound (A), (B) and (G).?
In this case the group M of particularly preferred compound (A)1And M2With the group M of compound (B)16And M17Selected from including H's and Na
Group.In this case, applicable condition is that the amount of compound (A) has to be larger than the amount of compound (G).
In one embodiment, aqueous surfactant compositions of the present invention include compound (A), (B), (F) and
(G).The group M of particularly preferred compound (A) in this case1And M2And the group M of compound (B)16And M17Selected from packet
Group containing H and Na.In this case, applicable condition is that the amount of compound (A) has to be larger than the amount of compound (F) and (G)
Summation.
In one embodiment, aqueous surfactant compositions of the present invention include compound (A), (B), (C), (D)
(F).The group M of particularly preferred compound (A) in this case1And M2, compound (B) group M16And M17, compound
(C) group M5With the group M of compound (D)6Selected from the group comprising H and Na.In this case, applicable condition is chemical combination
The amount of object (A) has to be larger than the amount of compound (F).
In one embodiment, aqueous surfactant compositions of the present invention include compound (A), (B), (C), (D)
(G).The group M of particularly preferred compound (A) in this case1And M2, compound (B) group M16And M17, compound
(C) group M5With the group M of compound (D)6Selected from the group comprising H and Na.In this case, applicable condition is chemical combination
The amount of object (A) has to be larger than the amount of compound (G).
In one embodiment, aqueous surfactant compositions of the present invention include compound (A), (B), (C), (D),
(F) and (G).The group M of particularly preferred compound (A) in this case1And M2, compound (B) group M16And M17, chemical combination
The group M of object (C)5With the group M of compound (D)6Selected from the group comprising H and Na.In this case, applicable being of condition
The amount for closing object (A) has to be larger than the summation of compound (F) and the amount of (G).
If desired, aqueous surfactant compositions of the present invention can additionally include one or more other surface-actives
Agent is not belonging to above compound (A), (B), (D), (E), (F) or (G) for structure.These surfactants can be
Anion, cation, nonionic or amphoteric surfactant.The purposes of composition
Another theme of the invention is purposes of the aforementioned composition in cosmetic product and detergent and detergent.
For cosmetic product, here particularly preferably especially with shampoo, bath gels, soap, synthetic detergent, washing
Cream, cleans preparation, bubble bath, oil bath, bath, shaving foam, shaving emulsion, shaving cream and dental care products at cleaning solution
Those of (such as toothpaste, mouthwash etc.) form presence.
For detergent, here preferably in particular for the product with low ph value of cleaning of hard surfaces, such as bathroom
With detergent for toilet etc., and cleaning and/or fragrant gel (frangrance gel) for sanitary installation.
Embodiment
Substance used
DM water=softened water
SFA: it is based on original C12/14The α-sulfofattyacidsaltb with technical grade quality of fatty acid；Composition: 74 weights
Measure %2- sulfolauric acid disodium, 13 weight % sodium laurates, 11 weight % sodium sulphate, 2 weight % water.In this case,
Indicate the C of the mixture for the original fatty acid that " laruate " indicates that they are based on12/14Weight ratio is 70:30.
SB3:Texapon SB3, lauryl polyethers disodium sulfosuccinate (INCI title), 33 weight % active materials,
The commodity of BASF PCN
Measurement and test method
The measurement of foaming capacity:
In order to test foaming behavior (rotor foam method), business measuring instrument (Sita Foam TesterR- is used
2000).Prepare aqueous surfactant solution as follows first: by each sample 1g active material to be tested (using SFA or SB3 or
The mixture of these substances sees below as sample；In the case where SFA-as described above-activity substance content is interpreted as anticipating
Refer to two salt contents) it is dissolved at 20 DEG C in 1 liter of DM water.The pH of solution is adjusted to 5.5 with citric acid.The solution that will thus prepare
Temperature control at 30 DEG C.
Measurement: the raw material of 250ml controlled temperature is transferred in measuring instrument and with 1300 revs/min of rotation speed hair
Bubble 10 seconds measures existing foam volume (in terms of ml), then foams again 10 seconds, measures existing foam volume (in terms of ml)
Deng the every 10 seconds measurement foam heights that is, in foaming process.After 80 seconds foamed times, measurement is terminated.To each sample
Duplicate measurements 3 times, the fresh solution from identical batch is used every time, and the measurement result after 80 seconds is averaged with what this was measured three times
Value (see the table below) indicates.
Embodiment
E1=embodiment 1 (present invention):
Using the mixture of SFA and Texapon SB3, wherein the weight ratio of the corresponding active material of SFA and SB3 is set
For the value of 2:1.Experiment described in " measurement of foaming capacity " as carried out above.Experimental data is found in table 1.
E2=embodiment 2 (present invention):
Using the mixture of SFA and Texapon SB3, wherein the weight ratio of the corresponding active material of SFA and SB3 is set
For the value of 1:1.
E3=embodiment 3 (present invention):
Using the mixture of SFA and Texapon SB3, wherein the weight ratio of the corresponding active material of SFA and SB3 is set
For the value of 1:2.
E4=embodiment 4 (present invention):
Using the mixture of SFA and Texapon SB3, wherein the weight ratio of the corresponding active material of SFA and SB3 is set
For the value of 1:5.
C1=comparative example 1:
Using only SFA.
C2=comparative example 2:
Using only SB3.
Table 1: the measurement of foaming capacity
Individual SFA is shown unsatisfactory foam volume (comparative example 1), and the mixture of all SFA and SB3
(surprisingly, even embodiment 1 is with significant excess of SFA) has very high foam volume, suitable with SB3.
Claims (10)
1. a kind of aqueous surfactant compositions, include:
The α-sulfofattyacidsaltb (A) of one or more logical formula (I)s,
R1CH(SO3M1)COOM2 (I)
Wherein group R1It is that there is the straight chain or branched-alkyl or alkenyl of 6-18 carbon atom, and group M1And M2Mutually solely
It is on the spot selected from and includes following group: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine,
The sulfosuccinate (B) of one or more logical formula (II)s,
R31-O-CO-CH(SO3M16)-CH2-COOM17 (II)
Wherein group R31It is the straight chain or branched-alkyl or alkenyl or with 6-22 carbon atom with 6-22 carbon atom
Alkoxylate straight chain or branched-alkyl or alkenyl, and group M16And M17It is independently selected from comprising following group: H,
Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine,
Water,
Wherein it is applicable in the following conditions:
If aqueous surfactant compositions include the sulfonated ester (E) of one or more logical formula (V)s,
R2CH(SO3M7)COOR3 (V)
Wherein group R2It is that there is the straight chain or branched-alkyl or alkenyl of 6-18 carbon atom, and group R3It is with 1-20
The straight chain or branched-alkyl or alkenyl of a carbon atom, wherein group R3Logically only it can be in 3 or more carbon atoms
Alkenyl or branching, and group M7Selected from following group: Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine is included, then
Situation is that the total amount that compound (A) is based on compound (A) and (E) must exist with the degree of 50 weight % or more.
2. composition according to claim 1, the wherein group R in formula (I)1It is the saturated straight chain alkane with 10-16 carbon atom
Base, wherein for compound (A), situation is wherein group R1It is that the ratio of the compound (A) of decyl or dodecyl is based on
The total amount of compound (A) is 90 weight % or more.
3. composition according to claim 1 or 2, wherein group M1And M2Selected from including following group: H (hydrogen) and Na (sodium).
4. composition as claimed in one of claims 1-3, wherein the composition additionally includes one or more general formulas
(III) compound (C):
R4COOM5 (III)
Wherein group R4It is that there is the straight chain or branched-alkyl or alkenyl of 7-19 carbon atom, and group M5Selected from comprising as follows
Group: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine.
5. composition as claimed in one of claims 1-4, wherein the composition additionally includes one or more general formulas
(IV) inorganic salts (D) of sulfuric acid:
(M6)2SO4 (IV)
Wherein M6Selected from including following group: Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine.
6. composition as claimed in one of claims 1-5, wherein the composition additionally contains one or more general formulas
(VI) single sulfo group ketone (F):
R6CH2-CO-CHR7(SO3M8) (VI),
Wherein group R6And R7It is that there is the straight chain or branched-alkyl of 6-18 carbon atom independently of each other, and group M8It is selected from
Include following group: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine.
7. composition as claimed in one of claims 1-6, wherein the composition additionally includes one or more general formulas
(VII) disulfo ketone (G):
(SO3M9)R8CH-CO-CHR9(SO3M10) (VII),
Wherein group R8And R9It is that there is the straight chain or branched-alkyl of 6-18 carbon atom independently of each other, and group M9And M10
It is independently selected from comprising following group: H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamine.
8. purposes of the composition as claimed in one of claims 1-7 in cosmetic product and detergent and detergent.
9. composition as claimed in one of claims 1-7 is in shampoo, bath gels, soap, synthetic detergent, washing
Cream, cleans preparation, bubble bath, oil bath, bath, shaving foam, shaving emulsion, shaving cream and dental care products at cleaning solution
Purposes in the cosmetic product of form.
10. composition as claimed in one of claims 1-7 is in the product with low ph value for cleaning of hard surfaces, such as
Bathroom and detergent for toilet etc., and for the purposes in the cleaning and/or fragrant gel of sanitary installation.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16170204.8 | 2016-05-18 | ||
| EP16170204.8A EP3246010A1 (en) | 2016-05-18 | 2016-05-18 | Aqueous tenside compositions |
| PCT/EP2017/061324 WO2017198537A1 (en) | 2016-05-18 | 2017-05-11 | Aqueous surfactant compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109195577A true CN109195577A (en) | 2019-01-11 |
Family
ID=56024149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780030454.5A Pending CN109195577A (en) | 2016-05-18 | 2017-05-11 | aqueous surfactant compositions |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10933006B2 (en) |
| EP (2) | EP3246010A1 (en) |
| JP (1) | JP6980700B2 (en) |
| KR (1) | KR102400210B1 (en) |
| CN (1) | CN109195577A (en) |
| BR (1) | BR112018073297B1 (en) |
| ES (1) | ES2863668T3 (en) |
| PL (1) | PL3458024T3 (en) |
| WO (1) | WO2017198537A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3246007A1 (en) | 2016-05-18 | 2017-11-22 | Basf Se | Aqueous tenside compositions |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4861508A (en) * | 1987-03-05 | 1989-08-29 | Henkel Kommanditgesellschaft Auf Aktien | Moulded detergent compositions |
| DE4220580A1 (en) * | 1992-06-24 | 1994-01-13 | Henkel Kgaa | New alpha-sulpho carbonyl cpds. useful as surfactants - prepd. by sulphonating higher aldehyde or ketone with sulphur tri:oxide |
| WO1998044907A1 (en) * | 1997-04-08 | 1998-10-15 | Henkel Kommanditgesellschaft Auf Aktien | Aqueous skin and hair care products |
| WO2016030172A1 (en) * | 2014-08-27 | 2016-03-03 | Basf Se | Aqueous surfactant compositions |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2195088A (en) * | 1938-04-30 | 1940-03-26 | Ig Farbenindustrie Ag | Sulphonated ketones |
| DE3707014A1 (en) * | 1987-03-05 | 1988-09-15 | Henkel Kgaa | AQUEOUS SURFACTANT COMPOSITIONS WITH ALPHA SULFOUR ACID SALTS |
| JPH02105896A (en) * | 1988-10-14 | 1990-04-18 | Sanyo Chem Ind Ltd | Liquid detergent composition |
| EP0964674A2 (en) * | 1996-12-19 | 1999-12-22 | Rhodia Inc. | Liquid delivery systems |
| US5965508A (en) * | 1997-10-21 | 1999-10-12 | Stepan Company | Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and long chain fatty acids |
| KR102281376B1 (en) * | 2013-07-12 | 2021-07-27 | 스테판 컴파니 | Personal cleansers and surfactant blend therefor |
| FR3013968B1 (en) * | 2013-11-29 | 2016-12-09 | Oreal | AQUEOUS GEL FOAM CLEANING COMPOSITION COMPRISING ALKYL SULFOACETATE, SULFOSUCCINATE, AND SULFONATE FATTY ACID SALT |
| ES2667168T3 (en) * | 2014-02-04 | 2018-05-09 | Basf Se | Aqueous surfactant compositions |
| DK3292180T3 (en) * | 2015-05-07 | 2019-07-15 | Rhodia Operations | FORMULATIONS FOR IMPROVED OIL DEVICE INCLUDING SULPHONATES |
-
2016
- 2016-05-18 EP EP16170204.8A patent/EP3246010A1/en not_active Withdrawn
-
2017
- 2017-05-11 KR KR1020187036431A patent/KR102400210B1/en active IP Right Grant
- 2017-05-11 JP JP2018560578A patent/JP6980700B2/en active Active
- 2017-05-11 PL PL17722047T patent/PL3458024T3/en unknown
- 2017-05-11 WO PCT/EP2017/061324 patent/WO2017198537A1/en unknown
- 2017-05-11 ES ES17722047T patent/ES2863668T3/en active Active
- 2017-05-11 CN CN201780030454.5A patent/CN109195577A/en active Pending
- 2017-05-11 BR BR112018073297-4A patent/BR112018073297B1/en active IP Right Grant
- 2017-05-11 EP EP17722047.2A patent/EP3458024B1/en active Active
- 2017-05-11 US US16/301,472 patent/US10933006B2/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4861508A (en) * | 1987-03-05 | 1989-08-29 | Henkel Kommanditgesellschaft Auf Aktien | Moulded detergent compositions |
| DE4220580A1 (en) * | 1992-06-24 | 1994-01-13 | Henkel Kgaa | New alpha-sulpho carbonyl cpds. useful as surfactants - prepd. by sulphonating higher aldehyde or ketone with sulphur tri:oxide |
| WO1998044907A1 (en) * | 1997-04-08 | 1998-10-15 | Henkel Kommanditgesellschaft Auf Aktien | Aqueous skin and hair care products |
| WO2016030172A1 (en) * | 2014-08-27 | 2016-03-03 | Basf Se | Aqueous surfactant compositions |
Non-Patent Citations (4)
| Title |
|---|
| BEN MILWIDSKY: ""磺基琥珀酸盐"", 《日用化学工业译丛》 * |
| ESIKA: "《Hair and Body Shampoo》", 31 December 2015 * |
| 方亮等: "《全国高等医药院校药学类第四轮规划教材 药剂学 第3版》", 31 March 2016, 中国医药科技出版社 * |
| 曾作祥等: "《普通高等教育"十二五"规划教材 界面现象》", 31 January 2016, 华东理工大学出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2863668T3 (en) | 2021-10-11 |
| JP2019516716A (en) | 2019-06-20 |
| KR102400210B1 (en) | 2022-05-20 |
| JP6980700B2 (en) | 2021-12-15 |
| BR112018073297B1 (en) | 2022-01-18 |
| EP3246010A1 (en) | 2017-11-22 |
| US20190216706A1 (en) | 2019-07-18 |
| KR20190008563A (en) | 2019-01-24 |
| EP3458024B1 (en) | 2021-01-13 |
| BR112018073297A2 (en) | 2019-02-26 |
| WO2017198537A1 (en) | 2017-11-23 |
| PL3458024T3 (en) | 2021-07-19 |
| US10933006B2 (en) | 2021-03-02 |
| EP3458024A1 (en) | 2019-03-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106659658B (en) | Aqueous surfactant composition | |
| JP2018009189A (en) | Internal olefin sulfonate composition and detergent composition containing the same | |
| CN105934236B (en) | Aqueous surfactant composition | |
| ES2599030T3 (en) | Liquid cleaning compositions | |
| JP6231393B2 (en) | Internal olefin sulfonate composition | |
| BR112012010370B1 (en) | alkyl sulfomethyl succinates, process for making a sulfomethyl succinate and products comprising the same | |
| JP2014077126A (en) | Internal olefin sulfonate composition and detergent composition containing the same | |
| MX2009000272A (en) | Alkyl lactyllactates and processes of making the same. | |
| JP6542935B2 (en) | Internal olefin sulfonate composition | |
| CN105934237A (en) | Aqueous surfactant compositions | |
| JP6272058B2 (en) | Internal olefin sulfonate composition | |
| CN109195577A (en) | aqueous surfactant compositions | |
| CN109196084A (en) | aqueous surfactant compositions | |
| CN109153939A (en) | aqueous surfactant compositions | |
| CN109152715A (en) | aqueous surfactant compositions | |
| CN109152717A (en) | aqueous surfactant compositions | |
| CN109195576A (en) | aqueous surfactant compositions | |
| CN109312264A (en) | Aqueous surfactant compositions | |
| JPH02206695A (en) | Detergent composition | |
| CN109475481A (en) | Aqueous surfactant compositions | |
| US10869824B2 (en) | Aqueous surfactant compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190111 |