CN109187904A - A kind of water quality heavy metal home monitor device for Ca+ displacement - Google Patents

A kind of water quality heavy metal home monitor device for Ca+ displacement Download PDF

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Publication number
CN109187904A
CN109187904A CN201811126658.1A CN201811126658A CN109187904A CN 109187904 A CN109187904 A CN 109187904A CN 201811126658 A CN201811126658 A CN 201811126658A CN 109187904 A CN109187904 A CN 109187904A
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China
Prior art keywords
titanium
water
water quality
ion exchange
heavy metal
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CN201811126658.1A
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Chinese (zh)
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CN109187904B (en
Inventor
张晓婷
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Jiaxing Sheng Yuan industrial designs Co.,Ltd.
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张晓婷
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Priority to CN201811126658.1A priority Critical patent/CN109187904B/en
Publication of CN109187904A publication Critical patent/CN109187904A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • G01N33/1813Water specific cations in water, e.g. heavy metals
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K13/00Thermometers specially adapted for specific purposes
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • G01N33/1886Water using probes, e.g. submersible probes, buoys

Abstract

The invention discloses a kind of water quality heavy metal home monitor device for Ca+ displacement, structure includes waterproof fuselage, low-power chip, detection display screen, battery, top cover, temperature sensor, Titanium TDS probe, pen cap.The utility model has the advantages that the present invention utilizes the water being equipped with to wipe resistance antistructure, the water and contacts ionic exchange resin for avoiding its surface of Titanium TDS probe from adhering to, to influence Ca+Replacement result, while the hydroxide also completely cut off inside its water causes to aoxidize to Titanium, and then so that it becomes fragile, influence using, using the ion exchange mechanism being equipped with, the Ca to dissociate for Titanium TDS detecting probe surface+It is replaced; avoiding it from reacting during Titanium TDS probe subsequent use with detection liquid generation influences testing result; so that it is guaranteed that the normal water of patient; pass through the revived structure being equipped with; under the action of burr by it inside common salt aqueous solution be delivered to inside ion exchange mechanism so that the ion exchange resin expanded is regenerated.

Description

A kind of water quality heavy metal home monitor device for Ca+ displacement
Technical field
The present invention relates to water quality heavy metal monitoring instrument fields, more precisely, being a kind of water quality weight for Ca+ displacement Metal home monitor device.
Background technique
With the raising of people's quality of the life, more and more people more focus on water quality, it contains very in drinking water Mostly micro- minerals, when detecting water quality, the Ca that inside contains+、Fe+、Mg+To solution colour developing, it will cause false positives, so for With calculosis and still for the patient of calcium calculus, its state of an illness can then be aggravated by drinking the water containing calcium ion, be directed to such Patient's existing market release can use at home and have this Ca+The monitoring instrument of detection greatly facilitates the water of patient Matter drinks problem, avoids having an impact the state of an illness in terms of drinking-water, because monitor probe its to use be titanium alloy, titanium closes Gold its there are such impurity such as oxygen, nitrogen, carbon, hydrogen, be usually to be wiped to probe after detection, but because of the calcium in drinking water Ion is free state, while monitor detects water quality, can be reacted with the oxygen in probe, and be attached to detecting head surface, Then there are dirts for its detecting head surface in long-term use for instrument, and its main component of dirt is calcium ion, is made next time in user Used time, calcium ion then will affect detection effect, while titanium of the titanium alloy in it be when encountering hydroxide, then can tender.
Summary of the invention
In view of the deficienciess of the prior art, it is an object of the present invention to provide a kind of water quality heavy metal men for Ca+ displacement With monitoring instrument, with solve the prior art monitor probe its to use be titanium alloy, titanium alloy its there are oxygen, nitrogen, Such impurity such as carbon, hydrogen usually wipes probe after detection, but because the calcium ion in drinking water is free shape State while monitor detects water quality, can react, and be attached to detecting head surface, instrument makes for a long time with the oxygen in probe Then there are dirts for its detecting head surface in, and its main component of dirt is calcium ion, next in use, its calcium ion in user Then will affect detection effect, while titanium of the titanium alloy in it makes encountering hydroxide, then can tender defect.
To achieve the goals above, the present invention is to realize by the following technical solutions:
A kind of water quality heavy metal home monitor device for Ca+ displacement, structure includes waterproof fuselage, low-power consumption core Piece, detection display screen, battery, top cover, temperature sensor, Titanium TDS probe, pen cap, the low-power chip are set to waterproof Fuselage interior is simultaneously electrically connected, and the detection display screen is installed on waterproof fuselage front surface middle and upper part, the electricity by being embedded mode Pond is installed on waterproof fuselage internal upper part and is fastened by top cover, and the temperature sensor is set to waterproof underbelly, the metal Titanium TDS probe is installed on temperature sensor lower part and is electrically connected, and the pen cap is set to waterproof underbelly and passes through manner It is connected, the pen cap includes that inner casing, water wipe resistance antistructure, ion exchange mechanism, revived structure, and the water wipes resistance antistructure peace Loaded on inner casing middle and lower part and four edges are by glued fixed, and the ion exchange mechanism is equipped with two altogether and is respectively arranged in regeneration At left and right sides of structure, the revived structure is installed on lower wall in inner casing.
As the present invention, further scheme, the water wipe resistance antistructure and include hollow limiting slot, movable roll shaft, position bullet Spring, extrusion cylinder, the hollow limiting slot set there are two altogether and are respectively arranged in inner casing front and rear wall, and the activity roll shaft is equipped with four altogether Root and respectively in pairs and protruding into inside hollow limiting slot, the activity roll shaft is connected by retaining spring, described to squeeze Pressure cylinder sets there are four altogether and is connected respectively with movable roll shaft by fitting.
As the present invention further scheme, the extrusion cylinder surface is equipped with method suede sliver, extrusion cylinder spacing two-by-two No more than 1mm, realizes the water stain wiping to its surface of Titanium TDS probe, dissociant in excessive water is avoided to enter ion Exchange mechanism, to Ca+Displacement have an impact.
As the present invention further scheme, the ion exchange mechanism includes column precipitator, deformation layer, burr, described to set It changes column and is equipped with two altogether, the deformation layer is equipped with two layers altogether and is respectively arranged in the middle part of column precipitator, and the burr is equipped with several And respectively 331 groups be installed on deformation layer by revived structure side, deformation layer is squeezed after being expanded using ion exchange resin Pressure, so that burr is contacted with revived structure, and then its internal liquid is delivered in column precipitator, realizes ion exchange resin again It is raw.
As the present invention further scheme, the column precipitator interior layer hollow structure and with Titanium TDS probe diameter It is identical, ion exchange resin is equipped with inside the column precipitator, its volume of the ion exchange resin is 2/3rds of column precipitator, Free diffusing after facilitating ion exchange resin to expand.
As the present invention, further scheme, the revived structure include limited post, isocon, selfreparing pad, the limit Position column is installed in the middle part of inner casing lower inner wall, and the isocon is equipped with two groups altogether and is respectively arranged at left and right sides of limited post and runs through It is connected, the selfreparing pad is equipped with two pieces altogether and is respectively arranged in and shunts outside inside pipe wall.
As the present invention, further scheme, the limited post inside are in hollow structure, are equipped with food inside the limited post Saline solution realizes regeneration of ion-exchange resin.
As the present invention, further scheme, the selfreparing pad are PET polyethylene terephthalate composition, are realized Burr can be automatically repaired broken hole after detaching selfreparing pad, avoid its internal solution outflow.
Invention beneficial effect
Relatively in traditional water quality heavy metal monitor, the invention has the following advantages:
The present invention utilizes the water being equipped with to wipe resistance antistructure, and the water and ion for avoiding its surface of Titanium TDS probe from adhering to are handed over Resin contact is changed, to influence Ca+Replacement result, while the hydroxide also completely cut off inside its water causes oxygen to Titanium Change, and then so that it becomes fragile, influence using.
The present invention utilizes the ion exchange mechanism being equipped with, the Ca to dissociate for Titanium TDS detecting probe surface+It is replaced, Avoiding it from reacting during Titanium TDS probe subsequent use with detection liquid generation influences testing result, so that it is guaranteed that The normal water of patient.
The present invention passes through the revived structure that is equipped with, under the action of burr by it inside common salt aqueous solution be delivered to ion Inside exchange mechanism, so that the ion exchange resin expanded is regenerated.
Detailed description of the invention
By reading referring to attached drawing detailed description of non-limiting embodiments, other feature of the invention, purpose It will be become more apparent upon with advantage.
In the accompanying drawings:
Fig. 1 is a kind of structural schematic diagram of the water quality heavy metal home monitor device for Ca+ displacement of the present invention.
Fig. 2 is a kind of positive sectility structural plan figure of pen cap of the present invention.
Fig. 3 is the overlooking structure diagram that a kind of water of the present invention wipes resistance antistructure.
Fig. 4 is a kind of inside top structural schematic diagram of pen cap of the present invention.
In figure: waterproof fuselage -1, low-power chip -2, detection display screen -3, battery -4, top cover -5, temperature sensor -6, Titanium TDS probe -7, pen cap -8, inner casing -80, water wipe resistance antistructure -81, ion exchange mechanism -82, revived structure -83, sky Heart limiting slot -810, movable roll shaft -811, retaining spring -812, extrusion cylinder -813, column precipitator -820, deformation layer -821, burr - 822, limited post -830, isocon -831, selfreparing pad -832.
Specific embodiment
To be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, below with reference to Specific embodiment, the present invention is further explained.
As Figure 1-Figure 4, the present invention provides a kind of technology of water quality heavy metal home monitor device for Ca+ displacement Scheme:
A kind of water quality heavy metal home monitor device for Ca+ displacement, structure includes waterproof fuselage 1, low-power consumption core Piece 2, detection display screen 3, battery 4, top cover 5, temperature sensor 6, Titanium TDS probe 7, pen cap 8, the low-power chip 2 It set on 1 inside of waterproof fuselage and is electrically connected, the detection display screen 3 is installed in 1 front surface of waterproof fuselage by being embedded mode Top, the battery 4 are installed on 1 internal upper part of waterproof fuselage and are fastened by top cover 5, and the temperature sensor 6 is set to splashproof machine 1 lower part of body, the Titanium TDS probe 7 are installed on 6 lower part of temperature sensor and are electrically connected, and the pen cap 8 is set to waterproof fuselage 1 lower part is simultaneously connected by manner, the pen cap 8 include inner casing 80, water wipe resistance antistructure 81, ion exchange mechanism 82, Revived structure 83, the water wipe resistance antistructure 81 and are installed on 80 middle and lower part of inner casing and four edges by glued fixed, the ion Exchange mechanism 82 is equipped with two altogether and is respectively arranged in 83 left and right sides of revived structure, and the revived structure 83 is installed on inner casing 80 Middle lower wall.
It includes hollow limiting slot 810, movable roll shaft 811, retaining spring 812, extrusion cylinder that the water, which wipes resistance antistructure 81, 813, the hollow limiting slot 810 sets there are two altogether and is respectively arranged in 80 front and rear wall of inner casing, and the activity roll shaft 811 is equipped with altogether Four and respectively in pairs and protruding into inside hollow limiting slot 810, the activity roll shaft 811 passes through 812 phase of retaining spring Connection, the extrusion cylinder 813 set there are four altogether and are connected respectively with movable roll shaft 811 by fitting.
813 surface of extrusion cylinder is equipped with method suede sliver, and spacing is no more than 1mm to the extrusion cylinder 813 two-by-two, realizes to gold The water stain wiping for belonging to 7 its surface of titanium TDS probe, avoids dissociant in excessive water from entering ion exchange mechanism, to Ca+Set It changes and has an impact.
The ion exchange mechanism 82 includes column precipitator 820, deformation layer 821, burr 822, and the column precipitator 820 is equipped with altogether Two, the deformation layer 821 is equipped with two layers altogether and is respectively arranged in the middle part of column precipitator 820, the burr 822 be equipped with several and Respectively deformation layer 821 is installed on by 83 side of revived structure, to deformation layer 821 after expanding using ion exchange resin for 331 groups Extruding realize that ion is handed over so that burr 822 is contacted with revived structure 83, and then its internal liquid is delivered in column precipitator Change the regeneration of resin.
The 820 interior layer hollow structure of column precipitator and identical as Titanium TDS 7 diameters of probe, in the column precipitator 820 Portion is equipped with ion exchange resin, its volume of the ion exchange resin is 2/3rds of column precipitator 820, facilitates amberlite Free diffusing after rouge expansion.
The revived structure 83 includes limited post 830, isocon 831, selfreparing pad 832, and the limited post 830 is installed on In the middle part of 80 lower inner wall of inner casing, the isocon 831 is equipped with two groups altogether and is respectively arranged in 830 left and right sides of limited post and runs through phase Connection, the selfreparing pad 832 are equipped with two pieces altogether and are respectively arranged in outside 831 inner wall of isocon.
It is in hollow structure inside the limited post 830, is equipped with common salt aqueous solution inside the limited post 830, realizes ion The regeneration of exchanger resin.
The selfreparing pad 832 is PET polyethylene terephthalate composition, realizes that burr 822 is detaching selfreparing After pad 832, it can be automatically repaired broken hole, avoid its internal solution outflow.
In conclusion the absorption using ion exchange resin to high-valence cationic, 7 surface of Titanium TDS probe is dissociated Ca+It is adsorbed, avoids it from forming dirt in detecting probe surface, connect and influence subsequent detection, simultaneously also by ion exchange resin Transition, carries out palingenesis to it by common salt aqueous solution.
It is as follows that it implements principle: will test the Titanium TDS probe 7 finished and is inserted into inside pen cap 8, fastens and avoid It being destroyed, Titanium TDS probe 7, which is inserted into pen cap 8 to first pass around water and wipe, hinders antistructure 81, and what Titanium TDS probe 7 was equipped with Two probes pass through the gap of two extrusion cylinders 813, have wiped under the method suede sliver rubbing action that its surface is equipped with by water stain Finish, avoids influencing in water stain entrance ion exchange mechanism 82 to Ca+Absorption, because movable roll shaft 811 is connected by retaining spring 812 It connects, so expanding when probe passes through 813 gap of extrusion cylinder to two sides, probe is inserted into inside column precipitator 820, then in it Lower generate with it of the ion exchange resin effect in portion is reacted, the Ca that its surface is dissociated+It carries out absorption and is replaced as other cations, To which probe in use next time can Ca in accurate detection water quality+, make its testing result will not impacted while probe table It face will not be because of Ca+And dirt is generated, and ion exchange resin is in absorption Ca+During its can then expand, while to deformation layer 821 cause to squeeze, so that deformation layer 821 expands outwardly, and burr 822 then finishes in ion exchange resin absorption and is expanded into maximum While value, it is inserted into selfreparing pad 832, the common salt aqueous solution inside limited post 830 is delivered to by displacement by isocon 831 Inside column 820, and the contacts ionic exchange resin after absorption, and then realize regeneration of ion-exchange resin.
Problems solved by the invention be the prior art because monitor probe its to use be titanium alloy, titanium alloy its There are such impurity such as oxygen, nitrogen, carbon, hydrogen, usually wipe to probe after detection, but because of the calcium ion in drinking water For free state, while monitor detects water quality, can react with the oxygen in probe, and be attached to detecting head surface, instrument Then its detecting head surface is there are dirt in long-term use, and its main component of dirt is calcium ion, in user's next time in use, Its calcium ion then will affect detection effect, while titanium of the titanium alloy in it makes encountering hydroxide, then can tender, the present invention By being combined with each other for above-mentioned component, the present invention utilizes the water being equipped with to wipe resistance antistructure, avoids its surface of Titanium TDS probe attached Water and contacts ionic exchange resin, to influence Ca+Replacement result, while also completely cutting off the hydroxide inside its water Titanium is caused to aoxidize, and then so that it becomes fragility, influences using using the ion exchange mechanism being equipped with, for Titanium The free Ca of TDS detecting probe surface+Replaced, avoid its during Titanium TDS probe subsequent use with detection liquid Generating reaction influences testing result, so that it is guaranteed that the normal water of patient, through the revived structure being equipped with, under the action of burr Its internal common salt aqueous solution is delivered to inside ion exchange mechanism, so that the ion exchange resin expanded is regenerated.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention, for this field skill For art personnel, it is clear that invention is not limited to the details of the above exemplary embodiments, and without departing substantially from spirit of the invention or In the case where essential characteristic, the present invention can be realized in other specific forms.Therefore, in all respects, should all incite somebody to action Embodiment regards exemplary as, and is non-limiting, the scope of the present invention by appended claims rather than on state Bright restriction, it is intended that including all changes that fall within the meaning and scope of the equivalent elements of the claims in the present invention It is interior.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (8)

1. a kind of water quality heavy metal home monitor device for Ca+ displacement, structure includes waterproof fuselage (1), low-power consumption core Piece (2), detection display screen (3), battery (4), top cover (5), temperature sensor (6), Titanium TDS probe (7), pen cap (8), Be characterized in that: the low-power chip (2) is set to waterproof fuselage (1) inside and is electrically connected, and the detection display screen (3) passes through embedding If mode is installed on waterproof fuselage (1) front surface middle and upper part, the battery (4) is installed on waterproof fuselage (1) internal upper part and passes through Top cover (5) fastens, and the temperature sensor (6) is set to waterproof fuselage (1) lower part, and the Titanium TDS probe (7) is installed on temperature Degree sensor (6) lower part is simultaneously electrically connected, and the pen cap (8) is set to waterproof fuselage (1) lower part and is connected by manner;
The pen cap (8) includes that inner casing (80), water wipe resistance antistructure (81), ion exchange mechanism (82), revived structure (83), institute It states water and wipes resistance antistructure (81) and be installed on inner casing (80) middle and lower part and four edges by glued fixed, the ion exchange mechanism (82) it is equipped with two altogether and is respectively arranged at left and right sides of revived structure (83), the revived structure (83) is installed on inner casing (80) Middle lower wall.
2. a kind of water quality heavy metal home monitor device for Ca+ displacement according to claim 1, it is characterised in that: It includes hollow limiting slot (810), movable roll shaft (811), retaining spring (812), extrusion cylinder that the water, which wipes resistance antistructure (81), (813), the hollow limiting slot (810) sets there are two altogether and is respectively arranged in inner casing (80) front and rear wall, the activity roll shaft (811) it is equipped with four altogether and is respectively in pairs and to protrude into hollow limiting slot (810) inside, the activity roll shaft (811) is logical It crosses retaining spring (812) to be connected, the extrusion cylinder (813) sets there are four altogether and passes through fitting with movable roll shaft (811) respectively It is connected.
3. a kind of water quality heavy metal home monitor device for Ca+ displacement according to claim 2, it is characterised in that: Extrusion cylinder (813) surface is equipped with method suede sliver, and spacing is no more than 1mm to the extrusion cylinder (813) two-by-two.
4. a kind of water quality heavy metal home monitor device for Ca+ displacement according to claim 1, it is characterised in that: The ion exchange mechanism (82) includes column precipitator (820), deformation layer (821), burr (822), and the column precipitator (820) sets altogether There are two, the deformation layer (821) is equipped with two layers altogether and is respectively arranged in the middle part of column precipitator (820), and the burr (822) is equipped with Several and respectively 331 groups are installed on deformation layer (821) by revived structure (83) side.
5. a kind of water quality heavy metal home monitor device for Ca+ displacement according to claim 4, it is characterised in that: Column precipitator (820) the interior layer hollow structure and, column precipitator (820) inside identical as Titanium TDS probe (7) diameter Equipped with ion exchange resin, its volume of the ion exchange resin is 2/3rds of column precipitator (820).
6. a kind of water quality heavy metal home monitor device for Ca+ displacement according to claim 1, it is characterised in that: The revived structure (83) includes limited post (830), isocon (831), selfreparing pad (832), limited post (830) installation In the middle part of inner casing (80) lower inner wall, the isocon (831) is equipped with two groups altogether and is respectively arranged at left and right sides of limited post (830) And through being connected, the selfreparing pad (832) is equipped with two pieces altogether and is respectively arranged in outside isocon (831) inner wall.
7. a kind of water quality heavy metal home monitor device for Ca+ displacement according to claim 6, it is characterised in that: It is in hollow structure inside the limited post (830), is equipped with common salt aqueous solution inside the limited post (830).
8. a kind of water quality heavy metal home monitor device for Ca+ displacement according to claim 6, it is characterised in that: The selfreparing pad (832) is PET (polyethylene terephthalate) composition.
CN201811126658.1A 2018-09-26 2018-09-26 Domestic monitoring instrument of quality of water heavy metal to Ca2+ replacement Active CN109187904B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110186449A1 (en) * 2008-06-06 2011-08-04 Ecole Polytechnique Method and device using nanoporous membrane for detecting and quantifying heavy metal ions in a fluid by anodic stripping voltammetry
CN203750898U (en) * 2014-03-27 2014-08-06 重庆润泽医药有限公司 Wiping supporting base for electric coagulation forceps
CN104990960A (en) * 2015-06-30 2015-10-21 佛山市云米电器科技有限公司 TDS detector pen
CN205556166U (en) * 2016-04-13 2016-09-07 上海腾玉节能科技有限公司 Automatic domestic soft water apparatus for producing of control quality
CN106153621A (en) * 2015-03-16 2016-11-23 北京中清国研环境技术研究院 A kind of water quality monitoring automatically cleaning film sensors
CN206440656U (en) * 2016-11-22 2017-08-25 郝娇阳 A kind of improved domestic type water quality detection pen device of structure
CN206772960U (en) * 2017-05-24 2017-12-19 中科兴创(北京)科技有限公司 A kind of water quality detection pen
CN206988495U (en) * 2017-05-02 2018-02-09 北京洁明伟业环境工程有限公司 A kind of scale-free heat conductive flow controller

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110186449A1 (en) * 2008-06-06 2011-08-04 Ecole Polytechnique Method and device using nanoporous membrane for detecting and quantifying heavy metal ions in a fluid by anodic stripping voltammetry
CN203750898U (en) * 2014-03-27 2014-08-06 重庆润泽医药有限公司 Wiping supporting base for electric coagulation forceps
CN106153621A (en) * 2015-03-16 2016-11-23 北京中清国研环境技术研究院 A kind of water quality monitoring automatically cleaning film sensors
CN104990960A (en) * 2015-06-30 2015-10-21 佛山市云米电器科技有限公司 TDS detector pen
CN205556166U (en) * 2016-04-13 2016-09-07 上海腾玉节能科技有限公司 Automatic domestic soft water apparatus for producing of control quality
CN206440656U (en) * 2016-11-22 2017-08-25 郝娇阳 A kind of improved domestic type water quality detection pen device of structure
CN206988495U (en) * 2017-05-02 2018-02-09 北京洁明伟业环境工程有限公司 A kind of scale-free heat conductive flow controller
CN206772960U (en) * 2017-05-24 2017-12-19 中科兴创(北京)科技有限公司 A kind of water quality detection pen

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