CN109183197A - A kind of antidetonation anticorrosion carbon fiber pipeline and preparation method thereof - Google Patents
A kind of antidetonation anticorrosion carbon fiber pipeline and preparation method thereof Download PDFInfo
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- CN109183197A CN109183197A CN201810983473.6A CN201810983473A CN109183197A CN 109183197 A CN109183197 A CN 109183197A CN 201810983473 A CN201810983473 A CN 201810983473A CN 109183197 A CN109183197 A CN 109183197A
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- Prior art keywords
- carbon fiber
- powder
- antidetonation
- metal oxide
- anticorrosion
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Abstract
The present invention relates to submarine pipeline shake-proof technology field, in particular to a kind of antidetonation anticorrosion carbon fiber pipeline and preparation method thereof.It is intended to provide a kind of antidetonation anticorrosion carbon fiber pipeline, which is characterized in that the electrostatic spinning after hydro-thermal reaction forms eutectic is made carbon fiber pipeline by carbon fiber and metal oxide powder.The anti-seismic performance and Corrosion Protection that sea transport pipeline can be effectively improved, improve the transmission performance of oil field pipe.Its drip irrigation device is as follows, and carbon fiber and the metal oxide powder electrostatic spinning after hydro-thermal reaction forms eutectic are made.Metal oxide powder includes following components: Y2O3、ZrO2、Al2O3、Yb2O3.Preparation method is by Y2O3、ZrO2、Al2O3And Yb2O3The uniform in the mixed solvent that is dissolved in of powder color, which is ground to, with agate mortar obtains mixed solution；Carbon fiber is added into mixed solution and organic amine template obtains suspension；Suspension is put into crystallization in baking oven and is centrifugally separating to obtain powder, powder calcining crystal powder is subjected to electrostatic spinning into pipe again.
Description
Technical field
The present invention relates to submarine pipeline shake-proof technology field, in particular to a kind of antidetonation anticorrosion carbon fiber pipeline and its preparation
Method.
Background technique
In today of sea transport industry high development, ocean engineering and all kinds of ocean operations are all increasingly frequent, however due to
The characteristic of seawater itself, so that it causes strong corrosion attack to many facilities, meanwhile, tsunami, earthquake took place frequently in recent years,
Great destruction is caused to the transport pipeline in ocean, therefore, marine anticorrosion is shockproof to have become a highly important project.
Shockproof in view of marine anticorrosion is a highly important cause, according to measuring and calculating, China every year because marine facility it is damaged caused by warp
Ji loss alreadys exceed 1 trillion yuan, and wherein marine corrosion proportion reaches one third.Wherein submarine pipeline transport is that ocean is anti-
Rotten shockproof pith.At sea in oil exploitation, offshore oil pipeline is by marine petroleum-gas fiedl oil storage facility or land processing
Terminal connects into an organic whole, and offshore production facility links is made to form interrelated, mutually coordinated work by pipeline
Industry production operation system, offshore oil pipeline is the important component in marine engineering equipment, in the prior art, to Yu Haiyang
The etch-proof research of transport pipeline is more, but does not almost have in the etch-proof research shockproof simultaneously for sea transport pipeline
Have.
Summary of the invention
The object of the present invention is to provide a kind of shockproof transport carbon fiber pipelines, have good shock resistance and anticorrosive property, together
When make sea transport pipeline lightweight, convenient stand paving and transport.
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of shockproof transport carbon fiber pipeline, carbon fiber pipeline are formed altogether by carbon fiber and metal oxide powder through hydro-thermal reaction
Electrostatic spinning is made after crystalline substance.
Further, metal oxide powder includes following components: Y2O3: 5-8, ZrO2: 59-73, Al2O3: 13-19,
Yb2O3: 1-15.
Further, the diameter of carbon fiber is 0.3 μm -1.2 μm.
Further, a kind of preparation method of shockproof transport carbon fiber pipeline, comprising the following steps:
Step 1. is by Y2O3、ZrO2、Al2O3And Yb2O3It is uniform that powder color is ground to agate mortar, and it is mixed to obtain metal oxide
Close powder；
Metal oxide mixed-powder obtained in step 1 is dissolved in the mixed solvent by step 2., and stirring 3-5h obtains mixing molten
Liquid；
Carbon fiber and organic amine template are added into the mixed solution in step 2 for step 3., continue stir 4-8h obtain it is suspended
Liquid；
The suspension that step 4. obtains step 3 is put into baking oven, and temperature is kept for 120-150 DEG C, centrifugation point after crystallization 12-48h
From obtaining powder, powder calcined 1h at 300-400 DEG C, obtains crystal powder；
Crystal powder electrostatic spinning is become the carbon fiber pipe by step 5..
Further, organic amine template is ethylenediamine, n-butylamine, cetyl trimethylammonium bromide, urea or four fourths
Any one in base ammonium bromide.
Further, mixed solvent is water-organic solvent and deionized mixture；The matter of organic solvent and deionized water
Amount is than being (0.8-1.2): 1.
Further, organic solvent is appointing in ethylene glycol, glycerine, ethyl alcohol, acetone, tetrahydrofuran, DMF or n-hexane
It anticipates one kind.
Further, it calculates as mass fraction, the metal oxide mixed-powder, organic amine template, mixes carbon fiber
The mass ratio of bonding solvent is 20-30:25-40:1-5:40-80.
By using above-mentioned technical proposal, the shockproof transport carbon fiber pipeline of one kind provided by the invention makes carbon fiber and gold
After belonging to oxide formation eutectic, it is directly formed to tubing by the way of electrostatic spinning, there is good anti seismic efficiency and anti-corrosion
Lose effect.
In conclusion the invention has the following advantages:
1. the shockproof transport carbon fiber pipeline of one kind provided by the invention, the incorporation of Yb can introduce association defect, one side Yb, Y with
Defect association between oxygen defect can make crystal more stable, and doped chemical is not easy to be lost from crystal；Even if on the other hand
The case where there are doped chemical losses due to long-time military service, the lesser Yb of defect association energy is more easy to run off, so that it is guaranteed that Y retains
In crystalline framework, the corrosion resistance of coating is improved；
2. a kind of antidetonation anticorrosion carbon fiber pipeline provided by the invention, under hydrothermal conditions with carbon fiber by metal oxide
Eutectic is formed, then carries out electrostatic spinning, the chemical bond for foring strength between object and carbon fiber is oxidized metal, with traditional spray
Painting is compared with coating processes, and contacting between metal oxide and carbon fiber is even closer, the situation that will not be lost powder, simultaneously
The compactness for increasing carbon fibre material reduces the electric conductivity of carbon fibre material, improves the wearability of carbon fibre material,
The service life for effectively increasing carbon fiber pipeline is allowed to be more applicable for the transport of ocean pipeline section；
3. a kind of antidetonation anticorrosion carbon fiber pipeline provided by the invention, organic amine template joined in step 2, and
Calcining is sloughed in step 4, it is intended to form micropore and mesoporous in the eutectic structure of metal oxide and carbon fiber, micropore and
Mesoporous tool, being capable of sulphur effectively in extraction duct so that there are high specific surface area in the eutectic of metal oxide and carbon fiber
Change the pernicious gases such as hydrogen, further functions as the effect for preventing pipeline to be corroded；
4. a kind of antidetonation anticorrosion carbon fiber pipeline provided by the invention, select diameter for 0.3 μm -1.2 μm of carbon fiber, if
Expected anti seismic efficiency is then not achieved less than 0.3 μm in diameter, and if more than 1.2 μm, it is blocked up to will lead to carbon fiber duct wall, after giving
The construction of phase causes certain difficulty；
5. a kind of antidetonation anticorrosion carbon fiber pipeline provided by the invention, metal oxide mixed-powder and carbon fiber are 20-
30:25-40, if carbon fiber is excessive, metal oxide can not coat carbon fiber, be unable to reach and improve the wear-resisting of tubing
Property purpose, if metal oxide powder is excessive, the anti-seismic performance of tubing declines.
Specific embodiment
A kind of antidetonation anticorrosion carbon fiber pipeline, carbon fiber pipeline is by carbon fiber and metal oxide powder through hydro-thermal reaction
Electrostatic spinning is made after forming eutectic.
As a preferred embodiment, it calculates as mass fraction, metal oxide powder includes following components: Y2O3: 5-8,
ZrO2: 59-73, Al2O3: 13-19, Yb2O3: 1-15.
As a preferred embodiment, the diameter of carbon fiber is 0.3 μm -1.2 μm.
As a preferred embodiment, a kind of preparation method of antidetonation anticorrosion carbon fiber pipeline the following steps are included:
Step 1. is by Y2O3、ZrO2、Al2O3And Yb2O3It is uniform that powder color is ground to agate mortar, and it is mixed to obtain metal oxide
Close powder；
Metal oxide mixed-powder obtained in step 1 is dissolved in the mixed solvent by step 2., and stirring 3-5h obtains mixing molten
Liquid；
Carbon fiber and organic amine template are added into the mixed solution in step 2 for step 3., continue stir 4-8h obtain it is suspended
Liquid；
The suspension that step 4. obtains step 3 is put into baking oven, and temperature is kept for 120-150 DEG C, centrifugation point after crystallization 12-48h
From obtaining powder, powder calcined 1h at 300-400 DEG C, obtains crystal powder；
Crystal powder electrostatic spinning is become the carbon fiber pipe by step 5..
As a preferred embodiment, organic amine template is ethylenediamine, n-butylamine, cetyl trimethylammonium bromide, urine
Element or tetrabutylammonium bromide in any one.
As a preferred embodiment, mixed solvent is water-organic solvent and deionized mixture；The organic solvent with
The mass ratio of deionized water is (0.8-1.2): 1.
As a preferred embodiment, organic solvent be ethylene glycol, glycerine, ethyl alcohol, acetone, tetrahydrofuran, DMF or just oneself
Any one in alkane.
As a preferred embodiment, it calculates as mass fraction, the metal oxide mixed-powder, carbon fiber, organic amine
The mass ratio of template, mixed solvent are as follows: 20-30:25-40:1-5:40-80.
Embodiment 1: a kind of antidetonation anticorrosion carbon fiber pipeline, preparation step are as follows:
Step 1. is by 5 parts of Y2O3, 59 parts of ZrO2, 19 parts of Al2O3With 15 parts of Yb2O3It is uniform that powder color is ground to agate mortar,
Obtain metal oxide mixed-powder；
Step 2. takes metal oxide mixed-powder obtained in 20 parts of steps 1 to be dissolved in 22 parts of deionized waters and 18 parts of ethylene glycol
In, stirring 3h obtains mixed solution；
40 parts of carbon fibers and 5 parts of ethylenediamines are added into the mixed solution in step 2 for step 3., continue stir 8h obtain it is suspended
Liquid；
The suspension that step 4. obtains step 3 is put into baking oven, and temperature is kept for 120 DEG C, is centrifugated, is obtained after crystallization 48h
Powder is calcined 1h at 400 DEG C, obtains crystal powder by powder；
Crystal powder electrostatic spinning is become the carbon fiber pipe by step 5..
Embodiment 2: a kind of antidetonation anticorrosion carbon fiber pipeline, preparation step are as follows:
Step 1. is by 8 parts of Y2O3, 73 parts of ZrO2, 13 parts of Al2O3With 1 part of Yb2O3It is uniform that powder color is ground to agate mortar, is obtained
To metal oxide mixed-powder；
Step 2. takes metal oxide mixed-powder obtained in 30 parts of steps 1 to be dissolved in 40 parts of deionized waters and 40 parts of glycerine
In, stirring 3h obtains mixed solution；
25 parts of carbon fibers and 1 part of n-butylamine are added into the mixed solution in step 2 for step 3., continue stir 4h obtain it is suspended
Liquid；
The suspension that step 4. obtains step 3 is put into baking oven, and temperature is kept for 150 DEG C, and crystallization is centrifugated afterwards for 24 hours, is obtained
Powder is calcined 1h at 300 DEG C, obtains crystal powder by powder；
Crystal powder electrostatic spinning is become the carbon fiber pipe by step 5..
Embodiment 3: a kind of antidetonation anticorrosion carbon fiber pipeline, preparation step are as follows:
Step 1. is by 7 parts of Y2O3, 60 parts of ZrO2, 15 parts of Al2O3With 10 parts of Yb2O3It is uniform that powder color is ground to agate mortar,
Obtain metal oxide mixed-powder；
Step 2. takes metal oxide mixed-powder obtained in 25 parts of steps 1 to be dissolved in 18 parts of deionized waters and 22 parts of ethyl alcohol,
Stirring 3h obtains mixed solution；
30 parts of carbon fibers and 3 parts of cetyl trimethylammonium bromides are added into the mixed solution in step 2 for step 3., continue to stir
It mixes 6h and obtains suspension；
The suspension that step 4. obtains step 3 is put into baking oven, and temperature is kept for 150 DEG C, is centrifugated, is obtained after crystallization 12h
Powder is calcined 1h at 350 DEG C, obtains crystal powder by powder；
Crystal powder electrostatic spinning is become the carbon fiber pipe by step 5..
Embodiment 4: a kind of antidetonation anticorrosion carbon fiber pipeline, preparation step are as follows:
Step 1. is by 6 parts of Y2O3, 15 parts of ZrO2, 10 parts of Al2O3With 2 parts of Yb2O3It is uniform that powder color is ground to agate mortar, is obtained
To metal oxide mixed-powder；
Step 2. takes metal oxide mixed-powder obtained in 25 parts of steps 1 to be dissolved in 25 parts of deionized waters and 25 parts of tetrahydrofurans
In, stirring 3h obtains mixed solution；
30 parts of carbon fibers and 3 parts of tetrabutylammonium bromide are added into the mixed solution in step 2 for step 3., continue stirring 6h and obtain
Suspension；
The suspension that step 4. obtains step 3 is put into baking oven, and temperature is kept for 150 DEG C, and crystallization is centrifugated afterwards for 24 hours, is obtained
Powder is calcined 1h at 300 DEG C, obtains crystal powder by powder；
Crystal powder electrostatic spinning is become the carbon fiber pipe by step 5..
Embodiment 5: a kind of antidetonation anticorrosion carbon fiber pipeline, preparation step are as follows:
Step 1. is by 7 parts of Y2O3, 60 parts of ZrO2, 15 parts of Al2O3With 10 parts of Yb2O3It is uniform that powder color is ground to agate mortar,
Obtain metal oxide mixed-powder；
Step 2. takes metal oxide mixed-powder obtained in 25 parts of steps 1 to be dissolved in 18 parts of deionized waters and 22 parts of DMF, stirs
It mixes 3h and obtains mixed solution；
30 parts of carbon fibers and 3 parts of urea are added into the mixed solution in step 2 for step 3., continue stirring 6h and obtain suspension；
The suspension that step 4. obtains step 3 is put into baking oven, and temperature is kept for 150 DEG C, is centrifugated, is obtained after crystallization 12h
Powder is calcined 1h at 350 DEG C, obtains crystal powder by powder；
Crystal powder electrostatic spinning is become the carbon fiber pipe by step 5..
Embodiment 6: a kind of antidetonation anticorrosion carbon fiber pipeline, preparation step are as follows:
Step 1. is by 6 parts of Y2O3, 15 parts of ZrO2, 10 parts of Al2O3With 2 parts of Yb2O3It is uniform that powder color is ground to agate mortar, is obtained
To metal oxide mixed-powder；
Step 2. takes metal oxide mixed-powder obtained in 25 parts of steps 1 to be dissolved in 25 parts of deionized waters and 25 parts of tetrahydrofurans
In, stirring 3h obtains mixed solution；
30 parts of carbon fibers and 3 parts of cetyl trimethylammonium bromides are added into the mixed solution in step 2 for step 3., continue to stir
It mixes 6h and obtains suspension；
The suspension that step 4. obtains step 3 is put into baking oven, and temperature is kept for 150 DEG C, and crystallization is centrifugated afterwards for 24 hours, is obtained
Powder is calcined 1h at 300 DEG C, obtains crystal powder by powder；
Crystal powder electrostatic spinning is become the carbon fiber pipe by step 5..
A kind of antidetonation anticorrosion carbon fiber pipeline, preparation step are as follows:
Step 1. is by 6 parts of Y2O3, 15 parts of ZrO2, 10 parts of Al2O3With 4 parts of Yb2O3It is uniform that powder color is ground to agate mortar, is obtained
To metal oxide mixed-powder；
Step 2. takes metal oxide mixed-powder obtained in 25 parts of steps 1 to be dissolved in 25 parts of deionized waters and 25 parts of DMF, stirs
It mixes 3h and obtains mixed solution；
27 parts of carbon fibers and 4 parts of organic amine templates are added into the mixed solution in step 2 for step 3., continue stirring 8h and obtain
Suspension；
The suspension that step 4. obtains step 3 is put into baking oven, and temperature is kept for 150 DEG C, and crystallization is centrifugated afterwards for 24 hours, is obtained
Powder is calcined 1h at 400 DEG C, obtains crystal powder by powder；
Crystal powder electrostatic spinning is become the carbon fiber pipe by step 5..
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Claims (8)
1. a kind of antidetonation anticorrosion carbon fiber pipeline, which is characterized in that the carbon fiber pipeline is by carbon fiber and metal oxide
Powder electrostatic spinning after hydro-thermal reaction forms eutectic is made.
2. a kind of antidetonation anticorrosion carbon fiber pipeline according to claim 1, which is characterized in that it calculates as mass fraction,
The metal oxide powder includes following components: Y2O3: 5-8, ZrO2: 59-73, Al2O3: 13-19, Yb2O3: 1-15.
3. a kind of antidetonation anticorrosion carbon fiber pipeline according to claim 1, which is characterized in that the diameter of the carbon fiber
It is 0.3 μm -1.2 μm.
4. a kind of preparation method of antidetonation anticorrosion carbon fiber pipeline, which comprises the following steps:
Step 1. is by Y2O3、ZrO2、Al2O3And Yb2O3It is uniform that powder color is ground to agate mortar, and it is mixed to obtain metal oxide
Close powder；
Metal oxide mixed-powder obtained in step 1 is dissolved in the mixed solvent by step 2., and stirring 3-5h obtains mixing molten
Liquid；
Carbon fiber and organic amine template are added into the mixed solution in step 2 for step 3., continue stir 4-8h obtain it is suspended
Liquid；
The suspension that step 4. obtains step 3 is put into baking oven, and temperature is kept for 120-150 DEG C, centrifugation point after crystallization 12-48h
From obtaining powder, powder calcined 1h at 300-400 DEG C, obtains crystal powder；
Crystal powder electrostatic spinning is become the carbon fiber pipe by step 5..
5. a kind of preparation method of antidetonation anticorrosion carbon fiber pipeline according to claim 4, which is characterized in that described to have
Machine amine template is any one in ethylenediamine, n-butylamine, cetyl trimethylammonium bromide, urea or tetrabutylammonium bromide
Kind.
6. a kind of preparation method of antidetonation anticorrosion carbon fiber pipeline according to claim 4, which is characterized in that described mixed
Bonding solvent is water-organic solvent and deionized mixture；The organic solvent and the mass ratio of deionized water are (0.8-1.2):
1。
7. a kind of preparation method of antidetonation anticorrosion carbon fiber pipeline according to claim 6, the organic solvent is second
Any one in glycol, glycerine, ethyl alcohol, acetone, tetrahydrofuran, DMF or n-hexane.
8. a kind of preparation method of antidetonation anticorrosion carbon fiber pipeline according to claim 4, which is characterized in that press quality
Score calculate, the metal oxide mixed-powder, carbon fiber, organic amine template, mixed solvent mass ratio be 20-30:
25-40:1-5:40-80。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103531756A (en) * | 2013-11-01 | 2014-01-22 | 北京化工大学 | Carbon nanofiber loaded lithium titanate thin film materials and manufacturing method thereof |
| CN104499096A (en) * | 2014-12-21 | 2015-04-08 | 东南大学 | Preparation method of nano carbon fiber-metal composite capable of removing medium/low-concentration volatile organic compounds |
| CN104646038A (en) * | 2015-03-18 | 2015-05-27 | 重庆文理学院 | Bismuthyl iodide-carbon fiber composite nano material for visible light catalysis and preparation method thereof |
| CN104779378A (en) * | 2015-04-24 | 2015-07-15 | 福建师范大学泉港石化研究院 | Preparation method of cathode material of germanium-mesoporous carbon fiber composite lithium battery |
-
2018
- 2018-08-27 CN CN201810983473.6A patent/CN109183197A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103531756A (en) * | 2013-11-01 | 2014-01-22 | 北京化工大学 | Carbon nanofiber loaded lithium titanate thin film materials and manufacturing method thereof |
| CN104499096A (en) * | 2014-12-21 | 2015-04-08 | 东南大学 | Preparation method of nano carbon fiber-metal composite capable of removing medium/low-concentration volatile organic compounds |
| CN104646038A (en) * | 2015-03-18 | 2015-05-27 | 重庆文理学院 | Bismuthyl iodide-carbon fiber composite nano material for visible light catalysis and preparation method thereof |
| CN104779378A (en) * | 2015-04-24 | 2015-07-15 | 福建师范大学泉港石化研究院 | Preparation method of cathode material of germanium-mesoporous carbon fiber composite lithium battery |
Non-Patent Citations (4)
| Title |
|---|
| 刘献华: "不同结构碳增强铝复合材料的制备及组织性能研究", 《中国优秀硕士学位论文全文数据库工程科技I辑》 * |
| 徐俊等: "Yb/Y双掺杂氧化锆在熔盐腐蚀环境中的元素扩散和相变机理研究", 《材料研究学报》 * |
| 梁耀能: "《机械工程材料》", 31 January 2011, 华南理工大学出版社 * |
| 陈照峰: "《无机非金属材料学》", 29 February 2016, 西北工业大学出版社 * |
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