CN109181506A - A kind of no-solvent type curing glass coating and the preparation method and application thereof - Google Patents
A kind of no-solvent type curing glass coating and the preparation method and application thereof Download PDFInfo
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- CN109181506A CN109181506A CN201810960440.XA CN201810960440A CN109181506A CN 109181506 A CN109181506 A CN 109181506A CN 201810960440 A CN201810960440 A CN 201810960440A CN 109181506 A CN109181506 A CN 109181506A
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- solvent type
- type curing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/38—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal at least one coating being a coating of an organic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/118—Deposition methods from solutions or suspensions by roller-coating
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/32—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The present invention discloses a kind of no-solvent type curing glass coating and the preparation method and application thereof, wherein, the coating includes: three official's polyester acrylates of the silane coupling agent grafting of 40-50% by weight percentage, three official's urethane acrylates of 20-25%, two official's urethane acrylates of 5-10%, the hydroxyethyl methacrylate of 8-15%, the pentaerythritol triacrylate of 8-15%, the photoinitiator of 4-6% and the levelling agent 2100 of 0.02-0.05%.Since the silane coupling agent being grafted on three official's polyester acrylates can form covalent bond with the molecular action of the silanol groups or other inorganic filler surfaces of glass surface, the i.e. described silane coupling agent can play the function served as bridge interconnected between inorganic phase and organic phase, to effectively improve coating in the adhesive force of glass surface.
Description
Technical field
The present invention relates to paint field more particularly to a kind of no-solvent type curing glass coating and preparation method thereof with answer
With.
Background technique
For glass phase for other substrates, structure has very big difference.Glass itself is a kind of random knot
The non-crystalline solids of structure are also a kind of liquid from microcosmic, and it is a kind of metastable solids material that main component, which is silica,
Material, due to its particularity, general coating is difficult to generate adhesive force on its surface, and traditional coating is by adding coupling agent high temperature again
The mode of baking can solve the problem of its hardly possible attachment substantially.
Although addition coupling agent is very helpful to the adhesive force for solving heat curing coating, in UV photocureable coating
It is very unstable, it adds a few minutes or even polymerization reaction will be generated in tens seconds, it is difficult to implement in process of production,
It is difficult to control implementing stability.
Therefore, the existing technology needs to be improved and developed.
Summary of the invention
In view of above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide a kind of no-solvent type curing glass coating
And the preparation method and application thereof, it is intended to solving the problems, such as existing UV photocureable coating coating, adhesive force is poor on the glass substrate.
Technical scheme is as follows:
A kind of no-solvent type curing glass coating, wherein by weight percentage include: the silane coupling agent grafting of 40-50%
Three official's polyester acrylates, three official's urethane acrylates of 20-25%, two official's urethane acrylates of 5-10%, 8-15%
Hydroxyethyl methacrylate, the pentaerythritol triacrylate of 8-15%, the photoinitiator of 4-6% and the stream of 0.02-0.05%
Flat agent 2100.
The no-solvent type curing glass coating, wherein further include the phosphate of 0.5-1.5%.
The no-solvent type curing glass coating, wherein the photoinitiator is photoinitiator 184, photoinitiator
One of BDK and photoinitiator TPO or a variety of.
A kind of preparation method of no-solvent type curing glass coating, wherein comprising steps of
Dispersion cylinder is added in hydroxyethyl methacrylate and opens stirring, the photoinitiator is then added and stirs to being completely dissolved,
It is subsequently added into three official's polyester acrylates, three official's urethane acrylates and the two official's polyurethane propylene of silane coupling agent grafting
Acid esters is eventually adding levelling agent 2100 and is discharged after mixing evenly with 200 mesh net filtrations, the no-solvent type curing glass is made
Coating.
A kind of application of no-solvent type curing glass coating, wherein for gold stamped characters and pattern on the glass substrate, packet
Include step:
The no-solvent type curing glass coating is rolled on glass substrate, levelling 2-5min is toasted at 60-100 DEG C
Afterwards, it carries out being formed by curing the first paint film for the first time by UV photo solidification machine；
Vacuum plating is carried out in first surface of the paint film to aluminize, and is continued no-solvent type curing glass described in roller coating after degree is good and is applied
Material is formed by curing the second paint film by UV photo solidification machine after toasting levelling 2-5min at 60-100 DEG C for the second time；
Gold stamping transfer Decal is attached to second surface of the paint film, toasted at 150-200 DEG C tear after 25-40min it is described
Gold stamping transfer Decal, is left in gold stamped characters and pattern on the second paint film.
The application of the no-solvent type curing glass coating, wherein the first time solidifies and second cured solid
Changing energy is 1200-1500mj/cm2。
The utility model has the advantages that no-solvent type curing glass coating provided by the invention its by weight percentage include: 40-
Three official's polyester acrylates of 50% silane coupling agent grafting, three official's urethane acrylates of 20-25%, two officials of 5-10%
Urethane acrylate, the hydroxyethyl methacrylate of 8-15%, the pentaerythritol triacrylate of 8-15%, 4-6%'s is light-initiated
The levelling agent 2100 of agent and 0.02-0.05%.Since the silane coupling agent being grafted on three official's polyester acrylates can be with glass
The molecular action of the silanol groups on surface or other inorganic filler surfaces forms covalent bond, i.e., the described silane coupling agent can play
It is acted on as bridge interconnected between inorganic phase and organic phase, to effectively improve coating in the attachment of glass surface
Power.
Detailed description of the invention
Fig. 1 is a kind of flow chart using preferred embodiment of no-solvent type curing glass coating of the present invention.
Specific embodiment
It is of the invention to make the present invention provides a kind of no-solvent type curing glass coating and the preparation method and application thereof
Purpose, technical solution and effect are clearer, clear, and the present invention is described in more detail below.It should be appreciated that this place is retouched
It states that specific examples are only used to explain the present invention, is not intended to limit the present invention.
Traditional solvent type coating can only be carried out when doing plating and thermal transfer bronzing effect on glass in a manner of spraying, spray
It is toasted in 80-120 DEG C of hot environment 1-3 hours after applying coating, then carries out the plating and thermal transfer of next step, it is described molten
Dosage form coating has the following deficiencies: during production and construction
1), volatile organic compounds (VOC) discharges pollution that is excessively high, causing atmosphere and environment, does not meet national requirements for environmental protection；
2), the waste of the energy needs heating and thermostatic equipment for a long time, the effective component in coating due to the overlong time of baking
Low, through overbaking, all in air, and in order to reduce cost and improve workability, effective component reduces solvent for volatilization
To twenties to thirties, the waste of a large amount of power wastage and solvent is caused, the use of solvent can also be brought to construction personnel
Infliction of body.
Based on this, the present invention provides a kind of no-solvent type curing glass coating, wherein includes: by weight percentage
Three official's polyester acrylates of the silane coupling agent grafting of 40-50%, three official's urethane acrylates of 20-25%, the two of 5-10%
The light of official's urethane acrylate, the hydroxyethyl methacrylate of 8-15%, the pentaerythritol triacrylate of 8-15%, 4-6% draws
Send out agent and the levelling agent 2100 of 0.02-0.05%.
The coating of the present embodiment is a kind of environment-friendly type coating of solvent-free VOC free discharge, and the effective component of the coating is hundred
/ hundred, and the coating does not have to high-temperature baking, reduces the energy consumption in producer's production process, has saved a large amount of production cost；
The curing time of the coating UV be 1-5 seconds, and traditional paint solidification take time it is long, while energy saving significantly
Improve production efficiency.
It further, is also one kind from microcosmic due to the non-crystalline solids that glass itself is a kind of random structure
Liquid, main component are silica, are a kind of metastable solids materials, due to its particularity, traditional photocureable coating
Difficulty generates adhesive force on its surface.And the no-solvent type curing glass coating in the present embodiment connects by using silane coupling agent
Three official's polyester acrylates of branch can effectively solve the problem that photocureable coating the glass surface poor adhesive force the problem of.Specifically,
Since silane coupling agent contains two different chemical functional groups, described silane coupling agent one end is grafted to the three officials polyester third
Covalent bond is formed on olefin(e) acid ester, the other end can then be made with the silanol groups of glass surface or the molecule of other inorganic filler surfaces
With another covalent bond of formation；It is connected with each other between inorganic phase and organic phase that is, the silane coupling agent can be played
Function served as bridge, to effectively improve the present embodiment coating in the adhesive force of glass surface.
In the present embodiment, three official's polyester acrylates of the silane coupling agent grafting not only have very on glass
Strong adhesive force, and heat resistance is preferable.
In the present embodiment, the three officials urethane acrylate viscosity is very small, and reactivity is high, attached on glass
It is also very good to put forth effort.
In a preferred embodiment, the no-solvent type curing glass coating includes: by weight percentage
Three official's polyester acrylates of 45% silane coupling agent grafting, 23% three official's urethane acrylates, 8% two official's polyurethane
Acrylate, 10% hydroxyethyl methacrylate, 10% pentaerythritol triacrylate, 3.95% photoinitiator and
0.05% levelling agent 2100.
In a preferred embodiment, the photoinitiator is photoinitiator 184, photoinitiator b DK and light-initiated
One of agent TPO or a variety of, but not limited to this.
In a preferred embodiment, the no-solvent type curing glass coating, which can not only be used for priming paint, also can be used as
Finishing coat.Preferably, when as finishing coat, the no-solvent type curing glass coating further includes the phosphate of 0.5-1.5%, institute
Stating phosphate can be used for enhancing attachment to electroplated coating.
Further, the present invention also provides a kind of preparation methods of no-solvent type curing glass coating, wherein including step
It is rapid: dispersion cylinder is added in hydroxyethyl methacrylate and opens stirring, the photoinitiator is then added and stirs to being completely dissolved, connects
Be added silane coupling agent grafting three official's polyester acrylates, three official's urethane acrylates and two official's polyurethane acroleic acids
Ester is eventually adding levelling agent 2100 and is discharged after mixing evenly with 200 mesh net filtrations, and the no-solvent type curing glass is made and applies
Material.
In a kind of specific embodiment, dispersion cylinder first is added in hydroxyethyl methacrylate (HEMA) and opens stirring,
Then photoinitiator 184, photoinitiator b DK are sequentially added, then silicon is added to being completely dissolved in photoinitiator TPO high speed dispersion
Three official's polyester acrylates, three official's urethane acrylates and the stirring of two official's urethane acrylates of alkane coupling agent grafting are
It is even, it is eventually adding levelling agent 2100 and stirs 5 minutes, discharged with 200 mesh net filtrations, the no-solvent type curing glass is made and applies
Material.
Further, the present invention also provides a kind of applications of no-solvent type curing glass coating, wherein in glass
Gold stamped characters and pattern on substrate, as shown in Figure 1, comprising steps of
S100, the no-solvent type curing glass coating is rolled on glass substrate, levelling 2- is toasted at 60-100 DEG C
After 5min, carry out being formed by curing the first paint film for the first time by UV photo solidification machine；
S200, it aluminizes in first surface of the paint film progress vacuum plating, continues no-solvent type photocuring described in roller coating after degree is good
Glass coating is formed by curing the second paint by UV photo solidification machine after toasting levelling 2-5min at 60-100 DEG C for the second time
Film；
S300, gold stamping transfer Decal is attached to second surface of the paint film, is torn after toasting 25-40min at 150-200 DEG C
The gold stamping transfer Decal, is left in gold stamped characters and pattern on the second paint film.
In a preferred embodiment, the first coating is rolled on glass by roll coater, film thickness 12-
18ml is toasted levelling 3 minutes at 80 DEG C, crosses UV photo solidification machine, and curing is two 3.6 kilowatts of fluorescent tubes, solidification energy 1200-
1500 mj/cm2, vacuum plating is carried out after solidification and is aluminized, and is plated good rear roller coating or heating the second coating of spraying, is toasted stream at 80 DEG C
It is 3 minutes flat, UV photo solidification machine is crossed, curing is two 3.6 kilowatts of fluorescent tubes, solidification energy 1200-1500mj/cm2, after solidification
Gold stamping transfer Decal is attached to surface, 180 degree is toasted 30 minutes, tears film, gold stamped characters and pattern are left on paint film, complete
At the processing of finished product.
In the present embodiment, the formula components of first coating and the second coating are essentially the same, include 45% silane
Three official's polyester acrylates of coupling agent grafting, 23% three official's urethane acrylates, 8% two official's urethane acrylates,
10% hydroxyethyl methacrylate, 10% pentaerythritol triacrylate, 4% photoinitiator, the photoinitiator include light
Initiator 184, photoinitiator b DK, photoinitiator TPO and light levelling agent 2100；First coating and the second coating in the present embodiment
Being formulated almost the same is that can not scalded in order to which gold stamped characters can scald up with other conventional vacuum electroplating surface paints.Unlike
The phosphate of 0.5-1.5% is added in second coating, the phosphate can be used for enhancing the attachment to electroplated coating.
Further, the coating solidified in the present embodiment on the glass substrate is tested for the property, it is as a result as follows: described
The adhesive force of coating on the glass substrate is 5B, and the hardness of the coating is 1-2H, and the coating impregnates 7 days without blistering in water
Nothing falls off, adhesive force 5B；Without blistering, adhesive force is 5B to the coating after cooling within 1 hour in 180 DEG C of environment；The coating
Adhesive force is still 5B after boiling 1h at 100 DEG C；
Further, through detecting, the gold stamped characters are after 180 baking 1 hour without blistering, cracking, pin-free, the dry stir-frying of paint film etc.
Phenomenon, no changes have been made for other performances such as boiling 100 DEG C of 1 hour paint films attachment, meets the requirements of the customers.
In conclusion no-solvent type curing glass coating provided by the invention its by weight percentage include: 40-
Three official's polyester acrylates of 50% silane coupling agent grafting, three official's urethane acrylates of 20-25%, two officials of 5-10%
Urethane acrylate, the hydroxyethyl methacrylate of 8-15%, the pentaerythritol triacrylate of 8-15%, 4-6%'s is light-initiated
The levelling agent 2100 of agent and 0.02-0.05%.Since the silane coupling agent being grafted on three official's polyester acrylates can be with glass
The molecular action of the silanol groups on surface or other inorganic filler surfaces forms covalent bond, i.e., the described silane coupling agent can play
The function served as bridge interconnected between inorganic phase and organic phase, to effectively improve coating in the adhesive force of glass surface.
It should be understood that the application of the present invention is not limited to the above for those of ordinary skills can
With improvement or transformation based on the above description, all these modifications and variations all should belong to the guarantor of appended claims of the present invention
Protect range.
Claims (6)
1. a kind of no-solvent type curing glass coating, which is characterized in that by weight percentage include: the silane idol of 40-50%
Join three official's polyester acrylates of agent grafting, three official's urethane acrylates of 20-25%, two official's polyurethane acroleic acids of 5-10%
Ester, the hydroxyethyl methacrylate of 8-15%, the pentaerythritol triacrylate of 8-15%, the photoinitiator and 0.02- of 4-6%
0.05% levelling agent 2100.
2. no-solvent type curing glass coating according to claim 1, which is characterized in that further include the phosphorus of 0.5-1.5%
Acid esters.
3. no-solvent type curing glass coating according to claim 1, which is characterized in that the photoinitiator draws for light
Send out one of agent 184, photoinitiator b DK and photoinitiator TPO or a variety of.
4. a kind of preparation method of no-solvent type curing glass coating a method according to any one of claims 1-3, which is characterized in that
Comprising steps of
Dispersion cylinder is added in hydroxyethyl methacrylate and opens stirring, the photoinitiator is subsequently added into and stirs to being completely dissolved,
Then three official's polyester acrylates, three official's urethane acrylates and the two official's polyurethane propylene of silane coupling agent grafting are added
Acid esters is eventually adding levelling agent 2100 and is discharged after mixing evenly with 200 mesh net filtrations, the no-solvent type curing glass is made
Coating.
5. a kind of application of the no-solvent type curing glass coating as described in claim 1-3 is any, which is characterized in that be used for
Gold stamped characters and pattern on glass substrate, comprising steps of
The no-solvent type curing glass coating is rolled on glass substrate, levelling 2-5min is toasted at 60-100 DEG C
Afterwards, it carries out being formed by curing the first paint film for the first time by UV photo solidification machine；
Vacuum plating is carried out in first surface of the paint film to aluminize, and is continued no-solvent type curing glass described in roller coating after degree is good and is applied
Material is formed by curing the second paint film by UV photo solidification machine after toasting levelling 2-5min at 60-100 DEG C for the second time；
Gold stamping transfer Decal is attached to second surface of the paint film, toasted at 150-200 DEG C tear after 25-40min it is described
Gold stamping transfer Decal, is left in gold stamped characters and pattern on the second paint film.
6. the application of no-solvent type curing glass coating according to claim 5, which is characterized in that the first time solidification
It is 1200-1500mj/cm with second of cured solidification energy2。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810960440.XA CN109181506B (en) | 2018-08-22 | 2018-08-22 | Solvent-free photocuring glass coating and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810960440.XA CN109181506B (en) | 2018-08-22 | 2018-08-22 | Solvent-free photocuring glass coating and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109181506A true CN109181506A (en) | 2019-01-11 |
| CN109181506B CN109181506B (en) | 2020-11-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810960440.XA Active CN109181506B (en) | 2018-08-22 | 2018-08-22 | Solvent-free photocuring glass coating and preparation method and application thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116042083A (en) * | 2022-12-21 | 2023-05-02 | 长飞光纤光缆股份有限公司 | Silane modified low-refractive-index optical fiber coating |
| CN116042083B (en) * | 2022-12-21 | 2024-06-11 | 长飞光纤光缆股份有限公司 | Silane modified low-refractive-index optical fiber coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533068A (en) * | 2011-12-23 | 2012-07-04 | 上海紫江喷铝包装材料有限公司 | Ultraviolet curing aluminized transferring coating and preparation method and application thereof |
| CN107974193A (en) * | 2018-01-06 | 2018-05-01 | 珠海东诚光固化新材料股份有限公司 | A kind of ultraviolet light for glass color mirror cures pigmented finiss and its application |
| CN108264838A (en) * | 2017-12-29 | 2018-07-10 | 上海乘鹰新材料有限公司 | A kind of flexible, anti-pollution ultraviolet cured paint composition and preparation method thereof |
-
2018
- 2018-08-22 CN CN201810960440.XA patent/CN109181506B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533068A (en) * | 2011-12-23 | 2012-07-04 | 上海紫江喷铝包装材料有限公司 | Ultraviolet curing aluminized transferring coating and preparation method and application thereof |
| CN108264838A (en) * | 2017-12-29 | 2018-07-10 | 上海乘鹰新材料有限公司 | A kind of flexible, anti-pollution ultraviolet cured paint composition and preparation method thereof |
| CN107974193A (en) * | 2018-01-06 | 2018-05-01 | 珠海东诚光固化新材料股份有限公司 | A kind of ultraviolet light for glass color mirror cures pigmented finiss and its application |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116042083A (en) * | 2022-12-21 | 2023-05-02 | 长飞光纤光缆股份有限公司 | Silane modified low-refractive-index optical fiber coating |
| CN116042083B (en) * | 2022-12-21 | 2024-06-11 | 长飞光纤光缆股份有限公司 | Silane modified low-refractive-index optical fiber coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109181506B (en) | 2020-11-20 |
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