CN109181372A - A kind of ceramic coating of cracking resistance - Google Patents
A kind of ceramic coating of cracking resistance Download PDFInfo
- Publication number
- CN109181372A CN109181372A CN201810696913.XA CN201810696913A CN109181372A CN 109181372 A CN109181372 A CN 109181372A CN 201810696913 A CN201810696913 A CN 201810696913A CN 109181372 A CN109181372 A CN 109181372A
- Authority
- CN
- China
- Prior art keywords
- parts
- agent
- cracking resistance
- ceramic coating
- ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of ceramic coating of cracking resistance, ceramic industry technical field, it include: 80-85 parts of gas-phase silica by mass parts composition, 56-64 parts of epoxy curing agent, 20-28 parts of cesium hydroxide, 16-22 parts of silane coupling agent, 4-9 parts of surfactant, 10-15 parts of promotor, 4-8 parts of anti-aging agent, 1-5 parts of modified filler, 15-21 parts of nano ceramic powder, 23-28 parts of melamine, 4-10 parts of isophorone diisocyanate, 19-25 parts of methyl diphenylene diisocyanate, 11-16 parts of succinic anhydride, 20-25 parts of hydrazine hydrate, 13-19 parts of ammonium oxalate, 13-19 parts of anti-crack fiber, 23-28 parts of polyacrylic acid, 28-36 parts of deionized water.Usefulness of the present invention is to apply dye to arrive ceramic surface, effectively avoids ceramics from cracking, prolongs the service life.
Description
Technical field
The present invention relates to ceramic industry technical field, especially a kind of ceramic coating of cracking resistance.
Background technique
Coating Industry in Our Country is with a long history, and output and consumption figure are in rank first, and development prospect is wide, just
It is being increasingly becoming national economy new growth point.The early detection U.S., Japan, South Korea have some ceramic coatings in terms of research,
Report, but Related product is had not seen in its domestic market；With the development of society, ceramic coating occupy in many fields it is important
Status, and the approval by many consumers, ceramic use environment is sufficiently complex, this is greatly reduced using ceramics
Service life increases cost, so traditional ceramic material can no longer meet increasingly harsh job requirement and therefore develop one
The novel ceramic protective material of kind.
Summary of the invention
The present invention overcomes the disadvantages of the prior art, provides a kind of ceramic coating with cracking resistance function, applies dye and arrives
Ceramic surface effectively avoids ceramics from cracking, prolongs the service life.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of ceramic coating of cracking resistance includes: 80-85 parts of gas-phase silica, epoxy resin cure by mass parts composition
56-64 parts of agent, 16-22 parts of silane coupling agent, 4-9 parts of surfactant, 10-15 parts of promotor, is prevented 20-28 parts of cesium hydroxide
Old agent 4-8 parts, 1-5 parts of modified filler, 15-21 parts of nano ceramic powder, 23-28 parts of melamine, isophorone diisocyanate
4-10 parts of ester, 19-25 parts of methyl diphenylene diisocyanate, 11-16 parts of succinic anhydride, 20-25 parts of hydrazine hydrate, ammonium oxalate 13-
19 parts, 13-19 parts of anti-crack fiber, 23-28 parts of polyacrylic acid, 28-36 parts of deionized water.
It preferably, include: 83 parts of gas-phase silica, 58 parts of epoxy curing agent, cesium hydroxide 24 by mass parts composition
Part, 18 parts of silane coupling agent, 5 parts of surfactant, 13 parts of promotor, 6 parts of anti-aging agent, 4 parts of modified filler, nano ceramic powder
18 parts, 25 parts of melamine, 8 parts of isophorone diisocyanate, 20 parts of methyl diphenylene diisocyanate, succinic anhydride 15
Part, 23 parts of hydrazine hydrate, 15 parts of ammonium oxalate, 15 parts of anti-crack fiber, 25 parts of polyacrylic acid, 30 parts of deionized water.
Preferably, a kind of ceramic coating of cracking resistance, production method include the following steps:
(1) by polyacrylic acid, anti-crack fiber, deionized water, epoxy curing agent, cesium hydroxide, surfactant, rush
It is put into stirring ware into agent, is first heated to 70-75 DEG C, 20-25min is then stirred with the speed of 45-55r/min, then will
Anti-aging agent, modified filler, isophorone diisocyanate, methyl diphenylene diisocyanate, ammonium oxalate pour into, and use instead with 60-
The speed of 65r/min stirs 35-40min, finally again by gas-phase silica, silane coupling agent, nano ceramic powder, melamine
Amine, succinic anhydride, hydrazine hydrate pour into, and stir 28-34min with the speed of 15-18r/min；
(2) step (1) coating is poured into grinder, in 68-73 DEG C of grinding 10-12h.
Preferably, the promotor is dibutyl tin dilaurate.
Preferably, the anti-aging agent is N- phenyl-α-aniline.
Compared with prior art, the beneficial effects of the present invention are:
By the way that anti-crack fiber is added in formula, enables the ceramic coating have the function of cracking resistance, apply dye and arrive ceramic surface, have
Effect avoids ceramics from cracking, and prolongs the service life.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of ceramic coating of cracking resistance includes: 80 parts of gas-phase silica, epoxy curing agent 56 by mass parts composition
Part, 20 parts of cesium hydroxide, 16 parts of silane coupling agent, 4 parts of surfactant, 10 parts of promotor, 4 parts of anti-aging agent, modified filler 1
Part, 15 parts of nano ceramic powder, 23 parts of melamine, 4 parts of isophorone diisocyanate, methyl diphenylene diisocyanate 19
Part, 11 parts of succinic anhydride, 20 parts of hydrazine hydrate, 13 parts of ammonium oxalate, 13 parts of anti-crack fiber, 23 parts of polyacrylic acid, 28 parts of deionized water.
Preferably, a kind of ceramic coating of cracking resistance, production method include the following steps:
(1) by polyacrylic acid, anti-crack fiber, deionized water, epoxy curing agent, cesium hydroxide, surfactant, rush
Be put into stirring ware into agent, be first heated to 70 DEG C, 20min is then stirred with the speed of 45r/min, then by anti-aging agent, change
Property filler, isophorone diisocyanate, methyl diphenylene diisocyanate, ammonium oxalate pour into, and use the speed with 60r/min instead
35min is stirred, finally again by gas-phase silica, silane coupling agent, nano ceramic powder, melamine, succinic anhydride, hydrazine hydrate
It pours into, 28min is stirred with the speed of 15r/min；
(2) step (1) coating is poured into grinder, in 68 DEG C of grinding 10h.
Preferably, promotor is dibutyl tin dilaurate.
Preferably, anti-aging agent is N- phenyl-α-aniline.
Embodiment 2
A kind of ceramic coating of cracking resistance includes: 85 parts of gas-phase silica, epoxy curing agent 64 by mass parts composition
Part, 28 parts of cesium hydroxide, 22 parts of silane coupling agent, 9 parts of surfactant, 15 parts of promotor, 8 parts of anti-aging agent, modified filler 5
Part, 21 parts of nano ceramic powder, 28 parts of melamine, 10 parts of isophorone diisocyanate, methyl diphenylene diisocyanate
25 parts, 16 parts of succinic anhydride, 25 parts of hydrazine hydrate, 19 parts of ammonium oxalate, 19 parts of anti-crack fiber, 28 parts of polyacrylic acid, deionized water 36
Part.
Preferably, a kind of ceramic coating of cracking resistance, production method include the following steps:
(1) by polyacrylic acid, anti-crack fiber, deionized water, epoxy curing agent, cesium hydroxide, surfactant, rush
Be put into stirring ware into agent, be first heated to 75 DEG C, 25min is then stirred with the speed of 55r/min, then by anti-aging agent, change
Property filler, isophorone diisocyanate, methyl diphenylene diisocyanate, ammonium oxalate pour into, and use the speed with 65r/min instead
40min is stirred, finally again by gas-phase silica, silane coupling agent, nano ceramic powder, melamine, succinic anhydride, hydrazine hydrate
It pours into, 34min is stirred with the speed of 18r/min；
(2) step (1) coating is poured into grinder, in 73 DEG C of grinding 12h.
Preferably, promotor is dibutyl tin dilaurate.
Preferably, anti-aging agent is N- phenyl-α-aniline.
Finally, it should be noted that these are only the preferred embodiment of the present invention, it is not intended to restrict the invention, although
Referring to embodiment, invention is explained in detail, for those skilled in the art, still can be to aforementioned
Technical solution documented by each embodiment is modified or equivalent replacement of some of the technical features, but it is all
Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in protection of the invention
Within the scope of.
Claims (5)
1. a kind of ceramic coating of cracking resistance, which is characterized in that forming by mass parts includes: 80-85 parts of gas-phase silica, epoxy
56-64 parts of resin curing agent, 20-28 parts of cesium hydroxide, 16-22 parts of silane coupling agent, 4-9 parts of surfactant, promotor 10-
15 parts, 4-8 parts of anti-aging agent, 1-5 parts of modified filler, 15-21 parts of nano ceramic powder, 23-28 parts of melamine, isophorone two
4-10 parts of isocyanates, 19-25 parts of methyl diphenylene diisocyanate, 11-16 parts of succinic anhydride, 20-25 parts of hydrazine hydrate, oxalic acid
13-19 parts of ammonium, 13-19 parts of anti-crack fiber, 23-28 parts of polyacrylic acid, 28-36 parts of deionized water.
2. a kind of ceramic coating of cracking resistance according to claim 1, which is characterized in that forming by mass parts includes: gas phase
83 parts of white carbon black, 24 parts of cesium hydroxide, 18 parts of silane coupling agent, 5 parts of surfactant, promotes 58 parts of epoxy curing agent
13 parts of agent, 6 parts of anti-aging agent, 4 parts of modified filler, 18 parts of nano ceramic powder, 25 parts of melamine, isophorone diisocyanate
8 parts, 20 parts of methyl diphenylene diisocyanate, 15 parts of succinic anhydride, 23 parts of hydrazine hydrate, 15 parts of ammonium oxalate, 15 parts of anti-crack fiber,
25 parts of polyacrylic acid, 30 parts of deionized water.
3. a kind of ceramic coating of cracking resistance according to claim 1 or claim 2, which is characterized in that production method includes following step
It is rapid:
(1) by polyacrylic acid, anti-crack fiber, deionized water, epoxy curing agent, cesium hydroxide, surfactant, promotor
It is put into stirring ware, is first heated to 70-75 DEG C, 20-25min is then stirred with the speed of 45-55r/min, it then will be anti-old
Agent, modified filler, isophorone diisocyanate, methyl diphenylene diisocyanate, ammonium oxalate pour into, and use instead with 60-65r/
The speed of min stirs 35-40min, finally again by gas-phase silica, silane coupling agent, nano ceramic powder, melamine, amber
Amber acid anhydrides, hydrazine hydrate pour into, and stir 28-34min with the speed of 15-18r/min；
(2) step (1) coating is poured into grinder, in 68-73 DEG C of grinding 10-12h.
4. a kind of ceramic coating of cracking resistance according to claim 1, which is characterized in that the promotor is tin dilaurate two
Butyl tin.
5. a kind of ceramic coating of cracking resistance according to claim 1, which is characterized in that the anti-aging agent is N- phenyl-α-
Aniline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810696913.XA CN109181372A (en) | 2018-06-29 | 2018-06-29 | A kind of ceramic coating of cracking resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810696913.XA CN109181372A (en) | 2018-06-29 | 2018-06-29 | A kind of ceramic coating of cracking resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109181372A true CN109181372A (en) | 2019-01-11 |
Family
ID=64948732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810696913.XA Pending CN109181372A (en) | 2018-06-29 | 2018-06-29 | A kind of ceramic coating of cracking resistance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109181372A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101680193A (en) * | 2007-04-20 | 2010-03-24 | 研磨剂与耐火品研究与开发中心C.A.R.R.D.有限公司 | Anti abrasion layer |
| EP2548854A1 (en) * | 2011-07-18 | 2013-01-23 | Silicalia S.L. | Hybride polymer coating for petrous or ceramic substrates, petrous or ceramic substrate and obtaining method |
-
2018
- 2018-06-29 CN CN201810696913.XA patent/CN109181372A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101680193A (en) * | 2007-04-20 | 2010-03-24 | 研磨剂与耐火品研究与开发中心C.A.R.R.D.有限公司 | Anti abrasion layer |
| EP2548854A1 (en) * | 2011-07-18 | 2013-01-23 | Silicalia S.L. | Hybride polymer coating for petrous or ceramic substrates, petrous or ceramic substrate and obtaining method |
Non-Patent Citations (1)
| Title |
|---|
| 张洋等: "《装饰装修材料第2版》", 30 April 2006, 中国建材工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW412582B (en) | Compositions having improved stability and substrates having a coating | |
| CN104119644B (en) | Encapsulating material for transformer | |
| CN108516774B (en) | High-strength and high-toughness concrete and preparation method thereof | |
| CN108841268A (en) | Overlay waterproof roll anti-stick coating coating and preparation method thereof | |
| CN103357813A (en) | Lost foam steel-casting paint formula and technology method thereof | |
| CN105669228A (en) | Spray coating for making lining of iron-smelting blast furnace | |
| CN109181372A (en) | A kind of ceramic coating of cracking resistance | |
| CN105505105A (en) | Preparation method of anti-corrosion and wear-resistant coating for flutes | |
| CN108841286A (en) | A kind of wear resistant corrosion resistant coating material and preparation method thereof | |
| CN102675991B (en) | Dew point corrosion resisting paint and preparation method and use thereof | |
| CN110216823A (en) | A kind of cast mineral method of surface finish | |
| CN100387669C (en) | Antiwear ceramic-metal adhesive | |
| CN104529292A (en) | Anticorrosive high-hardness mortar and preparation method thereof | |
| CN102636278B (en) | Quick thermocouple | |
| CN115558379A (en) | Preparation method of carbon steel polyurethane terrace | |
| CN108976946A (en) | A kind of ceramic coating resistant to high temperature | |
| CN102114620A (en) | Resin matrix composite for flexible grinding and polishing | |
| CN105860675A (en) | Color paste for water-based paints and production technique thereof | |
| CN106280884A (en) | The nontoxic epoxy mortar that a kind of anticorrosion waterproofing reinforcement is special | |
| CN108821703A (en) | A kind of exterior-wall heat insulation finishing mucilage and preparation method thereof | |
| KR101806388B1 (en) | Composition of mortar powder with organic acid and natural fiber | |
| CN116253536B (en) | Alkali-activated geopolymer coating and preparation method and application thereof | |
| CN103951442B (en) | Furnace retaining infra-red china furnace charge and preparation method thereof | |
| CN110437583B (en) | High-temperature high-strength adhesive wear-resistant material and preparation method thereof | |
| CN110407525A (en) | The mortar pasted for outdoor tile |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190111 |
|
| RJ01 | Rejection of invention patent application after publication |