CN109174070A - A kind of novel absorbent charcoal Analytic Tower and active carbon analytic method - Google Patents
A kind of novel absorbent charcoal Analytic Tower and active carbon analytic method Download PDFInfo
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- CN109174070A CN109174070A CN201811203770.0A CN201811203770A CN109174070A CN 109174070 A CN109174070 A CN 109174070A CN 201811203770 A CN201811203770 A CN 201811203770A CN 109174070 A CN109174070 A CN 109174070A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3416—Regenerating or reactivating of sorbents or filter aids comprising free carbon, e.g. activated carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
Abstract
The present invention provides a kind of novel absorbent charcoal Analytic Tower, includes the bringing-up section being arranged from top to bottom, First Transition section, transition cooling section, the second changeover portion and heat exchange cooling section by active carbon Analytic Tower;Transition cooling section, the second changeover portion collectively form " buffer area ", so that First Transition section is not directly contacted with heat exchange cooling section, avoid active carbon sharp temperature drop in Analytic Tower, to prevent active carbon in the non-open surface fouling of cooling section upper perforated plate, prevent Analytic Tower from blocking and being corroded.Simultaneously as " buffer area " is arranged, avoids " bridging " active carbon and directly fall to the case where parsing tower bottom causes spontaneous combustion.
Description
Technical field
The present invention relates to a kind of active carbon Thermal desorption tower and active carbon analytic method, particularly one kind prevent fouling and
The active carbon parsing tower apparatus and active carbon analytic method of active carbon spontaneous combustion, belong to sintering flue gas process field.
Background technique
For the sintering device flue gas of industrial smoke, especially steel and iron industry, conciliate using including activated carbon adsorber
The desulphurization and denitration device and technique for analysing tower are more satisfactory.It is including activated carbon adsorber and Analytic Tower (or regenerator)
In desulphurization and denitration device, activated carbon adsorber is used for from sintering flue gas or exhaust gas (the especially sintering cigarette of the sintering machine of steel and iron industry
Gas) pollutant of the absorption including oxysulfide, nitrogen oxides and dioxin, and Analytic Tower is used for the hot recycling of active carbon.
Activated carbon desulfurization has desulfurization degree height, denitration can be achieved at the same time, de- dioxin, dedusting, do not generate waste water and dregs
The advantages that, it is extremely promising flue gas purifying method.Active carbon can regenerate at high temperature, when temperature is higher than 350 DEG C, absorption
(sulfur dioxide is solved for the pollutants such as oxysulfide, nitrogen oxides, dioxin on the activated carbon generation fast resolving or decomposition
Analysis, nitrogen oxides and dioxin are decomposed).And as the temperature rises, the reproduction speed of active carbon is further speeded up, regeneration
Time shortens, and preferably regenerating active carbon temperature is approximately equal to 430 DEG C in general control Analytic Tower, therefore, ideal parsing temperature
Spending (or regeneration temperature) is for example in 390-450 DEG C of range, more preferably in 400-440 DEG C of range.
For sintering flue gas exhaust temperature between 110-170 DEG C, SO is contained in the inside2, NOx, dust, dioxin, heavy metal etc.
Multiple pollutant, and active carbon flue gases purification is suitable for sintering flue gas temperature discharge section, it can be achieved that multi-pollutant just
High-efficient purification is cooperateed with, multiple pollutant can be deviate from simultaneously on a set of equipment, realizes by-product SO2Resource utilization, and
The technology has pollutant removing high-efficient, does not consume water resource substantially, without secondary pollution to wait a little.Active carbon gas cleaning dress
It installing and is equipped with multiple subsystems such as adsorption system, resolution system, acid making system, flue gas passes through activated carbon adsorption unit after-purification,
Active carbon particle circulates between absorbing unit and resolution unit, realizes that " absorption pollutant -> heating parsing activation (makes dirt
Dye object evolution) -> cooling -> absorption pollutant " and recycle.
The purpose of resolution system is that high temperature parsing regeneration is carried out to the active carbon for having adsorbed pollutant, is produced in gas containing height
Concentration SO2, multiple pollutants (SRG), the SRG gas such as large quantity of moisture be sent to acid making system relieving haperacidity.It is cold in entire resolving
But the upper perforated plate upper active charcoal temperature of section heat exchanger is about 400 DEG C (heats to get off for bringing-up section band), is mixed in active carbon
Certain parsing gas, ingredient are mainly vapor, SO2、SO3、NH3, dust etc.;And the upper perforated plate lower part of cooling section heat exchanger
Cooling air temperature is only about 100 DEG C.Cooling section upper perforated plate is metal material, and heat transfer property is very good, once active carbon exists
Flowing is deteriorated in Analytic Tower, and upper perforated plate and the active carbon temperature close to upper perforated plate will be reduced quickly, parsing in this amount of activated charcoal
Gas mixes dust in the surface scale of the non-aperture of upper perforated plate because liquid water and ammonium salt crystal will be precipitated in condensation.After fouling, knot
The active carbon of dirt stops non-fouling active carbon flowing, and active carbon mobility continues to be deteriorated, be adsorbed on dirty body, and dirty body continues to grow
Greatly, until the blanking hole of blocking heat exchanger, causes Analytic Tower fouling blockage and corrosion.
In addition to this, the active carbon in active carbon Analytic Tower is grain structure, and " bridging " is easy to appear in changeover portion
Situation, if there is active carbon " bridging ", as shown in figure 8, leading to the active carbon stream below " bridging " in Analytic Tower cooling section
Dynamic pipeline is sky, before the discharge gate discharge below the active carbon in the pipeline analytically tower, and is certainly existed at blow-off valve
The situation of leaking out of air, the enough oxygen content into the air in Analytic Tower, air along hole active carbon flow duct
Into changeover portion, at 400 DEG C or more the spontaneous combustion of active carbon easily occurs for the active carbon temperature in changeover portion, damage Analytic Tower and
Active carbon in Analytic Tower.In addition, if there is the case where " bridging ", due to the flowing of active carbon in bringing-up section or changeover portion,
The active carbon of " bridging " is easy " Tower Bridge ", and 400 DEG C or more of active carbon is caused directly to fall near Analytic Tower bottom discharging mouth
Active carbon on, parsing tower bottom leaks into oxygen content in the air in Analytic Tower from discharge gate due to the presence of discharge gate, 400
DEG C or more active carbon fall down, easily cause active carbon Analytic Tower discharge gate neighbouring position burn, and burn activity
Charcoal is fed directly to the equipment such as adsorption tower from discharge gate discharge, and the oxygen content adsorbed in tower is more sufficient, suction of easily igniting
Active carbon in attached tower, consequence are hardly imaginable.
Summary of the invention
For in the prior art, be easy to appear in active carbon Analytic Tower fouling condition, active carbon " bridging " cause active carbon
The problem of spontaneous combustion, present invention aims to the temperature of adsorption tower cooling section upper end close to the temperature of heating zone, and there are one
Buffer area prevents active carbon fouling on the upper perforated plate of adsorption tower cooling section, and Analytic Tower is caused to block and corrode;It is arranged simultaneously
" buffer area " avoids " bridging " from leading to the spontaneous combustion of active carbon.The present invention provides a kind of novel absorbent charcoal Analytic Tower, by active carbon solution
Analysis tower includes the bringing-up section being arranged from top to bottom, First Transition section, transition cooling section, the second changeover portion and heat exchange cooling section;It crosses
Cross cooling section, the second changeover portion collectively forms " buffer area " so that First Transition section with heat exchange cooling section be not directly contacted with, avoid
Active carbon sharp temperature drop in Analytic Tower, thus prevent active carbon in the non-open surface fouling of cooling section upper perforated plate,
Prevent Analytic Tower from blocking and being corroded.Simultaneously as " buffer area " is arranged, avoids " bridging " active carbon and directly fall to parsing
Tower bottom causes the case where spontaneous combustion.
According to an embodiment of the invention, providing a kind of novel absorbent charcoal Analytic Tower.
A kind of novel absorbent charcoal Analytic Tower, the active carbon Analytic Tower include the bringing-up section being arranged from top to bottom, First Transition
Section, transition cooling section, the second changeover portion and heat exchange cooling section.Bringing-up section, transition cooling section and heat exchange cooling section are shell knot
Structure.
Preferably, the lower part of bringing-up section is equipped with heating gas inlet, the top of bringing-up section is exported equipped with heat gas.Add
Hot gas outlet is connected to the gas access of hot-blast stove by first pipe, and the gas vent of hot-blast stove is connected by second pipe
To heating gas inlet.The lower part of heat exchange cooling section is equipped with heat exchange cooling gas inlet, and the top for the cooling section that exchanges heat is equipped with heat exchange
Cooling gas outlet.Heat exchange cooling gas inlet is connect by third pipeline with cooling blower.It is set on the side wall of First Transition section
There is SRG gas vent.Transition cooling section is confined space.
Preferably, the lower part of transition cooling section is equipped with transition cooling gas inlet, the top of transition cooling section was equipped with
Cross cooling gas outlet.
Preferably, the lower part of bringing-up section is equipped with heating gas inlet, the top of bringing-up section is exported equipped with heat gas.Add
Hot gas outlet is connected to the gas access of hot-blast stove by first pipe, and the gas vent of hot-blast stove is connected by second pipe
To heating gas inlet.It is the 4th pipeline that second pipe, which separates one article of branch, and the 4th pipeline is connected to transition cooling section gas and enters
Mouthful, transition cooling section gas vent is connected to bringing-up section by the 5th pipeline or is incorporated into first pipe.
Preferably, the lower part of bringing-up section is equipped with heating gas inlet, the top of bringing-up section is exported equipped with heat gas.Add
Hot gas outlet is connected to the gas access of hot-blast stove by first pipe, and the gas vent of hot-blast stove is connected by second pipe
To heating gas inlet.It is the 6th pipeline that first pipe, which separates one article of branch, and the 6th pipeline is connected to transition cooling section gas and enters
Mouthful.
Preferably, transition cooling section and heat exchange cooling section height ratio be 1:1-50, preferably 1:2-30, more preferably
1:3-20。
Preferably, the height ratio of First Transition section and the second changeover portion is 1:0.01-10, preferably 1:0.05-5, more
Preferably 1:0.1-1.
Preferably, being equipped with temperature-detecting device in the second changeover portion;
Preferably, the 4th pipeline or the 6th pipeline are equipped with regulating valve.
A kind of active carbon analytic method uses the parsing active carbon of active carbon Analytic Tower described in the first embodiment
Method, method includes the following steps:
1) active carbon for having adsorbed pollutant enters active carbon Analytic Tower from the feed inlet of active carbon Analytic Tower, has adsorbed dirt
The active carbon for contaminating object under the effect of gravity, moves from up to down, successively by the bringing-up section of active carbon Analytic Tower, First Transition
Section, transition cooling section, the second changeover portion and heat exchange cooling section, are then discharged from the discharge gate of active carbon Analytic Tower;
2) active carbon for having adsorbed pollutant is heated in bringing-up section, is decomposed and is parsed, subsequently into the first mistake
Section is crossed, the pollutant for decomposing and parsing is discharged from the SRG gas vent of First Transition section;
3) active carbon after having parsed enters transition cooling section, and first passing through transition cooling section, to carry out transition cooling, into the
Then two changeover portions enter back into heat exchange cooling section and carry out heat exchange cooling, discharge of the active carbon after cooling from active carbon Analytic Tower
Mouth discharge.
It is that separate one article of branch be the 4th pipe for the second pipe of bringing-up section conveying heat gas preferably, in step 3)
A part in gas that hot-blast stove generates is delivered to transition cooling section gas access by road, the 4th pipeline, cooling by transition
Gas after section to bringing-up section or is incorporated into the first pipe by transition cooling section gas vent, then by the 5th pipeline
Road.
Preferably, the gas after bringing-up section exchanges heat, exports from heat gas and is discharged, be delivered to by first pipe
The gas access of hot-blast stove, it is the 6th pipeline that first pipe, which separates one article of branch, and the 6th pipeline will be after bringing-up section exchanges heat
A part in gas is delivered to transition cooling section gas access.
Preferably, the temperature in temperature-detecting device detection transition cooling section controls transition cooling section by regulating valve
Interior temperature is 150-400 DEG C, preferably 180-350 DEG C, more preferably 200-320 DEG C.
Through inspection information it is found that carbon steel heat transfer coefficient 48.85W/ (m DEG C), air conduction coefficient 0.0317W/ (m
DEG C), since the thermal coefficient of air is low, parsing active carbon that can effectively to cooling section upper end (or in First Transition section)
It is isolated with the heat transfer of the cooling air in heat exchange cooling section.
Century-old in flue gas adsorption treatment technical operation, active carbon Analytic Tower is used for the Dissociative adsorption active carbon of pollutant,
Enter the active carbon in active carbon Analytic Tower by high-temperature heating (indirect heating), so that the pollutant parsing adsorbed in active carbon
With separate, then the gas containing pollutant is delivered to the techniques such as the acid making system in downstream recycled and handled.Through
Active carbon after crossing active carbon Analytic Tower bringing-up section, eliminates the pollutant wherein adsorbed, cools down after cooling section, so
After be recycled to the devices such as adsorption tower recycling.But active carbon is heated to 400 DEG C or so in bringing-up section, subsequently into
Cooling section, the interior input of cooling section is that normal temperature air is cooled down.In general, cooling section upper section (close to the position of changeover portion) by
In the presence of cooling gas, temperature is generally 100-150 DEG C or so, even lower than 100 DEG C, and the top of cooling section is transition
Section, changeover portion is interior containing a large amount of parsing gas, and the ingredient for parsing gas is mainly vapor, SO2、SO3、NH3, dust etc., mistake
The top for crossing section is bringing-up section, and temperature is 400 DEG C or more, parses gas in changeover portion, sharply due to the temperature in cooling section
It reduces, because liquid water and ammonium salt crystal will be precipitated in condensation in resolution gas body, mixes dust in the surface scale of the non-aperture of upper perforated plate.
Precisely due to parsing gas is influenced in changeover portion by cooling gas in cooling section, parsing gas is easily condensed, and is caused
Active carbon is in cooling section upper perforated plate fouling.And the ingredients such as the vapor in gas, ammonium, sulfide are parsed because condensation programs
The substances such as liquid water, ammonium salt crystal and sulfate, Analytic Tower are metal structure, and upper perforated plate is metal material, condensed substance
It is huge to the corrosiveness of Analytic Tower, especially upper perforated plate, cause the damage of Analytic Tower.Simultaneously as fouling on upper perforated plate
Occur, influences proper flow of the active carbon in Analytic Tower, further increase the generation of fouling.
It in the present invention, include the bringing-up section being arranged from top to bottom, First Transition section, transition cooling by active carbon Analytic Tower
Section, the second changeover portion and heat exchange cooling section.Transition cooling section, the second changeover portion collectively constitute " buffer area ", and " buffer area " is by
One changeover portion (being equivalent to changeover portion in the prior art) and heat exchange cooling section (being equivalent to cooling section in the prior art) separate
It comes, the active carbon avoided in First Transition section is directly connect with the interior air in heat exchange cooling section by upper perforated plate (steel plate)
Touching.It is normally passed through cooling gas in heat exchange cooling section, active carbon is cooled down.
In the present invention, bringing-up section, transition cooling section and heat exchange cooling section are shell structure, and recuperated gas walks shell side,
Active carbon walks tube side, and active carbon and recuperated gas pass through indirect heat exchange.Wherein, in bringing-up section, heated gas heats bringing-up section
Interior active carbon parses the pollutant adsorbed in active carbon so that active carbon temperature in the section increases.In heat exchange cooling section
Then interior, in cooling gas cooling heat transferring cooling section active carbon passes through Analytic Tower so that active carbon temperature in the section reduces
Discharge gate discharge, is recycled to the equipment such as adsorption tower and continues to use.First Transition section and the second changeover portion are holostrome activated carbon structure.
Wherein: First Transition section is for being discharged the pollutant parsed from active carbon, and the gas containing pollutant is from First Transition section
SRG gas vent discharge on side wall.Second changeover portion is used for buffers active charcoal, avoids entering cooling section due to First Transition section
There is the case where " bridging " in position (upper tube Board position);Due to the presence of the second changeover portion, even if First Transition section enters cooling
There is the case where " bridgings " in fragment position (upper tube Board position), the presence of the second changeover portion and the cooling section still active charcoal that exchanges heat,
Play the role of material envelope, avoids air from blow-off valve and leak into Analytic Tower, directly contacted with high temperature active charcoal.
In transition cooling section, closed space can be.By the way that one section of transition cooling section is arranged, due to air conduction system
Number is far smaller than carbon steel heat transfer coefficient, and there are the transition cooling sections of one section of air exclusion for First Transition section and heat exchange cooling section centre
With the second changeover portion, play good heat insulation, avoid active carbon in First Transition section with heat exchange cooling section in temperature
Greatest differences lead to quick refrigeration.Due to the presence of transition cooling section and the second changeover portion, active carbon is in First Transition section
Temperature be 400 DEG C or so, by the buffering of transition cooling section and the second changeover portion, enter back into heat exchange cooling section and cooling air
Body heat exchange cooling, transition cooling section and the second changeover portion are located between changeover portion and heat exchange cooling section, play the work of temperature buffer
With, avoid the sharply temperature drop of active carbon, so as to avoid parsing gas condensation situations generation, effectively prevent fouling.It protects
Proper flow of the active carbon in Analytic Tower has been demonstrate,proved, while having avoided corrosion of the fouling to Analytic Tower.
Preferably, gas can be passed through in transition cooling section, the temperature being further ensured that in transition cooling section, more added with
Effect plays the role of transition and heat preservation.For example, the temperature in changeover portion is 400 DEG C or so, the temperature to exchange heat in cooling section is
150 DEG C hereinafter, be passed through gas in transition cooling section, guarantee that the temperature in transition cooling section is 150-400 DEG C, thus well
Transitional function is played, so that active carbon realizes that ladder cools down in Analytic Tower, avoids the sharply decline of temperature.
Preferably, it is delivered to gas in transition cooling section, the gas after can be hot wind stove heating, certainly due to Analytic Tower
Body is furnished with hot blast stove system, and a part in the hot wind of hot-blast stove generation is delivered in transition cooling section, guarantees that transition is cooling
Temperature in section.It is also possible to after bringing-up section, from the gas of bringing-up section heat gas outlet discharge, since the position is arranged
Gas out still has 200 DEG C or more of temperature, and it is cold that a part of the gas of heat gas outlet discharge is delivered to transition
But the heat preservation transition to active carbon is carried out in section.It can also be external heat preservation gas, as long as can guarantee in transition cooling section
Temperature be 150-400 DEG C.
Preferably, the gas being discharged out of transition cooling section, can be delivered to the upper section of bringing-up section or by first
Pipeline is fed directly to hot-blast stove;There are also utilized the gas of heat to pass through transition cooling section gas transition cooling section
Body exports direct outlet, can be with outlet after having utilized its waste heat since the efflux gas does not generate additional pollutant.
Therefore in this application, the setting of transition cooling section and the second changeover portion will can effectively be in cooling section upper end
It has parsed active carbon (or active carbon in First Transition section) to be isolated with cooling air by space, to prevent
Parsing active carbon is cooled in cooling section upper section, and condensation vapor leads to fouling.
In the present invention, the high-temperature gas that hot-blast stove is accessed in transition cooling section can make the temperature in transition cooling section high
In the temperature in cooling section, i.e. temperature in transition cooling section is higher than the temperature in heat exchange cooling section, and having parsed active carbon will not
It can be in cooling section upper perforated plate condensation liquid water and ammonium salt crystal.
In the present invention, transition cooling section, the second changeover portion collectively constitute " buffer area ", it is possible to prevente effectively from such as Fig. 8 institute
Active carbon " bridging " situation shown.Novel absorbent charcoal Analytic Tower of the invention, due to being provided with transition cooling section, the second transition
Section occurs the case where " bridging " when the active carbon in First Transition section enters cooling section (transition cooling section of the invention), by
In lower section there are also the second changeover portion and heat exchange cooling section, active carbon is holostrome active carbon state, the second mistake in the second changeover portion
The active carbon for crossing section and exchanging heat in cooling section can still play the role of material envelope, avoid air and enter high temperature active charcoal area
Domain.Further, since the presence of transition cooling section, even if the case where " Tower Bridge " occurs in the active carbon of " bridging ", active carbon directly falls
It falls, since transition cooling section can play the effect of heat preservation and temperature buffer, the active carbon in the second changeover portion still has 200
DEG C or more high temperature, also avoid be discharged out of First Transition section 400 DEG C or more of high temperature active charcoal and directly drop to 100 DEG C of left sides
On right active carbon, so as to avoid the sharp temperature drop of active carbon.
Using novel absorbent charcoal Analytic Tower of the invention, can occur condensing shape in First Transition section to avoid resolution gas body
Condition avoids active carbon structure in Analytic Tower, prevents or significantly reduce the generation of corrosion;Simultaneously as transition cooling section,
The presence of " buffer area " that the second changeover portion is constituted, avoids high temperature active charcoal and directly falls to parsing tower bottom, it is therefore prevented that high
Warm active carbon is contacted with oxygen content air abundant, so that the spontaneous combustion for effectively preventing active carbon occurs, ensure that Analytic Tower
Normal operation and security performance;In addition, the active carbon for also avoiding burning enters the equipment such as subsequent adsorption tower, ensure that significantly
Safety in production.
Active carbon Analytic Tower is included cleverly the bringing-up section being arranged from top to bottom, First Transition by Analytic Tower of the invention
Section, transition cooling section, the second changeover portion and heat exchange cooling section.So that transition cooling section, the second changeover portion have been naturally formed one
A " buffer area " greatly improves the production security of Analytic Tower, avoids temperature sharp fall of the active carbon in Analytic Tower, simultaneously
Avoiding active carbon Tower Bridge causes high temperature active charcoal to contact with the air of rich oxygen content, prevents the hair of active carbon spontaneous combustion or burning
It is raw.
In the present invention, the height of transition cooling section and the height of heat exchange cooling section refer to the height along active carbon Analytic Tower
Spend direction.In general, the height of heat exchange cooling section is less than or equal to the height of heat exchange cooling section.Transition cooling section primarily serves transition
And buffer function, avoid active carbon quick refrigeration or to the cold in changeover portion, avoid active carbon in First Transition section by
The influence of cooling gas in cooling section and condensation situations occur, to avoid or reduce the generation of fouling.Exchange heat cooling section
Effect is cooling active carbon, and active carbon is cooling by indirect heat exchange with cooling gas in heat exchange cooling section, reduces active carbon
Temperature.
In the present invention, temperature-detecting device is used to detect the temperature in transition cooling section.First regulating valve purposes is adjusted
The amount of gas in into transition cooling section, thus guarantee that the temperature in transition cooling section is maintained in the range of 150-400 DEG C, it is excellent
It is selected as in the range of 180-350 DEG C, in the range of more preferably 200-320 DEG C.
In the present invention, regulating valve is arranged in the upstream of hot air circulation blower, is adjusted in bringing-up section and transition cooling section
Air circulation.
Preferably, the device further include: cooling blower;The cold wind outlet of cooling blower is connected to cold via the 5th pipeline
But the cooling gas import of section;Cooling gas outlet is communicated with the atmosphere.
In the present invention, cooling blower provides gas at normal temperature for the heat exchanger of cooling section, takes away active carbon by heat exchange
Heat, to have parsed active carbon cooling.
In the present invention, the height of active carbon Analytic Tower is 8-30 meters, preferably 10-25 meters, more preferably 12-20 meters;
Such as 15 meters or so.The height of cooling section is 3-20 meters, preferably 5-15 meters, more preferably 6-10 meters.
Compared with prior art, novel absorbent charcoal Analytic Tower of the invention has the advantages that
1, in the present invention, active carbon Analytic Tower includes the bringing-up section being arranged from top to bottom, First Transition section, transition cooling
Section, the second changeover portion and heat exchange cooling section, transition cooling section, the second changeover portion collectively constitute " buffer area ", and buffer area is to activity
Charcoal has a transitional function in Analytic Tower, and temperature will not reduce suddenly, in the upper perforated plate i.e. First Transition section of cooling section
Bottom plate on non flouling behaviour, the case where effectively preventing blocking and corrode.
2, due to the presence of " buffer area ", temperature in " buffer area " is 200 DEG C or so, while lower section also exchanges heat cooling
Section plays the role of material envelope, effectively prevents air from blow-off valve and enters the higher active carbon region of temperature, to effectively avoid
The spontaneous combustion of active carbon in Analytic Tower.
3, in the present invention, the high-temperature gas of access hot-blast stove in transition cooling section can make the temperature in transition cooling section high
Then temperature in heat exchange cooling section, i.e. active carbon are fully cooled to protect again in cooling section by a temp buffer
Active carbon of the card after by Thermal desorption will not be in upper perforated plate condensation liquid water and ammonium salt crystal;
4, in the present invention, the gas vent of transition cooling section connects the heat outlet of bringing-up section or is recycled to hot-blast stove, i.e.,
Transition cooling section and the gas of bringing-up section can return to hot-blast stove through hot air circulation blower, be heated again, and heat losses are reduced.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of good antiscale property active carbon Analytic Tower of the present invention;
Fig. 2 is the structural representation that transition cooling section is equipped with gas inlet-outlet in a kind of good antiscale property active carbon Analytic Tower of the present invention
Figure;
Fig. 3 is that the heat exchanger gas of transition cooling section in a kind of good antiscale property active carbon Analytic Tower of the present invention comes from hot wind furnace gas
Body, discharge gas are delivered to bringing-up section structural schematic diagram;
Fig. 4 is that the heat exchanger gas of transition cooling section in a kind of good antiscale property active carbon Analytic Tower of the present invention comes from hot wind furnace gas
Body, discharge gas are delivered to hot-blast stove structural schematic diagram;
Fig. 5 is that the heat exchanger gas of transition cooling section in a kind of good antiscale property active carbon Analytic Tower of the present invention is arranged from bringing-up section
Gas, discharge gas are delivered to the structural schematic diagram of bringing-up section out;
Fig. 6 is that the heat exchanger gas of transition cooling section in a kind of good antiscale property active carbon Analytic Tower of the present invention is arranged from bringing-up section
Gas, discharge gas are delivered to the structural schematic diagram of hot-blast stove out;
Fig. 7 is a kind of use state diagram of good antiscale property active carbon Analytic Tower of the present invention;
Fig. 8 is the schematic diagram of active carbon bridging blocking inside prior art active carbon Analytic Tower.
Appended drawing reference:
A: active carbon Analytic Tower;1: bringing-up section;101: heating gas inlet;102: heat gas outlet;2: First Transition
Section;3: transition cooling section;301: transition cooling gas inlet;302: the outlet of transition cooling gas;4: the second changeover portions;5: heat exchange
Cooling section;501: heat exchange cooling gas inlet;502: the outlet of heat exchange cooling gas;6: hot-blast stove;7: cooling blower;8: temperature inspection
Survey device;9: regulating valve;10:SRG gas vent;L1: first pipe;L2: second pipe;L3: third pipeline;L4: the four pipe
Road;L5: the five pipeline;L6: the six pipeline.
Specific embodiment
A kind of novel absorbent charcoal Analytic Tower, active carbon Analytic Tower A include the bringing-up section 1 being arranged from top to bottom, the first mistake
Cross section 2, transition cooling section 3, the second changeover portion 4 and heat exchange cooling section 5.Bringing-up section 1, transition cooling section 3 and heat exchange cooling section 5 are equal
For shell structure.
Preferably, the lower part of bringing-up section 1 is equipped with heating gas inlet 101, the top of bringing-up section 1 goes out equipped with heat gas
Mouth 102.Heat gas outlet 102 is connected to the gas access of hot-blast stove 6, the gas vent of hot-blast stove 6 by first pipe L1
Heating gas inlet 101 is connected to by second pipe L2.The lower part of heat exchange cooling section 5 is equipped with heat exchange cooling gas inlet 501,
The top of heat exchange cooling section 5 is equipped with heat exchange cooling gas outlet 502.Exchange heat cooling gas inlet 501 by third pipeline L3 with
Cooling blower 7 connects.The side wall of First Transition section 2 is equipped with SRG gas vent 10.Transition cooling section 3 is confined space.
Preferably, the lower part of transition cooling section 3 is equipped with transition cooling gas inlet 301, the top of transition cooling section 3 is set
There is transition cooling gas to export 302.
Preferably, the lower part of bringing-up section 1 is equipped with heating gas inlet 101, the top of bringing-up section 1 goes out equipped with heat gas
Mouth 102.Heat gas outlet 102 is connected to the gas access of hot-blast stove 6, the gas vent of hot-blast stove 6 by first pipe L1
Heating gas inlet 101 is connected to by second pipe L2.It is the 4th pipeline L4, the 4th pipe that second pipe L2, which separates one article of branch,
Road L4 is connected to transition cooling section gas access 301.Transition cooling section gas vent 302 is connected to heating by the 5th pipeline L5
Section 1 is incorporated into first pipe L1.
Preferably, the lower part of bringing-up section 1 is equipped with heating gas inlet 101, the top of bringing-up section 1 goes out equipped with heat gas
Mouth 102.Heat gas outlet 102 is connected to the gas access of hot-blast stove 6, the gas vent of hot-blast stove 6 by first pipe L1
Heating gas inlet 101 is connected to by second pipe L2.It is the 6th pipeline L6, the 6th pipe that first pipe L1, which separates one article of branch,
Road L6 is connected to transition cooling section gas access 301.
Preferably, transition cooling section 301 and heat exchange cooling section 302 height ratio be 1:1-50, preferably 1:2-30, more
Preferably 1:3-20.
Preferably, the height ratio of First Transition section 2 and the second changeover portion 4 be 1:0.01-10, preferably 1:0.05-5,
More preferably 1:0.1-1.
Preferably, being equipped with temperature-detecting device 8 in the second changeover portion 4.
Preferably, the 4th pipeline L4 or the 6th pipeline L6 is equipped with regulating valve 9.
Embodiment 1
As shown in Figure 1, a kind of novel absorbent charcoal Analytic Tower, active carbon Analytic Tower A includes the heating being arranged from top to bottom
Section 1, First Transition section 2, transition cooling section 3, the second changeover portion 4 and heat exchange cooling section 5.It bringing-up section 1, transition cooling section 3 and changes
Hot cooling section 5 is shell structure.
Embodiment 2
A kind of novel absorbent charcoal Analytic Tower, active carbon Analytic Tower A include the bringing-up section 1 being arranged from top to bottom, the first mistake
Cross section 2, transition cooling section 3, the second changeover portion 4 and heat exchange cooling section 5.Bringing-up section 1, transition cooling section 3 and heat exchange cooling section 5 are equal
For shell structure.
The lower part of bringing-up section 1 is equipped with heating gas inlet 101, and the top of bringing-up section 1 is equipped with heat gas outlet 102.Add
Hot gas outlet 102 is connected to the gas access of hot-blast stove 6 by first pipe L1, and the gas vent of hot-blast stove 6 passes through second
Pipeline L2 is connected to heating gas inlet 101.The lower part of heat exchange cooling section 5 is equipped with heat exchange cooling gas inlet 501, heat exchange cooling
The top of section 5 is equipped with heat exchange cooling gas outlet 502.The cooling gas inlet 501 that exchanges heat passes through third pipeline L3 and cooling blower 7
Connection.The side wall of First Transition section 2 is equipped with SRG gas vent 10.Transition cooling section 3 is confined space.
Embodiment 3
As shown in Fig. 2, a kind of novel absorbent charcoal Analytic Tower, active carbon Analytic Tower A includes the heating being arranged from top to bottom
Section 1, First Transition section 2, transition cooling section 3, the second changeover portion 4 and heat exchange cooling section 5.It bringing-up section 1, transition cooling section 3 and changes
Hot cooling section 5 is shell structure.
The lower part of transition cooling section 3 is equipped with transition cooling gas inlet 301, and it is cold that the top of transition cooling section 3 is equipped with transition
But gas vent 302.Temperature-detecting device 8 is equipped in second changeover portion 4.4th pipeline L4 or the 6th pipeline L6, which is equipped with, to be adjusted
Valve 9.
Embodiment 4
As shown in figure 3, repeating embodiment 3, only the lower part of bringing-up section 1 is equipped with heating gas inlet 101, bringing-up section 1
Top is equipped with heat gas outlet 102.Heat gas outlet 102 is connected to the gas access of hot-blast stove 6 by first pipe L1,
The gas vent of hot-blast stove 6 is connected to heating gas inlet 101 by second pipe L2.Second pipe L2 separates a branch
4th pipeline L4, the 4th pipeline L4 are connected to transition cooling section gas access 301.Transition cooling section gas vent 302 passes through the
Five pipeline L5 are connected to bringing-up section 1.
Embodiment 5
As shown in figure 4, repeating embodiment 3, only the lower part of bringing-up section 1 is equipped with heating gas inlet 101, bringing-up section 1
Top is equipped with heat gas outlet 102.Heat gas outlet 102 is connected to the gas access of hot-blast stove 6 by first pipe L1,
The gas vent of hot-blast stove 6 is connected to heating gas inlet 101 by second pipe L2.Second pipe L2 separates a branch
4th pipeline L4, the 4th pipeline L4 are connected to transition cooling section gas access 301.Transition cooling section gas vent 302 passes through the
Five pipeline L5 are incorporated into first pipe L1.
Embodiment 6
As shown in figure 5, repeating embodiment 3, only the lower part of bringing-up section 1 is equipped with heating gas inlet 101, bringing-up section 1
Top is equipped with heat gas outlet 102.Heat gas outlet 102 is connected to the gas access of hot-blast stove 6 by first pipe L1,
The gas vent of hot-blast stove 6 is connected to heating gas inlet 101 by second pipe L2.First pipe L1 separates a branch
6th pipeline L6, the 6th pipeline L6 are connected to transition cooling section gas access 301.
Embodiment 7
Embodiment 4 is repeated, only the height ratio of transition cooling section 3 and heat exchange cooling section 5 is 1:5, First Transition section 2 and the
The height ratio of two changeover portions 4 is 1:0.05.
Embodiment 8
Repeat embodiment 5, only transition cooling section 3 and heat exchange cooling section 5 height ratio be 1:20, First Transition section 2 with
The height ratio of second changeover portion 4 is 1:0.1.
Embodiment 9
Repeat embodiment 6, only transition cooling section 3 and heat exchange cooling section 5 height ratio be 1:30, First Transition section 2 with
The height ratio of second changeover portion 4 is 1:0.5.
Embodiment 10
A kind of active carbon analytic method or the method using active carbon Analytic Tower described in embodiment 2, this method includes following
Step:
1) active carbon for having adsorbed pollutant enters active carbon Analytic Tower A from the feed inlet of active carbon Analytic Tower A, absorption
The active carbon of pollutant under the effect of gravity, moves from up to down, successively passes through bringing-up section 1, the first mistake of active carbon Analytic Tower A
Section 2, transition cooling section 3, the second changeover portion 4 and heat exchange cooling section 5 are crossed, is then discharged from the discharge gate of active carbon Analytic Tower A;
2) active carbon for having adsorbed pollutant is heated in bringing-up section 1, is decomposed and is parsed, subsequently into the first mistake
Section 2 is crossed, the pollutant for decomposing and parsing is discharged from the SRG gas vent 10 of First Transition section 2;
3) active carbon after having parsed enters transition cooling section 3, first passes through transition cooling section 3 and carries out transition cooling, enters
Then second changeover portion 4 enters back into heat exchange cooling section 5 and carries out heat exchange cooling, active carbon after cooling is from active carbon Analytic Tower A's
Discharge gate discharge.
Embodiment 11
A kind of active carbon analytic method or the method using active carbon Analytic Tower described in embodiment 4, this method includes following
Step:
1) active carbon for having adsorbed pollutant enters active carbon Analytic Tower A from the feed inlet of active carbon Analytic Tower A, absorption
The active carbon of pollutant under the effect of gravity, moves from up to down, successively passes through bringing-up section 1, the first mistake of active carbon Analytic Tower A
Section 2, transition cooling section 3, the second changeover portion 4 and heat exchange cooling section 5 are crossed, is then discharged from the discharge gate of active carbon Analytic Tower A;
2) active carbon for having adsorbed pollutant is heated in bringing-up section 1, is decomposed and is parsed, subsequently into the first mistake
Section 2 is crossed, the pollutant for decomposing and parsing is discharged from the SRG gas vent 10 of First Transition section 2;
3) active carbon after having parsed enters transition cooling section 3, first passes through transition cooling section 3 and carries out transition cooling, enters
Then second changeover portion 4 enters back into heat exchange cooling section 5 and carries out heat exchange cooling, active carbon after cooling is from active carbon Analytic Tower A's
Discharge gate discharge.
Wherein: being that bringing-up section 1 conveys the second pipe L2 of heat gas to separate one article of branch be the 4th pipeline in step 3)
A part in gas that hot-blast stove 6 generates is delivered to transition cooling section gas access 301 by L4, the 4th pipeline L4, is passed through
Gas after crossing cooling section 3 is by transition cooling section gas vent 302, then is delivered to bringing-up section 1 by the 5th pipeline L5.
Temperature-detecting device 8 detects the temperature in transition cooling section 3, by adjusting regulating valve 9, controls transition cooling section 3
In the range of interior temperature is 150-400 DEG C.
Embodiment 12
A kind of active carbon analytic method or the method using active carbon Analytic Tower described in embodiment 5, this method includes following
Step:
1) active carbon for having adsorbed pollutant enters active carbon Analytic Tower A from the feed inlet of active carbon Analytic Tower A, absorption
The active carbon of pollutant under the effect of gravity, moves from up to down, successively passes through bringing-up section 1, the first mistake of active carbon Analytic Tower A
Section 2, transition cooling section 3, the second changeover portion 4 and heat exchange cooling section 5 are crossed, is then discharged from the discharge gate of active carbon Analytic Tower A;
2) active carbon for having adsorbed pollutant is heated in bringing-up section 1, is decomposed and is parsed, subsequently into the first mistake
Section 2 is crossed, the pollutant for decomposing and parsing is discharged from the SRG gas vent 10 of First Transition section 2;
3) active carbon after having parsed enters transition cooling section 3, first passes through transition cooling section 3 and carries out transition cooling, enters
Then second changeover portion 4 enters back into heat exchange cooling section 5 and carries out heat exchange cooling, active carbon after cooling is from active carbon Analytic Tower A's
Discharge gate discharge.
Wherein: being that bringing-up section 1 conveys the second pipe L2 of heat gas to separate one article of branch be the 4th pipeline in step 3)
A part in gas that hot-blast stove 6 generates is delivered to transition cooling section gas access 301 by L4, the 4th pipeline L4, is passed through
Gas after crossing cooling section 3 is by transition cooling section gas vent 302, then is incorporated into first pipe L1 by the 5th pipeline L5.
Temperature-detecting device 8 detects the temperature in transition cooling section 3, by adjusting regulating valve 9, controls transition cooling section 3
In the range of interior temperature is 180-350 DEG C.
Embodiment 13
A kind of active carbon analytic method or the method using active carbon Analytic Tower described in embodiment 4, this method includes following
Step:
1) active carbon for having adsorbed pollutant enters active carbon Analytic Tower A from the feed inlet of active carbon Analytic Tower A, absorption
The active carbon of pollutant under the effect of gravity, moves from up to down, successively passes through bringing-up section 1, the first mistake of active carbon Analytic Tower A
Section 2, transition cooling section 3, the second changeover portion 4 and heat exchange cooling section 5 are crossed, is then discharged from the discharge gate of active carbon Analytic Tower A;
2) active carbon for having adsorbed pollutant is heated in bringing-up section 1, is decomposed and is parsed, subsequently into the first mistake
Section 2 is crossed, the pollutant for decomposing and parsing is discharged from the SRG gas vent 10 of First Transition section 2;
3) active carbon after having parsed enters transition cooling section 3, first passes through transition cooling section 3 and carries out transition cooling, enters
Then second changeover portion 4 enters back into heat exchange cooling section 5 and carries out heat exchange cooling, active carbon after cooling is from active carbon Analytic Tower A's
Discharge gate discharge.
Gas after the heat exchange of bringing-up section 1 is delivered to heat by first pipe L1 from 102 discharge of heat gas outlet
The gas access of wind furnace 6, it is the 6th pipeline L6 that first pipe L1, which separates one article of branch, and the 6th pipeline L6 will be changed by bringing-up section 1
A part in gas after heat is delivered to transition cooling section gas access 301.
Temperature-detecting device 8 detects the temperature in transition cooling section 3, by adjusting regulating valve 9, controls transition cooling section 3
In the range of interior temperature is 200-320 DEG C.
Using good antiscale property active carbon Analytic Tower of the invention, since the active carbon in thermal insulation board, after bringing-up section is arranged
Successively by transition cooling section 3, the second changeover portion 4 and heat exchange cooling section 5, transition cooling section 3, the second changeover portion 4 are collectively constituted
One " buffer area ", buffer area has a transitional function to active carbon in Analytic Tower, and temperature will not reduce suddenly, in cooling section
Upper perforated plate i.e. First Transition section bottom plate on non flouling behaviour, the case where effectively preventing blocking and corrode.
If be passed through in transition cooling section 3 because then Analytic Tower needs are out of service for the failure of the components such as baiting valve
The recuperated gas of proper temperature exchanges heat with the active carbon of this section, avoids the quick refrigeration of active carbon in Analytic Tower, avoid active carbon
Interior parsing gas will be because liquid water and ammonium salt crystal will be precipitated in condensation, to effectively avoid fouling blockage and corrosion.
In addition, transition cooling section 3, the second changeover portion 4 collectively constitute one " buffer area ", if active carbon is in First Transition
In section 2, there is " bridging " situation into the position of active carbon pipeline, the temperature due to the presence of " buffer area ", in " buffer area "
It is 200 DEG C or so, while there are also heat exchange cooling sections 5 to play the role of material envelope for lower section, effectively prevents air and enter from blow-off valve
The higher active carbon region of temperature, to effectively prevent the spontaneous combustion of active carbon in Analytic Tower.
Claims (10)
1. a kind of novel absorbent charcoal Analytic Tower, which includes the bringing-up section (1) being arranged from top to bottom, first
Changeover portion (2), transition cooling section (3), the second changeover portion (4) and heat exchange cooling section (5);Bringing-up section (1), transition cooling section (3)
It is shell structure with heat exchange cooling section (5).
2. active carbon Analytic Tower according to claim 1, it is characterised in that: the lower part of bringing-up section (1) is equipped with heat gas
Entrance (101), the top of bringing-up section (1) are equipped with heat gas outlet (102), and heat gas outlet (102) passes through first pipe
(L1) it is connected to the gas access of hot-blast stove (6), the gas vent of hot-blast stove (6) is connected to heating gas by second pipe (L2)
Body entrance (101);The lower part of heat exchange cooling section (5) is equipped with heat exchange cooling gas inlet (501), the top of heat exchange cooling section (5)
Equipped with heat exchange cooling gas outlet (502);Heat exchange cooling gas inlet (501) passes through third pipeline (L3) and cooling blower (7)
Connection;The side wall of First Transition section (2) is equipped with SRG gas vent (10);Transition cooling section (3) is confined space.
3. active carbon Analytic Tower according to claim 1, it is characterised in that: the lower part of transition cooling section (3) is equipped with transition
The top of cooling gas inlet (301), transition cooling section (3) is equipped with transition cooling gas outlet (302).
4. active carbon Analytic Tower according to claim 3, it is characterised in that: the lower part of bringing-up section (1) is equipped with heat gas
Entrance (101), the top of bringing-up section (1) are equipped with heat gas outlet (102), and heat gas outlet (102) passes through first pipe
(L1) it is connected to the gas access of hot-blast stove (6), the gas vent of hot-blast stove (6) is connected to heating gas by second pipe (L2)
Body entrance (101);It is the 4th pipeline (L4) that second pipe (L2), which separates one article of branch, and it is cooling that the 4th pipeline (L4) is connected to transition
Section gas access (301), transition cooling section gas vent (302) are connected to bringing-up section (1) by the 5th pipeline (L5) or close
And to first pipe (L1).
5. active carbon Analytic Tower according to claim 3, it is characterised in that: the lower part of bringing-up section (1) is equipped with heat gas
Entrance (101), the top of bringing-up section (1) are equipped with heat gas outlet (102), and heat gas outlet (102) passes through first pipe
(L1) it is connected to the gas access of hot-blast stove (6), the gas vent of hot-blast stove (6) is connected to heating gas by second pipe (L2)
Body entrance (101);It is the 6th pipeline (L6) that first pipe (L1), which separates one article of branch, and it is cooling that the 6th pipeline (L6) is connected to transition
Section gas access (301).
6. active carbon Analytic Tower according to any one of claims 1-5, it is characterised in that: transition cooling section (301) with
The height ratio of heat exchange cooling section (302) is 1:1-50, preferably 1:2-30, more preferably 1:3-20;And/or
The height ratio of First Transition section (2) and the second changeover portion (4) is 1:0.01-10, preferably 1:0.05-5, more preferably 1:
0.1-1。
7. active carbon Analytic Tower according to claim 4 or 5, it is characterised in that: be equipped with temperature in the second changeover portion (4) and examine
It surveys device (8);And/or
4th pipeline (L4) or the 6th pipeline (L6) are equipped with regulating valve (9).
8. a kind of active carbon analytic method uses the parsing active carbon of active carbon Analytic Tower described in any one of claim 1-7
Method, method includes the following steps:
1) active carbon for having adsorbed pollutant enters active carbon Analytic Tower (A) from the feed inlet of active carbon Analytic Tower (A), absorption
The active carbon of pollutant under the effect of gravity, moves from up to down, successively by the bringing-up section (1) of active carbon Analytic Tower (A), the
One changeover portion (2), transition cooling section (3), the second changeover portion (4) and heat exchange cooling section (5), then from active carbon Analytic Tower (A)
Discharge gate discharge;
2) active carbon for having adsorbed pollutant is heated in bringing-up section (1), is decomposed and is parsed, subsequently into First Transition
Section (2), the pollutant for decomposing and parsing are discharged from the SRG gas vent (10) of First Transition section (2);
3) active carbon after having parsed enters transition cooling section (3), first passes through transition cooling section (3) and carries out transition cooling, enters
Second changeover portion (4) then enters back into heat exchange cooling section (5) and carries out heat exchange cooling, and active carbon after cooling is parsed from active carbon
The discharge gate of tower (A) is discharged.
9. according to the method described in claim 8, it is characterized by: in step 3), convey heat gas for bringing-up section (1) the
It is the 4th pipeline (L4), one in gas that the 4th pipeline (L4) generates hot-blast stove (6) that two pipelines (L2), which separate one article of branch,
Part is delivered to transition cooling section gas access (301), and the gas after transition cooling section (3) passes through transition cooling section gas
It exports (302), then is delivered to bringing-up section (1) by the 5th pipeline (L5) or is incorporated into first pipe (L1);Or
Gas after bringing-up section (1) heat exchange, is discharged from heat gas outlet (102), is delivered to by first pipe (L1)
The gas access of hot-blast stove (6), it is the 6th pipeline (L6) that first pipe (L1), which separates one article of branch, and the 6th pipeline (L6) will pass through
A part in gas after bringing-up section (1) heat exchange is delivered to transition cooling section gas access (301).
10. according to the method described in claim 9, it is characterized by: in temperature-detecting device (8) detection transition cooling section (3)
Temperature, by regulating valve (9), controlling the temperature in transition cooling section (3) is 150-400 DEG C, preferably 180-350 DEG C, more
Preferably 200-320 DEG C.
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CN112403178A (en) * | 2019-10-14 | 2021-02-26 | 中冶长天国际工程有限责任公司 | Activated carbon adsorption system with atmosphere protection structure and method for treating flue gas |
CN112705009A (en) * | 2019-10-25 | 2021-04-27 | 中冶长天国际工程有限责任公司 | Cooling fan control method and device for analytic tower |
CN112807932A (en) * | 2021-01-05 | 2021-05-18 | 湖南中冶长天节能环保技术有限公司 | Method for optimally controlling discharge temperature of desorption tower and cooling air system |
CN113884322A (en) * | 2020-07-03 | 2022-01-04 | 中冶长天国际工程有限责任公司 | Method and system for rapidly evaluating working state of analysis tower |
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