CN109173572A - A kind of indoor pollution organic gas purification paper and preparation method thereof - Google Patents
A kind of indoor pollution organic gas purification paper and preparation method thereof Download PDFInfo
- Publication number
- CN109173572A CN109173572A CN201811398224.7A CN201811398224A CN109173572A CN 109173572 A CN109173572 A CN 109173572A CN 201811398224 A CN201811398224 A CN 201811398224A CN 109173572 A CN109173572 A CN 109173572A
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- Prior art keywords
- paper
- gas purification
- organic gas
- indoor pollution
- indoor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4508—Gas separation or purification devices adapted for specific applications for cleaning air in buildings
Abstract
The present invention provides a kind of indoor pollution organic gas purification paper, raw material includes waste paper pulp, graphene and ZnWO4.Indoor pollution organic gas purification paper of the invention is raw material using secondary stock, not only at low cost, also the processing of waste is solved the problems, such as, the purification paper adsorption effect being prepared is good, easy to use, it can be affixed on wall, desktop, ground etc. can also be affixed on, it is applied widely.Indoor pollution organic gas purification paper of the invention, in addition to there is good adsorption effect to indoor organic pollutant, also there is good mechanical property, it can reach 15kNm/kg than tensile strength, it can reach 5MNm/kg than elasticity modulus, packaging material and flame retardant composite material are also used as in addition to can be used for indoor air purification with good thermal stability and fire protecting performance.The preparation method that the present invention purifies paper is simple, can be produced in enormous quantities.
Description
Technical field
The invention belongs to Techniques for Indoor Air Purification fields, and in particular to a kind of indoor pollution organic gas purification paper and its
Preparation method.
Background technique
People daily about 80% or more time spend indoors, the air breathed mostlys come from room
Interior, room air pollution will directly threaten human health.Currently, various building decoration materials, furniture, household chemicals pour in room
Interior, the source of indoor air pollutants and type increase increasingly, and room air pollution degree is caused to be even more than outdoor air dirt
Dye.World Health Organization's investigation display, the disease of human body about 68% is as caused by room air pollution.Foreign study
Mechanism is by detection discovery, and indoors there are more than 500 kinds of volatile organic compounds in air, wherein carcinogen just has more than 20
Kind, more than 200 kinds of Causative virus, harm is biggish mainly to be had: radon, formaldehyde, benzene, ammonia and ester, trichloro ethylene etc..Meanwhile it can inhale
Entering particulate matter (partial size less than 10 μm, PM10) is also to endanger one of biggish pollutant in room air, since its partial size is smaller,
It is easily inhaled the deeper position of human respiratory tract and accumulation, it is larger to human health damage, as influence indoor air quality
An important factor for, pellet is also gradually concerned by people.
In the prior art, Techniques for Indoor Air Purification includes mechanical filter method, Cottrell process, physisorphtion, and light is urged
Change oxidizing process, anion method and low temperature plasma method etc..In recent years, pollution air is carried out using low temperature nonequilibrium plasma
Processing have become the research hotspot of domestic and foreign scholars.Wherein, the relevant equipment volume of mechanical filter method and energy consumption are big, uncomfortable
Front yard uses of the whole family；Cottrell process can only adsorb dust, can not adsorb organic pollutant；Physisorphtion application is most, but its
Treatment effect is limited to adsorbent, while adsorbent is due to needing timing to replace after adsorption saturation so that its application limitation compared with
Greatly；The purification efficiency of photocatalytic oxidation is relatively low；It can be produced when molecular collision in the high energy electron and air that plasma is possessed
A series of raw primitive physical reactions, can generate various active free radical and ecological oxygen during the reaction, ecological oxygen can rapidly by
A variety of macromolecule gas with foreign flavor decompose or partial reduction is low molecule innocuous substance, however, the relevant purification of plasma method is set
Standby with high costs, average family is unbearable.
Therefore, it still needs to develop a kind of new indoor air purification product, be deposited with solving indoor air purification in the prior art
The problem of.
Summary of the invention
To solve the problem of that indoor air purification exists in the prior art, an object of the present invention is to provide a kind of room
Interior pollution organic gas purification paper.
The second object of the present invention is to provide the preparation method of above-mentioned purification paper.
To achieve the above object, the invention adopts the following technical scheme:
A kind of indoor pollution organic gas purification paper, raw material include the component of following parts by weight meter:
80~120 parts of waste paper pulp,
10~150 parts of graphene,
ZnWO41~50 part.
Preferably, the graphene and ZnWO4Mesh number be 80~500 mesh.
Preferably, the moisture content of the waste paper pulp is 20~30%.
Preferably, it is described purification paper with a thickness of 0.1~20mm.
The preparation method of indoor pollution organic gas purification paper, step include:
(1) waste paper pulp, graphene and ZnWO are weighed according to the ratio4It mixes, laminates；
(2) two-sided clad can is carried out to get the indoor pollution organic gas purification to thin plate obtained by step (1) with non-woven fabrics
Paper.
Preferably, the non-woven fabrics is spunlace non-woven cloth.
Waste paper pulp abandons object as reproducible, is a kind of potential biomass material, the Mixed Office WasteMOW of recycling
Contain about 50~70% cellulose, inorganic constituents such as lime stone (CaCO in waste paper with old corrugated carton etc.3), clay
(Al2Si2O5(OH)4) etc. shared by the specific gravity of waste paper total weight may be up to 15%.
Beneficial effects of the present invention
1, indoor pollution organic gas purification paper of the invention is raw material using secondary stock, not only at low cost, is also solved
The processing problem of waste, the purification paper adsorption effect being prepared is good, easy to use, can be affixed on wall, can also be with
It is affixed on desktop, ground etc., can be not only used for purifying the air of a room, new there may be the commodity of peculiar smell, such as case for some
Packet, leather shoes, plastic toy etc. do packing box with purification paper of the invention or place it in package interior, can adsorb new commodity
Peculiar smell, improve client buy commodity when satisfaction, it is applied widely；
2, indoor pollution organic gas purification paper of the invention, in addition to being imitated to indoor organic pollutant with good absorption
Fruit also has good mechanical property, can reach 15kNm/kg than tensile strength, can reach 5MNm/kg than elasticity modulus,
Packaging material and resistance are also used as in addition to can be used for indoor air purification with good thermal stability and fire protecting performance
Retardant composite material；
3, the preparation method of present invention purification paper is simple, can be produced in enormous quantities.
Specific embodiment
The following is specific embodiments of the present invention, and further retouches to technical solution of the present invention work in conjunction with the embodiments
It states, however, the present invention is not limited to these examples.
Embodiment 1
A kind of indoor pollution organic gas purification paper, raw material include the component of following parts by weight meter:
80 parts of waste paper pulp,
10 parts of graphene,
ZnWO41 part.
The graphene and ZnWO4Mesh number be 200 mesh.
The moisture content of the waste paper pulp is 25%.
It is described purification paper with a thickness of 10mm.
Embodiment 2
A kind of indoor pollution organic gas purification paper, raw material include the component of following parts by weight meter:
120 parts of waste paper pulp,
150 parts of graphene,
ZnWO450 parts.
The graphene and ZnWO4Mesh number be 200 mesh.
The moisture content of the waste paper pulp is 25%.
It is described purification paper with a thickness of 10mm.
Embodiment 3
A kind of indoor pollution organic gas purification paper, raw material include the component of following parts by weight meter:
100 parts of waste paper pulp,
80 parts of graphene,
ZnWO430 parts.
The graphene and ZnWO4Mesh number be 200 mesh.
The moisture content of the waste paper pulp is 25%.
It is described purification paper with a thickness of 10mm.
Embodiment 4
The preparation method of indoor pollution organic gas purification paper, step include:
(1) waste paper pulp, graphene and ZnWO are weighed according to the ratio4It mixes, prepares thin plate；
(2) two-sided clad can is carried out to thin plate obtained by step (1) with non-woven fabrics, remembers the indoor pollution organic gas purification
Paper.
Comparative example 1
A kind of indoor pollution organic gas purification paper, raw material include the component of following parts by weight meter:
100 parts of waste paper pulp,
80 parts of graphene.
The mesh number of the graphene is 200 mesh.
The moisture content of the waste paper pulp is 25%.
It is described purification paper with a thickness of 10mm.
Comparative example 2
A kind of indoor pollution organic gas purification paper, raw material include the component of following parts by weight meter:
100 parts of waste paper pulp,
5 parts of graphene,
ZnWO430 parts.
The graphene and ZnWO4Mesh number be 200 mesh.
The moisture content of the waste paper pulp is 25%.
It is described purification paper with a thickness of 10mm.
Comparative example 3
A kind of indoor pollution organic gas purification paper, raw material include the component of following parts by weight meter:
50 parts of waste paper pulp,
80 parts of graphene,
ZnWO430 parts.
The mesh number of the graphene and ZnWO4 are 200 mesh.
The moisture content of the waste paper pulp is 25%.
It is described purification paper with a thickness of 10mm.
Detect example
It is prepared according to the purification paper formula that Examples 1 to 3 and comparative example 1~3 provide using the method for embodiment 4
6 kinds of purification paper of reference numeral.
The exceeded room of certain indoor air pollutants is chosen, airtight door window for 24 hours, measures indoor air pollutants before testing
Content, then by area 2m2Present invention purification paper be affixed on wall, indoor pollutant load is detected afterwards for 24 hours, as a result such as table 1
It is shown.
1 indoor air pollutants testing result of table
As it can be seen from table 1 purification paper of the invention can significantly reduce indoor air pollutants content.Room of the invention
Interior pollution organic gas purification paper is raw material using secondary stock, not only at low cost, also solves the problems, such as the processing of waste, makes
Standby obtained purification paper adsorption effect is good, easy to use, can be affixed on wall, can also be affixed on desktop, ground etc., is applicable in
Range is wide.Indoor pollution organic gas purification paper of the invention, in addition to there is good adsorption effect to indoor organic pollutant,
Also there is good mechanical property, can reach 15kNm/kg than tensile strength, can reach 5MNm/kg than elasticity modulus, have
There are good thermal stability and fire protecting performance, in addition to can be used for indoor air purification, is also used as packaging material and fire-retardant
Composite material.The preparation method that the present invention purifies paper is simple, can be produced in enormous quantities.
Purification paper of the invention can be also used for production packing box, or purification paper is directly placed in package interior, right
In it is some it is new there may be the commodity of peculiar smell, such as luggage, leather shoes, plastic toy, do packing box with purification paper of the invention
Or package interior is placed it in, the peculiar smell of new commodity can be adsorbed, satisfaction when client buys commodity is improved.
Claims (6)
1. a kind of indoor pollution organic gas purification paper, which is characterized in that raw material includes the component of following parts by weight meter:
80~120 parts of waste paper pulp,
10~150 parts of graphene,
ZnWO41~50 part.
2. indoor pollution organic gas purification paper according to claim 1, which is characterized in that the graphene and ZnWO4Mesh
Number is 80~500 mesh.
3. indoor pollution organic gas purification paper according to claim 1, which is characterized in that the moisture content of the waste paper pulp
It is 20~30%.
4. indoor pollution organic gas purification paper according to claim 1, which is characterized in that it is described purification paper with a thickness of
0.1~20mm.
5. the preparation method of any one indoor pollution organic gas purification paper according to claim 1~4, which is characterized in that
Step includes:
(1) waste paper pulp, graphene and ZnWO are weighed according to the ratio4It mixes, laminates；
(2) two-sided clad can is carried out to get the indoor pollution organic gas purification paper to thin plate obtained by step (1) with non-woven fabrics.
6. the preparation method of indoor pollution organic gas purification paper according to claim 5, which is characterized in that the non-woven fabrics
For spunlace non-woven cloth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811398224.7A CN109173572A (en) | 2018-11-22 | 2018-11-22 | A kind of indoor pollution organic gas purification paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811398224.7A CN109173572A (en) | 2018-11-22 | 2018-11-22 | A kind of indoor pollution organic gas purification paper and preparation method thereof |
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| Publication Number | Publication Date |
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| CN109173572A true CN109173572A (en) | 2019-01-11 |
Family
ID=64938046
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| Application Number | Title | Priority Date | Filing Date |
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| CN201811398224.7A Pending CN109173572A (en) | 2018-11-22 | 2018-11-22 | A kind of indoor pollution organic gas purification paper and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102345249A (en) * | 2010-08-06 | 2012-02-08 | 范晓星 | Photocatalytic wallpaper for indoor air purification |
| WO2012113543A1 (en) * | 2011-02-26 | 2012-08-30 | Clariant International Ltd | Optimized layer-by-layer assemblies for indoor photo-catalytical pollutants removal |
| CN103623803A (en) * | 2012-08-30 | 2014-03-12 | 上海纳晶科技有限公司 | Visible light photocatalyst and preparation method therefor |
| CN104746382A (en) * | 2015-03-11 | 2015-07-01 | 山东鲁南新材料股份有限公司 | Wallpaper base paper capable of adsorbing formaldehyde and production method thereof |
| CN205531140U (en) * | 2016-01-22 | 2016-08-31 | 冯跃生 | Graphite alkene wall paper |
| CN108724825A (en) * | 2018-05-31 | 2018-11-02 | 合肥宸翊商贸有限公司 | Composite wall paper and preparation method thereof with air-cleaning function |
-
2018
- 2018-11-22 CN CN201811398224.7A patent/CN109173572A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102345249A (en) * | 2010-08-06 | 2012-02-08 | 范晓星 | Photocatalytic wallpaper for indoor air purification |
| WO2012113543A1 (en) * | 2011-02-26 | 2012-08-30 | Clariant International Ltd | Optimized layer-by-layer assemblies for indoor photo-catalytical pollutants removal |
| CN103623803A (en) * | 2012-08-30 | 2014-03-12 | 上海纳晶科技有限公司 | Visible light photocatalyst and preparation method therefor |
| CN104746382A (en) * | 2015-03-11 | 2015-07-01 | 山东鲁南新材料股份有限公司 | Wallpaper base paper capable of adsorbing formaldehyde and production method thereof |
| CN205531140U (en) * | 2016-01-22 | 2016-08-31 | 冯跃生 | Graphite alkene wall paper |
| CN108724825A (en) * | 2018-05-31 | 2018-11-02 | 合肥宸翊商贸有限公司 | Composite wall paper and preparation method thereof with air-cleaning function |
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Application publication date: 20190111 |
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| RJ01 | Rejection of invention patent application after publication |