CN109161348A - A kind of modified water-soluble SBS lotion glue spraying and preparation method thereof - Google Patents
A kind of modified water-soluble SBS lotion glue spraying and preparation method thereof Download PDFInfo
- Publication number
- CN109161348A CN109161348A CN201810983207.3A CN201810983207A CN109161348A CN 109161348 A CN109161348 A CN 109161348A CN 201810983207 A CN201810983207 A CN 201810983207A CN 109161348 A CN109161348 A CN 109161348A
- Authority
- CN
- China
- Prior art keywords
- sbs
- lotion
- soluble
- glue spraying
- modified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/28—Emulsion polymerisation with the aid of emulsifying agents cationic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/006—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of modified water-soluble SBS lotion glue sprayings, are made of the component for including following mass fraction: 40~70wt% of acrylate modified SBS latex (solid content 50wt%)；Styrene-acrylic emulsion (45~60wt% of solid content) 10~30wt%；5~10wt% of tertiary carbon lotion；5~20wt% of Tackified emulsion；0.2~3wt% of coagulating agent aqueous solution；0.1~0.5wt% of anti-aging agent；0.1~1wt% of stabilizer；0.2~1wt% of thickener.The present invention has the advantages that function admirable, moderate cost, environment-protecting and non-poisonous, intensity establish it is fast, suitable for glue spraying industry and be easy to technological operation.
Description
Technical field
The present invention relates to water-soluble spraying glue fields, and in particular to a kind of modified water-soluble SBS lotion glue spraying and preparation method thereof.
Background technique
Glue spraying is a kind of gluing for closely connecting identical or different material interface, playing the role of transmitting application
Agent is widely used in furniture, leather and decoration industry.Currently, glue spraying on the market is based on solvent type glue spraying.Solvent type glue spraying master
To be made of high polymer and solvent, high polymer is generally neoprene (CR), styrol copolymer (SBS), solvent be then toluene,
Chloroalkene, butanone, ethyl acetate etc..In use, organic solvent, which can largely volatilize, very big danger to human health
Evil.Further, since these solvent volatilization points are extremely low, burning and explosion easily occurs, therefore solvent type glue spraying is in storage, transport, use
Exist in the process inflammable and explosive and waits major safety risks to human health is harmful.Therefore, water is used in the mutually competing research in countries in the world
Substitute the environment-friendly type aqueous glue spraying of organic solvent.In Germany, the developed countries such as the U.S. and Japan are proposed aqueous polyurethane glue spraying
With watersoluble neoprene glue spraying.It is domestic in recent years also to occur water-based polyurethane adhesive and watersoluble neoprene adhesive on the market, still
It is different due to haveing the shortcomings that, cause product promotion to be greatly affected.Monocomponent waterborne polyurethane adhesive tack is poor,
Need heat-activated that could use；The mono-component aqueous same tack of neoprene is bad, and atomization is serious when spraying, and the supply of material at high cost
It is unstable.For double-component aqueous glue spraying after connection solidification, glue-line is easy hardening, and especially junction border sclerosis is particularly acute；
Further for the heavier leather of oiliness and imitation leather material, traditional glue spraying grease resistance is poor, and especially initial bonding strength and whole viscous force be not
Enough ideals directly affect radian bonding fastness and stability between leather, sponge.
Summary of the invention
The object of the present invention is to provide a kind of function admirable, moderate cost, environment-protecting and non-poisonous, intensity to establish fastly, suitable for spray
Glue industry and the modified water-soluble SBS glue spraying and preparation method thereof for being easy to technological operation.
Concrete scheme of the invention is as follows: a kind of modified water-soluble SBS lotion glue spraying, by the component including following mass fraction
It is made:
40~70wt% of acrylate modified SBS latex (solid content 50wt%)；
Styrene-acrylic emulsion (45~60wt% of solid content) 10~30wt%；
5~10wt% of tertiary carbon lotion
5~20wt% of Tackified emulsion；
Coagulating agent aqueous solution 0.2~3；Wt%
0.1~0.5wt% of anti-aging agent；
0.1~1wt% of stabilizer；
0.2~1wt% of thickener.
In above-mentioned modified water-soluble SBS lotion glue spraying, the modified SBS latex the preparation method is as follows:
Step 1: a certain amount of monomer mixture is added in 500mL three-necked flask；The monomer mixture includes
SBS is added portionwise, to SBS in butyl acrylate, (methyl) methyl acrylate, vinylacetate, (methyl) acrylic acid while stirring
After being completely dissolved, emulsifier compound aqueous solution is added drop-wise in flask, 60 DEG C of emulsification pretreatment 30min are at SBS- monomer pre-emulsion；
Step 2: deionized water, carbon being added in the four-hole boiling flask with blender, condenser pipe, thermometer and constant pressure funnel
Sour hydrogen sodium and part persulfate aqueous solution, are warming up to 75-80 DEG C, start that monomer pre-emulsion and remaining over cure is added dropwise respectively
Sour aqueous solutions of potassium, 2.5-3h are dripped off, insulation reaction 0.5h, and modified SBS latex can be obtained, and are discharged spare.
In above-mentioned modified water-soluble SBS lotion glue spraying, in above-mentioned modified water-soluble SBS lotion glue spraying, SBS and monomer
The mass ratio of mixture is 1:0.6；It is total that emulsifier in the emulsifier compound aqueous solution is equivalent to modified SBS latex
The 2% of solid content；The emulsifier is by the cetyl trimethylammonium bromide that weight ratio is 2:2:1, dodecyl benzene sulfonic acid
Sodium: OP-10 composition.
In above-mentioned modified water-soluble SBS lotion glue spraying, the potassium peroxydisulfate is equivalent to modified SBS latex total solid content
0.5%；The sodium bicarbonate is equivalent to the 0.3% of modified SBS latex total solid content.
In above-mentioned modified water-soluble SBS lotion glue spraying, the composition of the monomer mixture are as follows: butyl acrylate
50wt%, methyl methacrylate 25wt%, vinylacetate 15wt%, methacrylic acid 10wt%.
In above-mentioned modified water-soluble SBS lotion glue spraying, the viscosity of the styrene-acrylic emulsion is 100-200mPa.s, partial size
100-300 nanometers, solid content is 45~60 mass %.
In above-mentioned modified water-soluble SBS lotion glue spraying, the tertiary carbon lotion be with tertiary ethylene carbonate (VV9 and
It VV10 is) the ambient self-crosslinking lotion of principal monomer, viscosity is 200~3000mPa.s.
In above-mentioned modified water-soluble SBS lotion glue spraying, the Tackified emulsion is commercially available terpene phenolic lotion or terpenes
Phenol resin and the elastomer blended aqueous dispersion lotion of SBS.
It further include the aromatic series with conjugated diene key of 2~4wt% in above-mentioned modified water-soluble SBS lotion glue spraying
Compound；The aromatic compound with conjugated diene key is 2- phenyl -1,3-butadiene.
In above-mentioned modified water-soluble SBS lotion glue spraying, the coagulating agent aqueous solution is binary organic acid or other are weak
Acid, the mass concentration of coagulating agent aqueous solution are 2~20%.
In above-mentioned modified water-soluble SBS lotion glue spraying, it is (anti-old that the anti-aging agent can choose N- phenyl-β-naphthylamine
Agent D) aqueous solution, 2,6-di-tert-butyl p-cresol (antioxidant 264) aqueous solution or 4- methyl-6-tert-butylphenol it is (anti-old
Agent 2246) aqueous solution, when use generally use above-mentioned mass percent concentration for 50% anti-aging agent aqueous dispersions, with 50%
For antioxidant D dispersion liquid, preparation method is as follows: antioxidant D 1g, and deionized water 1mL is put into ball milling in ball mill
Up to 50% antioxidant D dispersion liquid.
In above-mentioned modified water-soluble SBS lotion glue spraying, the stabilizer is that any nonionic or anionic surface are living
The mixture of property agent or both.
In above-mentioned modified water-soluble SBS lotion glue spraying, the thickener is hydroxymethyl cellulose, casein or polyethylene
Alcohol.
The invention also discloses a kind of preparation methods of modified water-soluble SBS lotion glue spraying as described above simultaneously, including such as
Lower step:
Modified SBS latex is weighed, in the case where being sufficiently stirred, stabilizer is added, stirring after ten minutes, is added under medium-shear
Styrene-acrylic emulsion and tertiary carbon lotion disperse 15 minutes, are finally stirring at low speed lower addition other components, stir evenly up to modified water
Property SBS lotion glue spraying.
Modified water-soluble SBS lotion glue spraying of the invention can be used for mattress, seat (sleeps) chair, sofa, screen, luggage, decoration material
The fields such as material.Compared with prior art, the invention has the following beneficial effects:
1. the present invention is sufficient using source, cheap acrylic ester monomer (butyl acrylate, vinylacetate,
Methacrylic acid etc.), SBS is modified by fine emulsion polymerization and prepares modified SBS latex, is equipped with styrene-acrylic emulsion, tertiary carbon
Lotion, coagulant solution and other auxiliary agents, the latex type SBS adhesive prepared, performance and commercially available solvent type SBS gluing
Agent is close, and intensity does not fly mist when establishing fast speed, spraying, applied widely, and the glue spraying is after use, and the abutting edge of glue is solid
Glue-line is non-sclerous after change, and abutting edge not hard-edge can solve the problem of hard-edge after the aqueous adhesive curing of neoprene.
2. styrene-acrylic emulsion initial bonding strength is big, it is wide to be bonded base material range, resists cold heat-resist, price is low.Tertiary carbon lotion due to
Macromolecular ester soluble group exists and space steric effect, to difficult substrates have excellent adhesive force and bonding force and water resistance,
Alkali resistance and excellent in weather.
3. one of disadvantage of emulsion adhesive is exactly slow drying speed compared with solvent-based adhesive.The present invention
Due to ingredient containing ambient self-crosslinking special in tertiary carbon lotion, it is equipped with coagulant solution, the intensity for accelerating emulsion-type SBS adhesive is built
Vertical speed is able to achieve moment bonding.
4, present invention employs 2- phenyl-functional aid of the 1,3-butadiene as performance improvement, the auxiliary agent energy is added
The water resistance and weatherability for enough effectively improving lotion, particularly in the validity that in acid-base environment, can be improved viscose.
Specific embodiment
Below with reference to embodiment, the invention will be further described, but does not constitute any limitation of the invention, any
In the modification for the limited times that scope of the invention as claimed is made, still in scope of the presently claimed invention.
Embodiment 1
Modified water-soluble SBS lotion glue spraying manufactured in the present embodiment (sleeps) bonding of chair, sofa sponge for mattress, seat, and
It is bonded using wet technique.
The each component formula of the watersoluble modified aqueous SBS lotion glue spraying of the present embodiment is as follows:
50 parts of modified SBS latex (weight)；24 parts of styrene-acrylic emulsion (weight)；5 parts of commercially available tertiary carbon lotion (weight)；Commercially available increasing
20 parts of slimy milk liquid (weight)；0.2 part of neopelex (weight), the antioxidant 264 that mass percent concentration is 50%
0.1 part of aqueous solution (weight), mass percent concentration is 0.5 part of oxalic acid (weight) of 20%, thickener hydroxymethyl cellulose 0.2
Part (weight).
By a certain amount of monomer mixture (butyl acrylate, methyl methacrylate, vinylacetate, methacrylic acid)
It is added in 500mL three-necked flask, SBS is added portionwise while stirring, after SBS is completely dissolved, by emulsifier compound aqueous solution
It is added drop-wise in flask, 60 DEG C of emulsification pretreatment 30min are at SBS- monomer pre-emulsion.Having blender, condenser pipe, thermometer and perseverance
It presses in the four-hole boiling flask of funnel and is added dissolved with a small amount of sodium bicarbonate and initiator potassium persulfate (KPS) aqueous solution, be warming up to 80 DEG C,
Start that monomer pre-emulsion is added dropwise respectively and initiator potassium persulfate (KPS) aqueous solution, 2.5-3h are dripped off, insulation reaction 0.5h, i.e.,
Modified SBS latex can be obtained, discharge spare.
Wherein the preparation method of modified SBS latex, detailed step are as follows: (1) weighing each list of following mass percent
Body: butyl acrylate 50%, methyl methacrylate 25%, vinylacetate 15%, methacrylic acid 10%；By weighed list
Stirring and dissolving SBS at 40-50 DEG C of body is uniformly mixed it, then emulsifier compound aqueous solution is added drop-wise in flask, 60 DEG C of shearings
30min is emulsified into SBS- monomer pre-emulsion.
(2) deionization is added in the four round flask equipped with electric mixer, condenser pipe, thermometer and dropping funel
The initiator solution of water, sodium bicarbonate and quality half, starts blender and heating device, is warming up to 70-80 DEG C, opens respectively
Begin that monomer pre-emulsion is added dropwise and initiator solution, 2.5-3h are dripped off, modified SBS latex can be obtained, out in insulation reaction 0.5h
Expect spare；
In above-mentioned steps (1), the mass ratio of SBS and total monomer is 1:0.6, and the additional amount of emulsifier (accounts for total solid for 2%
Amount), the additional amount of deionized water is 8%；The emulsifier be cationic emulsifier (cetyl trimethylammonium bromide): yin from
Sub- emulsifier (neopelex): nonionic emulsifier (OP-10)=2:2:1.
In above-mentioned steps (1), the amount of weighing of initiator is 0.5% (accounting for total solid), and the amount of weighing of deionized water is
17%；The initiator is potassium peroxydisulfate.
In above-mentioned steps (2), the additional amount of deionized water is 75%, and the additional amount of sodium bicarbonate (accounts for total solid for 0.3%
Amount).
According to above-mentioned formula, weigh modified SBS latex, in the case where being sufficiently stirred, be added stabilizer, stirring after ten minutes,
800rpm shearing is lower to be added styrene-acrylic emulsion and tertiary carbon lotion, disperses 15 minutes, is finally added with stirring Tackified emulsion in 300rpm,
Anti-aging agent aqueous solution, coagulating agent aqueous solution and thickener stir evenly up to modified water-soluble SBS lotion glue spraying.
Speed obtained by the present embodiment glues watersoluble modified aqueous SBS lotion glue spraying.For be bonded sponge, it can be achieved that moment be bonded,
Substrate sponge is destroyed after 24.
Embodiment 2
Modified water-soluble SBS lotion glue spraying manufactured in the present embodiment (sleeps) the viscous of chair, sofa sponge and plank for mattress, seat
It connects, and is bonded using wet technique.
The each component formula of the present embodiment modified water-soluble SBS lotion glue spraying is as follows:
65 parts of modified SBS latex (weight)；19.2 parts of styrene-acrylic emulsion (weight)；5 parts of commercially available tertiary carbon lotion (weight)；It is commercially available
10 parts of Tackified emulsion (weight)；0.2 part of neopelex (weight), the anti-aging agent that mass percent concentration is 50%
264 0.1 part of aqueous solutions (weight), mass percent concentration are 0.3 part of glycine (weight) of 5%, thickener hydroxylmethyl cellulose
Plain 0.2 part (weight).
A certain amount of monomer mixture (butyl acrylate, methyl acrylate, vinylacetate, methacrylic acid) is added
Into 500mL three-necked flask, SBS is added portionwise while stirring, after SBS is completely dissolved, emulsifier compound aqueous solution is added dropwise
Into flask, 60 DEG C of emulsification pretreatment 30min are at SBS- monomer pre-emulsion.With blender, condenser pipe, thermometer and constant pressure leakage
It is added in the four-hole boiling flask of bucket dissolved with a small amount of sodium bicarbonate and initiator KPS aqueous solution, is warming up to 70-80 DEG C, starts to drip respectively
Add monomer pre-emulsion and initiator potassium persulfate (KPS) aqueous solution, 2.5-3h is dripped off, and modification can be obtained in insulation reaction 0.5h
SBS latex discharges spare.
Wherein the preparation method of modified SBS latex, detailed step are as follows: (1) weighing each list of following mass percent
Body: butyl acrylate 50%, methyl methacrylate 25%, vinylacetate 15%, methacrylic acid 10%；By weighed list
Stirring and dissolving SBS at 50 DEG C of body is uniformly mixed it, then emulsifier compound aqueous solution is added drop-wise in flask, 60 DEG C of shearing creams
Change 30min into SBS- monomer pre-emulsion.
(2) deionization is added in the four round flask equipped with electric mixer, condenser pipe, thermometer and dropping funel
The initiator solution of water, sodium bicarbonate and quality half, starts blender and heating device, is warming up to 70-80 DEG C, opens respectively
Begin that monomer pre-emulsion is added dropwise and initiator solution, 2.5-3h are dripped off, modified SBS latex can be obtained, out in insulation reaction 0.5h
Expect spare；
In above-mentioned steps (1), the mass ratio of SBS and total monomer is 1:0.6, and the additional amount of emulsifier (accounts for total solid for 2%
Amount), the additional amount of deionized water is 8%；The emulsifier be cationic emulsifier (cetyl trimethylammonium bromide): yin from
Sub- emulsifier (neopelex): nonionic emulsifier (OP-10)=2:2:1.
In above-mentioned steps (1), the amount of weighing of initiator is 0.5% (accounting for total solid), and the amount of weighing of deionized water is
17%；The initiator is potassium peroxydisulfate.
In above-mentioned steps (2), the additional amount of deionized water is 75%, and the additional amount of sodium bicarbonate (accounts for total solid for 0.3%
Amount).
According to above-mentioned formula, weigh modified SBS latex, in the case where being sufficiently stirred, be added stabilizer, stirring after ten minutes,
800rpm shearing is lower to be added styrene-acrylic emulsion and tertiary carbon lotion, disperses 15 minutes, is finally added with stirring Tackified emulsion in 300rpm,
Anti-aging agent aqueous solution, metal oxide aqueous solution, coagulating agent aqueous solution and thickener, stir evenly and glue watersoluble modified water up to speed
Property SBS lotion glue spraying.
Modified water-soluble SBS lotion glue spraying obtained by the present embodiment.For being bonded sponge-plank, it can be achieved that moment is bonded, after 24
Destroy substrate sponge.
Embodiment 3
It is substantially the same with embodiment 1, different places is:
The each component formula of watersoluble modified aqueous SBS lotion glue spraying is as follows:
45 parts of modified SBS latex (weight)；30 parts of styrene-acrylic emulsion (weight)；10 parts of commercially available tertiary carbon lotion (weight)；It is commercially available
12 parts of Tackified emulsion (weight)；2- phenyl -2 parts of 1,3-butadiene (weight)；0.2 part of neopelex (weight), matter
Measure 0.1 part of antioxidant 264 aqueous solution (weight) that percent concentration is 50%, the oxalic acid 0.5 that mass percent concentration is 20%
Part (weight), 0.2 part of thickener hydroxymethyl cellulose (weight).
Using test
Modified water-soluble SBS lotion glue spraying is prepared using the preparation method of embodiment 1 and 3 according to above-mentioned formula,
The performance of the adhesive is compared with commercially available solvent type SBS adhesive, watersoluble neoprene gluing agent performance, as a result such as table 1 and 2
It is shown.
1 modified water-soluble SBS lotion glue spraying of table and commercial solvents type SBS adhesive and commercially available watersoluble neoprene latex type adhesive
Performance comparison (sponge is to sponge)
Note: 1 is commercially available watersoluble neoprene latex type adhesive, and 2 be commercially available solvent type SBS adhesive, and 3 be the present embodiment 1
Modified water-soluble SBS lotion glue spraying；4 be the modified water-soluble SBS lotion glue spraying of the present embodiment 3
2 modified water-soluble SBS lotion glue spraying of table and commercial solvents type SBS adhesive and commercially available watersoluble neoprene latex type adhesive
Performance comparison (sponge is to plank)
Note: 1 is commercially available watersoluble neoprene latex type adhesive, and 2 be commercially available solvent type SBS adhesive, and 3 be the present embodiment 1
Modified water-soluble SBS lotion glue spraying；4 be the modified water-soluble SBS lotion glue spraying of the present embodiment 3
3 modified water-soluble SBS lotion glue spraying of table and commercial solvents type SBS adhesive and commercially available watersoluble neoprene latex type adhesive
Performance comparison (sponge and canvas bond, and water resistance is tested in placement afterwards for 24 hours)
Note: 1 is commercially available watersoluble neoprene latex type adhesive, and 2 be commercially available solvent type SBS adhesive, and 3 be the present embodiment 1
Modified water-soluble SBS lotion glue spraying；4 be the modified water-soluble SBS lotion glue spraying of the present embodiment 3
4 modified water-soluble SBS lotion glue spraying of table and commercial solvents type SBS adhesive and commercially available watersoluble neoprene latex type adhesive
Performance comparison (sponge gluing, in 90 degree radian doublings bonding, after placing for 24 hours, test weatherability)
Note: 1 is commercially available watersoluble neoprene latex type adhesive, and 2 be commercially available solvent type SBS adhesive, and 3 be the present embodiment 1
Modified water-soluble SBS lotion glue spraying；4 be the modified water-soluble SBS lotion glue spraying of the present embodiment 3.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (10)
1. a kind of modified water-soluble SBS lotion glue spraying, which is characterized in that be made of the component for including following mass fraction:
40~70wt% of acrylate modified SBS latex (solid content 50wt%)；
Styrene-acrylic emulsion (45~60wt% of solid content) 10~30wt%；
5~10wt% of tertiary carbon lotion
5~20wt% of Tackified emulsion；
0.2~3wt% of coagulating agent aqueous solution；
0.1~0.5wt% of anti-aging agent；
0.1~1wt% of stabilizer；
0.2~1wt% of thickener.
2. modified water-soluble SBS lotion glue spraying according to claim 1, which is characterized in that modified SBS latex preparation side
Method is as follows:
Step 1: a certain amount of monomer mixture is added in 500mL three-necked flask；The monomer mixture includes propylene
SBS is added portionwise in acid butyl ester, (methyl) methyl acrylate, vinylacetate, (methyl) acrylic acid while stirring, complete to SBS
After dissolution, emulsifier compound aqueous solution is added drop-wise in flask, 60 DEG C of emulsification pretreatment 30min are at SBS- monomer pre-emulsion；
Step 2: deionized water, bicarbonate being added in the four-hole boiling flask with blender, condenser pipe, thermometer and constant pressure funnel
Sodium and part persulfate aqueous solution, are warming up to 75-80 DEG C, start that monomer pre-emulsion and remaining potassium peroxydisulfate is added dropwise respectively
Aqueous solution, 2.5-3h are dripped off, insulation reaction 0.5h, and modified SBS latex can be obtained, and are discharged spare.
3. modified water-soluble SBS lotion glue spraying according to claim 1, which is characterized in that the quality of SBS and monomer mixture
Than for 1:0.6；Emulsifier in the emulsifier compound aqueous solution is equivalent to the 2% of modified SBS latex total solid content；
Cetyl trimethylammonium bromide, the neopelex that the emulsifier is 2:2:1 by weight ratio: OP-10 is formed.
4. modified water-soluble SBS lotion glue spraying according to claim 3, which is characterized in that the potassium peroxydisulfate is equivalent to
The 0.5% of modified SBS latex total solid content；The sodium bicarbonate is equivalent to the 0.3% of modified SBS latex total solid content.
5. modified water-soluble SBS lotion glue spraying according to claim 3, which is characterized in that the group of the monomer mixture
Become: butyl acrylate 50wt%, methyl methacrylate 25wt%, vinylacetate 15wt%, methacrylic acid 10wt%.
6. modified water-soluble SBS lotion glue spraying according to claim 1, which is characterized in that the viscosity of the styrene-acrylic emulsion
For 100-200mPa.s, 100-300 nanometers of partial size, solid content is 45~60 mass %.
7. modified water-soluble SBS lotion glue spraying according to claim 1, which is characterized in that the tertiary carbon lotion is with uncle
Ethylene carbonate (VV9 and VV10) is the ambient self-crosslinking lotion of principal monomer, and viscosity is 200~3000mPa.s.
8. modified water-soluble SBS lotion glue spraying according to claim 1, which is characterized in that the Tackified emulsion is commercially available
Terpene phenolic lotion or terpene phenol resin and the elastomer blended aqueous dispersion lotion of SBS.
9. modified water-soluble SBS lotion glue spraying according to claim 1, which is characterized in that further include having for 2~4wt%
The aromatic compound of conjugated diene key；The aromatic compound with conjugated diene key is 2- phenyl -1,3- fourth two
Alkene.
10. a kind of preparation method of the modified water-soluble SBS lotion glue spraying as described in claim 1-9 is any, it is characterised in that: packet
Include following steps:
Modified SBS latex is weighed, in the case where being sufficiently stirred, stabilizer is added, after ten minutes, phenylpropyl alcohol is added under medium-shear in stirring
Lotion and tertiary carbon lotion disperse 15 minutes, are finally stirring at low speed lower addition other components, stir evenly up to modified water-soluble
SBS lotion glue spraying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810983207.3A CN109161348A (en) | 2018-08-27 | 2018-08-27 | A kind of modified water-soluble SBS lotion glue spraying and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810983207.3A CN109161348A (en) | 2018-08-27 | 2018-08-27 | A kind of modified water-soluble SBS lotion glue spraying and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109161348A true CN109161348A (en) | 2019-01-08 |
Family
ID=64896835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810983207.3A Pending CN109161348A (en) | 2018-08-27 | 2018-08-27 | A kind of modified water-soluble SBS lotion glue spraying and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109161348A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110003800A (en) * | 2019-04-10 | 2019-07-12 | 广东绿洲化工有限公司 | A kind of modified butadiene-styrene latex environmental protection glue spraying and preparation method thereof |
| CN113403004A (en) * | 2021-07-16 | 2021-09-17 | 西安汉港新材料科技有限公司 | Environment-friendly high-adhesion box pasting adhesive and preparation method thereof |
| CN113429918A (en) * | 2021-05-12 | 2021-09-24 | 广东泰强化工实业有限公司 | Single-component high-performance modified SBS water-based adhesive |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101463236A (en) * | 2009-01-12 | 2009-06-24 | 福建师范大学 | Preparation of environment protection aqueous SBS binder |
| WO2009143895A1 (en) * | 2008-05-30 | 2009-12-03 | Pirelli Tyre S.P.A. | Tyre comprising a sealing material comprising a partially cross-linked styrene-butadiene rubber |
| CN101698782A (en) * | 2009-07-01 | 2010-04-28 | 北京高盟化工有限公司 | Normal temperature adhesive composition and preparation method thereof |
| CN106753087A (en) * | 2017-03-15 | 2017-05-31 | 怀化大自然化工有限公司 | A kind of aqueous, environmental protective all-purpose adhesive and preparation method thereof |
-
2018
- 2018-08-27 CN CN201810983207.3A patent/CN109161348A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009143895A1 (en) * | 2008-05-30 | 2009-12-03 | Pirelli Tyre S.P.A. | Tyre comprising a sealing material comprising a partially cross-linked styrene-butadiene rubber |
| CN101463236A (en) * | 2009-01-12 | 2009-06-24 | 福建师范大学 | Preparation of environment protection aqueous SBS binder |
| CN101698782A (en) * | 2009-07-01 | 2010-04-28 | 北京高盟化工有限公司 | Normal temperature adhesive composition and preparation method thereof |
| CN106753087A (en) * | 2017-03-15 | 2017-05-31 | 怀化大自然化工有限公司 | A kind of aqueous, environmental protective all-purpose adhesive and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李广宇: "《胶黏剂原材料手册》", 3 August 2004, 国防工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110003800A (en) * | 2019-04-10 | 2019-07-12 | 广东绿洲化工有限公司 | A kind of modified butadiene-styrene latex environmental protection glue spraying and preparation method thereof |
| CN113429918A (en) * | 2021-05-12 | 2021-09-24 | 广东泰强化工实业有限公司 | Single-component high-performance modified SBS water-based adhesive |
| CN113429918B (en) * | 2021-05-12 | 2022-04-01 | 广东泰强化工实业有限公司 | Single-component high-performance modified SBS water-based adhesive |
| CN113403004A (en) * | 2021-07-16 | 2021-09-17 | 西安汉港新材料科技有限公司 | Environment-friendly high-adhesion box pasting adhesive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109161348A (en) | A kind of modified water-soluble SBS lotion glue spraying and preparation method thereof | |
| CN102617771B (en) | Aqueous printing ink binding agent and ink as well as preparation methods thereof | |
| CN103740304B (en) | A kind of neoprene latex adhesive containing amphipathic nature polyalcohol chain and preparation method thereof | |
| CN104497201B (en) | Rosin derivative/polyacrylate hybrid miniemulsion pressure sensitive adhesive and preparation method thereof | |
| CN106978107A (en) | The senior strength adhesive of multipurpose | |
| CN107236418A (en) | The preparation method of the water-based acrylic resin of epoxy resin modification | |
| CN103865439A (en) | Double-component aqueous neoprene spray glue | |
| CN101463138A (en) | Surface treating agent for binding silastic and plastic, preparation and use method thereof | |
| WO2008112644A1 (en) | Protein stabilized latex polymer emulsions, method of making, and adhesives containing such emulsions | |
| CN106833446A (en) | PP film gum Acrylate pressure-sensitive adhesive emulsions and application thereof and preparation method | |
| CN105567156A (en) | SBS-type nano deodorization spray adhesive | |
| CN105440982B (en) | Packing box used and wood-leather base material used environmentally-friendly aqueous binder | |
| CN103030914A (en) | Acrylic ester composition, preparation method of acrylic ester composition, and adhesive tape applying composition | |
| CN102808360B (en) | Temperature-resistant water-based gloss oil for high-gloss paper products and preparation method of temperature-resistant water-based gloss oil | |
| CN107739591A (en) | A kind of net taste strength glue spraying of environmental protection and preparation method thereof | |
| CN107502231A (en) | A kind of resistance to efflorescence glue spraying and preparation method thereof | |
| CN106634785A (en) | Method for preparing aqueous polyurethane adhesive with good water resistance | |
| CN106189950A (en) | A kind of aqueous, environmental protective high intensity sticker adhesive and preparation method thereof | |
| CN106753086A (en) | Environment-friendly water-based glue spraying and preparation method thereof | |
| JPH08231616A (en) | Curable water-based resin composition | |
| CN103539948B (en) | Preparation method of high-strength adhesive powder chloroprene rubber | |
| JPH09169832A (en) | Aqueous resin dispersion composition | |
| CN113528059A (en) | Environment-friendly toluene-free solvent type all-purpose adhesive and preparation method thereof | |
| CN101817965A (en) | Ester-soluble resin and preparation method thereof | |
| CN107722926A (en) | Transparent glue spraying of a kind of net taste of environmental protection and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190108 |
|
| RJ01 | Rejection of invention patent application after publication |