CN109158541A - The production method of magnesium alloy technique statue - Google Patents

The production method of magnesium alloy technique statue Download PDF

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Publication number
CN109158541A
CN109158541A CN201811047661.4A CN201811047661A CN109158541A CN 109158541 A CN109158541 A CN 109158541A CN 201811047661 A CN201811047661 A CN 201811047661A CN 109158541 A CN109158541 A CN 109158541A
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China
Prior art keywords
magnesium alloy
casting
alloy
sand
magnesium
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CN201811047661.4A
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Chinese (zh)
Inventor
朱广东
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Wenxi Yuanhua Metallurgical Materials Co Ltd
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Wenxi Yuanhua Metallurgical Materials Co Ltd
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Priority to CN201811047661.4A priority Critical patent/CN109158541A/en
Publication of CN109158541A publication Critical patent/CN109158541A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C23/00Alloys based on magnesium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

The magnesium alloy handicraft article of various beautiful colors is made in the production method of magnesium alloy technique statue disclosed by the invention, production, melted alloy, casting and the processing of casting including mold, finally surface treatment.Magnesium alloy is that a kind of small fusing point of density is low, the good light alloy of mobile performance.Replace copper alloy production technology product carving as light-weight, more cheap more than copper alloy of price, all very convenient as craftwork, the especially lifting of extensive process product, transport, exploitation magnesium alloy handicraft article is with extensive market and plump economic benefit with magnesium alloy.

Description

The production method of magnesium alloy technique statue
Technical field
The invention belongs to the field of deep of magnesium alloy, and in particular to utilize the life of magnesium alloy cast technique magnesium alloy statue Production method.
Background technique
Magnesium alloy is a kind of alloy that density is small.It is compared with the technique statue bronze statue of Chinese tradition, same volume Magnesium alloy weight is 1/4.5th of copper alloy or so.For the price of two kinds of materials, Cu alloy material price is about that magnesium closes The three times or so of price of gold lattice.The two considers in addition.The main raw material(s) of the technique statue of the magnesium alloy materials of same volume is only Ten one thirds of bronze have great cost advantage.
In addition, China is the maximum magnesium producing country in the whole world and exported country, actual conditions are that the magnesium factory of various regions relies at present Cheap resource, the energy and labour manufactures magnesium metal, by primary simple processing, a large amount of waste residues and exhaust gas is left, product It is sold to overseas.China has turned due to developing century-old left and right of more American-European evening, the external advanced state of the after-product of some high energy consumptions Backward and developing country is transferred to be produced.Magnesium metal just belongs to this product.Because of value-added content of product and rate of earning foreign exchange thus It is relatively high.
In addition, the fusing point of magnesium metal only has 651 DEG C, the fusing heat of magnesium is smaller, and the fluidity of molten of magnesium is good, and easy molding is poured Casting.Since the density of magnesium is small, casting severe is lighter, it is easier to move lifting and transport, this and iron and bronze casting technique Product have bigger superiority.Due to the above factors, magnesium alloy technique casting is developed, magnesium alloy application range is expanded. Flourishing national economy, provides more job opportunities for the people, enriches the culture life of the people, make Chinese ancient tradition Culture is further passed on.
In addition, the fusing point of magnesium metal only has 651 DEG C, the fusing heat of magnesium is smaller, and the fluidity of molten of magnesium is good, is easy molding Casting.Since the density of magnesium is small, casting severe is lighter, it is easier to move lifting and transport, this and iron and bronze casting work Skill product have bigger superiority.Due to the above factors, magnesium alloy technique casting is developed, magnesium alloy application model is expanded It encloses.Flourishing national economy, provides more job opportunities for the people, enriches the culture life of the people, make Chinese ancient Traditional culture is further passed on.
Summary of the invention
It is an object of the present invention to provide a kind of novel methods using magnesium alloy production technology product (statue), expand magnesium alloy Application range.
The present invention is achieved by the following technical scheme:
A kind of production method of magnesium alloy technique statue, includes the following steps:
(1), the production of mold
1.1, the production of aluminum alloy mould, using the aluminum alloy mould for manually producing product;
1.2, the manufacture of investment pattern die using wax or can issue polystyrene resin and produce investment pattern die;
1.3, coating is sprayed or immersed on investment pattern die and makes its solidification;
1.4, investment pattern die outer layer coating is dry;
1.5, the investment pattern die made be placed in sandbox firmly install, and load onto casting gate and riser and install sand, to It casts.
(2), the preparation of magnesium alloy fused mass
2.1, AZ91D magnesium alloy ingot used in furnace will be prepared according to product consumption;
2.2, the magnesium alloy flux for needing product fusion process is added to heat in melting pot and melt, magnesium alloy flux and magnesium alloy The ratio of ingot (melt) is 10 ~ 15:100(weight ratio), wherein magnesium alloy flux requires to guarantee to contain following composition and content (note: further including other impurities component, such as magnesia etc. in magnesium alloy flux)
KCl 40%
MgCl2 38~42%
NaCl2 5%
BaCl2 8~10%
Magnesium alloy flux can prevent magnesium alloy aoxidized in fusion process and scaling loss and magnesium alloy and slag separation it is good.
(3), magnesium alloy melts
3.1, in melting pot magnesium alloy flux melts amount up to 75% or more when slowly add magnesium alloy ingot to be melted, be melted to magnesium Alloy liquid-solid ratio is passed through argon gas when being 6 ~ 7:1 and is stirred, gas sampling to exhaust treatment system processing;
3.2, all beryllium-aluminium alloy (amount containing Be is 3.5% in beryllium-aluminium alloy) is added after fusing in magnesium alloy ingot in melting pot, In, beryllium-aluminium alloy additional amount is that Be content reaches the 20ppm of magnesium alloy (melt) amount, all fusing reaction;Melt temperature Start to cool down when up to 700 ~ 710 DEG C and settle, so that melt and slag separation are good.
(4), the processing of cast tubes and casting
4.1, when magnesium alloy fused mass temperature is up to 690 ~ 700 DEG C, liquid magnesium alloy addition is preheated to 380 DEG C with magnesium alloy liquid pressure pump In above tundish, prepare casting;Cast temperature can be further determined that according to temperature when season and work or ambient air temperature;
4.2, start intermediate packet switch, trough casting mouth alignment mold mouth is cast magnesium alloy liquid pressure into mold, it is produced Gas released from mold gases riser, into centrifugal fan and enter aeration tower purification it is qualified after empty;
4.3, temperature with thermocouple is detected up to after 200 DEG C or less, opening sandbox, taking-up casting in 1/3 depths in casting sand box;
4.4, the outer sand of casting and coating are removed in sand removal;
4.5, the outer sand of casting is carefully removed;
4.6, it repairs, checks the outer casting flaw of casting, the protrusions such as pouring channel riser part removes, and cheats recess portion soldering mode Filling-in;Pay attention to scratching statue casting face when sand removal;
4.7, casting idiosome amendment clean out after, after being surface-treated, dry and be packed and stored.
The method of the present invention is that a kind of small fusing point of density is low for magnesium alloy, and the good light alloy of mobile performance is closed with magnesium Jin Dynasty is carved for copper alloy production technology product as production method is production, melted alloy, casting and the processing of casting of mold, most The magnesium alloy handicraft article of various beautiful colors is made in rear surface processing, light-weight, more cheap more than copper alloy of price, as work The lifting of skill product, especially extensive process product, transport are all very convenient, and exploitation magnesium alloy handicraft article has extensive market and plump Economic benefit.
Specific embodiment
Specific embodiments of the present invention are described in detail below.
The method of the present invention be select magnesium alloy iron, copper, nickel content qualification the preferable magnesium alloy of AZ91D intensity, addition must Magnesium alloy flux that must be qualified, is melting into magnesium alloy in resistance furnace or main frequency furnace, outside mold dip-coating have coating wax or can Hair property polystyrene is cast molding in the sand mo(u)ld of model, and sand removal and surface rust protection processing are carried out after cooling, magnesium alloy work is made Skill product statue.
Specific embodiment is as follows:
Embodiment 1
A kind of production method of magnesium alloy technique statue, includes the following steps:
(1) production of mold
1.1, the production of aluminum alloy mould, using the aluminum alloy mould for manually producing product.
1.2, the manufacture of investment pattern die injected in aluminum alloy mould in the molten state using wax, after cooled and solidified, beaten Aluminum alloy mould is opened, casting die is produced.
1.3, dip-coating is coated on investment pattern die.
1.4, it is the coating dehydration on investment pattern die, solidification, dry.
1.5, the mold made is placed in sandbox and is firmly installed, and load onto casting gate and riser, and fill sand.
2, the preparation of magnesium alloy fused mass
2.1, will prepare according to product consumption into furnace AZ91D magnesium alloy ingot.
2.2, the magnesium alloy flux for needing product fusion process, by the ratio of magnesium alloy ingot and magnesium alloy flux 100:10 Heat fusing in example addition melting pot, magnesium alloy flux will at least guarantee following composition (remaining group is divided into impurity etc.)
KCl 40%
MgCl2 40%
NaCl2 5%
BaCl2 10%
3, magnesium alloy melts
3.1, in melting pot magnesium alloy flux melts amount up to 75% or more when slowly add magnesium alloy ingot to be melted.It is melted to magnesium Alloy liquid-solid ratio is passed through argon gas when being 7:1 and is stirred, gas sampling to exhaust treatment system processing.
3.2, magnesium alloy fused mass amount containing Be is added after magnesium alloy ingot all melts in melting pot up to amount containing Be needed for 20PPM For 3.5% beryllium-aluminium alloy, all fusing is uniform.Start to cool down when melt temperature is up to 700 DEG C and settle, so as to melt and slag Separation is good.
4, the processing of casting die and casting
4.1, when magnesium alloy fused mass temperature is up to 700 DEG C, liquid magnesium alloy addition is preheated to 380 DEG C or more with magnesium alloy liquid pressure pump Tundish in, prepare casting.
4.2, start intermediate packet switch, trough casting mouth alignment die casting mouth is cast liquid magnesium alloy into mold Body, generated gas are put into from mold gases riser.It is emptied into centrifugal fan and after entering aeration tower purification qualification.
4.3, temperature with thermocouple is detected up to 200 DEG C or less opening sandboxes in 1/3 depths in casting sand box, taking-up casting.
4.4, sand and coating in casting are removed in sand removal.
4.5, the outer sand of casting (paying attention to protecting statue casting face when sand removal) is carefully removed.
4.6, it repairs, checks the outer casting flaw of casting, the protrusions such as pouring channel riser part removes, and cheats recess portion soldering Mode filling-in;Pay attention to scratching statue casting face when sand removal.
4.7, it after the amendment of casting green body cleans out, is surface-treated, processing method can spray varnish, coating, differential of the arc oxygen Change, makes the color that cast(ing) surface is beautiful in silver gray, golden yellow, bronze colour etc. in several ways, be packed and stored after drying.
Embodiment 2
A kind of production method of magnesium alloy technique statue, includes the following steps:
(1) production of mold
1.1, the production of aluminum alloy mould, using the aluminum alloy mould for manually producing product.
1.2, the manufacture of investment pattern die is added in aluminium-making mould using expandable polystyrene plastic grain, adds steaming Vapour heats the investment pattern die that polystyrene plastics is made.
1.3, the dip-coating paint on investment pattern die.
1.4, the coating drying and dehydration on mold.
1.5, the mold made is placed in sandbox and is firmly installed, and load onto casting gate and riser, and fill sand.
2, the preparation of magnesium alloy fused mass
2.1, will prepare according to product consumption into furnace AZ91D magnesium alloy ingot.
2.2, the magnesium alloy flux for needing product fusion process, by the ratio of magnesium alloy ingot and magnesium alloy flux 100:15 Heat fusing in example addition melting pot, magnesium alloy flux will at least guarantee following composition (remaining group is divided into impurity etc.)
KCl 40%
MgCl2 42%
NaCl2 5%
BaCl2 8%
3, magnesium alloy melts
3.1, in melting pot magnesium alloy flux melts amount up to 75% or more when slowly add magnesium alloy ingot to be melted.It is melted to magnesium Alloy liquid-solid ratio is passed through argon gas when being 6:1 and is stirred, gas sampling to exhaust treatment system processing.
3.2, it is added after magnesium alloy ingot all melts in melting pot with beryllium content in magnesium alloy amount and is for the amount containing beryllium of 20ppm 3.5% aluminium-beryllium alloy, all fusing reaction.Start to cool down when melt temperature is up to 710 DEG C and settle, so as to melt and slag point From good.
4, the processing of cast article and casting
4.1, when magnesium alloy fused mass temperature is up to 690 DEG C, liquid magnesium alloy addition is preheated to 380 DEG C or more with magnesium alloy liquid pressure pump Tundish in, prepare casting.
4.2, start intermediate packet switch, trough casting mouth alignment mold mouth is cast magnesium alloy liquid pressure into mold, institute The gas of generation is put into from mold gases riser.It is emptied into centrifugal fan and after entering aeration tower purification qualification.
4.3, temperature with thermocouple is detected up to 200 DEG C or less opening sandboxes in 1/3 depths in casting sand box, taking-up casting.
4.4, sand and coating in casting are removed in sand removal.
4.5, the outer sand of casting and coating are carefully removed, pays attention to protecting statue surface.
4.6, it repairs, checks the outer casting flaw of casting, the protrusions such as pouring channel riser part removes, and cheats recess portion soldering Mode filling-in;Pay attention to scratching statue casting face when sand removal.
4.7, it after the amendment of casting green body cleans out, is surface-treated, processing method can spray varnish, coating, differential of the arc oxygen Change, makes the color that cast(ing) surface is beautiful in silver gray, golden yellow, bronze colour etc. in several ways, be packed and stored after drying.
It should be pointed out that for the those skilled in the art of the art, without departing from the principle of the present invention, Several improvement and application can also be made, these are improved and application is also considered as protection scope of the present invention.

Claims (1)

1. a kind of production method of magnesium alloy technique statue, characterized by the following steps:
(1), the production of mold
1.1, the production of aluminum alloy mould, using the aluminum alloy mould for manually producing product;
1.2, the manufacture of fusible pattern using wax or can issue polystyrene resin and produce investment pattern die;
1.3, dip-coating paint on investment pattern die;
1.4, investment pattern die is dried;
1.5, the investment pattern die made is placed in sandbox and is firmly installed, and load onto casting gate and riser, and fill sand;
(2), the preparation of magnesium alloy fused mass
2.1, will prepare according to product consumption into furnace AZ91D magnesium alloy ingot;
2.2, the magnesium alloy flux for needing product fusion process is added to heat in melting pot and melt, magnesium alloy flux and magnesium alloy The ratio of ingot is 10 ~ 15:100, and magnesium alloy flux requires to guarantee following composition
KCl 40%
MgCl2 38~42%
NaCl2 5%
BaCl2 8~10%
(3), magnesium alloy melts
3.1, in melting pot magnesium alloy flux melts amount up to 75% or more when slowly add magnesium alloy ingot to be melted, be melted to magnesium Alloy liquid-solid ratio is passed through argon gas when being 6 ~ 7:1 and is stirred, gas sampling to exhaust treatment system processing;
3.2, required when Be content is 20ppm in magnesium alloy ingot melt contain is added after magnesium alloy ingot all melts in melting pot Beryllium-aluminium alloy that Be amount is 3.5%, all fusing reaction;Start to cool down when melt temperature is up to 700 ~ 710 DEG C and settle;
(4), the processing of casting die and casting
4.1, when magnesium alloy fused mass temperature is up to 690 ~ 700 DEG C, liquid magnesium alloy addition is preheated to 380 DEG C with magnesium alloy liquid pressure pump In above tundish, prepare casting;
4.2, start intermediate packet switch, trough casting mouth alignment mold mouth is cast magnesium alloy liquid pressure into mold, it is produced Gas released from mold gases riser, into centrifugal fan and enter aeration tower purification it is qualified after empty;
4.3, temperature with thermocouple is detected up to after 200 DEG C or less, opening sandbox, taking-up casting in 1/3 depths in casting sand box;
4.4, sand and coating in casting are removed in sand removal;
4.5, the outer sand of casting is carefully removed;
4.6, it repairs, checks the outer casting flaw of casting, protrusion part removes, and cheats recess portion soldering mode filling-in;
4.7, it after the amendment of casting idiosome cleans out, after being surface-treated, dries and is packed and stored.
CN201811047661.4A 2018-09-10 2018-09-10 The production method of magnesium alloy technique statue Pending CN109158541A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386946A (en) * 2008-10-31 2009-03-18 中国科学院上海微***与信息技术研究所 Magnesium alloy suitable for compression casting ultrathin wall member and preparation method
CN101658918A (en) * 2008-08-26 2010-03-03 白聿钦 Water glass type magnesium alloy fusible pattern casting process
CN101824570A (en) * 2010-01-01 2010-09-08 内蒙古五二特种材料工程技术研究中心 AZ series magnesium-beryllium rare earth alloy material and method for preparing same
CN102321859A (en) * 2011-08-31 2012-01-18 燕山大学 A kind of method of AZ91D cast magnesium alloy grains
CN103114259A (en) * 2013-02-25 2013-05-22 太原理工大学 Method for preparing heat-resisting magnesium alloy containing silicon, zirconium and beryllium
CN107855467A (en) * 2017-11-22 2018-03-30 扬州峰明光电新材料有限公司 The model casting system and investment casting method of U-shaped magnesium alloy member

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101658918A (en) * 2008-08-26 2010-03-03 白聿钦 Water glass type magnesium alloy fusible pattern casting process
CN101386946A (en) * 2008-10-31 2009-03-18 中国科学院上海微***与信息技术研究所 Magnesium alloy suitable for compression casting ultrathin wall member and preparation method
CN101824570A (en) * 2010-01-01 2010-09-08 内蒙古五二特种材料工程技术研究中心 AZ series magnesium-beryllium rare earth alloy material and method for preparing same
CN102321859A (en) * 2011-08-31 2012-01-18 燕山大学 A kind of method of AZ91D cast magnesium alloy grains
CN103114259A (en) * 2013-02-25 2013-05-22 太原理工大学 Method for preparing heat-resisting magnesium alloy containing silicon, zirconium and beryllium
CN107855467A (en) * 2017-11-22 2018-03-30 扬州峰明光电新材料有限公司 The model casting system and investment casting method of U-shaped magnesium alloy member

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘静安等: "《简明镁合金材料手册》", 31 August 2016, 北京:冶金工业出版社 *
陈果: "镁合金消失模—壳型复合铸造工艺研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 *

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Address after: 043800 Shanxi city in Yuncheng province Xin Village Wenxi County town of Ao Di

Applicant after: Shanxi Baosheng Yuanhua New Material Co., Ltd

Applicant after: Zhu Guangdong

Address before: 043800 Shanxi city in Yuncheng province Xin Village Wenxi County town of Ao Di

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Application publication date: 20190108