CN109137527A - A kind of material treatment agent - Google Patents
A kind of material treatment agent Download PDFInfo
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- CN109137527A CN109137527A CN201810665398.9A CN201810665398A CN109137527A CN 109137527 A CN109137527 A CN 109137527A CN 201810665398 A CN201810665398 A CN 201810665398A CN 109137527 A CN109137527 A CN 109137527A
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- treatment agent
- material treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention belongs to fabric softener technical field, in particular to a kind of material treatment agent.A kind of material treatment agent, including following parts by weight substance: 1~6 part of cotton wax, 6~12 parts of amido silicon oil, 0.2~0.5 part of odium stearate, 0.1~0.4 part of anticaking agent, 0.05~0.2 part of N- hydroxy thiosuccinimide, 60~80 parts of water.The present invention is compounded using many kinds of substance, can assign the good softness of fabric and feel, and have preferable permeability, washability and yellowing-resistant effect.
Description
Technical field
The invention belongs to fabric softener technical field, in particular to a kind of material treatment agent.
Background technique
Fabric softener can make fabric have the medicament of soft feeling after washing is dry.Mainly there are three classes, i.e. on-surface-active
The mixture of agent, surfactant and surfactant and non-surface-active agent.Currently used mainly surfactant
Class such as softening agent EST, softening agent M5-20, softening agent PEN etc..
Amino in amido silicon oil can react with fiber, so that silicone molecule be enable to be distributed quickly and securely
Form smooth film in fiber surface, reduce the frictional force between fiber, improve feel, due to amido silicon oil hydrophobic performance compared with
By force, cause treated fabric hydrophilic performance bad.
With the continuous improvement of living standards, fabric softener will continue to that, xanthochromia degree good to hydrophilicity be low and feel
Good direction is developed, and introducing segment is most effectively one of mode at this stage.CN102643436A discloses a kind of super soft
Hydrophilic block silicone oil midbody compound and preparation method, polysiloxanes, amino, polyethers tri-block polysiloxane
It is modified that alkylated cation has been carried out on the basis of polyether block copolymer, is introduced polyether segment, is knitted to reach and significantly improve
The effect of object hydrophilicity, and further improve under conditions of less amino content the polarity of product, adsorptivity and react
Property, but increasing with polyether segment, the ratio of silicon oxygen segment gradually decrease, and softness is caused to decline, and washing fastness compared with
Difference.
The characteristic feature of tri-block polyethers amino-modified silicone oil is on the main chain of organosiloxane simultaneously containing organic
Silicon segment, polyether segment, amido functional group, the molecular weight for adjusting each segment respectively can obtain the softening agent production of different style
Product, exactly this special structure determine it compared to original common amino-silicone oil softening agent, in storage and use process
With extraordinary stability, higher product clean absorption rate.But it in actual use, also shows after being processed
The problems such as smooth hand of fabric does not reach requirement, then domestic and international correlative study is centered around to tri-block polyethers amino
Modified silicon oil is modified again, and main method, which has, to be re-introduced into the compound that may react in the amino group of main chain and changed
Property, such as: 2,3- epoxypropyltrimethylchloride chlorides, epoxidized polyether, epoxychloropropane etc..By such methods, have big
The matured product of amount comes out.But pass through product obtained by these methods, however it remains to be processed rear fabric feeling smooth
Spend the undesirable phenomenons such as difference.
CN104530434B discloses a kind of organosilicon polymer and its synthetic method, passes through the amino-terminated side chain of leading-in end
Modified amido polysiloxanes or the modified chain alkyl polysiloxanes of Amino End Group capped pendant, obtain a kind of main chain with new construction
Modified block amido silicon oil is total to side chain.Due to containing more amino in the organosilicon polymer, in routine use, through light
It is easy to happen decomposition reaction according to, oxidation, causes to generate chromophore, so that fabric is generated xanthochromia, xanthochromia degree can be with ammonia value
Raising and increase.
Summary of the invention
The present invention to solve the above-mentioned problems, provides a kind of material treatment agent.
The present invention is realized using following technical scheme:
A kind of material treatment agent, including following parts by weight substance: 1~6 part of cotton wax, 6~12 parts of amido silicon oil, odium stearate
0.2~0.5 part, 0.1~0.4 part of anticaking agent, 0.05~0.2 part of N- hydroxy thiosuccinimide, 60~80 parts of water.
Preferably, the amido silicon oil is the compound for having following structure general formula:
In formula, the natural number that n is 45~100, R2 is polyether amine substance.
It is furthermore preferred that the R2 is the compound for having following structure general formula:
In formula, y=39, (x+z)=6.
Preferably, the amido silicon oil is the compound for having following structure general formula:
In formula, the natural number that n is 10~40, R2 is polyether amine substance.
It is furthermore preferred that the R2 is the compound for having following structure general formula:
In formula, y=9, (x+z)=4.
Preferably, with following weight accounting substance in the cotton wax: Qana bar ceryl alcohol 2~6%, amyrin 4~
6%, kappa acid rouge 4~10%.
The beneficial effects of the present invention are:
1, the present invention is compounded using many kinds of substance, can assign the good softness of fabric and feel, and have
There are preferable permeability, washability and yellowing-resistant effect.
2, after handling fabric using material treatment agent of the invention, when fabric is in dry state, polysiloxane chain
Section can provide good softness and feel in the relatively outer layer of fiber, on the contrary when being in moisture state, due to polyethers
Segment is more hydrophilic, then can be located at the outer layer of fiber, and polysiloxanes segment can then be located at inner layer, and such transformation can make clearly
Clean to become to be more easier, amino then plays the role of reinforcement and fabric binding ability, and silicone molecule is made securely to be adsorbed on fiber
Surface.
3, amido silicon oil end of the invention is respectively provided with two polyether segments, and the dispersion of amino part is relatively broad but accounts for
It is smaller, it can be distributed in fiber surface securely and form smooth film, reduce the frictional force between fiber, improve softening agent
To the adhesion effect of fabric, and yellowing-resistant ability is higher.
4, preferably, the degree of polymerization of polysiloxanes segment is only 10~40 in molecule of the present invention, polyethers ammonia is selected
ED600, for the degree of polymerization of polyether segment less than 20, the degree of polymerization of obtained fabric softener entirety is in a lower water
Flat, intermolecular and intramolecule is not susceptible to distortion, agglomerating phenomenon, improves the effect that polysiloxanes segment forms a film in fiber surface
Fruit increases the resilience and softness of fabric to significantly reduce the frictional force between fibre bundle.
5, preferably, the degree of polymerization of polysiloxanes segment is 45~100 in molecule of the present invention, polyethers ammonia is selected
ED2000, the degree of polymerization of polyether segment are 39, have preferable hydrophily and are not susceptible to agglomerating phenomenon, with cotton wax, tristearin
It is used after the substances such as sour sodium, N- hydroxy thiosuccinimide compounding, makes fabric that there is good softness and feel, and
With preferable permeability, washability and yellowing-resistant effect.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's all other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1
A kind of material treatment agent, including following parts by weight substance: 4 parts of cotton wax, 10 parts of amido silicon oil, 0.5 part of odium stearate,
0.1 part of white carbon black, 0.15 part of N- hydroxy thiosuccinimide, 70 parts of water.
The amido silicon oil is the compound for having following structure general formula:
In formula, n=96, the R2 is the compound for having following structure general formula:
In formula, y=39, (x+z)=6.
The amido silicon oil is made by the steps:
S1 will weigh 1000g D4,5.3g HMM closure agent and the 6g concentrated sulfuric acid and be added in reaction kettle, in nitrogen atmosphere, 40
After being stirred to react 16h under the conditions of DEG C, the Na of diameter 3mm is added2CO3Particle 9g filters crude product, subtracts after neutralizing 14h
Pressure distillation obtains end hydrogen-based silicone intermediates；
S2 weighs end hydrogen-based silicone intermediates 100g, vinylene carbonate 4.1g that step S1 is obtained and reaction is added
In kettle, the Karstedt catalyst of 5ppm is added after stirring in nitrogen atmosphere, 18h is reacted under the conditions of 75 DEG C, after vacuumizing
Obtain bis-epoxy terminated polysiloxane intermediate；
S3 weighs 100g bis-epoxy terminated polysiloxane intermediate, 20g ED2000 and 100g ethyl alcohol, 50g magnesium sulfate, stirs
18h is reacted after mixing uniformly under the conditions of nitrogen atmosphere, 70 DEG C, it is flaxen transparency liquid that Filtration Filtration, which obtains appearance,.It is described
Appearance is that flaxen transparency liquid meets following general structure:
In formula, n=96, in formula, y=39, (x+z)=6.
The D4 refers to that octamethylcy-clotetrasiloxane, HMM closure agent refer to tetramethyldihydrogendisiloxane.
Embodiment 2
A kind of material treatment agent, including following parts by weight substance: 3 parts of cotton wax, 6 parts of amido silicon oil, 0.2 part of odium stearate,
0.1 part of silica, 0.05 part of N- hydroxy thiosuccinimide, 70 parts of water.
The amido silicon oil is the compound for having following structure general formula:
In formula, n=48, the R2 is the compound for having following structure general formula:
In formula, y=39, (x+z)=6.
The amido silicon oil is made by the steps:
S1 will weigh 500g D4,5.2g HMM closure agent and the 6g concentrated sulfuric acid and be added in reaction kettle, in nitrogen atmosphere, 40 DEG C
Under the conditions of be stirred to react 16h after, be added diameter 3mm Na2CO3Particle 9g filters crude product after neutralizing 14h, depressurizes
Distillation obtains end hydrogen-based silicone intermediates；
S2 weighs end hydrogen-based silicone intermediates 100g, vinylene carbonate 4.1g that step S1 is obtained and reaction is added
In kettle, the Karstedt catalyst of 5ppm is added after stirring in nitrogen atmosphere, 18h is reacted under the conditions of 75 DEG C, after vacuumizing
Obtain bis-epoxy terminated polysiloxane intermediate；
S3 weighs 100g bis-epoxy terminated polysiloxane intermediate, 20g ED2000 and 100g ethyl alcohol, 50g magnesium sulfate, stirs
18h is reacted after mixing uniformly under the conditions of nitrogen atmosphere, 70 DEG C, it is flaxen transparency liquid that Filtration Filtration, which obtains appearance,.It is described
Appearance is that flaxen transparency liquid meets following general structure:
In formula, n=96, in formula, y=39, (x+z)=6.
The D4 refers to that octamethylcy-clotetrasiloxane, HMM closure agent refer to tetramethyldihydrogendisiloxane.
Embodiment 3
A kind of material treatment agent, including following parts by weight substance: 1 part of cotton wax, 12 parts of amido silicon oil, 0.3 part of odium stearate,
0.4 part of silica, 0.05 part of N- hydroxy thiosuccinimide, 80 parts of water.
The amido silicon oil is the compound for having following structure general formula:
In formula, n=39, the R2 is the compound for having following structure general formula:
In formula, y=9, (x+z)=4.
The amido silicon oil is made by the steps: a kind of material treatment agent, comprising the following steps:
S1 will weigh 100g D4,1.2g HMM closure agent and the 4g concentrated sulfuric acid and be added in reaction kettle, in nitrogen atmosphere, 70 DEG C
Under the conditions of be stirred to react 12h after, be added diameter 2mm Na2CO3Particle 6g filters crude product after neutralizing 10h, depressurizes
Distillation obtains end hydrogen-based silicone intermediates；
S2 weighs end hydrogen-based silicone intermediates 100g, vinylene carbonate 1.6g that step S1 is obtained and reaction is added
In kettle, the Karstedt catalyst of 15ppm is added after stirring in nitrogen atmosphere, 14h is reacted under the conditions of 70 DEG C, after vacuumizing
Obtain bis-epoxy terminated polysiloxane intermediate；
S3 weighs 100g bis-epoxy terminated polysiloxane intermediate, 20g ED600 and 120g isopropanol, 50g magnesium sulfate,
14h is reacted under the conditions of nitrogen atmosphere, 86 DEG C after mixing evenly, it is flaxen transparency liquid that appearance, which is obtained by filtration,.It is described outer
See is that flaxen transparency liquid meets following general structure:
In formula, n=39, in formula, y=9, (x+z)=4.
The D4 refers to that octamethylcy-clotetrasiloxane, HMM closure agent refer to tetramethyldihydrogendisiloxane.
Embodiment 4
A kind of material treatment agent, including following parts by weight substance: 6 parts of cotton wax, 8 parts of amido silicon oil, 0.4 part of odium stearate,
0.2 part of silica, 0.2 part of N- hydroxy thiosuccinimide, 60 parts of water.
The amido silicon oil is the compound for having following structure general formula:
In formula, the natural number that n is 48, the R2 is the compound for having following structure general formula:
In formula, y=39, (x+z)=6.
The amido silicon oil is made by the steps:
S1 will weigh 1000g D4,5.3g HMM closure agent and the 6g concentrated sulfuric acid and be added in reaction kettle, in nitrogen atmosphere, 40
After being stirred to react 16h under the conditions of DEG C, the Na of diameter 3mm is added2CO3Particle 9g filters crude product, subtracts after neutralizing 14h
Pressure distillation obtains end hydrogen-based silicone intermediates；
S2 weighs end hydrogen-based silicone intermediates 100g, vinylene carbonate 4.1g that step S1 is obtained and reaction is added
In kettle, the Karstedt catalyst of 5ppm is added after stirring in nitrogen atmosphere, 18h is reacted under the conditions of 75 DEG C, after vacuumizing
Obtain bis-epoxy terminated polysiloxane intermediate；
S3 weighs 100g bis-epoxy terminated polysiloxane intermediate, 20g ED2000 and 100g ethyl alcohol, 50g magnesium sulfate, stirs
18h is reacted after mixing uniformly under the conditions of nitrogen atmosphere, 70 DEG C, it is flaxen transparency liquid that Filtration Filtration, which obtains appearance,.It is described
Appearance is that flaxen transparency liquid meets following general structure:
In formula, n=96, in formula, y=39, (x+z)=6.
The D4 refers to that octamethylcy-clotetrasiloxane, HMM closure agent refer to tetramethyldihydrogendisiloxane.
Comparative example 1
A kind of material treatment agent, group grade separation side is same as Example 1, the difference is that not adding stearic acid
Sodium.
Comparative example 2
A kind of material treatment agent, group grade separation side is same as Example 1, the difference is that not adding odium stearate
And amido silicon oil.
To embodiment 1, embodiment 2, embodiment 3, embodiment 4, comparative example 1, the processed fabric of comparative example 2 and untreated
Fabric tested.Processing technological flow are as follows: fabric-pre-treatment-dyeing-soft finish-dehydration-drying.Processing temperature
Degree is 35 DEG C, and the processing time is 20min, and material treatment agent dosage is the 2% of fabric weight.
Test method is as follows:
Flexibility: being indicated with bending stiffness, pliability instrument measurement is carried out with OX-896A pliability tester, after testing 5 times
Take its average value.
Whiteness: whiteness is measured with WSD-3U fluorescent whiteness instrument, takes its average value after test 5 times.
Water imbibition: away from the drop water that vertically drips at fabric 5cm height, when the lower record fabric of static state fully absorbs used
Between, it tests 5 times and is averaged.
Breaking strength: being measured with YG026T strength tester for clothes, is averaged after test 5 times.
Measurement result is as follows:
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (6)
1. a kind of material treatment agent, which is characterized in that including following parts by weight substance: 1~6 part of cotton wax, amido silicon oil 6~12
Part, 0.2~0.5 part of odium stearate, 0.1~0.4 part of anticaking agent, 0.05~0.2 part of N- hydroxy thiosuccinimide, water 60~
80 parts.
2. a kind of material treatment agent as described in claim 1, which is characterized in that the amido silicon oil is to have following structure general formula
Compound:
In formula, the natural number that n is 45~100, R2 is polyether amine substance.
3. a kind of material treatment agent as claimed in claim 2, which is characterized in that the R2 is the chemical combination for having following structure general formula
Object:
In formula, y=39, (x+z)=6.
4. a kind of material treatment agent as described in claim 1, which is characterized in that the amido silicon oil is to have following structure general formula
Compound:
In formula, the natural number that n is 10~40, R2 is polyether amine substance.
5. a kind of material treatment agent as claimed in claim 4, which is characterized in that the R2 is the chemical combination for having following structure general formula
Object:
In formula, y=9, (x+z)=4.
6. a kind of material treatment agent as described in claim 1, which is characterized in that have following weight accounting object in the cotton wax
Matter: Qana bar ceryl alcohol 2~6%, amyrin 4~6%, kappa acid rouge 4~10%.
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| CN201810665398.9A CN109137527A (en) | 2018-06-26 | 2018-06-26 | A kind of material treatment agent |
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| CN201810665398.9A CN109137527A (en) | 2018-06-26 | 2018-06-26 | A kind of material treatment agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116063611A (en) * | 2022-12-29 | 2023-05-05 | 广东银洋环保新材料有限公司 | Washable denim coating emulsion and preparation method thereof |
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| CN106381699A (en) * | 2016-10-13 | 2017-02-08 | 无锡市华诚印染剂厂 | Anti-wrinkling antistatic fabric softener |
| CN107724086A (en) * | 2017-09-13 | 2018-02-23 | 江苏新瑞贝科技股份有限公司 | A kind of silicone softening agent and preparation method thereof |
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2018
- 2018-06-26 CN CN201810665398.9A patent/CN109137527A/en active Pending
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| CN101575801A (en) * | 2008-05-11 | 2009-11-11 | 刘曦 | Nanometer modified functional-type softener |
| CN102585251A (en) * | 2011-12-29 | 2012-07-18 | 陕西省石油化工研究设计院 | Method for preparing diamine polyether/ polydimethylsiloxane block silicon oil |
| CN106381699A (en) * | 2016-10-13 | 2017-02-08 | 无锡市华诚印染剂厂 | Anti-wrinkling antistatic fabric softener |
| CN107724086A (en) * | 2017-09-13 | 2018-02-23 | 江苏新瑞贝科技股份有限公司 | A kind of silicone softening agent and preparation method thereof |
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|---|
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| 周勇: "三元嵌段有机硅柔软剂的制备及其在纺织品上的应用", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
| 山下晋三等: "《交联剂手册》", 31 July 1990, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116063611A (en) * | 2022-12-29 | 2023-05-05 | 广东银洋环保新材料有限公司 | Washable denim coating emulsion and preparation method thereof |
| CN116063611B (en) * | 2022-12-29 | 2024-05-14 | 广东银洋环保新材料有限公司 | Washable denim coating emulsion and preparation method thereof |
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Application publication date: 20190104 |