CN109133718A - A kind of bi-component porcelain tendre adhesive glue - Google Patents
A kind of bi-component porcelain tendre adhesive glue Download PDFInfo
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- CN109133718A CN109133718A CN201811331881.XA CN201811331881A CN109133718A CN 109133718 A CN109133718 A CN 109133718A CN 201811331881 A CN201811331881 A CN 201811331881A CN 109133718 A CN109133718 A CN 109133718A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0885—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements specially adapted for being adhesively fixed to the wall; Fastening means therefor; Fixing by means of plastics materials hardening after application
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
- C04B2111/00646—Masonry mortars
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention belongs to chemical building material technical fields, specifically disclose a kind of bi-component porcelain tendre adhesive glue.Bi-component porcelain tendre adhesive glue of the invention is mainly made of component A and B component；The component A includes the raw material components of following parts by weight: 0.02-0.04 parts of defoaming agent, 0.2-0.5 parts of cellulose ether, 0.03-0.05 parts of organobentonite, 0.01-0.03 parts of silica gel, 0.1-0.3 parts of calcium formate, 50-65 parts of quartz sand and 25-35 parts of modified industry inorganic powder；The B component is acrylic emulsion；The modified industry inorganic powder includes the raw material components of following parts by weight: 15-25 parts of calcium carbonate, 5-8 parts of magnesium carbonate and 3-7 parts of kaolin.Adhesive glue of the invention has adhesion strength height, and anti-extension stream effect is good, and the strong feature of basal plane wide adaptability, anti-accumulation of salt in the surface soil ability effectively increases the firmness of porcelain tendre paving.
Description
[technical field]
The present invention relates to chemical building material technical fields, and in particular to a kind of bi-component porcelain tendre adhesive glue.
[background technique]
Modified soil is a kind of novel energy-saving low-carbon ornament materials, is used as decorative material for wall surface, is had light, flexible
Well, the features such as appearance and modeling multiplicity, good weatherability；It is used as floor decorative material, has the spies such as wear-resisting, anti-skidding, comfortable foot feeling
Point；And simple and quick construction, shorten than the traditional material institute work consuming phase, saving space, save the cost, and not easily to fall off, is applicable in
In building decorations such as exterior wall, interior wall, ground, especially suitable for skyscraper exterior finish engineering, facade decorative engineering, city
The anisotropic building such as city's reconstruction of the old city town exterior wall plane materiel, the finish coat of external insulation system and curved wall, arch column it is surface-veneer engineered.
And porcelain tendre, not real porcelain, it is exactly to be modified soil as primary raw material, with special temperature control moulding system
One kind made of molding, baking, cross-linking radiation has the new plane materiel of building decoration flexible.Since at the beginning of being born, it has porcelain tendre
Appearance, therefore be commonly called as porcelain tendre.Later, with the development of technology, imitation stone, leather texture imitation, imitation wood etc. can be developed to, it is all
It can imagine, porcelain tendre can all be realized.
And existing ceramic tile adhesive glue does not have the dedicated bonding of porcelain tendre mainly based on paving ceramic tile substantially at present
Agent.And due to porcelain tendre have with the characteristics such as the different soft deformable and back side of ceramics is smooth, using existing tile bonding
Agent carrys out paving porcelain tendre, is easy to appear the problems such as being pasted not strongly solid, the metope accumulation of salt in the surface soil, not only influences the aesthetic feeling of porcelain tendre paving, also have
Some potential safety problems.A kind of adhesion strength for there is provided it is an object of the invention to overcome disadvantages mentioned above is high, weatherability, resistance to old
It is strong to change performance, constructing operation is easy, the strong porcelain tendre adhesive glue of basal plane wide adaptability, anti-accumulation of salt in the surface soil ability.
[summary of the invention]
Goal of the invention of the invention is: in view of the above problems, providing a kind of bi-component porcelain tendre adhesive glue.This hair
Bright two-component porcelain tendre adhesive glue being collocated with each other by each component, mass action make adhesive glue have adhesion strength height,
Weatherability, ageing-resistant performance are strong, and anti-extension stream effect is good, and constructing operation is easy, the strong spy of basal plane wide adaptability, anti-accumulation of salt in the surface soil ability
Point effectively increases the firmness of porcelain tendre paving.
To achieve the goals above, The technical solution adopted by the invention is as follows:
A kind of bi-component porcelain tendre adhesive glue is mainly made of component A and B component by weight 4:1 mixing；The A
Component includes the raw material components of following parts by weight: 0.02-0.04 parts of defoaming agent, 0.2-0.5 parts of cellulose ether, organobentonite
0.03-0.05 parts, 0.01-0.03 parts of silica gel, 0.1-0.3 parts of calcium formate, 50-65 parts of quartz sand and modified industry inorganic powder 25-
35 parts；The B component is acrylic emulsion；The modified industry inorganic powder includes the raw material components of following parts by weight: calcium carbonate
15-25 parts, 5-8 parts of magnesium carbonate and 3-7 parts of kaolin；
The modified industry inorganic powder is prepared by following methods: by weight, weighing 10-15 parts of calcium carbonate, carbon
Sour magnesium 5-8 parts and kaolin 3-7 parts, weighed calcium carbonate, magnesium carbonate and kaolin were crushed to 150 meshes respectively；It will
After smashed calcium carbonate and magnesium carbonate mixing, deionized water is added and is mixed evenly, obtains the slurry that mass concentration is 20-25%
Liquid is added silane coupling agent aqueous solution, keeps the temperature and stir under the pressure of 1-3MPa by the slurries heating stirring to after 85-90 DEG C
Mix 25-30min；Then it is added after smashed kaolin is stirred until homogeneous, continues pressure-maintaining and heat-preservation and stir 25-30min；Finally will
Slurries, which are put into disintegrating machine, grinds 30-40min, then is placed in 110-120 DEG C of drying and crosses 200 meshes to get the modified industry
Inorganic powder.
Further, the component A includes the raw material components of following parts by weight: 0.03 part of defoaming agent, cellulose ether 0.3
Part, 0.04 part of organobentonite, 0.02 part of silica gel, 0.2 part of calcium formate, 58 parts of quartz sand and 29 parts of modified industry inorganic powder；Institute
Stating B component is styrene-acrylic emulsion；The modified industry inorganic powder includes the raw material components of following parts by weight: 22 parts of calcium carbonate, carbonic acid
6 parts and 4 parts of kaolin of magnesium.
Further, the modified industry inorganic powder is prepared by following methods: by weight, weighing calcium carbonate 22
Part, 6 parts of magnesium carbonate and 4 parts of kaolin, were crushed to 150 meshes for weighed calcium carbonate, magnesium carbonate and kaolin respectively；It will
After smashed calcium carbonate and magnesium carbonate mixing, deionized water is added and is mixed evenly, obtains the slurries that mass concentration is 22%,
By the slurries heating stirring to after 87 DEG C, silane coupling agent aqueous solution, the insulated and stirred 28min under the pressure of 2MPa is added；
Then it is added after smashed kaolin is stirred until homogeneous, continues pressure-maintaining and heat-preservation and stir 28min；Slurries are finally put into disintegrating machine
Middle grinding 35min, then be placed in 115 DEG C of dryings and cross 200 meshes to get the modified industry inorganic powder.
Further, the mass concentration of the silane coupling agent aqueous solution is 1%, and the silane coupling agent aqueous solution adds
Dosage is the 50-55% of the weight of calcium carbonate.
Further, the partial size of the quartz sand is 80-120 mesh, and the viscosity of the cellulose ether is 100000mPas.
Further, the application method of the porcelain tendre adhesive glue are as follows: by weight 4:1, B component is first added to the water mixing
Afterwards, component A is added, 5min is stood, then stirs 10-20min, that is, can be used.
In conclusion by adopting the above-described technical solution, the beneficial effects of the present invention are:
(1) it sees on the whole, adhesive glue of the invention is made of compound the collocation of organic material and inorganic material
Bonded adhesives, organic material is in conjunction with inorganic material, so that the adhesive glue can make the metope of flexible finish coat porcelain tendre and rigid base
The cohesive forces such as floor are strong, and porcelain tendre adhesion-tight after paving will not fall off.Meanwhile each combination of raw materials collocation is so that this porcelain tendre
Adhesive glue is in alkalescent, itself has a strong anti-accumulation of salt in the surface soil ability, thus relative to organic glue, adhesive glue of the present invention it is resistance to old
Change performance and weatherability significantly improves, service life is obviously prolonged.In addition, adhesive glue scene of the present invention adds water allotment stirring
It uses, constructing operation is easy, and can be used in the basal plane of most of materials, and applicability is wide, although and most of adhesive glues have
The bond properties having had, but application method is complicated, it is unfavorable to construct immediately on site, such as Chinese patent CN106010388B.
(2) from the specific collocation of raw material, the defoaming agent in component A is for eliminating foam, reducing surface tension；Fiber
Plain ether, organobentonite, silica gel, calcium formate and the collocation of modified industry inorganic powder, synergistic effect not only have adhesive glue
Cohesive force, and the anti-extension fluidity having had.
(3) from modified industry inorganic powder, modified industry inorganic powder of the invention is by calcium carbonate, magnesium carbonate and kaolin
Collocation is made by a series of modifications, effectively enhances the structure-activity of inorganic powder so that its preferably with remaining component
Mixing, to effectively enhance the performance of adhesive glue.Wherein, first the small-pitch calcium carbonate of molecular layer and magnesium carbonate are mixed and idol
Joining agent processing, to carry out meromict modified, effectively enhances the surface-active of calcium carbonate and magnesium carbonate, add molecule interlamellar spacing compared with
Big kaolin continues to be modified, and effectively increases the degree of adhesion between three, so that it is multiple to have obtained the excellent stratiform of tensile strength
Close powder；Further, pressurized treatments further improve the interaction force between calcium carbonate, magnesium carbonate and kaolin, make
Its connection is more firm.
[specific embodiment]
Below in conjunction with specific embodiment, the present invention is further illustrated.
Embodiment 1
A kind of bi-component porcelain tendre adhesive glue is mainly made of component A and B component by weight 4:1 mixing；The A
Component includes the raw material components of following parts by weight: 0.02 part of defoaming agent, 0.2 part of cellulose ether (viscosity 100000mPas),
0.03 part of organobentonite, 0.01 part of silica gel, 0.1 part of calcium formate, 50 parts of quartz sand (partial size is 80 mesh) and modified industry are inorganic
25 parts of powder；By weight, it weighs above-mentioned raw materials component and is uniformly mixed to get the component A；The B component is phenylpropyl alcohol cream
Liquid；The modified industry inorganic powder includes the raw material components of following parts by weight: 15 parts of calcium carbonate, 5 parts of magnesium carbonate and kaolin 3
Part；
The modified industry inorganic powder is prepared by following methods: by weight, weighing 10 parts of calcium carbonate, magnesium carbonate
5 parts and 3 parts of kaolin, weighed calcium carbonate, magnesium carbonate and kaolin were crushed to 150 meshes respectively；It will be smashed
After calcium carbonate and magnesium carbonate mixing, deionized water is added and is mixed evenly, the slurries that mass concentration is 20% is obtained, by the slurry
The silane coupling agent water that weight is the weight of calcium carbonate 50% and mass concentration is 1% is added to after 85 DEG C in liquid heating stirring
Solution, the insulated and stirred 25min under the pressure of 1MPa；Then it is added after smashed kaolin is stirred until homogeneous, continues pressure maintaining
Insulated and stirred 25min；Finally slurries are put into disintegrating machine and grind 30min, then be placed in 110 DEG C of dryings and cross 200 meshes to get
The modified industry inorganic powder.
Application method of the above-mentioned two-component porcelain tendre adhesive in construction are as follows:
(1) base treatment: to paving base need it is smooth, and without it is floating ash, without greasy dirt；
(2) adhesive glue is deployed: by weight 4:1, first B group is confusingly added to the water, component A is then added and is stirred,
After standing 5min to component itself curing, it is stirred for 10min；
(3) laying method: deployed adhesive glue is equably applied to the porcelain tendre back side, with a thickness of 3mm or so, then directly
It connects and is pasted onto base, be compacted.
Embodiment 2
A kind of bi-component porcelain tendre adhesive glue is mainly made of component A and B component by weight 4:1 mixing；The A
Component includes the raw material components of following parts by weight: 0.03 part of defoaming agent, 0.3 part of cellulose ether (viscosity 100000mPas),
0.04 part of organobentonite, 0.02 part of silica gel, 0.2 part of calcium formate, 58 parts of quartz sand (partial size is 100 mesh) and modified industry are inorganic
29 parts of powder；By weight, it weighs above-mentioned raw materials component and is uniformly mixed to get the component A；The B component is phenylpropyl alcohol cream
Liquid；The modified industry inorganic powder includes the raw material components of following parts by weight: 22 parts of calcium carbonate, 6 parts of magnesium carbonate and kaolin 4
Part；
The modified industry inorganic powder is prepared by following methods: by weight, weighing 22 parts of calcium carbonate, magnesium carbonate
6 parts and 4 parts of kaolin, weighed calcium carbonate, magnesium carbonate and kaolin were crushed to 150 meshes respectively；It will be smashed
After calcium carbonate and magnesium carbonate mixing, deionized water is added and is mixed evenly, the slurries that mass concentration is 22% is obtained, by the slurry
Silane coupling agent aqueous solution, the insulated and stirred 28min under the pressure of 2MPa is added to after 87 DEG C in liquid heating stirring；Then it is added
After smashed kaolin is stirred until homogeneous, continues pressure-maintaining and heat-preservation and stir 28min；Finally slurries are put into disintegrating machine and are ground
35min, then be placed in 115 DEG C of dryings and cross 200 meshes to get the modified industry inorganic powder.
Application method of the above-mentioned two-component porcelain tendre adhesive in construction are as follows:
(1) base treatment: to paving base need it is smooth, and without it is floating ash, without greasy dirt；
(2) adhesive glue is deployed: by weight 4:1, first B group is confusingly added to the water, component A is then added and is stirred,
After standing 5min to component itself curing, it is stirred for 12min；
(3) laying method: deployed adhesive glue is equably applied to the porcelain tendre back side, with a thickness of 3mm or so, then directly
It connects and is pasted onto base, be compacted.
Embodiment 3
A kind of bi-component porcelain tendre adhesive glue is mainly made of component A and B component by weight 4:1 mixing；The A
Component includes the raw material components of following parts by weight: 0.04 part of defoaming agent, 0.5 part of cellulose ether (viscosity 100000mPas),
0.05 part of organobentonite, 0.03 part of silica gel, 0.3 part of calcium formate, 65 parts of quartz sand (partial size is 120 mesh) and modified industry are inorganic
35 parts of powder；By weight, it weighs above-mentioned raw materials component and is uniformly mixed to get the component A；The B component is phenylpropyl alcohol cream
Liquid；The modified industry inorganic powder includes the raw material components of following parts by weight: 25 parts of calcium carbonate, 8 parts of magnesium carbonate and kaolin 7
Part；
The modified industry inorganic powder is prepared by following methods: by weight, weighing 15 parts of calcium carbonate, magnesium carbonate
8 parts and 7 parts of kaolin, weighed calcium carbonate, magnesium carbonate and kaolin were crushed to 150 meshes respectively；It will be smashed
After calcium carbonate and magnesium carbonate mixing, deionized water is added and is mixed evenly, the slurries that mass concentration is 25% is obtained, by the slurry
The silane coupling agent water that weight is the weight of calcium carbonate 55% and mass concentration is 1% is added to after 90 DEG C in liquid heating stirring
Solution, the insulated and stirred 30min under the pressure of 3MPa；Then it is added after smashed kaolin is stirred until homogeneous, continues pressure maintaining
Insulated and stirred 30min；Finally slurries are put into disintegrating machine and grind 40min, then be placed in 120 DEG C of dryings and cross 200 meshes to get
The modified industry inorganic powder.
Application method of the above-mentioned two-component porcelain tendre adhesive in construction are as follows:
(1) base treatment: to paving base need it is smooth, and without it is floating ash, without greasy dirt；
(2) adhesive glue is deployed: by weight 4:1, first B group is confusingly added to the water, component A is then added and is stirred,
After standing 5min to component itself curing, it is stirred for 15min；
(3) laying method: deployed adhesive glue is equably applied to the porcelain tendre back side, with a thickness of 3mm or so, then directly
It connects and is pasted onto base, be compacted.
Compliance test result:
1, verifying one: impact effect of each raw material of component A to adhesive glue
Experimental group: the porcelain tendre adhesive glue of the embodiment of the present invention 1；
Control group 1: the adhesive glue slightly different from the porcelain tendre adhesive glue of the embodiment of the present invention 1, the difference is that: component A
In only do not contain cellulose ether；
Control group 2: the adhesive glue slightly different from the porcelain tendre adhesive glue of the embodiment of the present invention 1, the difference is that: component A
In only do not contain organobentonite；
Control group 3: the adhesive glue slightly different from the porcelain tendre adhesive glue of the embodiment of the present invention 1, the difference is that: component A
In only do not contain silica gel；
Control group 4: the adhesive glue slightly different from the porcelain tendre adhesive glue of the embodiment of the present invention 1, the difference is that: component A
In only do not contain calcium formate；
Control group 5: the adhesive glue slightly different from the porcelain tendre adhesive glue of the embodiment of the present invention 1, the difference is that: component A
In only do not contain modified industry inorganic powder.
Test and anti-extension are carried out to above-mentioned each group adhesive glue according to JC/T547-2005 " ceramic wall and floor bricks binder " standard
Fluidity test (amount of water is the 30% of adhesive glue total weight), test result is shown in Tables 1 and 2 respectively:
The bond properties of 1 each group adhesive glue of table is tested
As shown in Table 1, the adhesive glue tensile strength of experimental group, every tensile strength and alkali burnout resistance are optimal, and right
There is different degrees of decrease according to the adhesive glue properties of group 1-5, illustrates exist between each component of adhesive glue of the present invention
Interaction, each component interaction, can effectively promote the adhesive property of adhesive glue.
The anti-extension stream performance test of 2 each group adhesive glue of table
| Group | Experimental group | Control group 1 | Control group 2 | Control group 3 | Control group 4 | Control group 5 |
| It slides (mm) | 0.1 | 28.3 | 41.4 | 14.5 | 44.4 | 61.7 |
As shown in Table 2, the skidding distance of the adhesive glue of experimental group is most short, and the skidding distance of the adhesive glue of control group 1-5
There is different degrees of extension, illustrate there is interaction between each component of adhesive glue of the present invention, each component interaction can
Effectively promote the anti-extension fluidity energy of adhesive glue.
2. verifying two: the influence of each ingredient of the organic powder of modified industry and specific preparation method to adhesive property
Experimental group: the porcelain tendre adhesive glue of the embodiment of the present invention 1；
Control group 1: the adhesive glue slightly different from the porcelain tendre adhesive glue of the embodiment of the present invention 1, the difference is that: it is used
The organic powder of modified industry only not calcium carbonate, remaining is all the same with the organic powder of modified industry of embodiment 1；
Control group 2: the adhesive glue slightly different from the porcelain tendre adhesive glue of the embodiment of the present invention 1, the difference is that: it is used
The organic powder of modified industry is free of magnesium carbonate, remaining is all the same with the organic powder of modified industry of embodiment 1；
Control group 3: the adhesive glue slightly different from the porcelain tendre adhesive glue of the embodiment of the present invention 1, the difference is that: it is used
The organic powder of modified industry is free of kaolin, remaining is all the same with the organic powder of modified industry of embodiment 1；；
Control group 4: the adhesive glue slightly different from the porcelain tendre adhesive glue of the embodiment of the present invention 1, the difference is that: it is used
The organic powder of modified industry is prepared under normal pressure, remaining is all the same with the organic powder of modified industry of embodiment 1.
Above-mentioned each group adhesive glue is tested according to JC/T547-2005 " ceramic wall and floor bricks binder " standard, is as a result seen
Table 3:
The adhesive property of 3 each group adhesive glue of table is tested
As shown in Table 3, the adhesive glue tensile strength of experimental group, every tensile strength and alkali burnout resistance are optimal, and right
There is different degrees of decrease according to the adhesive glue properties of group 1-5, illustrates that the organic powder of adhesive glue modified industry of the present invention is each
There is interaction between component, each component interaction can effectively promote the adhesive property of adhesive glue.
It was proved that the adhesive glue of the embodiment of the present invention 2 and 3 is with identical as the adhesive glue of the embodiment of the present invention 1
Performance, i will not repeat them here.
Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair
Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to
In the covered the scope of the patents of the present invention.
Claims (6)
1. a kind of bi-component porcelain tendre adhesive glue, which is characterized in that be mainly mixed and made by weight 4:1 by component A and B component
At；The component A includes the raw material components of following parts by weight: 0.02-0.04 parts of defoaming agent, 0.2-0.5 parts of cellulose ether, organic
0.03-0.05 parts of bentonite, 0.01-0.03 parts of silica gel, 0.1-0.3 parts of calcium formate, 50-65 parts of quartz sand and modified industry are inorganic
25-35 parts of powder；The B component is acrylic emulsion；The modified industry inorganic powder includes the raw material components of following parts by weight: carbon
Sour calcium 15-25 parts, 5-8 parts of magnesium carbonate and 3-7 parts of kaolin；
The modified industry inorganic powder is prepared by following methods: by weight, weighing 10-15 parts of calcium carbonate, magnesium carbonate
5-8 parts and kaolin 3-7 parts, weighed calcium carbonate, magnesium carbonate and kaolin were crushed to 150 meshes respectively；It will crush
After calcium carbonate and magnesium carbonate afterwards mixes, deionized water is added and is mixed evenly, obtains the slurries that mass concentration is 20-25%,
By the slurries heating stirring to after 85-90 DEG C, silane coupling agent aqueous solution, the insulated and stirred under the pressure of 1-3MPa is added
25-30min；Then it is added after smashed kaolin is stirred until homogeneous, continues pressure-maintaining and heat-preservation and stir 25-30min；It finally will slurry
Liquid, which is put into disintegrating machine, grinds 30-40min, then be placed in 110-120 DEG C of drying and cross 200 meshes to get the modified industry without
Machine powder.
2. a kind of bi-component porcelain tendre adhesive glue according to claim 1, which is characterized in that the component A includes following weight
The raw material components of part: 0.03 part of defoaming agent, 0.3 part of cellulose ether, 0.04 part of organobentonite, 0.02 part of silica gel, calcium formate 0.2
Part, 58 parts of quartz sand and 29 parts of modified industry inorganic powder；The B component is styrene-acrylic emulsion；The modified industry inorganic powder includes
The raw material components of following parts by weight: 22 parts of calcium carbonate, 6 parts of magnesium carbonate and 4 parts of kaolin.
3. a kind of bi-component porcelain tendre adhesive glue according to claim 2, which is characterized in that the modified industry inorganic powder by with
Lower section method is prepared: by weight, 22 parts of calcium carbonate, 6 parts of magnesium carbonate and 4 parts of kaolin is weighed, by weighed carbonic acid
Calcium, magnesium carbonate and kaolin were crushed to 150 meshes respectively；After smashed calcium carbonate and magnesium carbonate are mixed, addition go from
Sub- water is mixed evenly, and obtains the slurries that mass concentration is 22%, and by the slurries heating stirring to after 87 DEG C, it is even that silane is added
Join agent aqueous solution, the insulated and stirred 28min under the pressure of 2MPa；Then it is added after smashed kaolin is stirred until homogeneous, after
Continuation of insurance pressure insulated and stirred 28min；Finally slurries are put into disintegrating machine and grind 35min, then is placed in 115 DEG C of dryings and crosses 200 mesh
Sieve is to get the modified industry inorganic powder.
4. a kind of bi-component porcelain tendre adhesive glue according to claim 3, which is characterized in that the silane coupling agent aqueous solution
Mass concentration is 1%, and the additive amount of the silane coupling agent aqueous solution is the 50-55% of the weight of calcium carbonate.
5. a kind of bi-component porcelain tendre adhesive glue according to claim 2, which is characterized in that the partial size of the quartz sand is 80-
120 mesh, the viscosity of the cellulose ether are 100000mPas.
6. a kind of bi-component porcelain tendre adhesive glue described in -5 any one according to claim 1, which is characterized in that the porcelain tendre bonding
The application method of glue are as follows: by weight 4:1, after B component is first added to the water mixing, add component A, stand 5min, then
10-20min is stirred, that is, can be used.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811331881.XA CN109133718B (en) | 2018-11-09 | 2018-11-09 | Bi-component soft porcelain adhesive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811331881.XA CN109133718B (en) | 2018-11-09 | 2018-11-09 | Bi-component soft porcelain adhesive |
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| CN109133718A true CN109133718A (en) | 2019-01-04 |
| CN109133718B CN109133718B (en) | 2020-05-12 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113651555A (en) * | 2021-09-26 | 2021-11-16 | 广西柔石新型建材有限公司 | Special adhesive for modified inorganic powder composite building decorative surface sheet |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2497558A (en) * | 2011-12-14 | 2013-06-19 | Bostik Ltd | Tile adhesive |
| CN105777040A (en) * | 2016-04-01 | 2016-07-20 | 重庆市胡特建材有限公司 | Novel ceramic tile adhesive and preparation method thereof |
| CN106010414A (en) * | 2016-06-30 | 2016-10-12 | 杭州福斯特光伏材料股份有限公司 | High-cohesiveness fluorocarbon coating and application |
| CN108358548A (en) * | 2018-02-13 | 2018-08-03 | 贵州皓科新型材料有限公司 | Porcelain tendre special bonding agent |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2497558A (en) * | 2011-12-14 | 2013-06-19 | Bostik Ltd | Tile adhesive |
| CN105777040A (en) * | 2016-04-01 | 2016-07-20 | 重庆市胡特建材有限公司 | Novel ceramic tile adhesive and preparation method thereof |
| CN106010414A (en) * | 2016-06-30 | 2016-10-12 | 杭州福斯特光伏材料股份有限公司 | High-cohesiveness fluorocarbon coating and application |
| CN108358548A (en) * | 2018-02-13 | 2018-08-03 | 贵州皓科新型材料有限公司 | Porcelain tendre special bonding agent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113651555A (en) * | 2021-09-26 | 2021-11-16 | 广西柔石新型建材有限公司 | Special adhesive for modified inorganic powder composite building decorative surface sheet |
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|---|---|
| CN109133718B (en) | 2020-05-12 |
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