CN109126716A - 一种对水中阿特拉津的吸附和催化降解方法 - Google Patents
一种对水中阿特拉津的吸附和催化降解方法 Download PDFInfo
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- CN109126716A CN109126716A CN201811198701.5A CN201811198701A CN109126716A CN 109126716 A CN109126716 A CN 109126716A CN 201811198701 A CN201811198701 A CN 201811198701A CN 109126716 A CN109126716 A CN 109126716A
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- atrazine
- moso bamboo
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- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 230000015556 catabolic process Effects 0.000 title claims abstract description 20
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 20
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 20
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 16
- 239000011572 manganese Substances 0.000 claims abstract description 54
- 244000302661 Phyllostachys pubescens Species 0.000 claims abstract description 45
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- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 14
- 238000001179 sorption measurement Methods 0.000 claims abstract description 10
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims abstract description 9
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims abstract description 5
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims abstract description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 5
- 229940099607 manganese chloride Drugs 0.000 claims abstract description 5
- 235000002867 manganese chloride Nutrition 0.000 claims abstract description 5
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- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 238000005374 membrane filtration Methods 0.000 claims description 7
- 229910021642 ultra pure water Inorganic materials 0.000 claims description 6
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- 238000001035 drying Methods 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000012046 mixed solvent Substances 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 51
- 239000000047 product Substances 0.000 description 16
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- 239000002689 soil Substances 0.000 description 7
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 229910002551 Fe-Mn Inorganic materials 0.000 description 5
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
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- 235000010344 sodium nitrate Nutrition 0.000 description 3
- 239000004317 sodium nitrate Substances 0.000 description 3
- 230000004913 activation Effects 0.000 description 2
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- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- -1 hydroxyl radical free radical Chemical class 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
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- 241000132931 Batrachia Species 0.000 description 1
- 208000037088 Chromosome Breakage Diseases 0.000 description 1
- 229910000616 Ferromanganese Inorganic materials 0.000 description 1
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 1
- 210000003484 anatomy Anatomy 0.000 description 1
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- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000003621 irrigation water Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
- 238000005297 material degradation process Methods 0.000 description 1
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- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/306—Pesticides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/36—Organic compounds containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
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Priority Applications (1)
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CN201811198701.5A CN109126716B (zh) | 2018-10-15 | 2018-10-15 | 一种对水中阿特拉津的吸附和催化降解方法 |
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CN201811198701.5A CN109126716B (zh) | 2018-10-15 | 2018-10-15 | 一种对水中阿特拉津的吸附和催化降解方法 |
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CN109126716A true CN109126716A (zh) | 2019-01-04 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110368900A (zh) * | 2019-08-20 | 2019-10-25 | 厦门理工学院 | 一种竹炭改性材料及其制备方法和用途 |
CN113019317A (zh) * | 2021-01-20 | 2021-06-25 | 桂林理工大学 | 一种负载双金属的活性炭高性能吸附剂及其制备方法和应用 |
CN113769756A (zh) * | 2021-08-05 | 2021-12-10 | 宁波神筹环保设备有限公司 | 一种新型铁锰氧化物催化剂及其应用 |
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US20100155335A1 (en) * | 2008-12-18 | 2010-06-24 | Ut-Battelle, Llc | Magnetic filtration process, magnetic filtering material, and methods of forming magnetic filtering material |
CN102020350A (zh) * | 2011-01-04 | 2011-04-20 | 华中师范大学 | 一种异相催化过硫酸盐芬顿氧化水处理方法 |
CN102895957A (zh) * | 2012-11-11 | 2013-01-30 | 桂林理工大学 | 一种毛竹遗态Fe2O3/Fe3O4复合重金属吸附剂的制备方法 |
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CN103864169A (zh) * | 2014-03-27 | 2014-06-18 | 广东省农业科学院农业资源与环境研究所 | 一种利用生物炭去除污水中除草剂的方法 |
CN105084512A (zh) * | 2015-08-12 | 2015-11-25 | 华中师范大学 | 利用堆肥产物合成的生物炭促进Fe(III)/H2O2体系修复有机物污染水体的方法 |
CN107082483A (zh) * | 2017-05-02 | 2017-08-22 | 四川大学 | 一种利用过硫酸盐及碳系纳米材料去除水中污染物的方法 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110368900A (zh) * | 2019-08-20 | 2019-10-25 | 厦门理工学院 | 一种竹炭改性材料及其制备方法和用途 |
CN113019317A (zh) * | 2021-01-20 | 2021-06-25 | 桂林理工大学 | 一种负载双金属的活性炭高性能吸附剂及其制备方法和应用 |
CN113769756A (zh) * | 2021-08-05 | 2021-12-10 | 宁波神筹环保设备有限公司 | 一种新型铁锰氧化物催化剂及其应用 |
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Application publication date: 20190104 Assignee: Guangxi Huayuan Environmental Protection Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044226 Denomination of invention: A Method for Adsorption and Catalytic Degradation of Atrazine in Water Granted publication date: 20210525 License type: Common License Record date: 20231023 Application publication date: 20190104 Assignee: Guangxi Borui Engineering Management Consulting Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044225 Denomination of invention: A Method for Adsorption and Catalytic Degradation of Atrazine in Water Granted publication date: 20210525 License type: Common License Record date: 20231023 Application publication date: 20190104 Assignee: Guangxi Borui Engineering Management Consulting Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044176 Denomination of invention: A Method for Adsorption and Catalytic Degradation of Atrazine in Water Granted publication date: 20210525 License type: Common License Record date: 20231024 Application publication date: 20190104 Assignee: Guangxi Huayuan Environmental Protection Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044168 Denomination of invention: A Method for Adsorption and Catalytic Degradation of Atrazine in Water Granted publication date: 20210525 License type: Common License Record date: 20231024 |
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Application publication date: 20190104 Assignee: Guangxi Guilin Xinda Guigong environmental science and Technology Center (L.P.) Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980045276 Denomination of invention: A Method for Adsorption and Catalytic Degradation of Atrazine in Water Granted publication date: 20210525 License type: Common License Record date: 20231102 |