CN109126180A - A kind of system and its workflow that organic matter recycles - Google Patents

A kind of system and its workflow that organic matter recycles Download PDF

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Publication number
CN109126180A
CN109126180A CN201811142642.XA CN201811142642A CN109126180A CN 109126180 A CN109126180 A CN 109126180A CN 201811142642 A CN201811142642 A CN 201811142642A CN 109126180 A CN109126180 A CN 109126180A
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Prior art keywords
condenser
gas
recycling
organic matter
level
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CN201811142642.XA
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Chinese (zh)
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郭锐
王俊
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Shanghai Jun Gang Environmental Protection Technology Co Ltd
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Shanghai Jun Gang Environmental Protection Technology Co Ltd
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Priority to CN201811142642.XA priority Critical patent/CN109126180A/en
Publication of CN109126180A publication Critical patent/CN109126180A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • B01D2257/7027Aromatic hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/704Solvents not covered by groups B01D2257/702 - B01D2257/7027
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

The invention discloses systems and its workflow that a kind of organic matter recycles, including condenser, super purifier, recycling can, circulation and condensation unit, the condenser includes first-stage condenser, secondary condenser and three-level condenser, first-stage condenser respectively with secondary condenser, recycling can is connected with organic gas air inlet pipe, secondary condenser is connected with three-level condenser and recycling can respectively, three-level condenser is connected with recycling can, three-level condenser also passes through recycle feed valve and is connected with secondary condenser, secondary condenser is connected by circulation outlet valve with super purifier, super purifier is connected with air cooler, air cooler is connected with tail gas discharging pipe, condensation unit is connected with the both ends of three-level condenser, circulation is connected with the both ends of first-stage condenser.This product has universality, can be used for the repository of oil tank memory block, liquid state organics, the especially recycling containing the aromatic hydrocarbons organic exhaust gas such as gasoline, diesel oil and benzene, toluene.

Description

A kind of system and its workflow that organic matter recycles
Technical field
The present invention relates to exhaust-gas resource and field of environmental technology, the system of specifically a kind of organic matter recycling.
Background technique
Petroleum, one of main object of geological prospecting are a kind of sticky, dark brown liquid, referred to as " industrial blood Liquid ".There are petroleum storage in upper crustal some areas, and main component is the mixture of various alkane, cycloalkane, aromatic hydrocarbon.Petroleum It is mainly used as fuel oil and gasoline, fuel oil and gasoline are in one of the most important secondary energy sources in the world of composition in 2012.Petroleum It is also the raw material of many chemical industries such as solvent, chemical fertilizer, insecticide and plastics etc..
Petroleum is mostly buried in underground or seabed, and people need to go to exploitation oil field to obtain petroleum, along with petroleum Exploitation, refining, storage and transport process, liquid organic component can generate a large amount of volatile organic gases in processing and storing process, Such as the evaporating loss of oil product of gasoline, the volatilization of the aromatic hydrocarbons organic matter such as benzene, toluene.These gaseous organic substances generally have certain poison Property and it is flammable and explosive, in turn result in that the wasting of resources, economic loss, environment is dirty so, it is a series of to influence human health and safety etc. Harm.
The recovery method of common at present oil gas and volatile organic matter has absorption method, absorption process, condensation method and UF membrane Method etc..Absorption method is to utilize binding force between each component and adsorbent (active carbon, activated carbon fiber, silica gel, molecular sieve etc.) different, Realize the separation of difficult absorbed component and easy absorbed component.Absorption process is the counter current contacting by organic gas and absorbent, benefit With each component in organic gas in absorbent the difference of solubility and separated.Condensation method is using organic matter in difference There is different saturated vapour pressures under temperature and pressure, by reducing temperature or increasing pressure, condense out organic gas. Membrane separation process is driven by pressure, by gas each component in the adsorption capacity on polymeric membrane surface and in film intrinsic permeability Difference separated, but the rate of recovery of the above method is not high, and the expection of people is not achieved.
Summary of the invention
The purpose of the present invention is to provide the systems that a kind of organic matter recycles, to solve to propose in above-mentioned background technique The problem of.
To achieve the above object, the invention provides the following technical scheme:
A kind of system that organic matter recycles, including condenser, super purifier, recycling can, circulation and condensation unit, institute Stating condenser includes first-stage condenser, secondary condenser and three-level condenser, first-stage condenser respectively with secondary condenser, recycling Tank is connected with organic gas air inlet pipe, and secondary condenser is connected with three-level condenser and recycling can respectively, three-level condenser It is connected with recycling can, three-level condenser also passes through recycle feed valve and is connected with secondary condenser, and secondary condenser is by following Ring outlet valve is connected with super purifier, and super purifier is connected with air cooler, and air cooler is connected with tail gas discharging pipe, condenses unit and three The both ends of grade condenser are connected, and circulation is connected with the both ends of first-stage condenser.
As a further solution of the present invention: the first liquid-phase outlet valve being installed, on secondary condenser in first-stage condenser Second liquid phase outlet valve is installed, third liquid-phase outlet valve is installed on three-level condenser.
As a further solution of the present invention: fire arrester is connected between secondary condenser and super purifier.
As a further solution of the present invention: the coolant media of three-level condenser uses freon.
The workflow for the system that the organic matter recycles, the specific steps are as follows:
Step 1, volatile organic gases enters first-stage condenser by organic gas air inlet pipe and carries out partial condensation, after condensation Gas-liquid mixture carry out partial condensation in the tube side of first-stage condenser, liquid phase is expelled to recycling can, and gas phase enters B-grade condensation Device;
Step 2, the gas phase into secondary condenser are further condensed, organic matter be condensed after in secondary condenser Bottom tube side carries out gas-liquid separation, and liquid phase drains into recycling can, and not condensed gas phase enters three-level condenser, and gas phase is cold in three-level Condenser condensation, liquid phase drain into recycling can, and not condensed gas phase enters secondary condenser;
Step 3 closes gas phase outlet valve, and the gas phase after exchanging heat enters super purifier, the not condensed organic matter in super purifier It is completely converted as nontoxic and pollution-free gas, then be emitted into tail gas discharging pipe via air cooler.
As a further solution of the present invention: in step 2 the not condensed gas phase of three-level condenser by gas phase recycle into Material valve enters secondary condenser.
As a further solution of the present invention: the gas phase after exchanging heat in step 3 is entered ultra-clean by gas phase circulation outlet valve Device.
Compared with prior art, the beneficial effects of the present invention are:
First, condensation method is combined with method of chemical treatment, it is simple and easy, it does not need additionally to use adsorbent and carry out at desorption Reason, the rate of recovery of organic matter is up to 99% or more, and the rate of recovery of oil gas is up to 95% or more;
Second, secondary condenser is carried out by the way of material-heat-exchanging in system, is efficiently utilized the heat of internal system, is kept away The waste for exempting from system capacity reduces the total energy consumption of whole system;
Third, this product have universality, can be applied to the recycling of the volatile organic matters such as oil gas, benzene, toluene;
4th, the equipment size in this product can be adjusted according to the treating capacity of organic matter, also, condenser and super purifier It is vertical equipment, occupied area is small, is easy to modularization.
Detailed description of the invention
Fig. 1 is the structural schematic diagram for the system that organic matter recycles.
Wherein: 1- organic gas air inlet pipe, 2- first-stage condenser, 3- secondary condenser, 4- three-level condenser, 5- are ultra-clean Device, 6- recycling can, 7- circulation, 8- condense unit, 9- fire arrester, 10- air cooler, 11- tail gas discharging pipe, 12- first Liquid-phase outlet valve, 13- second liquid phase outlet valve, 14- third liquid-phase outlet valve, 15- gas phase outlet valve, 16- gas phase recycle feed Valve, 17- gas phase recycle outlet valve, 18- recovered liquid outlet valve.
Specific embodiment
The technical solution of the patent is explained in further detail With reference to embodiment.
Embodiment 1
Exhaust gas containing benzene is recycled, wherein the volume fraction of benzene is 10%, and nitrogen volume fraction is 90%.Specific technique Process are as follows: tube side of the waste gas containing benzene first by organic gas air inlet pipe 1 Jing Guo first-stage condenser 2 carries out partial condensation, after condensation Gas-liquid mixture carry out gas-liquid separation in heat exchanger lower tube shell-space, liquid phase is expelled to recycling by the first liquid-phase outlet valve 12 Tank 6, the tube side that gas phase enters secondary condenser 3 are further condensed, organic matter be condensed after at the bottom of secondary condenser 3 Portion's tube side carries out gas-liquid separation, and liquid phase drains into recycling can 6 by second liquid phase outlet valve 13, and it is cold that not condensed gas phase enters three-level The tube side of condenser 4 carries out deep cooling, and organic matter in the bottom tube side of three-level condenser carries out gas-liquid separation after being condensed, liquid phase by Outlet valve 14 drains into recycling can 6, and not condensed gas phase is entered the shell side of secondary condenser 3 by gas phase recycle feed valve 16, closes Phase of holding one's breath outlet valve 15, the gas phase after exchanging heat recycles outlet valve 17 by gas phase and enters super purifier 5 through fire arrester 9, in super purifier 5 Interior, not condensed organic matter is completely converted as nontoxic and pollution-free gas, then is emitted into atmosphere via air cooler 10.
The rate of recovery of the present embodiment benzene is 99%, and the content of benzene is 2mg/m in tail gas discharging pipe3, fully meet existing environmental protection Emission request.
Embodiment 2
Exhaust gas containing benzene and toluene is recycled, wherein the volume fraction of benzene is 15%, the volume fraction 10% of toluene, nitrogen Volume fraction is 75%.Specific technical process are as follows: waste gas containing benzene is first by organic gas air inlet pipe 1 by first-stage condenser 2 Tube side carries out partial condensation, and condensed gas-liquid mixture carries out gas-liquid separation in heat exchanger lower tube shell-space, and liquid phase is by the One liquid-phase outlet valve 12 is expelled to recycling can 6, and the tube side that gas phase enters secondary condenser 3 is further condensed, organic matter quilt Gas-liquid separation is carried out in the bottom tube side of secondary condenser 3 after condensation, liquid phase drains into recycling can by second liquid phase outlet valve 13 6, not condensed gas phase enter three-level condenser 4 tube side carry out deep cooling, organic matter be condensed after in three-level condenser 4 Bottom tube side carries out gas-liquid separation, and liquid phase drains into recycling can 6 by third liquid-phase outlet valve 14, and not condensed gas phase is followed by gas phase Ring inlet valve 16 enters the shell side of secondary condenser 3, closes gas phase outlet valve 15, and the gas phase after exchanging heat is recycled by gas phase and discharged Valve 17 enters super purifier 5 through fire arrester 9, and in super purifier 5, it is nontoxic and pollution-free that not condensed organic matter, which is completely converted, Gas, then atmosphere is emitted into via air cooler 10.
The rate of recovery of benzene is 99.5% in the present embodiment, and the rate of recovery of toluene is 99.9%, the content of benzene in tail gas discharging pipe For 1mg/m3, toluene level 4mg/m3, fully meet the emission request of existing environmental protection.
Embodiment 3
Exhaust gas containing benzene,toluene,xylene is recycled, wherein the volume fraction of benzene is 20%, and the volume fraction of toluene is 10, the volume fraction of dimethylbenzene is 7.5%, and nitrogen volume fraction is 62.5%.Specific technical process are as follows: waste gas containing benzene first by Tube side of the organic gas air inlet pipe 1 Jing Guo first-stage condenser 2 carries out partial condensation, and condensed gas-liquid mixture is under heat exchanger Portion shell space carries out gas-liquid separation, and liquid phase is expelled to recycling can 6 by the first liquid-phase outlet valve 12, and gas phase enters secondary condenser 3 tube side is further condensed, organic matter be condensed after secondary condenser 3 bottom tube side carry out gas-liquid separation, liquid Recycling can 6 is mutually drained by second liquid phase outlet valve 13, the tube side that not condensed gas phase enters three-level condenser 4 carries out deep cooling, Organic matter be condensed after three-level condenser 4 bottom tube side carry out gas-liquid separation, liquid phase is by 14 row of third liquid-phase outlet valve To recycling can 6, not condensed gas phase is entered the shell side of secondary condenser 3 by gas phase recycle feed valve 16, closes gas phase discharging Valve 15, the gas phase after exchanging heat recycles outlet valve 17 by gas phase and enters super purifier 5 through fire arrester 9, not cold in super purifier 5 Solidifying organic matter is completely converted as nontoxic and pollution-free gas, then is emitted into atmosphere via air cooler 10.
The rate of recovery 99% of benzene in the present embodiment, the rate of recovery of toluene are 99.9%, and the rate of recovery of dimethylbenzene is 99.9%, tail The content of benzene is 2mg/m in gas delivery pipe3, toluene level 4mg/m3, xylene content 9mg/m3, fully meet existing ring The emission request of guarantor.
Embodiment 4
Exhaust gas containing gasoline is recycled, wherein the volume fraction of gasoline is 10%, and nitrogen volume fraction is 90%.Specifically Technical process are as follows: tube side of the waste gas containing benzene first by organic gas air inlet pipe 1 Jing Guo first-stage condenser 2 carries out partial condensation, cold Gas-liquid mixture after solidifying carries out gas-liquid separation in heat exchanger lower tube shell-space, and liquid phase is expelled to by the first liquid-phase outlet valve 12 Recycling can 6, the tube side that gas phase enters secondary condenser 3 are further condensed, organic matter be condensed after in secondary condenser 3 Bottom tube side carry out gas-liquid separation, liquid phase drains into recycling can 6 by second liquid phase outlet valve 13, and not condensed gas phase enters three Grade condenser 4 tube side carry out deep cooling, organic matter be condensed after three-level condenser 4 bottom tube side carry out gas-liquid separation, Liquid phase drains into recycling can 6 by third liquid-phase outlet valve 14, and not condensed gas phase is cold into second level by gas phase recycle feed valve 16 The shell side of condenser 3 closes gas phase outlet valve 15, and the gas phase after exchanging heat is entered by gas phase circulation outlet valve 17 through fire arrester 9 super Net device 5, in super purifier 5, not condensed organic matter is completely converted for nontoxic and pollution-free gas, then via air cooler 10 It is emitted into atmosphere.
The rate of recovery of the present embodiment gasoline is 95.4%, and the content of gasoline is less than 5mg/m in tail gas discharging pipe3, completely full The emission request that toe ring is protected.
The working principle of the invention is: volatile organic gases enters first-stage condenser 2 by organic gas air inlet pipe 1 first Tube side.Wherein, organic gas can adjust the pressure and flow of air inlet by supplement nitrogen.The refrigerant of the heat exchanger is circulation Water adjusts the outlet temperature of cooled medium by adjusting the flow of recirculated water, and the organic matter after being cooled forms gas-liquid Two-phase is mixed, carries out gas-liquid separation in heat exchanger tube pass bottom, liquid phase drains into recycling can 6 by bottom the first liquid-phase outlet valve 12, Gas phase enters the tube side of secondary condenser 3.
The shell side of secondary condenser 3 is the gas that three-level condenser 4 exports, and material-heat-exchanging can make full use of internal system Energy, save overall energy consumption, the gas-liquid mixture of partial condensation carries out gas-liquid separation in the tube side space of exchanger base, Liquid phase drains into recycling can 6 by the second liquid phase outlet valve 13 of bottom, and gas phase enters three-level condenser 4.
Not condensed gas phase is exchanged heat by the tube side of three-level condenser 4 with refrigerant (freon), by controlling refrigerant Dosage adjust the outlet temperature of 4 tube side of three-level condenser.After deep cooling, most of organic matter is condensed, via Third liquid-phase outlet valve 14 drains into recycling can 6.Not condensed organic matter and inert gas is further processed.
Not condensed gas exchanges heat as the refrigerant of secondary condenser 3 with tube side gas, heat exchange after again via Fire arrester 9 enters super purifier 5.In super purifier 5, not condensed gas is converted to nontoxic no dirt by series of chemical The gas of dye, remaining micro organic gas are removed totally, are emitted into atmosphere using air cooler 10.It is set on recycling can 6 It is equipped with recovered liquid outlet valve 18.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (7)

1. the system that a kind of organic matter recycles, which is characterized in that including condenser, super purifier (5), recycling can (6), circulation Water system (7) and condensation unit (8), the condenser includes first-stage condenser (2), secondary condenser (3) and three-level condenser (4), first-stage condenser (2) is connected with secondary condenser (3), recycling can (6) and organic gas air inlet pipe (1) respectively, second level Condenser (3) is connected with three-level condenser (4) and recycling can (6) respectively, and three-level condenser (4) is connected with recycling can (6), Three-level condenser (4) is also connected with secondary condenser (3), and secondary condenser (3) is connected with super purifier (5), super purifier (5) It is connected with air cooler (10), air cooler (10) is connected with tail gas discharging pipe (11), condensation unit (8) and three-level condenser (4) Both ends are connected, and circulation (7) is connected 1 with the both ends of first-stage condenser (2).
2. the system that organic matter according to claim 1 recycles, which is characterized in that on the first-stage condenser (2) First liquid-phase outlet valve (12) is installed, second liquid phase outlet valve (13), three-level condenser are installed on secondary condenser (3) (4) third liquid-phase outlet valve (14) is installed on.
3. the system that organic matter according to claim 1 recycles, which is characterized in that the secondary condenser (3) with Fire arrester (9) are connected between super purifier (5).
4. the system that organic matter according to claim 1 recycles, which is characterized in that the three-level condenser (4) Coolant media uses freon.
5. a kind of workflow for the system that the organic matter as described in claim 1-4 is any recycles, which is characterized in that tool Steps are as follows for body:
Step 1, volatile organic gases enters first-stage condenser by organic gas air inlet pipe and carries out partial condensation, after condensation Gas-liquid mixture carry out partial condensation in the tube side of first-stage condenser, liquid phase is expelled to recycling can, and gas phase enters B-grade condensation Device;
Step 2, the gas phase into secondary condenser are further condensed, organic matter be condensed after in secondary condenser Bottom tube side carries out gas-liquid separation, and liquid phase drains into recycling can, and not condensed gas phase enters three-level condenser, and gas phase is cold in three-level Condenser condensation, liquid phase drain into recycling can, and not condensed gas phase enters secondary condenser;
Step 3 closes gas phase outlet valve, and the gas phase after exchanging heat enters super purifier, the not condensed organic matter in super purifier It is completely converted as nontoxic and pollution-free gas, then be emitted into tail gas discharging pipe via air cooler.
6. the workflow for the system that organic matter according to claim 5 recycles, which is characterized in that the step 2 The not condensed gas phase of middle three-level condenser (4) enters secondary condenser (3) by gas phase recycle feed valve (16).
7. the workflow for the system that organic matter according to claim 5 recycles, which is characterized in that the step 3 Gas phase after middle heat exchange enters super purifier (5) by gas phase circulation outlet valve (17).
CN201811142642.XA 2018-09-28 2018-09-28 A kind of system and its workflow that organic matter recycles Pending CN109126180A (en)

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CN109289227A (en) * 2018-09-30 2019-02-01 上海峻岗环保科技有限公司 A kind of organic matter recovery system and its recovery method
CN112033178A (en) * 2020-09-07 2020-12-04 边会婷 Condensing equipment that exhaust-gas treatment used

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CN202289823U (en) * 2011-10-17 2012-07-04 中国石油化工股份有限公司 Device for condensing and absorbing oil and gas at low temperature and producing ethanol gasoline
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109289227A (en) * 2018-09-30 2019-02-01 上海峻岗环保科技有限公司 A kind of organic matter recovery system and its recovery method
CN112033178A (en) * 2020-09-07 2020-12-04 边会婷 Condensing equipment that exhaust-gas treatment used

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