CN109112510A - A kind of aluminum non-chromium passivator - Google Patents

A kind of aluminum non-chromium passivator Download PDF

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Publication number
CN109112510A
CN109112510A CN201710480415.7A CN201710480415A CN109112510A CN 109112510 A CN109112510 A CN 109112510A CN 201710480415 A CN201710480415 A CN 201710480415A CN 109112510 A CN109112510 A CN 109112510A
Authority
CN
China
Prior art keywords
parts
chromium
aluminum non
chromium passivator
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710480415.7A
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Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Haimen Beauty Art Graphic Design Co Ltd
Original Assignee
Haimen Beauty Art Graphic Design Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haimen Beauty Art Graphic Design Co Ltd filed Critical Haimen Beauty Art Graphic Design Co Ltd
Priority to CN201710480415.7A priority Critical patent/CN109112510A/en
Priority to PCT/CN2017/096580 priority patent/WO2018232876A1/en
Publication of CN109112510A publication Critical patent/CN109112510A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

The invention discloses a kind of aluminum non-chromium passivator, are made up of the raw material of following parts by weight: 15-20 parts of silane coupling agent, 15-25 parts of aluminium silicate polymer, 10-12 parts of nano zircite, 5-10 parts of nanometer titanium dioxide, 2-8 parts of disodium ethylene diamine tetraacetate, 1-5 parts of metasilicic acid, 40-50 parts of deionized water.The present invention provides a kind of aluminum non-chromium passivator, and the aluminium after processing, chromium-free passivating film is greatly improved with aluminum substrate, the adhesion property of spray-on coating and corrosion resisting property.

Description

A kind of aluminum non-chromium passivator
Technical field
Present invention relates particularly to a kind of aluminum non-chromium passivator.
Background technique
In order to reduce the harm to environment and human body, people begin look for replace the Chrome-free of chromating in recent years Passivating technique.Extensive research has been done to chromium-free deactivation technology both at home and abroad at present, and industrialization is done step-by-step, and it is domestic Autonomous innovation has been started to the research of chromium-free deactivation, has substituted the road of import.Existing non-chromium inactivating technique is divided into two major classes, organic Object passivation and inorganic matter passivation, wherein the used raw material of inorganic passivation be mainly Ti, Zr, Hf, V, Si, Mo, W, Mn, La, The oxide or inorganic salts and some organic matters of addition of the elements such as Ce.
Summary of the invention
The purpose of the present invention is to provide a kind of aluminum non-chromium passivator.
The present invention is realized by following technical solution:
A kind of aluminum non-chromium passivator is made up of the raw material of following parts by weight: 15-20 parts of silane coupling agent, aluminium silicate polymer 15- It 25 parts, 10-12 parts of nano zircite, 5-10 parts of nanometer titanium dioxide, 2-8 parts of disodium ethylene diamine tetraacetate, 1-5 parts of metasilicic acid, goes 40-50 parts of ionized water.
Preferably, the aluminum non-chromium passivator is made up of: silane coupling agent 17.5 raw material of following parts by weight Part, 20 parts of aluminium silicate polymer, 11 parts of nano zircite, 7.5 parts of nanometer titanium dioxide, 5 parts of disodium ethylene diamine tetraacetate, 3 parts of metasilicic acid, 45 parts of deionized water.
Preferably, the aluminum non-chromium passivator is made up of the raw material of following parts by weight: 15 parts of silane coupling agent, 15 parts of aluminium silicate polymer, 10 parts of nano zircite, 5 parts of nanometer titanium dioxide, 2 parts of disodium ethylene diamine tetraacetate, 1 part of metasilicic acid, go from 40 parts of sub- water.
Preferably, the aluminum non-chromium passivator is made up of the raw material of following parts by weight: 20 parts of silane coupling agent, 25 parts of aluminium silicate polymer, 12 parts of nano zircite, 10 parts of nanometer titanium dioxide, 8 parts of disodium ethylene diamine tetraacetate, 5 parts of metasilicic acid, go from 50 parts of sub- water.
The technology of the present invention effect:
The present invention provides a kind of aluminum non-chromium passivator, the aluminium after processing, chromium-free passivating film and aluminum substrate, spray-on coating Adhesion property and corrosion resisting property greatly improve.
Specific embodiment
Essentiality content of the invention is specifically introduced below with reference to embodiment.
Embodiment 1
The aluminum non-chromium passivator is made up of the raw material of following parts by weight: 17.5 parts of silane coupling agent, aluminium silicate polymer 20 Part, 11 parts of nano zircite, 7.5 parts of nanometer titanium dioxide, 5 parts of disodium ethylene diamine tetraacetate, 3 parts of metasilicic acid, 45 parts of deionized water.
Embodiment 2
The aluminum non-chromium passivator is made up of the raw material of following parts by weight: 15 parts of silane coupling agent, aluminium silicate polymer 15 Part, 10 parts of nano zircite, 5 parts of nanometer titanium dioxide, 2 parts of disodium ethylene diamine tetraacetate, 1 part of metasilicic acid, 40 parts of deionized water.
Embodiment 3
The aluminum non-chromium passivator is made up of the raw material of following parts by weight: 20 parts of silane coupling agent, aluminium silicate polymer 25 Part, 12 parts of nano zircite, 10 parts of nanometer titanium dioxide, 8 parts of disodium ethylene diamine tetraacetate, 5 parts of metasilicic acid, 50 parts of deionized water.
The present invention provides a kind of aluminum non-chromium passivator, the aluminium after processing, chromium-free passivating film and aluminum substrate, spraying The adhesion property and corrosion resisting property of coating greatly improve.

Claims (4)

1. a kind of aluminum non-chromium passivator, which is characterized in that be made up of the raw material of following parts by weight: silane coupling agent 15-20 Part, 15-25 parts of aluminium silicate polymer, 10-12 parts of nano zircite, 5-10 parts of nanometer titanium dioxide, 2-8 parts of disodium ethylene diamine tetraacetate, 1-5 parts of metasilicic acid, 40-50 parts of deionized water.
2. aluminum non-chromium passivator according to claim 1, which is characterized in that be made up of the raw material of following parts by weight: 17.5 parts of silane coupling agent, 20 parts of aluminium silicate polymer, 11 parts of nano zircite, 7.5 parts of nanometer titanium dioxide, disodium ethylene diamine tetraacetate 5 parts, 3 parts of metasilicic acid, 45 parts of deionized water.
3. aluminum non-chromium passivator according to claim 1, which is characterized in that be made up of the raw material of following parts by weight: 15 parts of silane coupling agent, 15 parts of aluminium silicate polymer, 10 parts of nano zircite, 5 parts of nanometer titanium dioxide, 2 parts of disodium ethylene diamine tetraacetate, 1 part of metasilicic acid, 40 parts of deionized water.
4. aluminum non-chromium passivator according to claim 1, which is characterized in that be made up of the raw material of following parts by weight: 20 parts of silane coupling agent, 25 parts of aluminium silicate polymer, 12 parts of nano zircite, 10 parts of nanometer titanium dioxide, disodium ethylene diamine tetraacetate 8 Part, 5 parts of metasilicic acid, 50 parts of deionized water.
CN201710480415.7A 2017-06-22 2017-06-22 A kind of aluminum non-chromium passivator Withdrawn CN109112510A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201710480415.7A CN109112510A (en) 2017-06-22 2017-06-22 A kind of aluminum non-chromium passivator
PCT/CN2017/096580 WO2018232876A1 (en) 2017-06-22 2017-08-09 Chromium-free passivator for aluminum product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710480415.7A CN109112510A (en) 2017-06-22 2017-06-22 A kind of aluminum non-chromium passivator

Publications (1)

Publication Number Publication Date
CN109112510A true CN109112510A (en) 2019-01-01

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CN201710480415.7A Withdrawn CN109112510A (en) 2017-06-22 2017-06-22 A kind of aluminum non-chromium passivator

Country Status (2)

Country Link
CN (1) CN109112510A (en)
WO (1) WO2018232876A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112226754A (en) * 2020-10-19 2021-01-15 武汉科润表面新材料有限公司 Non-washing acrylic acid chromium-free passivator suitable for aluminum profile

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040485A (en) * 2019-11-29 2020-04-21 浙江九合金属表面处理技术有限公司 Environment-friendly metal surface treating agent and use method thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5294265A (en) * 1992-04-02 1994-03-15 Ppg Industries, Inc. Non-chrome passivation for metal substrates
CN102443794B (en) * 2011-12-06 2013-07-24 中国科学院金属研究所 Aluminum alloy scratch resistant and fingerprint resistant chromium-free chemical conversion solution for ship and preparation method of conversion film
EP2907894B1 (en) * 2014-02-13 2019-04-10 Ewald Dörken Ag Method for production of a substrate with a chromium VI free and cobalt-free passivation
CN104561970A (en) * 2014-12-31 2015-04-29 苏州禾川化学技术服务有限公司 Corrosion-resistant magnesium aluminum alloy chromium-free passivation solution
CN105177549A (en) * 2015-09-16 2015-12-23 马鞍山杰创塑胶科技有限公司 High-tenacity aluminum profile rare earth silane processing liquid and preparation method thereof
CN106282987A (en) * 2016-08-29 2017-01-04 常熟市虞东磷化材料有限公司 Aluminum passivator

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112226754A (en) * 2020-10-19 2021-01-15 武汉科润表面新材料有限公司 Non-washing acrylic acid chromium-free passivator suitable for aluminum profile

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