CN109111248A - A kind of rubbish hydrolyzed formulas - Google Patents
A kind of rubbish hydrolyzed formulas Download PDFInfo
- Publication number
- CN109111248A CN109111248A CN201811050419.2A CN201811050419A CN109111248A CN 109111248 A CN109111248 A CN 109111248A CN 201811050419 A CN201811050419 A CN 201811050419A CN 109111248 A CN109111248 A CN 109111248A
- Authority
- CN
- China
- Prior art keywords
- organic matter
- elected
- parts
- rubbish
- hydrolyzed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F9/00—Fertilisers from household or town refuse
- C05F9/04—Biological compost
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
The present invention relates to a kind of rubbish hydrolyzed formulas, step 1: the organic matter sub-elected is sent into horizontal hydrolytic decomposition pot；Step 2: dilution heat of sulfuric acid is sprayed on the organic matter sub-elected, makes that horizontal hydrolytic decomposition pot is heated to 180 DEG C of high temperature and reaction is hydrolyzed in the 1.0Mpa that adds high pressure simultaneously；Step 3: high temperature and high pressure hydrolysis reacts 2 hours；Step 4: temperature in horizontal hydrolytic decomposition pot is down to 40 DEG C, normal pressure；Step 5: being then sprayed into biological enzyme agent hydrolyzes the organic matter sub-elected thoroughly and plays solid ammonia.The technique that the present invention goes out organic matter total system as central inventive to hydrolyze solid ammonia technology.
Description
Technical field
The present invention relates to a kind of rubbish hydrolyzed formulas.
Background technique
The processing of perishable organic matter in conventional garbage, hydrolysis spray exposure method is all made of in similar technique, and hydrolysis spray exposes tank and is
Vertical tank is above cylindrical tube, and lower is cone.Feed inlet D=600, discharge port D=500.Organic matter from upper port into
Material is heaped always from lower cone to upper shell, and sprinkling catalyst and material heating in this way is uneven, and medicine spraying tube, heating tube are basic
On be all disposed within cylinder, if cone arrangement pipeline material sticks it is unclean in pipeline loading and unloading material.Material is after the completion of hydrolysis
Thick, it all squeezes down, forms blocking.Generally use~0.3Mpa compressed air carries out spray exposure, this makes foul smell in tank
It gushes out, and generates noise, cause environmental pollution, when material Severe blockage, spray exposure is also of no avail, can only manual cleaning
(manually clawing), because there is heat preservation outside tank body, in tank temperature it is higher > 100 DEG C, heat dissipation is slow, to be cooled to take 2-3 days, therefore seriously
Influence manufacturing schedule.In addition organic matter can not uniformly spray catalyst, can not be evenly heated in tank, then hydrolysis of organic matter is not thorough
Bottom is unable to reach hydrolysis effect, influences the fertile quality of subsequent system.
Summary of the invention
The object of the present invention is to provide a kind of rubbish hydrolyzed formulas, to solve the above problems, are to hydrolyze solid ammonia technology
The technique that central inventive goes out organic matter total system.
Above-mentioned purpose is realized by following technical scheme:
A kind of rubbish hydrolyzed formulas, comprising the following steps:
Step 1: the organic matter sub-elected is sent into horizontal hydrolytic decomposition pot；
Step 2: dilution heat of sulfuric acid is sprayed on the organic matter sub-elected, and horizontal hydrolytic decomposition pot is made to be heated to 180 DEG C of high temperature
And reaction is hydrolyzed in the 1.0Mpa that adds high pressure simultaneously；
Step 3: high temperature and high pressure hydrolysis reacts 2 hours；
Step 4: temperature in horizontal hydrolytic decomposition pot is down to 40 DEG C, normal pressure；
Step 5: being then sprayed into biological enzyme agent hydrolyzes the organic matter sub-elected thoroughly and plays solid ammonia.
Further, dilution heat of sulfuric acid concentration described in step 2 is 25%~35%.
Further, the fountain height of dilution heat of sulfuric acid described in step 2 and the organic matter sub-elected is 0.08-
0.12L/m3。
Further, biological enzyme agent described in step 5 includes 30-40 parts of peptase, 10-16 parts of lipase, fibre
6-9 parts and water 936-913 parts of plain 18-22 parts of enzyme, ribozyme are tieed up, generated solution is sufficiently mixed.
Further, the fountain height of biological enzyme agent described in step 5 and the organic matter sub-elected is 3-5L/
m3。
Beneficial effect
1. the present invention is the hydrolysis principle according to organic matter, data are then matched by the sulfuric acid that n times test just obtains,
The dilute sulfuric acid for spraying various concentration under high temperature, high pressure by several times can just obtain satisfied hydrolysis of organic matter effect.
2. hydrolysis of organic matter is divided into three phases by the present invention, first is that high temperature, high pressure carry out tentatively by catalyst of sulfuric acid
Hydrolysis is fully hydrolyzed organic matter, third is that hydrolysis reactant rises under anaerobic state second is that spraying into biological enzyme under low (normal) temperature
Nitrogen fixation.Organic matter in rubbish can be just converted to the qualified base-material of organic fertilizer processed in this way.
3. maximum harvest of the invention is that hydrolysis of organic matter is thorough, the subsequent fermentation time is short, as long as 2 days can enter system
Fertilizer, so that municipal refuse enters workshop progress recycling treatment and becomes a reality.
4. another major benefit of the invention is that percolate is eradicated in rubbish.Hydrolysis of organic matter it is quick, thorough,
So that municipal refuse daily output day is clear.Percolate is that organic matter rots and generates, and the daily output day of rubbish is clear, also not rotten in organic matter
Rotten pre-treatment, the overwhelming majority do not generate percolate also.It is exactly that some percolate is pumped into hydrolytic decomposition pot and organic matter one
And hydrolyze except reason, solve garbage disposal the biggest problem.
Specific embodiment
Embodiment 1
A kind of rubbish hydrolyzed formulas, comprising the following steps:
Step 1: the organic matter sub-elected is sent into horizontal hydrolytic decomposition pot；
Step 2: dilution heat of sulfuric acid is sprayed on the organic matter sub-elected, and horizontal hydrolytic decomposition pot is made to be heated to 180 DEG C of high temperature
And reaction is hydrolyzed in the 1.0Mpa that adds high pressure simultaneously；
Step 3: high temperature and high pressure hydrolysis reacts 2 hours；
Step 4: temperature in horizontal hydrolytic decomposition pot is down to 40 DEG C, normal pressure (0-0.1Mpa is normal pressure)；
Step 5: being then sprayed into biological enzyme agent hydrolyzes the organic matter sub-elected thoroughly and plays solid ammonia.
Further, dilution heat of sulfuric acid concentration described in step 2 is 25%~35%.
Further, the fountain height of dilution heat of sulfuric acid described in step 2 and the organic matter sub-elected is 0.08-
0.12L/m3。
Further, biological enzyme agent described in step 5 includes 30-40 parts of peptase, 10-16 parts of lipase, fibre
6-9 parts and water 936-913 parts of plain 18-22 parts of enzyme, ribozyme are tieed up, generated solution is sufficiently mixed.
Further, the fountain height of biological enzyme agent described in step 5 and the organic matter sub-elected is 3-5L/
m3。
Embodiment 2
Embodiment 1 is further, and dilution heat of sulfuric acid concentration described in step 2 is 25%.
Further, the fountain height of dilution heat of sulfuric acid described in step 2 and the organic matter sub-elected is 0.12L/m3
Further, biological enzyme agent described in step 5 includes 30 parts of peptase, 10 parts of lipase, cellulase 18
6 parts and 936 parts of water of part, ribozyme, are sufficiently mixed generated solution.
Further, the fountain height of biological enzyme agent described in step 5 and the organic matter sub-elected is 5L/m3。
Embodiment 3
Embodiment 1 is further, and dilution heat of sulfuric acid concentration described in step 2 is 35%.
Further, the fountain height of dilution heat of sulfuric acid described in step 2 and the organic matter sub-elected is 0.08L/m3。
Further, biological enzyme agent described in step 5 includes 40 parts of peptase, 16 parts of lipase, cellulase 22
9 parts and 913 parts of water of part, ribozyme, are sufficiently mixed generated solution.
Further, the fountain height of biological enzyme agent described in step 5 and the organic matter sub-elected is 3L/m3。
Embodiment 4
Embodiment 1 is further, and dilution heat of sulfuric acid concentration described in step 2 is 30%.
Further, the fountain height of dilution heat of sulfuric acid described in step 2 and the organic matter sub-elected is 0.1L/m3。
Further, biological enzyme agent described in step 5 includes 35 parts of peptase, 13 parts of lipase, cellulase 20
7.5 parts and 924.5 parts of water of part, ribozyme, are sufficiently mixed generated solution.
Further, the fountain height of biological enzyme agent described in step 5 and the organic matter sub-elected is 4L/m3。
Embodiment 5
Embodiment 1 is further, and dilution heat of sulfuric acid concentration described in step 2 is 33%.
Further, the fountain height of dilution heat of sulfuric acid described in step 2 and the organic matter sub-elected is 0.09L/m3。
Further, biological enzyme agent described in step 5 includes 38 parts of peptase, 15 parts of lipase, cellulase 21
8.5 parts and 917.5 parts of water of part, ribozyme, are sufficiently mixed generated solution.
Further, the fountain height of biological enzyme agent described in step 5 and the organic matter sub-elected is 3.5L/
m3。
Embodiment 6
Embodiment 1 is further, and dilution heat of sulfuric acid concentration described in step 2 is 28%.
Further, the fountain height of dilution heat of sulfuric acid described in step 2 and the organic matter sub-elected is 0.11L/m3。
Further, biological enzyme agent described in step 5 includes 32 parts of peptase, 11 parts of lipase, cellulase 19
6.5 parts and 931.5 parts of water of part, ribozyme, are sufficiently mixed generated solution.
Further, the fountain height of biological enzyme agent described in step 5 and the organic matter sub-elected is 4.5L/
m3。
Embodiment 7
Rubbish hydrolyzed formulas described in embodiment 1, organic matter in rubbish each ingredient in hydrolytic process have occurred as follows
Reaction；
1；Carbohydrate hydrolysis；Starch, fat, protein, nucleic acid；
(1) Starch Hydrolysis；
Starch is natural polymer and most important polysaccharide, is hydrolyzed into grape under acidic catalyst effect
Sugar.
(2) cellulose hydrolyzes；
For cellulosic molecule at filiform, these molecules connect into cellulose micelle in the form of hydrogen bond, the number of hydrogen bond in micella
There are many mesh, so chemical property is more stable, and the complete water of cellulose can be just made under sulfuric acid and heat treatment in conjunction with very securely
Solution generates the products such as six sugar, tetrose, trisaccharide in hydrolysis, ultimately produces disaccharides and glucose.
(3) fat splitting；
R: for carbon atom number
Fat is hydrolyzed into fatty acid and glycerol as catalyst by acid and enzyme.
(4) protein hydrolyzes；
Protein is the material base of life, is the unit constituted substantially, and there are many type of protein, but is all by more than 20
Kind amino acid is composed by different proportion.
The initial hydrolysate of protein is polypeptide, and final hydrolysate is amino acid.
(5) nucleic acid hydrolysis；
Nucleic acid is the macromolecular compound generated by many nucleotide polymerizations, is widely present in all plant cells, dimension life
In object, the intracorporal nucleic acid of biology often forms nucleoprotein in conjunction with protein.Its chemical composition of different nucleic acid is different.
The hydrolysate of nucleic acid；Pentose, nitrogenous base, phosphoric acid.
Fixed nitrogen reaction occurs organic matter in rubbish for the phase after hydrolyzing；
Pass through the reaction that carbonyl (including aldehyde, ketone) ammonia combines in the hydrolysis later period, i.e. hydrolysis generates amino acids, sugar early period
Class, carbohydrate etc. guarantees certain temperature and pressure in the case where azotase is as catalyst action in horizontal tank, by amino
Gu resetting fixed nitrogen in carbochain, generating the small molecule carboritride of stable state being easily absorbed by plants, can be used as good has
Machine fertilizer base-material.
N2+3H2=2N H3 (high temperature, high pressure, catalyst)
Contain ferritin and Mo-Fe protein in azotase, only both substances, which exist simultaneously, just there is good fixed nitrogen to make
With both substances are extremely sensitive to oxygen, cause azotase to inactivate quickly once working as chance oxygen, therefore fixed nitrogen must be detested in stringent
It is carried out under the conditions of oxygen.And phase after hydrolyzing extracts air out and becomes anaerobic environment using horizontal hydrolytic decomposition pot, but also as solid
Nitrogen tank guarantees nitrogen fixation after hydrolysis of organic matter.
Embodiment 8
The device that rubbish hydrolyzed formulas described in embodiment 1 is used has hydrolytic decomposition pot and bin stock vehicle can refer to, and " one kind is for city
The horizontal hydrolysis reactor tank that city's house refuse is handled in real time "；
001: the organic matter sorted out is packed into bin stock vehicle by material distributing machine.
002: one hydrolytic decomposition pot design is packed into 8 frame bin stock vehicles.
003: hydrolytic decomposition pot is provided with the fixed guide rail of driving, is connected with ground guide level.Lead at tube body entrance and exit
Cross section guide rail flexible connection.
004: bin stock vehicle bottom is equipped with 4 wheels, can roll along track.
005: bin stock vehicle is semi-cylindrical shaped, and size is not touch subject to hydrolytic decomposition pot internal sparger pipe.
006: bin stock vehicle body is stainless steel plate production, can play antisepsis, vehicle body and end plate are all drilled with the hole D=20, are conducive to
Vapor spraying and catalyst sprinkling are uniformly used.
007: bin stock vehicle two end plates are designed to the door that can be started upwards, are convenient for discharging.
008: hydrolytic decomposition pot is provided with axial, circumferential spray tube, and spray tube tank is along 2 row's aperture of tank centre drill, to tank body center
The uniform spraying steam of trolley and catalyst.
009: hydrolytic decomposition pot two end cap is sealing cap together with flange welding, forms the close of one group of electric quick-open with shell flange
Seal apparatus, interlocking design, i.e., fail to open hermatic door when having pressure in tank.
010: tank body has relief valve port, gauge port, thermometer mouth, vapour inlet, catalyst inlet, sewage draining exit and pumping
Vacuum port.
Certainly, the above description is not a limitation of the present invention, and the present invention is also not limited to the example above, this technology neck
The variations, modifications, additions or substitutions that the technical staff in domain is made within the essential scope of the present invention also should belong to of the invention
Protection scope.
Claims (5)
1. a kind of rubbish hydrolyzed formulas, it is characterized in that: the following steps are included:
Step 1: the organic matter sub-elected is sent into horizontal hydrolytic decomposition pot；
Step 2: dilution heat of sulfuric acid is sprayed on the organic matter sub-elected, so that horizontal hydrolytic decomposition pot is heated to 180 DEG C of high temperature simultaneously same
When the 1.0Mpa that adds high pressure reaction is hydrolyzed；
Step 3: high temperature and high pressure hydrolysis reacts 2 hours；
Step 4: temperature in horizontal hydrolytic decomposition pot is down to 40 DEG C, normal pressure；
Step 5: being then sprayed into biological enzyme agent hydrolyzes the organic matter sub-elected thoroughly and plays solid ammonia.
2. a kind of rubbish hydrolyzed formulas according to claim 1, it is characterized in that: dilution heat of sulfuric acid described in step 2 is dense
Degree is 25%~35%.
3. a kind of rubbish hydrolyzed formulas according to claim 1, it is characterized in that: dilution heat of sulfuric acid described in step 2 with
The fountain height of the organic matter sub-elected is 0.08-0.12L/m3。
4. a kind of rubbish hydrolyzed formulas according to claim 1, it is characterized in that: biological enzyme agent described in step 5
Including 30-40 parts of peptase, 10-16 parts of lipase, 18-22 parts of cellulase, 6-9 parts and water 936-913 parts of ribozyme, it is sufficiently mixed
Generated solution.
5. a kind of rubbish hydrolyzed formulas according to claim 1, it is characterized in that: biological enzyme agent described in step 5
Fountain height with the organic matter sub-elected is 3-5L/m3。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811050419.2A CN109111248A (en) | 2018-09-10 | 2018-09-10 | A kind of rubbish hydrolyzed formulas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811050419.2A CN109111248A (en) | 2018-09-10 | 2018-09-10 | A kind of rubbish hydrolyzed formulas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109111248A true CN109111248A (en) | 2019-01-01 |
Family
ID=64858279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811050419.2A Pending CN109111248A (en) | 2018-09-10 | 2018-09-10 | A kind of rubbish hydrolyzed formulas |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109111248A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070011738A (en) * | 2005-07-21 | 2007-01-25 | 주식회사 바이오제닉 | Food waste handling method using calcium oxide |
| CN101274859A (en) * | 2007-03-30 | 2008-10-01 | 杨计明 | Treating method for organic refuse and special equipment therefor |
| CN102757263A (en) * | 2011-04-28 | 2012-10-31 | 上海季明环保设备有限公司 | Organic garbage disposal method based on special equipment |
| CN104370582A (en) * | 2014-11-04 | 2015-02-25 | 四川联星环保科技有限公司 | Organic garbage odorless aerobic composting method |
| CN108015098A (en) * | 2017-12-27 | 2018-05-11 | 郑州凯山生化工程有限公司 | A kind of domestic garbage resource processing method |
-
2018
- 2018-09-10 CN CN201811050419.2A patent/CN109111248A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070011738A (en) * | 2005-07-21 | 2007-01-25 | 주식회사 바이오제닉 | Food waste handling method using calcium oxide |
| CN101274859A (en) * | 2007-03-30 | 2008-10-01 | 杨计明 | Treating method for organic refuse and special equipment therefor |
| CN102757263A (en) * | 2011-04-28 | 2012-10-31 | 上海季明环保设备有限公司 | Organic garbage disposal method based on special equipment |
| CN104370582A (en) * | 2014-11-04 | 2015-02-25 | 四川联星环保科技有限公司 | Organic garbage odorless aerobic composting method |
| CN108015098A (en) * | 2017-12-27 | 2018-05-11 | 郑州凯山生化工程有限公司 | A kind of domestic garbage resource processing method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101423424B (en) | Liquid bacterial manure production technique by comprehensive utilization of marsh liquid and method thereof | |
| Hashimoto | Pretreatment of wheat straw for fermentation to methane | |
| CN112159824B (en) | Full resource recycling method for livestock manure | |
| CN104357362A (en) | Complex microbial agent for fast decaying straws to produce organic fertilizer as well as preparation method and application | |
| CN114108349A (en) | Bio-based polyurethane coated slow-controlled release fertilizer for pretreating crop straws through steam explosion and preparation method thereof | |
| CN101886144B (en) | Method for preparing reducing sugar by catalyzing biomass hydrolysis with carbon dioxide | |
| CN103966265A (en) | Method for preparing biogas by pretreating manioc waste with NaOH through anaerobic fermentation | |
| CN106929539B (en) | Method for improving biogas yield through combined digestion of cow dung and pretreated corn straws | |
| CN110615704A (en) | Method for preparing biological fertilizer by using dregs of decoction containing fat, saponin and protein | |
| CN109111248A (en) | A kind of rubbish hydrolyzed formulas | |
| Manikandan et al. | Microbial approaches for bioconversion of agro-industrial wastes: A review | |
| CN106636224A (en) | Process for producing ethanol through fermentation of maize straws | |
| Agbogbo | Anaerobic fermentation of rice straw and chicken manure to carboxylic acids | |
| CN106434761A (en) | Method for increasing yield of methane of fermentation system | |
| CN100494094C (en) | Treatment method for radical curing of black liquor of straw pulp from alkaline process | |
| CN105367142B (en) | A kind of preparation method of Water Soluble Organic Carbon | |
| CN108707039A (en) | It is a kind of to utilize residents in rural community fermenting organism organic liquid fertilizer and its method | |
| CN104826855A (en) | Pretreatment method of straws for anaerobic fermentation | |
| JP4886074B2 (en) | Biotreatment saccharification pretreatment method and saccharification method using the pretreatment method | |
| CN112898078A (en) | Process method for producing fulvic acid by fermenting culture waste liquid | |
| CN102816811B (en) | Method for pre-treating biomass by means of microwave dry method or semidry method | |
| Sultanov | UTILIZATION OF AGRICULTURAL WASTE IN THE PRODUCTION OF BIOGAS | |
| Mashi | Comparative study of biogas production from sugarcane bagasse and cow dung | |
| CN100519489C (en) | Method for manufacturing multi-element high-efficiency foliar fertilizer enriched in organic matter | |
| NL2035530B1 (en) | Gas high-efficiency and cyclic ammonia removal apparatus for closed meat product fermentation workshop |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 350001 Fujian Province, Gulou District of Fuzhou City Road 128-1 East 54 Street drum brigade city two 15 storey office building 05 room -03 Applicant after: Fujian pinxing Environmental Protection Technology Co.,Ltd. Address before: 350000 Room 05-03, 15th Floor, Second Stage Office Building of Zhonglu City, 128-1 Wusi Road, Gudong Street, Gulou District, Fuzhou City, Fujian Province Applicant before: FUJIAN DEZHAO RENEWABLE RESOURCES Co.,Ltd. |
|
| CB02 | Change of applicant information | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190101 |
|
| RJ01 | Rejection of invention patent application after publication |