CN109097979A - A kind of aqueous on-slip waxy-feeling treatment agent of use for synthetic leather and preparation method thereof - Google Patents
A kind of aqueous on-slip waxy-feeling treatment agent of use for synthetic leather and preparation method thereof Download PDFInfo
- Publication number
- CN109097979A CN109097979A CN201810614105.4A CN201810614105A CN109097979A CN 109097979 A CN109097979 A CN 109097979A CN 201810614105 A CN201810614105 A CN 201810614105A CN 109097979 A CN109097979 A CN 109097979A
- Authority
- CN
- China
- Prior art keywords
- agent
- weight
- aqueous
- parts
- slip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The present invention provides a kind of aqueous on-slip waxy-feeling treatment agent of use for synthetic leather and preparation method thereof, inorganic agent is made of following raw material: aqueous wax disk(-sc), water, waterborne polyurethane resin, superfine silicon dioxide powder, dispersing agent, levelling agent, defoaming agent, thickener, raw material of the present invention is aqueous, thus different from conventional synthesis leather inorganic agent, which has the advantages that environment-protecting and non-poisonous evil；In addition, the inorganic agent gloss is naturally, and there is special wax sense to be also provided for the glossiness of good surface touch with similar corium while guaranteeing synthetic leather surface anti-slip effect.
Description
Technical field
The present invention relates to a kind of synthetic leather treatment agents, more particularly to a kind of aqueous on-slip waxy-feeling treatment agent of use for synthetic leather
Preparation method.
Background technique
With the development of science and technology, the synthetic leather product such as luggage, footwear, sofa, clothes has become in people's daily life
Indispensable a part.Wherein, gloves for game leather, sofa artificial leather, baseball leather etc. have the anti-slip effect of synthetic leather very high
It is required that although oiliness synthetic leather material this problem of very good solution, however, including dimethyl in oiliness synthetic leather more
The organic solvents such as formamide, toluene, butanone, in direct contact with the skin for a long time, the health of the mankind will be by serious prestige
The side of body.To which the aqueous on-slip synthetic leather product of environment-protecting and non-poisonous evil comes into being.Currently, existing a few studies person proposes aqueous stop
Sliding synthetic leather material, but class is removed from office for sofa artificial leather, baseball leather etc., simple anti-slip effect has been unable to satisfy the demand of people,
While pursuing anti-slip effect, people gradually begin to focus on the surface touch of product.
Summary of the invention
In view of the foregoing deficiencies of prior art, the purpose of the present invention is to provide a kind of Waterborne synthetic leathers of environmental protection to stop
Sliding waxy-feeling treatment agent and preparation method thereof, the inorganic agent are provided simultaneously with on-slip, good surface touch and similar corium gloss
The excellent effect of degree.
In order to achieve the above objects and other related objects, the present invention provides a kind of aqueous on-slip wax sense processing of use for synthetic leather
Agent, the inorganic agent are made of following raw material: wax disk(-sc), waterborne polyurethane resin, silicon dioxide powder, dispersing agent, levelling agent, disappears at water
Infusion, thickener, and all raw materials are aqueous.
Preferably, the parts by weight of the wax disk(-sc) are 15~25, and the parts by weight of the water are 18~25, described aqueous poly-
The parts by weight of urethane resin are 50~60, and the parts by weight of the silica point are 5~10, the parts by weight of the dispersing agent
Number is 0.5~1, and the parts by weight of the levelling agent are 0.2~0.5, and the parts by weight of the defoaming agent are 0.1~0.3, described
The parts by weight of thickener are 0.5~1.
Preferably, the wax disk(-sc) is Brazil wax.
Preferably, the waterborne polyurethane resin is the model of Lanzhou Ke Tian high molecular material Co., Ltd production
The polyurethane resin of KT635F, solid content 40%, the milky white liquid that pH value is 6.5~7.0.
Preferably, the silicon dioxide powder is the superfine silicon dioxide powder of SH100.
Preferably, the aqueous wetting dispersing agent is organosilicon wetting dispersing agent.
It is highly preferred that model AD405, EB-FF or TM311W of the aqueous wetting dispersing agent.
Preferably, the levelling agent is organosilicon levelling agent, model NKS-5323 type levelling agent.
Preferably, the defoaming agent is organic silicon defoamer.
It is highly preferred that it is easy to emulsify in water, and also referred to as self-emulsifying type disappears using Polyether Modified Polysiloxanes Defoaming Agent
Infusion when more than its cloud point temperature, loses the dissolubility and mechanical stability to water, and acid and alkali resistance and inorganic salts, can be used for
Defoaming under harsh conditions.Polyether Modified Polysiloxanes Defoaming Agent is using " Si-O-C type organic silicon modified by polyether defoaming in the present invention
The preparation of agent emulsion and performance study " method in (Wu Rende etc., Tianjin Polytechnic University's journal, the 1st phase of volume 29 in 2010)
It is prepared.
Preferably, the thickener is nonionic polyurethane polymer, and wherein aqueous polyurethane thickener can be preferred
Nonionic polyurethane polymer, thickening efficiency is high, and waterborne polyurethane resin can be made to reach certain viscosity, complied with
The standard needed provides the viscosity within the scope of moderate shear and high shearing, and has excellent levelling, mobility.
It is highly preferred that the thickener is one of PTF, TT935, BYK-425, BYK-428 or BYK-420.
Preferably, the water is tap water.
The present invention also provides a kind of preparation methods of the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather, comprising the following steps:
1) wax disk(-sc) that parts by weight are 15~25 is weighed, the water that parts by weight are 18~25 is added mixing vessel, sufficiently stirs
It mixes to wax disk(-sc) and dissolves；
2) waterborne polyurethane resin that parts by weight are 50~60 is weighed, wax disk(-sc) aqueous solution mixed by step 1) is added,
The silicon dioxide powder that parts by weight are 5~10, the dispersing agent that parts by weight are 0.5~1 are added, parts by weight are 0.2~0.5
Levelling agent, parts by weight be 0.05~0.15 defoaming agent, stir 2~3 hours, mixing speed be 300~400r/min；
3) levelling agent that parts by weight are 0.2~0.5, the defoaming agent that parts by weight are 0.05~0.15, stirring are added
0.5~1 hour, mixing speed was 200~300r/min；
4) mixture prepared by step 3) is filtered, Waterborne synthetic leather on-slip waxy-feeling treatment agent can be obtained.
Preferably, the mesh number of filter screen is 150 mesh.
As described above, aqueous on-slip waxy-feeling treatment agent of use for synthetic leather of the invention and preparation method thereof, has beneficial below
Effect:
1. inorganic agent provided by the invention is not related to any organic solvent, there is the good characteristic of environmental protection, nonhazardous.
2. inorganic agent obtained by the technical program can be applied to a variety of leather classes for having on-slip demand such as sofa artificial leather, baseball leather, only
Cunning works well.
3. inorganic agent obtained by the technical program has good wax sense, surface touch is excellent, while having similar corium
Glossiness.
4. inorganic agent provided by the invention can be applied on existing synthetic leather production line, without changing existing production technology
With equipment, and strong operability, high production efficiency.
Specific embodiment
The present invention is further explained combined with specific embodiments below, it should be appreciated that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.
Illustrate embodiments of the present invention below by way of specific specific example, those skilled in the art can be by this specification
Other advantages and efficacy of the present invention can be easily understood for disclosed content.The present invention can also pass through in addition different specific realities
The mode of applying is embodied or practiced, the various details in this specification can also based on different viewpoints and application, without departing from
Various modifications or alterations are carried out under spirit of the invention.
Each raw material and weight proportion in 1 Examples 1 to 4 of table
Embodiment 1
A kind of preparation of the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather, comprising the following steps:
1) Brazil wax of 5kg is weighed, mixing vessel is added in the tap water of 5kg, is stirred well to wax disk(-sc) dissolution；
2) the KT635F waterborne polyurethane resin that parts by weight are 10kg is weighed, it is water-soluble that wax disk(-sc) mixed by step 1) is added
Liquid adds the organosilicon stream of the dispersant A D405,0.04kg of superfine silicon dioxide powder SH100,0.2kg that parts by weight are 2kg
Flat agent NKS-5323, the Polyether Modified Polysiloxanes Defoaming Agent of 0.01kg stir 2 hours, mixing speed 400r/min；
3) organic silicon modified by polyether of organosilicon levelling thickener TT935,0.01kg that parts by weight are 0.1kg are added
Defoaming agent stirs 0.5 hour, mixing speed 300r/min；
4) mixture prepared by step 3) is filtered, Waterborne synthetic leather on-slip waxy-feeling treatment agent can be obtained.
Embodiment 2
A kind of preparation of the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather, comprising the following steps:
1) Brazil wax of 6.5kg is weighed, the tap water of 6.5kg is added mixing vessel, it is molten to be stirred well to wax disk(-sc)
Solution；
2) the KT635F waterborne polyurethane resin that parts by weight are 13kg is weighed, it is water-soluble that wax disk(-sc) mixed by step 1) is added
Liquid adds the organic of the dispersant A D405,0.05kg of superfine silicon dioxide powder SH100,0.3kg that parts by weight are 2.6kg
The Polyether Modified Polysiloxanes Defoaming Agent of silicon levelling agent NKS-5323,0.015kg stir 2 hours, mixing speed 400r/min；
3) the polyether-modified organic of organosilicon levelling the thickener TT935,0.015kg that parts by weight are 0.15kg is added
Silicon defoaming agent stirs 0.5 hour, mixing speed 200r/min；
4) mixture prepared by step 3) is filtered, Waterborne synthetic leather on-slip waxy-feeling treatment agent can be obtained.
Embodiment 3
A kind of preparation of the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather, comprising the following steps:
1) Brazil wax of 7.5kg is weighed, the tap water of 7.5kg is added mixing vessel, it is molten to be stirred well to wax disk(-sc)
Solution；
2) the KT635F waterborne polyurethane resin that parts by weight are 15kg is weighed, it is water-soluble that wax disk(-sc) mixed by step 1) is added
Liquid adds the organosilicon of the dispersant A D405,0.06kg of superfine silicon dioxide powder SH100,0.4kg that parts by weight are 3kg
The Polyether Modified Polysiloxanes Defoaming Agent of levelling agent NKS-5323,0.02kg stir 2 hours, mixing speed 400r/min；
3) organic silicon modified by polyether of organosilicon levelling thickener TT935,0.02kg that parts by weight are 0.2kg are added
Defoaming agent stirs 0.5 hour, mixing speed 300r/min；
4) mixture prepared by step 3) is filtered, Waterborne synthetic leather on-slip waxy-feeling treatment agent can be obtained.
Embodiment 4
A kind of preparation of the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather, comprising the following steps:
1) Brazil wax of 8.5kg is weighed, the tap water of 8.5kg is added mixing vessel, it is molten to be stirred well to wax disk(-sc)
Solution；
2) the KT635F waterborne polyurethane resin that parts by weight are 18kg is weighed, it is water-soluble that wax disk(-sc) mixed by step 1) is added
Liquid adds the organic of the dispersant A D405,0.07kg of superfine silicon dioxide powder SH100,0.5kg that parts by weight are 3.2kg
The Polyether Modified Polysiloxanes Defoaming Agent of silicon levelling agent NKS-5323,0.025kg stir 2 hours, mixing speed 400r/min；
3) the polyether-modified organic of organosilicon levelling the thickener TT935,0.025kg that parts by weight are 0.25kg is added
Silicon defoaming agent stirs 0.5 hour, mixing speed 300r/min；
4) mixture prepared by step 3) is filtered, Waterborne synthetic leather on-slip waxy-feeling treatment agent can be obtained.
The technical performance index of Waterborne synthetic leather on-slip waxy-feeling treatment agent prepared by above-described embodiment 1~4 is examined
It surveys, testing result is as shown in table 2:
The performance test results of Waterborne synthetic leather on-slip waxy-feeling treatment agent prepared by 2 Examples 1 to 4 of table
From table 2 it can be seen that Waterborne synthetic leather on-slip waxy-feeling treatment agent performance prepared by the present invention is stablized, 6 are stored
Month non-discolouring, no precipitating, viscosity within the scope of 3500~4500 require, stablize, the processing by light yellow viscous liquid, pH value
Agent is provided simultaneously with non-skid property and good surface touch.
Above embodiment is can not to be interpreted as in order to illustrate embodiment disclosed by the invention to limit of the invention
System.In addition, in various modifications and invention listed herein method, composition variation, do not departing from the scope of the present invention
Be obvious for those skilled in the art under the premise of spirit.Although having combined of the invention a variety of specific
Preferred embodiment has carried out specific description to the present invention, it is to be understood that, the present invention should not be limited only to these specific embodiments.
In fact, various obviously modify as described above for those skilled in the art to obtain invention all should include
Within the scope of the invention.
Claims (10)
1. a kind of aqueous on-slip waxy-feeling treatment agent of use for synthetic leather, which is characterized in that be made of following raw material: wax disk(-sc), water, aqueous poly-
Urethane resin, silicon dioxide powder, dispersing agent, levelling agent, defoaming agent, thickener, and above-mentioned all raw materials are aqueous.
2. the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather according to claim 1, it is characterised in that: the weight of the wax disk(-sc)
Number is 15~25, and the parts by weight of the water are 18~25, and the parts by weight of the waterborne polyurethane resin are 50~60, institute
The parts by weight for stating silica point are 5~10, and the parts by weight of the dispersing agent are 0.5~1, the parts by weight of the levelling agent
Number is 0.2~0.5, and the parts by weight of the defoaming agent are 0.1~0.3, and the parts by weight of the thickener are 0.5~1.
3. the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather according to claim 2, it is characterised in that: the wax disk(-sc) is palm
Wax.
4. the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather according to claim 2, it is characterised in that: the aqueous polyurethane
The solid content of resin is 40%, the milky white liquid that pH value is 6.5~7.0.
5. the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather according to claim 2, it is characterised in that: the silicon dioxide powder
For the superfine silicon dioxide powder of SH100.
6. the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather according to claim 2, it is characterised in that: the levelling agent is to have
Machine silicon levelling agent.
7. the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather according to claim 2, it is characterised in that: the defoaming agent is to have
Machine silicon defoaming agent.
8. the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather according to claim 2, it is characterised in that: the thickener is non-
Ionic polyurethanes polymer.
9. the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather according to claim 2, it is characterised in that: the water is originally
Water.
10. a kind of method of the aqueous on-slip waxy-feeling treatment agent of use for synthetic leather prepared as described in claim 1~9, feature exist
In, comprising the following steps:
1) wax disk(-sc) that parts by weight are 15~25 is weighed, the water that parts by weight are 18~25 is added mixing vessel, is stirred well to
Wax disk(-sc) dissolution；
2) weigh parts by weight be 50~60 waterborne polyurethane resin, be added step 1) mixed by wax disk(-sc) aqueous solution, then plus
Enter the silicon dioxide powder that parts by weight are 5~10, the dispersing agent that parts by weight are 0.5~1, the stream that parts by weight are 0.2~0.5
Flat agent, the defoaming agent that parts by weight are 0.05~0.15 stir 2~3 hours, and mixing speed is 300~400r/min；
3) add parts by weight be 0.2~0.5 levelling agent, parts by weight be 0.05~0.15 defoaming agent, stirring 0.5~
1 hour, mixing speed was 200~300r/min；
4) mixture prepared by step 3) is filtered, Waterborne synthetic leather on-slip waxy-feeling treatment agent can be obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810614105.4A CN109097979A (en) | 2018-06-14 | 2018-06-14 | A kind of aqueous on-slip waxy-feeling treatment agent of use for synthetic leather and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810614105.4A CN109097979A (en) | 2018-06-14 | 2018-06-14 | A kind of aqueous on-slip waxy-feeling treatment agent of use for synthetic leather and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109097979A true CN109097979A (en) | 2018-12-28 |
Family
ID=64796822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810614105.4A Pending CN109097979A (en) | 2018-06-14 | 2018-06-14 | A kind of aqueous on-slip waxy-feeling treatment agent of use for synthetic leather and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109097979A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102168377A (en) * | 2010-12-02 | 2011-08-31 | 江苏宝泽高分子材料股份有限公司 | Matt-surface high-permeability moisture acerbity treating agent for synthetic leather and preparation method thereof |
| CN102851982A (en) * | 2011-06-27 | 2013-01-02 | 江苏宝泽高分子材料股份有限公司 | Water-based PU silky waxy-feeling treatment agent for synthetic leather and its preparation method |
| CN105064034A (en) * | 2015-08-04 | 2015-11-18 | 合肥市科天化工有限公司 | Synthetic leather surface conditioning agent |
| CN107524008A (en) * | 2017-09-05 | 2017-12-29 | 江苏宝泽高分子材料股份有限公司 | A kind of puckery waxy-feeling treatment agent of use for synthetic leather cloudy surface and preparation method thereof |
-
2018
- 2018-06-14 CN CN201810614105.4A patent/CN109097979A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102168377A (en) * | 2010-12-02 | 2011-08-31 | 江苏宝泽高分子材料股份有限公司 | Matt-surface high-permeability moisture acerbity treating agent for synthetic leather and preparation method thereof |
| CN102851982A (en) * | 2011-06-27 | 2013-01-02 | 江苏宝泽高分子材料股份有限公司 | Water-based PU silky waxy-feeling treatment agent for synthetic leather and its preparation method |
| CN105064034A (en) * | 2015-08-04 | 2015-11-18 | 合肥市科天化工有限公司 | Synthetic leather surface conditioning agent |
| CN107524008A (en) * | 2017-09-05 | 2017-12-29 | 江苏宝泽高分子材料股份有限公司 | A kind of puckery waxy-feeling treatment agent of use for synthetic leather cloudy surface and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 强涛涛等: "《合成革化学品》", 31 July 2016, 中国轻工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101445695B (en) | High hardness abrasive resistance bi-component waterborne wood lacquer and preparation method thereof | |
| CN103740173B (en) | Ink | |
| CN105064034A (en) | Synthetic leather surface conditioning agent | |
| CN103627279B (en) | Mono-component aqueous elastic finish paint and preparation method thereof | |
| CN102675979A (en) | Water-based ink for water transfer printing and preparation method for water-based ink | |
| CN101508857A (en) | Ammonium stearate emulsion and producing method thereof | |
| CN102702872A (en) | Environment-friendly type aqueous cloud pattern coating | |
| CN107858087A (en) | A kind of high extension aqueous polyurethane water-repellent paint and preparation method | |
| CN102492789B (en) | Leather care agent as well as preparation method and preparation device thereof | |
| CN105316947A (en) | Water-based super-fogging super-blackening treating agent for synthetic leather and preparation method thereof | |
| CN101705622A (en) | Water-based PU Nubuck high-temperature foamex for synthetic leather | |
| CN106366881A (en) | Preparation method of water-based fast dry low VOC alkyd paint | |
| CN106700747B (en) | Single-component waterproof coating material composition and preparation method thereof | |
| CN105504941B (en) | A kind of polyurethane aqueous enamel paint and preparation method thereof, application method | |
| CN109097979A (en) | A kind of aqueous on-slip waxy-feeling treatment agent of use for synthetic leather and preparation method thereof | |
| CN101603273A (en) | Hydraulic PU crazy horse resin for synthetic leather | |
| CN102863885B (en) | Polyurethane resin composition for synthetic leather with discoloration effect and preparation method thereof | |
| CN109181446B (en) | Roller finishing hammer effect water-based transparent coating and preparation method and application thereof | |
| CN101440253A (en) | Environment-friendly aqueous glove coating , and preparation thereof | |
| KR20160149910A (en) | Manufacturing method and Gloves coating compositions using polyurea resins | |
| CN105316948A (en) | Water-based skin-feeling treating agent for synthetic leather and preparation method thereof | |
| CN108403456A (en) | A kind of titanium dioxide composite powder convenient for dispersion | |
| CN109837755A (en) | A kind of matte skin feel treatment agent and preparation method thereof | |
| CN102535174B (en) | Mist-washing bright carbon black treatment agent special used for clothing leather and preparation method thereof | |
| CN108841258A (en) | Environmental Protective Water-paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181228 |
|
| RJ01 | Rejection of invention patent application after publication |