CN109096697A - A kind of glass reinforced plastic elbow die processing technology - Google Patents

A kind of glass reinforced plastic elbow die processing technology Download PDF

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Publication number
CN109096697A
CN109096697A CN201810310057.XA CN201810310057A CN109096697A CN 109096697 A CN109096697 A CN 109096697A CN 201810310057 A CN201810310057 A CN 201810310057A CN 109096697 A CN109096697 A CN 109096697A
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CN
China
Prior art keywords
parts
adhesive
reinforced plastic
glass reinforced
glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810310057.XA
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Chinese (zh)
Inventor
周建军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Drayson Composites Co Ltd
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Nantong Drayson Composites Co Ltd
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Priority to CN201810310057.XA priority Critical patent/CN109096697A/en
Publication of CN109096697A publication Critical patent/CN109096697A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • B29L2023/004Bent tubes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Abstract

The invention discloses a kind of glass reinforced plastic elbow die processing technology, step 1: stirs and adhesive A is made;Step 2: it stirs and adhesive B is made;Step 3: mould tire surface is cleaned out, then sprays silane coupling agent on its surface;Step 4: granite fibers cloth is set to by mould tire surface by adhesive A;Step 5: being overlying on granite fibers cloth by adhesive B by glass fabric is flat, the adhesive coating B finished product again on glass fabric;Step 6: passing through isothermal reaction for finished product, after curing molding, obtain glass reinforced plastic elbow die, and the invention processing technology is simple, and intensity is high, and abrasion-resistant surface is good, and corrosion resistance and high temperature resistance are excellent, substantially prolongs service life.

Description

A kind of glass reinforced plastic elbow die processing technology
Technical field
The present invention relates to fiber reinforced plastic mold technical field, specially a kind of glass reinforced plastic elbow die processing technology.
Background technique
Mold makes blank become the tool for having the product of specific shape and size under external force.Be widely used in punching, The compression moulding of the products such as die forging, cold-heading, extruding, metallic sintered products compacting, compression casting and engineering plastics, rubber, ceramics or note In the forming of modeling.Mold has specific profile or cavity shape, can make blank using the chamfered shape with cutting edge Separation (punching) occurs by profile wire shaped.
Mold used at present, intensity is low, wear resistence is poor, it would therefore be highly desirable to which a kind of improved technology is existing to solve This problem in the presence of technology.
Summary of the invention
The purpose of the present invention is to provide a kind of glass reinforced plastic elbow die processing technologys, and intensity is high, and abrasion-resistant surface is good, resistance to Corrosive nature and high temperature resistance are excellent, substantially prolong service life, to solve the problems mentioned in the above background technology.
To achieve the above object, the invention provides the following technical scheme: a kind of glass reinforced plastic elbow die processing technology, including Following steps:.
Step 1: by A40-50 parts of epoxy resin, 3-5 parts of white carbon black, 3-6 parts of magnesia, 7-9 parts of tetrabutyl ammonium fluoride, 1-3 parts of addition blenders of dinonyl phthalate are stirred, and obtain adhesive A, for use;
Step 2: by B45-55 parts of epoxy resin, 14-18 parts of boron oxide, 3-6 parts of lithium slag, 1-3 parts of cyanurate melamine ester, 3-6 parts of 1-3 parts of 3- propantheline bromide hydrobromide, fire retardant addition blenders are stirred, and obtain adhesive B, for use;
Step 3: mould tire surface is cleaned out, then sprays distilled water on mould tire surface, after being sufficiently humidified so as to, then in the sprinkling of its surface 10-20 parts of silane coupling agent;
Step 4: by mould tire surface coated with adhesive A, waiting for 5-10min quietly, and granite fibers cloth is put down and is overlayed on adhesive A;
Step 5: the adhesive coating B on granite fibers cloth, then put down again on adhesive B and cover glass fabric, finally in glass Adhesive coating B again in glass fiber cloth, finished product;
Step 6: finished product is passed through into 80 DEG C of constant temperature of 3-4 hour, resin is reacted completely in 80 DEG C of constant temperature, is solidified into After type, glass reinforced plastic elbow die is both obtained.
Preferably, silane coupling agent is isobutyl ethyl triethoxy silicane.
Preferably, fire retardant is antimony oxide.
Compared with prior art, the beneficial effects of the present invention are:
Intensity is high, and abrasion-resistant surface is good, and corrosion resistance and high temperature resistance are excellent, substantially prolongs service life.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
The present invention provides a kind of technical solution: a kind of glass reinforced plastic elbow die processing technology, comprising the following steps:.
Step 1: by A40-50 parts of epoxy resin, 3-5 parts of white carbon black, 3-6 parts of magnesia, 7-9 parts of tetrabutyl ammonium fluoride, 1-3 parts of addition blenders of dinonyl phthalate are stirred, and obtain adhesive A, for use;
Step 2: by B45-55 parts of epoxy resin, 14-18 parts of boron oxide, 3-6 parts of lithium slag, 1-3 parts of cyanurate melamine ester, 3-6 parts of 1-3 parts of 3- propantheline bromide hydrobromide, fire retardant addition blenders are stirred, and obtain adhesive B, for use;
Step 3: mould tire surface is cleaned out, then sprays distilled water on mould tire surface, after being sufficiently humidified so as to, then in the sprinkling of its surface 10-20 parts of silane coupling agent;
Step 4: by mould tire surface coated with adhesive A, waiting for 5-10min quietly, and granite fibers cloth is put down and is overlayed on adhesive A;
Step 5: the adhesive coating B on granite fibers cloth, then put down again on adhesive B and cover glass fabric, finally in glass Adhesive coating B again in glass fiber cloth, finished product;
Step 6: finished product is passed through into 80 DEG C of constant temperature of 3-4 hour, resin is reacted completely in 80 DEG C of constant temperature, is solidified into After type, glass reinforced plastic elbow die is both obtained.
Embodiment one:
One the present embodiment processing technology, comprising the following steps:
Step 1: by A40 parts of epoxy resin, 3 parts of white carbon black, 3 parts of magnesia, 7 parts of tetrabutyl ammonium fluoride, two nonyl of phthalic acid 1 part of addition blender of ester is stirred, and obtains adhesive A, for use;
Step 2: by B45 parts of epoxy resin, 14 parts of boron oxide, 3 parts of lithium slag, 1 part of cyanurate melamine ester, 3- bromine propylamine hydrogen 3 parts of 1 part of bromate, fire retardant addition blenders are stirred, and obtain adhesive B, for use;
Step 3: mould tire surface is cleaned out, then sprays distilled water on mould tire surface, after being sufficiently humidified so as to, then in the sprinkling of its surface 10 parts of silane coupling agent;
Step 4: by mould tire surface coated with adhesive A, waiting for 8min quietly, and granite fibers cloth is put down and is overlayed on adhesive A;
Step 5: the adhesive coating B on granite fibers cloth, then put down again on adhesive B and cover glass fabric, finally in glass Adhesive coating B again in glass fiber cloth, finished product;
Step 6: finished product is passed through into 3.5 hours, 80 DEG C of constant temperature, resin is reacted completely in 80 DEG C of constant temperature, is solidified into After type, glass reinforced plastic elbow die is both obtained.
Embodiment two:
The present embodiment processing technology, comprising the following steps:
Step 1: by A52 parts of epoxy resin, 3 parts of white carbon black, 3 parts of magnesia, 7 parts of tetrabutyl ammonium fluoride, two nonyl of phthalic acid 1 part of addition blender of ester is stirred, and obtains adhesive A, for use;
Step 2: by B47 parts of epoxy resin, 14 parts of boron oxide, 3 parts of lithium slag, 3 parts of cyanurate melamine ester, 3- bromine propylamine hydrogen 4 parts of 1 part of bromate, fire retardant addition blenders are stirred, and obtain adhesive B, for use;
Step 3: mould tire surface is cleaned out, then sprays distilled water on mould tire surface, after being sufficiently humidified so as to, then in the sprinkling of its surface 12 parts of silane coupling agent;
Step 4: by mould tire surface coated with adhesive A, waiting for 8min quietly, and granite fibers cloth is put down and is overlayed on adhesive A;
Step 5: the adhesive coating B on granite fibers cloth, then put down again on adhesive B and cover glass fabric, finally in glass Adhesive coating B again in glass fiber cloth, finished product;
Step 6: finished product is passed through into 3.5 hours, 80 DEG C of constant temperature, resin is reacted completely in 80 DEG C of constant temperature, is solidified into After type, glass reinforced plastic elbow die is both obtained.
By Experimental Comparison, glass reinforced plastic elbow die made from embodiment two is than fiberglass elbow mould made from embodiment one Have intensity and wear resistance is good.
Embodiment three:
The present embodiment processing technology, comprising the following steps:
Step 1: by A45 parts of epoxy resin, 4 parts of white carbon black, 4 parts of magnesia, 8 parts of tetrabutyl ammonium fluoride, two nonyl of phthalic acid 2 parts of addition blenders of ester are stirred, and obtain adhesive A, for use;
Step 2: by B50 parts of epoxy resin, 16 parts of boron oxide, 5 parts of lithium slag, 2 parts of cyanurate melamine ester, 3- bromine propylamine hydrogen 5 parts of 2 parts of bromate, fire retardant addition blenders are stirred, and obtain adhesive B, for use;
Step 3: mould tire surface is cleaned out, then sprays distilled water on mould tire surface, after being sufficiently humidified so as to, then in the sprinkling of its surface 15 parts of silane coupling agent;
Step 4: by mould tire surface coated with adhesive A, waiting for 8min quietly, and granite fibers cloth is put down and is overlayed on adhesive A;
Step 5: the adhesive coating B on granite fibers cloth, then put down again on adhesive B and cover glass fabric, finally in glass Adhesive coating B again in glass fiber cloth, finished product;
Step 6: finished product is passed through into 3.5 hours, 80 DEG C of constant temperature, resin is reacted completely in 80 DEG C of constant temperature, is solidified into After type, glass reinforced plastic elbow die is both obtained.
Overtesting compares, and glass reinforced plastic elbow die made from embodiment three is than glass reinforced plastic elbow die made from embodiment two Pipe intensity and wear resistance are good
Example IV:
The present embodiment processing technology, comprising the following steps:
Step 1: by A45 parts of epoxy resin, 4 parts of white carbon black, 5 parts of magnesia, 8 parts of tetrabutyl ammonium fluoride, two nonyl of phthalic acid 2 parts of addition blenders of ester are stirred, and obtain adhesive A, for use;
Step 2: by B45 parts of epoxy resin, 16 parts of boron oxide, 5 parts of lithium slag, 2 parts of cyanurate melamine ester, 3- bromine propylamine hydrogen 4 parts of 2 parts of bromate, fire retardant addition blenders are stirred, and obtain adhesive B, for use;
Step 3: mould tire surface is cleaned out, then sprays distilled water on mould tire surface, after being sufficiently humidified so as to, then in the sprinkling of its surface 15 parts of silane coupling agent;
Step 4: by mould tire surface coated with adhesive A, waiting for 8min quietly, and granite fibers cloth is put down and is overlayed on adhesive A;
Step 5: the adhesive coating B on granite fibers cloth, then put down again on adhesive B and cover glass fabric, finally in glass Adhesive coating B again in glass fiber cloth, finished product;
Step 6: finished product is passed through into 3.5 hours, 80 DEG C of constant temperature, resin is reacted completely in 80 DEG C of constant temperature, is solidified into After type, glass reinforced plastic elbow die is both obtained.
Overtesting compares, and glass reinforced plastic elbow die made from example IV is than glass reinforced plastic elbow die made from embodiment three Intensity and wear resistance are good.
Embodiment five:
The present embodiment processing technology, comprising the following steps:
Step 1: by A50 parts of epoxy resin, 5 parts of white carbon black, 6 parts of magnesia, 9 parts of tetrabutyl ammonium fluoride, two nonyl of phthalic acid 3 parts of addition blenders of ester are stirred, and obtain adhesive A, for use;
Step 2: by B55 parts of epoxy resin, 18 parts of boron oxide, 6 parts of lithium slag, 3 parts of cyanurate melamine ester, 3- bromine propylamine hydrogen 6 parts of 3 parts of bromate, fire retardant addition blenders are stirred, and obtain adhesive B, for use;
Step 3: mould tire surface is cleaned out, then sprays distilled water on mould tire surface, after being sufficiently humidified so as to, then in the sprinkling of its surface 20 parts of silane coupling agent;
Step 4: by mould tire surface coated with adhesive A, waiting for 8min quietly, and granite fibers cloth is put down and is overlayed on adhesive A;
Step 5: the adhesive coating B on granite fibers cloth, then put down again on adhesive B and cover glass fabric, finally in glass Adhesive coating B again in glass fiber cloth, finished product;
Step 6: finished product is passed through into 3.5 hours, 80 DEG C of constant temperature, resin is reacted completely in 80 DEG C of constant temperature, is solidified into After type, glass reinforced plastic elbow die is both obtained.
Overtesting compares, and glass reinforced plastic elbow die made from example IV is than glass reinforced plastic elbow die made from embodiment five Intensity and wear resistance are good.
Glass reinforced plastic elbow die made from various embodiments of the present invention is subjected to resistance to compression and wear-resistant experiment, after comparison It obtains, the glass reinforced plastic elbow die of example IV preparation can reach optimum performance.
Flame resistant glass steel pipe made from various embodiments of the present invention is subjected to calcination experiment, is obtained after comparison, is implemented Flame resistant glass steel pipe prepared by example four can reach optimum performance
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, it is possible to understand that These embodiments can be carried out with a variety of variations, modification, replacement without departing from the principles and spirit of the present invention and become Type, the scope of the present invention is defined by the appended.

Claims (4)

1. a kind of glass reinforced plastic elbow die processing technology, it is characterised in that: the following steps are included:.
2. step 1: by A40-50 parts of epoxy resin, 3-5 parts of white carbon black, 3-6 parts of magnesia, 7-9 parts of tetrabutyl ammonium fluoride, neighbour Phthalic acid 1-3 parts of addition blenders of two nonyl esters are stirred, and obtain adhesive A, for use;
Step 2: by B45-55 parts of epoxy resin, 14-18 parts of boron oxide, 3-6 parts of lithium slag, 1-3 parts of cyanurate melamine ester, 3-6 parts of 1-3 parts of 3- propantheline bromide hydrobromide, fire retardant addition blenders are stirred, and obtain adhesive B, for use;
Step 3: mould tire surface is cleaned out, then sprays distilled water on mould tire surface, after being sufficiently humidified so as to, then in the sprinkling of its surface 10-20 parts of silane coupling agent;
Step 4: by mould tire surface coated with adhesive A, waiting for 5-10min quietly, and granite fibers cloth is put down and is overlayed on adhesive A;
Step 5: the adhesive coating B on granite fibers cloth, then put down again on adhesive B and cover glass fabric, finally in glass Adhesive coating B again in glass fiber cloth, finished product;
Step 6: finished product is passed through into 80 DEG C of constant temperature of 3-4 hour, resin is reacted completely in 80 DEG C of constant temperature, is solidified into After type, glass reinforced plastic elbow die is both obtained.
3. a kind of glass reinforced plastic elbow die according to claim 1, it is characterised in that: fire retardant described in step 2 is three Aoxidize two antimony.
4. a kind of glass reinforced plastic elbow die according to claim 1, it is characterised in that: silane coupling agent described in step 3 For isobutyl ethyl triethoxy silicane.
CN201810310057.XA 2018-04-09 2018-04-09 A kind of glass reinforced plastic elbow die processing technology Pending CN109096697A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109989371A (en) * 2019-03-29 2019-07-09 河南安赛机制玻璃钢实业有限公司 A kind of glass reinforced plastic angle block of right angle and its processing technology and particular manufacturing craft

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102683849A (en) * 2012-05-02 2012-09-19 深圳光启创新技术有限公司 Glass fiber reinforced plastic antenna cover and preparation method thereof
CN103286957A (en) * 2012-03-02 2013-09-11 深圳光启创新技术有限公司 Preparation method of glass-reinforced plastic, and glass-reinforced plastic antenna housing and preparation method thereof
CN104725779A (en) * 2015-02-09 2015-06-24 江苏旭日新能源科技发展有限公司 Glass fiber reinforced plastic
CN107696352A (en) * 2017-11-18 2018-02-16 蚌埠市华鼎机械科技有限公司 A kind of preparation method of fiber reinforced plastic mold

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103286957A (en) * 2012-03-02 2013-09-11 深圳光启创新技术有限公司 Preparation method of glass-reinforced plastic, and glass-reinforced plastic antenna housing and preparation method thereof
CN102683849A (en) * 2012-05-02 2012-09-19 深圳光启创新技术有限公司 Glass fiber reinforced plastic antenna cover and preparation method thereof
CN104725779A (en) * 2015-02-09 2015-06-24 江苏旭日新能源科技发展有限公司 Glass fiber reinforced plastic
CN107696352A (en) * 2017-11-18 2018-02-16 蚌埠市华鼎机械科技有限公司 A kind of preparation method of fiber reinforced plastic mold

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109989371A (en) * 2019-03-29 2019-07-09 河南安赛机制玻璃钢实业有限公司 A kind of glass reinforced plastic angle block of right angle and its processing technology and particular manufacturing craft

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Application publication date: 20181228