CN109090733A - A kind of production method of anti-stab flame retardant special clothes - Google Patents

A kind of production method of anti-stab flame retardant special clothes Download PDF

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Publication number
CN109090733A
CN109090733A CN201810870657.1A CN201810870657A CN109090733A CN 109090733 A CN109090733 A CN 109090733A CN 201810870657 A CN201810870657 A CN 201810870657A CN 109090733 A CN109090733 A CN 109090733A
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China
Prior art keywords
clothes
stab
flame
flame retardant
fabric
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CN109090733B (en
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尚军
李峻
郭雪健
王柯钦
段净尘
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Xinxiang Xinke Protection Technology Co Ltd
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Xinxiang Xinke Protection Technology Co Ltd
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B17/00Protective clothing affording protection against heat or harmful chemical agents or for use at high altitudes
    • A62B17/003Fire-resistant or fire-fighters' clothes
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B17/00Protective clothing affording protection against heat or harmful chemical agents or for use at high altitudes
    • A62B17/006Protective clothing affording protection against heat or harmful chemical agents or for use at high altitudes against contamination from chemicals, toxic or hostile environments; ABC suits

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  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)

Abstract

The present invention provides a kind of production method of anti-stab flame retardant special clothes, it is related to clothes preparation field, the preparation of preparation, Anti-prick clothes fabric including flame-retardant garment plus material, fabric processing, by raw material, optimizing raw material and preparation process, so that being finally reached anti-stab, fire-retardant effect, and light material is selected, increases anti-stab fire retardancy while reducing clothes weight to greatest extent.

Description

A kind of production method of anti-stab flame retardant special clothes
Technical field
The present invention relates to clothes preparation fields, and in particular to a kind of production method of anti-stab flame retardant special clothes.
Background technique
High-performance apparel refers to that those have a clothes of specific function or specific use, and when work has the occasion of particular/special requirement to make With, such as acid-proof clothes, fireproof garment, oil resistant water repellent clothes, antistatic clothing, flame-retardant clothing, welding protective garment, arc protection clothes etc., modern society It can be the civilized society of a high speed development, but still be no lack of the generation of incident of violence or accident in social life, Certain specific occupations generally require professional people in the work of burning location or the prestige at certain moment needing to face sharp instrument or impact force The side of body, high-performance apparel require the performance that there is good protection flame retardant property and protecting against shock to puncture.
Currently, to achieve the purpose that for high-performance apparel anti-stab, fire-retardant, it is overweight often to will cause apparel quality, and wearing is not Just the case where, wearing can cause the discomfort of user of service for a long time.Traditional fire-entry suit has a single function, cannot be preferably to current Fire-fighting and rescue operation high-quality guarantee is provided.
Summary of the invention
The present invention in view of the deficiencies of the prior art, the present invention provides a kind of production method of anti-stab flame retardant special clothes, There is flame retarding function while anti-stab, and select light material, increase while reducing clothes weight to greatest extent Anti-stab fire retardancy, while the problem of solve existing fire-entry suit and have a single function, be unable to effective protection fireman's personal safety.
To solve the above-mentioned problems, the present invention provides a kind of technical solutions: a kind of production of anti-stab flame retardant special clothes Method, comprising the following steps:
(1) polystyrene the preparation of flame-retardant garment plus material: is put into several reaction kettles once heating simultaneously until in melting State, is separately added into after the nanometer Zirconia of equivalent secondary temperature elevation and is stirred continuously until and be uniformly dispersed, will from osculum extruding and discharging One end of material is connect with braider, and drier is arranged between discharge port and braider, by shaft rotate pull raw material at Silk molding, while being woven to get flame-retardant garment plus material is arrived;
(2) preparation of Anti-prick clothes fabric: with aramid fiber-High molecular weight polyethylene-aramid fiber three-decker parallel Cloth, and immerse in resin, premix is formed, premix is overlapped by different directions, catalytic curing agent is added in resin, solidifies Anti-prick clothes fabric is obtained afterwards;
(3) fabric is handled: according to clothes template, being modified cutting to flame-retardant garment plus material and Anti-prick clothes fabric, then by outer To the inner flame-retardant clothing completed according to Anti-prick clothes fabric-flame-retardant garment plus material-Anti-prick clothes fabric three-layer arrangement structure to cutting Fill fabric, Anti-prick clothes fabric carries out close sewer to get anti-stab flame retardant special clothing semi product is arrived, by SiC semi-molten raw material The outer surface that anti-stab flame retardant special clothing semi product is deposited to by plasma spray technology obtains anti-stab after cooling completely is fixed Flame retardant special clothes.
Preferably, the partial size of nanometer Zirconia described in step (1) is less than 40nm.
Preferably, once heating is is warming up to 240-250 DEG C with the rate of 20 DEG C/min described in step (1), and described two Secondary heating is warming up to 260-265 DEG C with the rate of 10 DEG C/min.
Preferably, the mass ratio of polystyrene described in step (1) and the nanometer Zirconia is 10-12:1.
Preferably, catalytic curing agent described in step (2) is tertiary amine, imidazoles, any one in boron trifluoride complex.
Preferably, resin described in step (2) is polyurethane, in rubber, sarin resin, epoxy resin, phenolic resin Any one.
The present invention provides a kind of production methods of anti-stab flame retardant special clothes, have the advantages that
Mixing is carried out firstly, selecting and nanometer Zirconia being added in polystyrene, and further limits the particle size of nanometer Zirconia, It is uniformly dispersed in polymer material by Nanometer ZrO2 particle, so that polymer molecule is bound in inorganic interlayer, is reduced The rotation and translation of molecular weight, and then increase polystyrene fire retardancy, secondly, being original with High molecular weight polyethylene and aramid fiber Material is superimposed by three layers, by improving the tightness and intensity of tissue, to improve the anti-shear performance of high-performance apparel, finally It is coated with SiC on high-performance apparel surface, is cooperated jointly with antipricking layer, flame-retardant layer, while improving anti-stab macro energy, increases clothes table The corrosion resistance in face.Fire-entry suit prepared by the anti-stab flame retardant special garment material of the present invention, has vdiverse in function, security performance High advantage.
Detailed description of the invention
Detailed description will be given by the following detailed implementation and drawings by the present invention for ease of explanation,.
Fig. 1 is the overall structure diagram of fire-entry suit in embodiment;
Fig. 2 is the cramp structure schematic diagram of fire-entry suit in embodiment;
Fig. 3 is the elbow support part structural schematic diagram of fire-entry suit in embodiment;
Fig. 4 is the elbow support part schematic diagram of internal structure of fire-entry suit in embodiment;
Fig. 5 is the fixing buckle structural schematic diagram of fire-entry suit in embodiment;
Fig. 6 is the main surface material structure schematic diagram of fire-entry suit in embodiment;
Fig. 7 is the inserting slot construction schematic diagram of fire-entry suit in embodiment;
Fig. 8 is the first V-type buckle structure schematic diagram of fire-entry suit in embodiment;
Fig. 9 is the dry powder can structural schematic diagram of fire-entry suit in embodiment;
Figure 10 is the drop cloth deployed configuration schematic diagram of fire-entry suit in embodiment;
Figure 11 is the front portion structural schematic diagram of fire-entry suit in embodiment;
Figure 12 is the negative pressure inflatable chamber schematic diagram of internal structure of fire-entry suit in embodiment.
In figure: 1, ontology;2, main surface material;3, neck;4, neck drop cloth;5, drop cloth;6, cloth is connected;7, magic is pasted;8, Magic fishing without hook;9, clasp nail;10, bottom cover;11, contact lid;12, connecting rod;13, ball is followed closely;14, Button Block;15, scapulet;16, elbow support Part;17, elbow support steel ring;18, upper connection sheet;19, lower connection sheet;20, fixed block;21, limit spring;22, fixing buckle;23, solid Determine sole piece;24, half arc-shaped workpiece;25, round hole;26, vertical bar;27, cross bar;28, slot;29, torsion spring presss;30, rotatable lamella;31, Block;32, square duct;33, the first V-type button;34, connecting band;35, dry powder can;36, arc panel;37, it links up with;38, the 2nd V Type is buckled;39, flour extraction pipe;40, regulating valve;41, oversleeve;42, plug-in unit is connected;43, negative pressure inflatable chamber;44, touch panel;45, slide bar; 46, link block;47, hollow cavity;48, head is pressed;49, sliding bar;50, spring;51, L-type link block;52, connected slot.
Specific embodiment
Embodiment 1:
A kind of production method of anti-stab flame retardant special clothes, comprising the following steps:
(1) polystyrene the preparation of flame-retardant garment plus material: is put into the rate one in several reaction kettles with 20 DEG C/min simultaneously It is secondary to be warming up to 240 DEG C, until being in molten condition, it is separately added into the rate secondary temperature elevation after the nanometer Zirconia of equivalent with 10 DEG C/min It to 265 DEG C and is stirred continuously until and is uniformly dispersed, the mass ratio for controlling polystyrene and nanometer Zirconia is 10:1, is squeezed from osculum Discharging, one end of material is connect with braider, drier is arranged between discharge port and braider, is rotated and is pulled by shaft Raw material is formed at silk, while being woven to get flame-retardant garment plus material is arrived;
(2) preparation of Anti-prick clothes fabric: with aramid fiber-High molecular weight polyethylene-aramid fiber three-decker parallel Cloth, and immerse in polyurethane, premix is formed, premix is overlapped by different directions, tertiary amine is added in resin, after solidification i.e. Obtain Anti-prick clothes fabric;
(3) fabric is handled: according to clothes template, being modified cutting to flame-retardant garment plus material and Anti-prick clothes fabric, then by outer To the inner flame-retardant clothing completed according to Anti-prick clothes fabric-flame-retardant garment plus material-Anti-prick clothes fabric three-layer arrangement structure to cutting Fill fabric, Anti-prick clothes fabric carries out close sewer to get anti-stab flame retardant special clothing semi product is arrived, by SiC semi-molten raw material The outer surface that anti-stab flame retardant special clothing semi product is deposited to by plasma spray technology obtains anti-stab after cooling completely is fixed Flame retardant special clothes.
Embodiment 2:
A kind of production method of anti-stab flame retardant special clothes, comprising the following steps:
(1) polystyrene the preparation of flame-retardant garment plus material: is put into the rate one in several reaction kettles with 20 DEG C/min simultaneously It is secondary to be warming up to 250 DEG C, until being in molten condition, it is separately added into the rate secondary temperature elevation after the nanometer Zirconia of equivalent with 10 DEG C/min It to 260 DEG C and is stirred continuously until and is uniformly dispersed, the mass ratio for controlling polystyrene and nanometer Zirconia is 12:1, is squeezed from osculum Discharging, one end of material is connect with braider, drier is arranged between discharge port and braider, is rotated and is pulled by shaft Raw material is formed at silk, while being woven to get flame-retardant garment plus material is arrived;
(2) preparation of Anti-prick clothes fabric: with aramid fiber-High molecular weight polyethylene-aramid fiber three-decker parallel Cloth, and soak in rubber, premix is formed, premix is overlapped by different directions, imidazoles is added in resin, is prevented after solidification Pierce garment material;
(3) fabric is handled: according to clothes template, being modified cutting to flame-retardant garment plus material and Anti-prick clothes fabric, then by outer To the inner flame-retardant clothing completed according to Anti-prick clothes fabric-flame-retardant garment plus material-Anti-prick clothes fabric three-layer arrangement structure to cutting Fill fabric, Anti-prick clothes fabric carries out close sewer to get anti-stab flame retardant special clothing semi product is arrived, by SiC semi-molten raw material The outer surface that anti-stab flame retardant special clothing semi product is deposited to by plasma spray technology obtains anti-stab after cooling completely is fixed Flame retardant special clothes.
Embodiment 3:
A kind of production method of anti-stab flame retardant special clothes, comprising the following steps:
(1) polystyrene the preparation of flame-retardant garment plus material: is put into the rate one in several reaction kettles with 20 DEG C/min simultaneously It is secondary to be warming up to 245 DEG C, until being in molten condition, it is separately added into the rate secondary temperature elevation after the nanometer Zirconia of equivalent with 10 DEG C/min It to 262 DEG C and is stirred continuously until and is uniformly dispersed, the mass ratio for controlling polystyrene and nanometer Zirconia is 11:1, is squeezed from osculum Discharging, one end of material is connect with braider, drier is arranged between discharge port and braider, is rotated and is pulled by shaft Raw material is formed at silk, while being woven to get flame-retardant garment plus material is arrived;
(2) preparation of Anti-prick clothes fabric: with aramid fiber-High molecular weight polyethylene-aramid fiber three-decker parallel Cloth, and immerse in sarin resin, premix is formed, premix is overlapped by different directions, boron trifluoride network is added in resin Object is closed, Anti-prick clothes fabric is obtained after solidification;
(3) fabric is handled: according to clothes template, being modified cutting to flame-retardant garment plus material and Anti-prick clothes fabric, then by outer To the inner flame-retardant clothing completed according to Anti-prick clothes fabric-flame-retardant garment plus material-Anti-prick clothes fabric three-layer arrangement structure to cutting Fill fabric, Anti-prick clothes fabric carries out close sewer to get anti-stab flame retardant special clothing semi product is arrived, by SiC semi-molten raw material The outer surface that anti-stab flame retardant special clothing semi product is deposited to by plasma spray technology obtains anti-stab after cooling completely is fixed Flame retardant special clothes.
Embodiment 4:
A kind of production method of anti-stab flame retardant special clothes, comprising the following steps:
(1) polystyrene the preparation of flame-retardant garment plus material: is put into the rate one in several reaction kettles with 20 DEG C/min simultaneously It is secondary to be warming up to 248 DEG C, until being in molten condition, it is separately added into the rate secondary temperature elevation after the nanometer Zirconia of equivalent with 10 DEG C/min It to 264 DEG C and is stirred continuously until and is uniformly dispersed, the mass ratio for controlling polystyrene and nanometer Zirconia is 11:1, is squeezed from osculum Discharging, one end of material is connect with braider, drier is arranged between discharge port and braider, is rotated and is pulled by shaft Raw material is formed at silk, while being woven to get flame-retardant garment plus material is arrived;
(2) preparation of Anti-prick clothes fabric: with aramid fiber-High molecular weight polyethylene-aramid fiber three-decker parallel Cloth, and immerse in epoxy resin, premix is formed, premix is overlapped by different directions, boron trifluoride network is added in resin Object is closed, Anti-prick clothes fabric is obtained after solidification;
(3) fabric is handled: according to clothes template, being modified cutting to flame-retardant garment plus material and Anti-prick clothes fabric, then by outer To the inner flame-retardant clothing completed according to Anti-prick clothes fabric-flame-retardant garment plus material-Anti-prick clothes fabric three-layer arrangement structure to cutting Fill fabric, Anti-prick clothes fabric carries out close sewer to get anti-stab flame retardant special clothing semi product is arrived, by SiC semi-molten raw material The outer surface that anti-stab flame retardant special clothing semi product is deposited to by plasma spray technology obtains anti-stab after cooling completely is fixed Flame retardant special clothes.
Embodiment 5:
A kind of production method of anti-stab flame retardant special clothes, comprising the following steps:
(1) polystyrene the preparation of flame-retardant garment plus material: is put into the rate one in several reaction kettles with 20 DEG C/min simultaneously It is secondary to be warming up to 246 DEG C, until being in molten condition, it is separately added into the rate secondary temperature elevation after the nanometer Zirconia of equivalent with 10 DEG C/min It to 262 DEG C and is stirred continuously until and is uniformly dispersed, the mass ratio for controlling polystyrene and nanometer Zirconia is 10:1, is squeezed from osculum Discharging, one end of material is connect with braider, drier is arranged between discharge port and braider, is rotated and is pulled by shaft Raw material is formed at silk, while being woven to get flame-retardant garment plus material is arrived;
(2) preparation of Anti-prick clothes fabric: with aramid fiber-High molecular weight polyethylene-aramid fiber three-decker parallel Cloth, and immerse in phenolic resin, premix is formed, premix is overlapped by different directions, boron trifluoride network is added in resin Object is closed, Anti-prick clothes fabric is obtained after solidification;
(3) fabric is handled: according to clothes template, being modified cutting to flame-retardant garment plus material and Anti-prick clothes fabric, then by outer To the inner flame-retardant clothing completed according to Anti-prick clothes fabric-flame-retardant garment plus material-Anti-prick clothes fabric three-layer arrangement structure to cutting Fill fabric, Anti-prick clothes fabric carries out close sewer to get anti-stab flame retardant special clothing semi product is arrived, by SiC semi-molten raw material The outer surface that anti-stab flame retardant special clothing semi product is deposited to by plasma spray technology obtains anti-stab after cooling completely is fixed Flame retardant special clothes.
Beneficial effect in order to further illustrate the present invention selects anti-stab fire-retardant spy made by 1-5 of the embodiment of the present invention Kind clothes, carrying out cardiac position, locally the vertical combustion (UL-94) of puncture experiment and internal ignition resistant garment material is tested, wherein hanging down Direct combustion is burnt in (UL-94) test, and t1 is that the burning time of point then, t2 are second point of burning time then, t1+ for the first time T2 is total burning time, and experimental result is recorded in following table.
Using fire-entry suit prepared by anti-stab flame retardant special garment material, as shown in figs. 1-12, including ontology 1, described Body 1 includes main surface material 2, neck 3, drop cloth 5, connection cloth 6, clasp nail 9, Button Block 14, scapulet 15, elbow support part 16, fixing buckle 22, slot 28, square duct 32, dry powder can 35, flour extraction pipe 39, negative pressure inflatable chamber 43 and touch panel 44,2 upper end of main surface material are fixedly connected Neck 3, the neck side are fixedly connected with neck drop cloth 4, and 2 side of main surface material is fixedly connected with drop cloth 5, the main surface material 2 Side is equipped with connection cloth 6, and 5 side of drop cloth is fixedly connected with evil spirit close to the edge of 4 side of edge and neck drop cloth Art pastes 7, and 6 side of connection cloth is fixedly connected with magic fishing without hook 8 at 3 one side edge of edge and neck, 7 and the connection of magic fishing without hook 8 are pasted by magic between the neck 3 and neck drop cloth 4 and between drop cloth 5 and connection cloth 6, The 5 one side edge junction of drop cloth is fixedly installed with several clasp nails 9, and the clasp nail 9 includes bottom cover 10, contact lid 11, connection Bar 12 and ball nail 13,10 upper end of bottom cover are fixedly installed with contact lid 11, and the 11 upper end center position of contact lid passes through company Extension bar 12 is fixedly connected with ball nail 13, and 6 side of connection cloth is fixedly installed with several Button Blocks 14, and the drop cloth 5 passes through connection cloth 6 Between be fixedly connected with Button Block 14 by clasp nail 9.
Wherein, the 2 upper end shoulder of main surface material is set there are two scapulet 15, and two scapulets 15 are constructed according to shoulders of human body Design, 2 two sides of main surface material are fixedly connected with oversleeve 41, and 41 middle part of oversleeve is fixedly installed with elbow support part 16, the shield Elbow part 16 includes two elbow support steel rings 17, passes through upper connection sheet 18 and lower connection sheet 19 respectively between two elbow support steel rings 17 It connects, is fixedly installed with fixed block 20 between two elbow support steel rings 17,20 lower end of fixed block is fixedly connected with limit bullet Spring 21,21 both ends of limit spring are connected to two elbow support steel rings, 17 side center, and 2 lower end of main surface material is solid Surely several fixing buckles 22 are connected, the fixing buckle 22 is equipped with fixed sole piece 23, fixes at the fixed 23 upper end two edges of sole piece Half arc-shaped workpiece 24 is connected, forms round hole 25 between two half arc-shaped workpieces 24, the side of the main surface material 2 is fixedly connected with two Vertical bar 26, two vertical bars 26 are relevant to the distribution of 2 longitudinal centre line axial symmetry of main surface material, and two 26 upper ends of vertical bar are logical It crosses two cross bars 27 to connect, slot 28,28 upper end of the slot installation is equipped between two vertical bars 26 and two cross bars 27 There is torsion spring presss 29,28 side of slot is equipped with rotatable lamella 30, and the rotatable lamella 30 and the one of output end of torsion spring presss 29 are solid Fixed connection, the another output of the torsion spring presss 29 are fixedly connected with 28 upper surface of slot, the lower end of 28 inner cavity of slot Equipped with block 31, the block 31 is adapted design with 30 lower end of rotatable lamella, and 2 one middle side part of main surface material is rectangular equipped with two Channel 32 is relevant to the distribution of 2 longitudinal centre line axial symmetry of main surface material between two square ducts 32, and two described rectangular logical 32 side of road is equipped with the first V-type button 33, and 33 side of the first V-type button is fixedly connected with connecting band 34,2 side of main surface material Equipped with dry powder can 35, the dry powder can 35 is fixedly connected with three arc panels 36, three arc panels 36 close to 28 side of slot Between respectively be fixedly mounted there are two hook 37, the dry powder can 35 by hook 37 and slot 28 be fixedly connected with main surface material 2, And the 35 two sides position of dry powder can is fixedly connected with the second V-type button 38, and the dry powder can 35 passes through two the second V-type buttons 38 and two the first V-type buttons 33 be fixedly connected with main surface material 2,35 output end of dry powder can is fixedly connected with flour extraction pipe 39, described 39 port position of flour extraction pipe is fixedly installed with regulating valve 40, and two connecting bands 34 are each passed through corresponding square duct 32, Connection plug-in unit 42 and connected slot 52,5 side of drop cloth are respectively fixedly connected at two ports of two connecting bands 34 It is fixedly installed with negative pressure inflatable chamber 43, is fixedly connected between two negative pressure inflatable chambers 43 by link block 46, the connection 46 upper end of block is equipped with touch panel 44, and hollow cavity 47 is equipped with inside the link block 46, and the 44 lower end center of touch panel is fixed to be connected Connecing slide bar 45,45 lower end of slide bar is arranged in hollow cavity 47, and 47 bottom of hollow cavity is set there are two pressing first 48, and two 43 interior side of negative pressure inflatable chamber is fixedly connected with spring 50, and two described 50 one end of spring pass through sliding bar 49 respectively and connect Pressure head 48 is contacted, two 49 two sides of sliding bar are fixedly connected with L-type link block 51, two 43 sides of negative pressure inflatable chamber It is equipped with air inlet, the opposite of air inlet is provided with L-type link block 51, and 46 lower end of link block is set there are two slideway, and two A sliding bar 49 slides in corresponding slideway respectively, and the main surface material 2 is that polyacrylonitrile scrim and aluminium foil are multiple It is made at compound, 39 outer diameter of flour extraction pipe is identical as 25 internal diameter of round hole of several fixing buckles 22.
Use state of the invention are as follows: anti-stab flame retardant special clothes have vdiverse in function, the high advantage of security performance, first First the hook 37 of dry powder can 35 is inserted into slot 28, and by connection plug-in unit 42 and connected slot 52 that dry powder can 35 is fixed It is buckled on fixing buckle 22 on vertical bar 26 and cross bar 27, then by flour extraction pipe 39, when use removes, and is controlled out by regulating valve 40 Powder amount, then by magic fishing without hook 8 and magic paste 7 and clasp nail 9 and bottom cover 10 drop cloth 5 is covered in main surface material 2, while by neck Portion's drop cloth 4 covers on neck 3, and when ontology 1 is by hitting, scapulet 15 and elbow support part 16 effectively reduce fireman's joint Damage, when front is by hitting, touch panel 44 is forced into hollow cavity 47, and two press first 48 and are forced into connection at this time In block 46, spring 50 is forced to compress, and two L-type link blocks 51 are inserted into the air inlet of two negative pressure inflatable chambers 43, by air inlet Sealing stopper jacking at mouthful is gone, the rapid air-breathing of negative pressure inflatable chamber 43, and expansion is completed to the positive protection of main surface material 2.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention, the technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention, the claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (6)

1. a kind of production method of anti-stab flame retardant special clothes, which comprises the following steps:
(1) polystyrene the preparation of flame-retardant garment plus material: is put into several reaction kettles once heating simultaneously until in melting State, is separately added into after the nanometer Zirconia of equivalent secondary temperature elevation and is stirred continuously until and be uniformly dispersed, will from osculum extruding and discharging One end of material is connect with braider, and drier is arranged between discharge port and braider, by shaft rotate pull raw material at Silk molding, while being woven to get flame-retardant garment plus material is arrived;
(2) preparation of Anti-prick clothes fabric: with aramid fiber-High molecular weight polyethylene-aramid fiber three-decker parallel Cloth, and immerse in resin, premix is formed, premix is overlapped by different directions, catalytic curing agent is added in resin, solidifies Anti-prick clothes fabric is obtained afterwards;
(3) fabric is handled: according to clothes template, being modified cutting to flame-retardant garment plus material and Anti-prick clothes fabric, then by outer To the inner flame-retardant clothing completed according to Anti-prick clothes fabric-flame-retardant garment plus material-Anti-prick clothes fabric three-layer arrangement structure to cutting Fill fabric, Anti-prick clothes fabric carries out close sewer to get anti-stab flame retardant special clothing semi product is arrived, by SiC semi-molten raw material The outer surface that anti-stab flame retardant special clothing semi product is deposited to by plasma spray technology obtains anti-stab after cooling completely is fixed Flame retardant special clothes.
2. the production method of anti-stab flame retardant special clothes as described in claim 1, which is characterized in that step is received described in (1) The partial size of rice ZrO2 is less than 40nm.
3. the production method of anti-stab flame retardant special clothes as described in claim 1, which is characterized in that one described in step (1) To be warming up to 240-250 DEG C with the rate of 20 DEG C/min, the secondary temperature elevation is warming up to the rate of 10 DEG C/min for secondary heating 260-265℃。
4. the production method of anti-stab flame retardant special clothes as described in claim 1, which is characterized in that gather described in step (1) The mass ratio of styrene and the nanometer Zirconia is 10-12:1.
5. the production method of anti-stab flame retardant special clothes as described in claim 1, which is characterized in that step is urged described in (2) Change curing agent is tertiary amine, imidazoles, any one in boron trifluoride complex.
6. the production method of anti-stab flame retardant special clothes as described in claim 1, which is characterized in that set described in step (2) Rouge is polyurethane, rubber, sarin resin, epoxy resin, any one in phenolic resin.
CN201810870657.1A 2018-08-02 2018-08-02 Manufacturing method of stab-resistant flame-retardant special garment Active CN109090733B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111535034A (en) * 2020-04-09 2020-08-14 安徽福斯特渔具有限公司 Preparation method of high-temperature-resistant composite material for fire-fighting protective clothing

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