CN109081749A - Hydrogen-rich compound fertilizer and preparation method thereof - Google Patents

Hydrogen-rich compound fertilizer and preparation method thereof Download PDF

Info

Publication number
CN109081749A
CN109081749A CN201811310680.1A CN201811310680A CN109081749A CN 109081749 A CN109081749 A CN 109081749A CN 201811310680 A CN201811310680 A CN 201811310680A CN 109081749 A CN109081749 A CN 109081749A
Authority
CN
China
Prior art keywords
parts
hydrogen
component
compound fertilizer
rich compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811310680.1A
Other languages
Chinese (zh)
Inventor
李青山
郝云云
洪伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yanshan University
Original Assignee
Yanshan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yanshan University filed Critical Yanshan University
Priority to CN201811310680.1A priority Critical patent/CN109081749A/en
Publication of CN109081749A publication Critical patent/CN109081749A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B1/00Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
    • C05B1/04Double-superphosphate; Triple-superphosphate; Other fertilisers based essentially on monocalcium phosphate
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

Abstract

The invention belongs to technical field of fertilizers, it is related to a kind of hydrogen-rich compound fertilizer comprising the component of following parts by weight: 100-150 parts of urea, 50-70 parts of ammonium dihydrogen phosphate, 100-130 parts of monoammonium phosphate, 40-60 parts of double superhosphate, 120-130 parts of potassium sulfate, 15-25 parts of potassium dihydrogen phosphate, 5-10 parts of boric acid, 3-5 parts of ammonium molybdate, 10-15 parts of magnesium sulfate, 8-12 parts of promotor and 1-3 parts of microelement;Promotor comprises the following components in parts by weight: component 0.4-1 parts of 60-80 parts of carcass component, 40-50 parts of hydrogen manufacturing component, 40-60 parts of substrate component and activation.Hydrogen-rich compound fertilizer of the invention is full of nutrition, in conjunction with the water in soil after can be long-term and stable release hydrogen, long action time, optimize soil flora, remarkably promote plant growth, and preparation method is simple.

Description

Hydrogen-rich compound fertilizer and preparation method thereof
Technical field
The invention belongs to technical field of fertilizers, it is related to a kind of hydrogen-rich compound fertilizer and preparation method thereof.
Background technique
A kind of attention of the hydrogen as medical gas by medical domain also has in botany and agriculture field and widely answers With prospect, the research for not only having hydrogen to act on plant stress-resistance also promotes plant growth about hydrogen, improves vegetable nutrient etc. The research of aspect.Also there is one " hydrogen fertilizer is theoretical ", cause largely to pay close attention to.2002, when Dong is put forward for the first time leguminous plant fixed nitrogen Release hydrogen can be utilized by soil hydrogen-oxidizing bacterium, further promote the hydrogen fertilizer new concept of plant growth.Hydrogen-oxidizing bacterium can increase Add soil fertility and crop yield, can promote the elongation of root with the hydrogen-oxidizing bacterium processing plant isolated.Recently Canada Ah Man Defulei Pierre research institute PhilippeConstant professor group publishes thesis again, it was demonstrated that hydrogen can influence hydrogen in soil Oxidation bacteria ratio improves soil bacterial diversity and function.
The hydrogen that nitrogen-fixing bacteria generate in nitrogen-fixing root nodule can nourish surrounding hydrogen-oxidizing bacterium, play the getting fat effect of improvement soil Fruit can improve various crop yield.It is considered that the substance that there is promotion plant growth in hydrogen-oxidizing bacterium metabolite is hydrogen The basis that fertilizer efficiency is answered, but hydrogen-oxidizing bacterium, possibly through the growth for influencing other microorganisms in soil, this respect does not have in the past It is taken seriously.Current research discovery can generate micropopulation in soil after soil is added in the hydrogen as microbial energy Entire effect changes the ratio of bacterium and fungi in soil, generates many-sided influence to soil flora.
Hydrogen-rich products application and agricultural production at present mainly passes through electrolysis hydraulic art hydrogen manufacturing, such as application No. is 201580046540.6 patent document discloses a kind of electrolytic water generating device, including the first electrode room with cathode, tool There are the second electrode room of anode, the internal electrolytic cell with the diaphragm for separating first electrode room and second electrode room, be connected to the The first water inlet road of first electrode room is fed on one electrode chamber and from outside by raw water, is connected on first electrode room and by first The first external water outlet path is discharged in electrode chamber by electrolytically generated electrolysis water element water, and is connected on electrolytic cell and is used for When being electrolysed, charge quantity regulating device that the quantity of electric charge for being applied to electrolysis water element water is adjusted;The quantity of electric charge adjusts dress It sets through control Faradaic current or decomposition voltage, and the quantity of electric charge of the per unit water yield of electrolysis water element water is adjusted, lead to It crosses the electrolytic water generating device and prepares hydrogen-rich water progress field irrigation online.The hydrogen-rich water of this method preparation has crop growth There is certain effect, but short there are action period, equipment is more complex, electricity consumption is needed, using limited, the disadvantages of being also easy to produce ozone.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of hydrogen-rich compound fertilizer, the water knot in full of nutrition and soil It closes and stablizes release hydrogen, long action time can promote plant growth.
The present invention is implemented as follows:
A kind of hydrogen-rich compound fertilizer comprising the component of following parts by weight: 100-150 parts of urea, ammonium dihydrogen phosphate 50-70 Part, 100-130 parts of monoammonium phosphate, 40-60 parts of double superhosphate, 120-130 parts of potassium sulfate, 15-25 parts of potassium dihydrogen phosphate, boric acid 5-10 parts, 3-5 parts of ammonium molybdate, 10-15 parts of magnesium sulfate, 8-12 parts of promotor and 1-3 parts of microelement;The promotor includes The component of following parts by weight: 60-80 parts of carcass component, 40-50 parts of hydrogen manufacturing component, 40-60 parts of substrate component and activation component 0.4-1 parts.
Preferably, the carcass component comprises the following components in parts by weight: 10-80 parts of clay, 10-30 parts of bentonite, height Soil 40-50 parts of ridge, 1-3 parts of dextrin and 2-4 parts of polyvinyl alcohol.
Preferably, the hydrogen manufacturing component includes following parts by weight of component: 50-70 parts of magnesium powder, 30-50 parts of zinc powder, aluminium oxide 10-60 parts, 1-10 parts of titanium dioxide and 1-10 parts of manganese dioxide.
Preferably, the substrate component comprises the following components in parts by weight: 40-50 parts of zeolite, opal shale 30-40 Part, 15-20 parts of active carbon and 20-30 parts of volcanic rock.
Preferably, the activation component comprises the following components in parts by weight: 0.05-1 parts of nitric acid rare earth, graphene 5-10 Part, 30-40 parts of tourmaline, 40-50 parts of stone needle, 20-30 parts of obsidian, 40-50 parts of opal and 1-50 parts of bamboo charcoal.
Preferably, the microelement includes zinc-amino acid chelate, amino acid chelated iron, chelating amino acids manganese and amino acid Boron is chelated, and the weight ratio of each component is 1:1-1.2:0.9-1.2:1-1.5.
A kind of preparation method of hydrogen-rich compound fertilizer comprising following steps:
S1, each component of promotor is crushed to 50-80 μm respectively, first by hydrogen manufacturing component and substrate component mixing 2h; Add water and carcass component, mixing 1h;Activation component, mixing 0.5h are added, pelletizer is granulated, and size controlling is in 20- 200mm, 900 DEG C of sintering 2h, obtains particle;Particle is crushed, 500-1000 mesh is crossed, is promoted agent;
S2, by urea, ammonium dihydrogen phosphate, monoammonium phosphate, double superhosphate, potassium sulfate, potassium dihydrogen phosphate, boric acid, molybdic acid Ammonium, magnesium sulfate and microelement smash it through 50-100 mesh respectively, are uniformly mixed, obtain powder;
S3, powder is divided into 5-10 parts, first first part of powder is added in the promotor of step S1, mixing is equal It is even, obtain the first material;
S4, second part of powder is added in the first material, is uniformly mixed, obtains the second material;
S5, and so on, the mixing of 5-10 material is carried out, until promotor and powder are all uniformly mixed, pelletizer Extrusion granulation is dried, cooling, is sieved, and packaging obtains hydrogen-rich compound fertilizer.
Preferably, in step S1, the weight ratio of water and carcass component is 0.3-0.5:1.
Compared with prior art, the invention has the following advantages:
Hydrogen-rich compound fertilizer of the invention is full of nutrition, in conjunction with the water in soil after can be long-term and stable release hydrogen, Long action time optimizes soil flora, remarkably promotes plant growth, and preparation method is simple.
Specific embodiment
It will be detailed below exemplary embodiment of the present invention, feature and aspect of performance.
A kind of hydrogen-rich compound fertilizer comprising the component of following parts by weight: 100-150 parts of urea, ammonium dihydrogen phosphate 50-70 Part, 100-130 parts of monoammonium phosphate, 40-60 parts of double superhosphate, 120-130 parts of potassium sulfate, 15-25 parts of potassium dihydrogen phosphate, boric acid 5-10 parts, 3-5 parts of ammonium molybdate, 10-15 parts of magnesium sulfate, 8-12 parts of promotor and 1-3 parts of microelement;Promotor includes following The component of parts by weight: 60-80 parts of carcass component, 40-50 parts of hydrogen manufacturing component, 40-60 parts of substrate component and activation component 0.4-1 Part;Carcass component comprises the following components in parts by weight: 10-80 parts of clay, 10-30 parts of bentonite, 40-50 parts of kaolin, dextrin 1-3 parts and 2-4 parts of polyvinyl alcohol;Hydrogen manufacturing component includes following parts by weight of component: 50-70 parts of magnesium powder, 30-50 parts of zinc powder, oxygen Aluminium 10-60 parts of change, 1-10 parts of titanium dioxide and 1-10 parts of manganese dioxide.Substrate component comprises the following components in parts by weight: boiling 40-50 parts of stone, 30-40 parts of opal shale, 15-20 parts of active carbon and 20-30 parts of volcanic rock;It includes following heavy for activating component Measure the component of part: 0.05-1 parts of arsenic determination, 5-10 parts of graphene, 30-40 parts of tourmaline, 40-50 parts of stone needle, obsidian 20-30 parts, 40-50 parts of opal and 1-50 parts of bamboo charcoal;Microelement includes zinc-amino acid chelate, amino acid chelated iron, ammonia Base acid Chelated Manganese and chelating amino acids boron, and the weight ratio of each component is 1:1-1.2:0.9-1.2:1-1.5.
A kind of preparation method of hydrogen-rich compound fertilizer comprising following steps:
S1, each component of promotor is crushed to 50-80 μm respectively, first by hydrogen manufacturing component and substrate component mixing 2h; Add water and carcass component, the weight ratio of water and carcass component is 0.3-0.5:1, mixing 1h;Add activation component, mixing 0.5h, pelletizer are granulated, and size controlling obtains particle in 20-200mm, 900 DEG C of sintering 2h;Particle is crushed, 500-1000 mesh is crossed Sieve, is promoted agent;First hydrogen manufacturing component and substrate component are uniformly mixed, make hydrogen manufacturing component is as much as possible to enter substrate component Inside prevents powder reuniting;
S2, by urea, ammonium dihydrogen phosphate, monoammonium phosphate, double superhosphate, potassium sulfate, potassium dihydrogen phosphate, boric acid, molybdic acid Ammonium, magnesium sulfate and microelement smash it through 50-100 mesh respectively, are uniformly mixed, obtain powder;
S3, powder is divided into 5-10 parts, first first part of powder is added in the promotor of step S1, mixing is equal It is even, obtain the first material;
S4, second part of powder is added in the first material, is uniformly mixed, obtains the second material;
S5, and so on, the mixing of 5-10 material is carried out, until promotor and powder are all uniformly mixed, pelletizer Extrusion granulation is dried, cooling, is sieved, and hydrogen-rich compound fertilizer is made in packaging.
Since promotor and powder weight difference are bigger, it be easy to cause mixing uneven if directly mixed the two, portion Poor material is divided to reunite, the Fertilizer nutrient difference after granulation is big;By the mixing of multiple material, it can be achieved that material uniformly mixes It closes, guarantees that every granulated fertilizer material nutrient is balanced.
Embodiment 1
A kind of hydrogen-rich compound fertilizer, comprising: 100 parts of urea, 70 parts of ammonium dihydrogen phosphate, 130 parts of monoammonium phosphate, double superhosphate 40 parts, 120 parts of potassium sulfate, 25 parts of potassium dihydrogen phosphate, 5 parts of boric acid, 5 parts of ammonium molybdate, 15 parts of magnesium sulfate, 8 parts of promotor and micro 1 part of element.Promotor includes: 0.4 part of component of 80 parts of carcass component, 40 parts of hydrogen manufacturing component, 60 parts of substrate component and activation.
Carcass component includes: 80 parts of clay, 10 parts of bentonite, 40 parts of kaolin, 3 parts of dextrin and 2 parts of polyvinyl alcohol.
Hydrogen manufacturing component includes: 50 parts of magnesium powder, 50 parts of zinc powder, 60 parts of aluminium oxide, 1 part of titanium dioxide and 10 parts of manganese dioxide.
Substrate component includes: 40 parts of zeolite, 30 parts of opal shale, 20 parts of active carbon and 20 parts of volcanic rock.
Activating component includes: 0.05 part of arsenic determination, 10 parts of graphene, 30 parts of tourmaline, 40 parts of stone needle, obsidian 30 parts, 50 parts of opal and 1 part of bamboo charcoal.
Microelement includes zinc-amino acid chelate, amino acid chelated iron, chelating amino acids manganese and chelating amino acids boron, weight Than for 1:1:1.2:1.5.
A kind of preparation method of hydrogen-rich compound fertilizer, specifically includes the following steps:
S1, promotor each component is crushed to 50 μm respectively, first by hydrogen manufacturing component and substrate component mixing 2h;It adds Weight ratio is the water and carcass component of 0.5:1, mixing 1h;Activation component, mixing 0.5h are added, pelletizer is granulated, partial size control System obtains particle in 200mm, 900 DEG C of sintering 2h;Particle is crushed, 500 meshes is crossed, obtains promotor;
2) by urea, ammonium dihydrogen phosphate, monoammonium phosphate, double superhosphate, potassium sulfate, potassium dihydrogen phosphate, boric acid, molybdic acid Ammonium, magnesium sulfate and microelement smash it through 100 meshes respectively, are uniformly mixed, obtain powder;
3) powder is divided into 5 parts, first first part of powder is added in promotor, be uniformly mixed, obtain the first material;
4) second part of powder is added in the first material, is uniformly mixed, obtains the second material;
5) and so on, the mixing of 5 materials is carried out, until promotor and powder are all uniformly mixed;Pelletizer extruding is made Grain is dried, cooling, is sieved, and packaging can be prepared by hydrogen-rich compound fertilizer.
Embodiment 2
A kind of hydrogen-rich compound fertilizer, comprising: 130 parts of urea, 60 parts of ammonium dihydrogen phosphate, 115 parts of monoammonium phosphate, double superhosphate 50 parts, 125 parts of potassium sulfate, 20 parts of potassium dihydrogen phosphate, 8 parts of boric acid, 4 parts of ammonium molybdate, 13 parts of magnesium sulfate, 10 parts of promotor and micro 2 parts of element.Promotor includes: 0.8 part of component of 70 parts of carcass component, 45 parts of hydrogen manufacturing component, 50 parts of substrate component and activation.
Carcass component includes: 50 parts of clay, 20 parts of bentonite, 45 parts of kaolin, 2 parts of dextrin and 3 parts of polyvinyl alcohol.
Hydrogen manufacturing component includes: 60 parts of magnesium powder, 40 parts of zinc powder, 30 parts of aluminium oxide, 5 parts of titanium dioxide and 5 parts of manganese dioxide.
Substrate component includes: 45 parts of zeolite, 35 parts of opal shale, 18 parts of active carbon and 25 parts of volcanic rock.
Activating component includes: 0.5 part of arsenic determination, 8 parts of graphene, 35 parts of tourmaline, 45 parts of stone needle, obsidian 25 Part, 45 parts of opal and 25 parts of bamboo charcoal.
Microelement includes zinc-amino acid chelate, amino acid chelated iron, chelating amino acids manganese and chelating amino acids boron, weight Than for 1:1.1:1:1.3.
A kind of preparation method of hydrogen-rich compound fertilizer, is as made from following steps:
S1, promotor each component is crushed to 60 μm respectively, first by hydrogen manufacturing component and substrate component mixing 2h;It adds Weight ratio is the water and carcass component of 0.4:1, mixing 1h;Activation component, mixing 0.5h are added, pelletizer is granulated, partial size control System obtains particle in 100mm, 900 DEG C of sintering 2h;Particle is crushed, 800 meshes is crossed, obtains promotor;
S2, by urea, ammonium dihydrogen phosphate, monoammonium phosphate, double superhosphate, potassium sulfate, potassium dihydrogen phosphate, boric acid, molybdic acid Ammonium, magnesium sulfate and microelement smash it through 80 meshes respectively, are uniformly mixed, obtain powder;
S3, powder is divided into 8 parts, first first part of powder is added in promotor, be uniformly mixed, obtain the first material;
S4, second part of powder is added in the first material, is uniformly mixed, obtains the second material;
S5, and so on, the mixing of 8 materials is carried out, until promotor and powder are all uniformly mixed;Pelletizer extruding is made Grain is dried, cooling, is sieved, and packaging can be prepared by hydrogen-rich compound fertilizer.
Embodiment 3
A kind of hydrogen-rich compound fertilizer, comprising: 150 parts of urea, 50 parts of ammonium dihydrogen phosphate, 100 parts of monoammonium phosphate, double superhosphate 60 parts, 130 parts of potassium sulfate, 15 parts of potassium dihydrogen phosphate, 10 parts of boric acid, 3 parts of ammonium molybdate, 10 parts of magnesium sulfate, 12 parts of promotor and micro- 3 parts of secondary element.Promotor includes: 1 part of component of 60 parts of carcass component, 50 parts of hydrogen manufacturing component, 40 parts of substrate component and activation.
Carcass component includes: 10 parts of clay, 30 parts of bentonite, 50 parts of kaolin, 1 part of dextrin and 4 parts of polyvinyl alcohol.
Hydrogen manufacturing component includes: 70 parts of magnesium powder, 30 parts of zinc powder, 10 parts of aluminium oxide, 10 parts of titanium dioxide and 1 part of manganese dioxide.
Substrate component includes: 50 parts of zeolite, 40 parts of opal shale, 15 parts of active carbon and 30 parts of volcanic rock.
Activating component includes: 1 part of arsenic determination, 5 parts of graphene, 40 parts of tourmaline, 50 parts of stone needle, obsidian 20 Part, 40 parts of opal and 50 parts of bamboo charcoal.
Microelement includes zinc-amino acid chelate, amino acid chelated iron, chelating amino acids manganese and chelating amino acids boron, weight Than for 1:1.2:0.9:1.
A kind of preparation method of hydrogen-rich compound fertilizer, specifically includes the following steps:
S1, promotor each component is crushed to 80 μm respectively, first by hydrogen manufacturing component and substrate component mixing 2h;It adds Weight ratio is the water and carcass component of 0.3:1, mixing 1h;Activation component, mixing 0.5h are added, pelletizer is granulated, partial size control System obtains particle in 20mm, 900 DEG C of sintering 2h;Particle is crushed, 1000 meshes is crossed, obtains promotor;
S2, by urea, ammonium dihydrogen phosphate, monoammonium phosphate, double superhosphate, potassium sulfate, potassium dihydrogen phosphate, boric acid, molybdic acid Ammonium, magnesium sulfate and microelement smash it through 50 meshes respectively, are uniformly mixed, obtain powder;
S3, powder is divided into 10 parts, first first part of powder is added in promotor, be uniformly mixed, obtain the first material;
S4, second part of powder is added in the first material, is uniformly mixed, obtains the second material;
S5, and so on, the mixing of 10 materials is carried out, until promotor and powder are all uniformly mixed;Pelletizer squeezes It is granulated, dries, it is cooling, it sieves, packaging can be prepared by hydrogen-rich compound fertilizer.
Comparative example
A kind of compound fertilizer is as made from the raw material of following parts by weight: 130 parts of urea, 60 parts of ammonium dihydrogen phosphate, phosphoric acid one 115 parts of ammonium, 50 parts of double superhosphate, 125 parts of potassium sulfate, 20 parts of potassium dihydrogen phosphate, 8 parts of boric acid, 4 parts of ammonium molybdate, magnesium sulfate 13 Part and 2 parts of microelement.
Microelement is zinc-amino acid chelate: amino acid chelated iron: chelating amino acids manganese: chelating amino acids boron is according to 1: 1.1:1:1.3 weight ratio composition.
A kind of preparation method of compound fertilizer, is as made from following methods: by urea, ammonium dihydrogen phosphate, monoammonium phosphate, again Calcium superphosphate, potassium sulfate, potassium dihydrogen phosphate, boric acid, ammonium molybdate, magnesium sulfate and microelement smash it through 80 meshes respectively, mix It closing uniformly, pelletizer extrusion granulation is dried, and it is cooling, it sieves, packaging can be prepared by compound fertilizer.
Hydrogen content performance test
Each 50g of compound fertilizer of hydrogen-rich compound fertilizer and comparative example preparation prepared by embodiment 1-3 is respectively put into beaker, Enter 300mL pure water, the hydrogen content for testing 5min, 10min, 60min, 720min respectively (uses U.S. Honeywell HoneywellXP-H2 hydrogen detector), testing result is as shown in table 1.
1 hydrogen content test result of table
As it can be seen from table 1 hydrogen-rich compound fertilizer prepared by the present invention after being combined with water can be long-term and stable release hydrogen, Hydrogen content is 7~17 times of the hydrogen content of the compound fertilizer of comparative example.
Crop field application effect
Experimental example: the hydrogen-rich compound fertilizer of embodiment 1-3 preparation.
Comparative example: the compound fertilizer of comparative example preparation.
Blank control group: without using any fertilizer.
Experimental cultivar: rose fragrant.
Test site: Hebei province Qinhuangdao grape cooperative society.
Processing mode: 30-50 centimetres of depth, 15-40 centimetres wide of ditch are dug in direct motion after grape harvesting in autumn, disposably will be fertile Material applies in ditch, waters after earthing, applies 50 kilograms per acre.Application effect compared with blank control group is shown in Table 2.Wherein, contain Saccharimetry uses anthrone colorimetry, and the measurement of vitamin content uses 2,6-dichloroindophenol titrations.
2 application effect of table
From table 2 it can be seen that hydrogen-rich compound fertilizer of the invention is applied to crop field, each index of grape is significantly better than that pair The compound fertilizer of ratio, especially yield are obviously improved, and plant out the grape that sugar content is high, vitamin content is high, and yield substantially mentions It is high.
To sum up, the invention has the following advantages that
Hydrogen-rich compound fertilizer of the invention is full of nutrition, by the effect of promotor each component, so that hydrogen-rich of the invention is multiple Hefei in conjunction with the water in soil after can be long-term and stable release hydrogen, long action time, hydrogen content is existing compound fertilizer 7~17 times of hydrogen content optimize soil flora, remarkably promote plant growth, and preparation method is simple.
Finally, it should be noted that above-described each embodiment is merely to illustrate technical solution of the present invention, rather than it is limited System;Although the present invention is described in detail referring to the foregoing embodiments, those skilled in the art should understand that: its It can still modify to technical solution documented by previous embodiment, or part of or all technical features are carried out Equivalent replacement;And these modifications or substitutions, technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution Range.

Claims (8)

1. a kind of hydrogen-rich compound fertilizer, it is characterised in that: it is comprised the following components in parts by weight: 100-150 parts of urea, biphosphate 50-70 parts of ammonium, 100-130 parts of monoammonium phosphate, 40-60 parts of double superhosphate, 120-130 parts of potassium sulfate, potassium dihydrogen phosphate 15-25 Part, 5-10 parts of boric acid, 3-5 parts of ammonium molybdate, 10-15 parts of magnesium sulfate, 8-12 parts of promotor and 1-3 parts of microelement;The rush Comprised the following components in parts by weight into agent: 60-80 parts of carcass component, 40-50 parts of hydrogen manufacturing component, 40-60 parts of substrate component and Component 0.4-1 parts of activation.
2. hydrogen-rich compound fertilizer according to claim 1, it is characterised in that: the carcass component includes the group of following parts by weight Point: 10-80 parts of clay, 10-30 parts of bentonite, 40-50 parts of kaolin, 1-3 parts of dextrin and 2-4 parts of polyvinyl alcohol.
3. hydrogen-rich compound fertilizer according to claim 1, it is characterised in that: the hydrogen manufacturing component includes following parts by weight group Point: 50-70 parts of magnesium powder, 30-50 parts of zinc powder, 10-60 parts of aluminium oxide, 1-10 parts of titanium dioxide and 1-10 parts of manganese dioxide.
4. hydrogen-rich compound fertilizer according to claim 1, it is characterised in that: the substrate component includes the group of following parts by weight Point: 40-50 parts of zeolite, 30-40 parts of opal shale, 15-20 parts of active carbon and 20-30 parts of volcanic rock.
5. hydrogen-rich compound fertilizer according to claim 1, it is characterised in that: the activation component includes the group of following parts by weight Point: 0.05-1 parts of nitric acid rare earth, 5-10 parts of graphene, 30-40 parts of tourmaline, 40-50 parts of stone needle, 20-30 parts of obsidian, albumen 40-50 parts of stone and 1-50 parts of bamboo charcoal.
6. hydrogen-rich compound fertilizer according to claim 1, it is characterised in that: the microelement include zinc-amino acid chelate, Amino acid chelated iron, chelating amino acids manganese and chelating amino acids boron, and the weight ratio of each component is 1:1-1.2:0.9-1.2:1- 1.5。
7. a kind of preparation method of the hydrogen-rich compound fertilizer as described in claim 1~6 is any, it is characterised in that: it includes following Step:
S1, each component of promotor is crushed to 50-80 μm respectively, first by hydrogen manufacturing component and substrate component mixing 2h;Again plus Enter water and carcass component, mixing 1h;Add activation component, mixing 0.5h, pelletizer is granulated, size controlling in 20-200mm, 900 DEG C of sintering 2h, obtain particle;Particle is crushed, 500-1000 mesh is crossed, is promoted agent;
S2, by urea, ammonium dihydrogen phosphate, monoammonium phosphate, double superhosphate, potassium sulfate, potassium dihydrogen phosphate, boric acid, ammonium molybdate, sulphur Sour magnesium and microelement smash it through 50-100 mesh respectively, are uniformly mixed, obtain powder;
S3, powder is divided into 5-10 parts, first first part of powder is added in the promotor of step S1, be uniformly mixed, obtain First material;
S4, second part of powder is added in the first material, is uniformly mixed, obtains the second material;
S5, and so on, the mixing of 5-10 material is carried out, until promotor and powder are all uniformly mixed, pelletizer is squeezed It is granulated, dries, it is cooling, it sieves, packaging obtains hydrogen-rich compound fertilizer.
8. the preparation method of hydrogen-rich compound fertilizer according to claim 7, it is characterised in that: in step S1, water and carcass group The weight ratio divided is 0.3-0.5:1.
CN201811310680.1A 2018-11-06 2018-11-06 Hydrogen-rich compound fertilizer and preparation method thereof Withdrawn CN109081749A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811310680.1A CN109081749A (en) 2018-11-06 2018-11-06 Hydrogen-rich compound fertilizer and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811310680.1A CN109081749A (en) 2018-11-06 2018-11-06 Hydrogen-rich compound fertilizer and preparation method thereof

Publications (1)

Publication Number Publication Date
CN109081749A true CN109081749A (en) 2018-12-25

Family

ID=64844769

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811310680.1A Withdrawn CN109081749A (en) 2018-11-06 2018-11-06 Hydrogen-rich compound fertilizer and preparation method thereof

Country Status (1)

Country Link
CN (1) CN109081749A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110746242A (en) * 2019-11-14 2020-02-04 福州钧鼎生物科技有限公司 Preparation process of graphene and titanium element synergistic micro-nano biological bacterial fertilizer

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7998236B2 (en) * 2008-08-18 2011-08-16 Albert Calderon Advanced method for processing fuels
CN106699330A (en) * 2016-08-19 2017-05-24 中国科学院华南植物园 Preparation method and application of sustained and controlled release hydrogen fertilizer or compound hydrogen fertilizer
CN107353141A (en) * 2017-09-11 2017-11-17 洪伟 A kind of hydrogen-rich composite fertilizer and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7998236B2 (en) * 2008-08-18 2011-08-16 Albert Calderon Advanced method for processing fuels
CN106699330A (en) * 2016-08-19 2017-05-24 中国科学院华南植物园 Preparation method and application of sustained and controlled release hydrogen fertilizer or compound hydrogen fertilizer
CN107353141A (en) * 2017-09-11 2017-11-17 洪伟 A kind of hydrogen-rich composite fertilizer and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110746242A (en) * 2019-11-14 2020-02-04 福州钧鼎生物科技有限公司 Preparation process of graphene and titanium element synergistic micro-nano biological bacterial fertilizer

Similar Documents

Publication Publication Date Title
CN102816021B (en) Special fertilizer for rape base fertilizer
CN105254452A (en) Fertilizer for fruit trees and production method of fertilizer
CN102180737B (en) Method for producing organic compound fertilizer by fermenting agricultural organic waste
CN102875236A (en) Total nutrient organic-inorganic compound fertilizer
CN102219604A (en) Rice charcoal slow-release fertilizer and preparation method thereof
CN102942423A (en) Specialized organic/inorganic composite biological medicine fertilizer for watermelon, and preparation method thereof
CN103553791A (en) Vegetable fertilizer prepared from wormcast and preparation method of vegetable fertilizer
CN103319218B (en) Preparation method for composite microbial fertilizer with bioleached sludge and composite microbial fertilizer
CN101475417A (en) Biological mineral compound fertilizer and production method thereof
CN105884449A (en) Method for producing organic fertilizer by means of monosodium glutamate wastewater and straw fermentation
CN104151018A (en) High-efficiency, loss-resistant and disease-preventing organic and inorganic compound fertilizer
CN107079796A (en) A kind of Vegetable Nutrition Soil and preparation method thereof
CN105016908A (en) Compound microbial fertilizer and preparation method thereof
CN103265378B (en) Organic-inorganic compound fertilizer containing biological bacterium and trace elements
CN106083448A (en) A kind of biologic organic, inorganic large-particle fertilizer and preparation method thereof
CN102180716B (en) Method for producing organic compound fertilizer by fermenting animal manure
CN104761371A (en) Special fertilizer for nelumbo nucifera gaertn as well as production method and application method of special fertilizer
CN102863295A (en) Special compound fertilizer for single cropping water oat
CN104058831A (en) Special biological organic compound fertilizer for crop base fertilizer and preparation method of compound fertilizer
CN100429184C (en) Special controlled-release fertilizer for sulfur, resin film coated ginger, garlic and manufacturing method therefor
CN109081749A (en) Hydrogen-rich compound fertilizer and preparation method thereof
CN106397043A (en) Liquid compound microbial fertilizer and preparation method thereof
CN107353141A (en) A kind of hydrogen-rich composite fertilizer and preparation method thereof
CN102010239B (en) Organic fertilizer and preparation method thereof
CN106831125A (en) A kind of fertilizer synergist of improved soil

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20181225

WW01 Invention patent application withdrawn after publication