CN109069392A - Liquid skin detergent and liquid skin cleaning article - Google Patents
Liquid skin detergent and liquid skin cleaning article Download PDFInfo
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- CN109069392A CN109069392A CN201780023756.XA CN201780023756A CN109069392A CN 109069392 A CN109069392 A CN 109069392A CN 201780023756 A CN201780023756 A CN 201780023756A CN 109069392 A CN109069392 A CN 109069392A
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- liquid skin
- cationization
- polygalactomannan
- skin detergent
- fatty acid
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
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Abstract
The subject of the invention is to provide dense and at low temperature from the discharge of the container with distributor good liquid skin detergent and the liquid skin cleaning articles with the smooth and foam using rear skin.It is a kind of liquid skin detergent as solution, it contains fatty acid soaps, cationization polygalactomannan and polyethylene glycol, the neutralization ratio of fatty acid soaps is 90mol% or more 99mol% or less, it is cationized polygalactomannan containing than being 2,000,000 or more for the weight average molecular weight Mw of 0.05 mass % or more, polyethylene glycol relative to liquid skin detergent total amount.
Description
Technical field
The present invention relates to liquid skin detergent and liquid skin cleaning articles.
Background technique
In recent years, as skin cleaner, it is desirable to be that skin is made to there is smooth, moist feeling and from foam after the cleaning
Feeling good when contacting with skin considers the thin and dense skin cleaner of foam.In order to meet such requirement, carry out
Various researchs.In order to be improved using the smooth of rear skin, moist feeling, it is well-known using cationization polymer.This
Outside, in order to keep foam dense, it is known to use the nonionic polymerics such as polyethylene glycol.
For example, being described in patent document 1 by using the cation combined with specific anionic surfactant
Property polymer, can get with adjustment effect cleaning compositions.In addition, describing in patent document 2 by using unneutralized
Fatty acid soaps, cation property copolymer and the polyethylene glycol of specific molecular weight etc., it is thin and extend good to can get foam
Paste detergent.In addition, further, being described in patent document 3 by using with specific degree ofacationic substitution and molecule
The cation property copolymer of amount can get the excellent composition of the protection to skin.
Existing technical literature
Patent document
Patent document 1: No. 4965452 bulletins of Japanese Patent No.
Patent document 2: No. 5555003 bulletins of Japanese Patent No.
Patent document 3: No. 5436778 bulletins of Japanese Patent No.
Summary of the invention
Problems to be solved by the invention
If known in order to using the smooth raising of rear skin, and make containing such as cationization polygalactomannan
For cation property copolymer, then the content viscosity of composition rises.Existing if content excess stickiness rises cannot be from
Liquid cleaner such problems is discharged in the outlet of container with distributor (dispenser).In addition, containing unneutralized
The cleaning compositions of fatty acid soaps have the tendency that viscosity rises in winter due to superfluous fatty acid.On the other hand, if in order to
Keep foam dense, and be excessively added polyethylene glycol, then has the tendency that there is the discharge from container using the smooth impaired of rear skin
Wire drawing such problems occurs for mouth.For liquid skin detergent, in order to and it is frothy dense and using rear skin it is smooth,
With, from the discharge of the container with distributor, prescription documented by above patent document is insufficient under low temperature.Here so-called
Liquid has mobility at normal temperature, is 50000mPas or less with the measured value that Brookfield viscometer measures.
The present invention is to propose in view of the foregoing, and the purpose is to provide to have the smooth and foam for using rear skin
It is dense and at low temperature from the discharge of distributor good liquid skin detergent and liquid skin cleaning system
Product.
Means for solving the problems
Liquid skin detergent of the invention is containing fatty acid soaps, cationization polygalactomannan and poly- second two
The liquid skin detergent of alcohol,
The neutralization ratio of fatty acid soaps be 90mol% or more 99mol% hereinafter,
Be cationized polygalactomannan relative to liquid skin detergent total amount containing than for 0.05 mass % with
On,
The weight average molecular weight Mw of polyethylene glycol is 2,000,000 or more.
It is preferred that polyethylene glycol is relative to liquid skin detergent total amount containing than for 0.01 mass % or more 0.1 mass %
Below.
It can be further containing the cationization polymer other than cationization polygalactomannan.
The N containing ratio of cationization polygalactomannan is preferably 0.2% or more 3.0% or less.
Liquid skin detergent of the invention can further contain dihydric alcohol.
It is preferred that mass ratio, that is, dihydric alcohol quality/cationization of the dihydric alcohol relative to cationization polygalactomannan
The quality of polygalactomannan is 20 or more.
Liquid skin cleaning article of the invention is that liquid skin detergent of the invention is filled in made of container.
The effect of invention
Liquid skin detergent of the invention is containing fatty acid soaps, cationization polygalactomannan and poly- second two
The liquid skin detergent of alcohol, the neutralization ratio of fatty acid soaps are 90mol% or more 99mol% hereinafter, the poly- gala that is cationized is sweet
Reveal glycan relative to liquid skin detergent total amount containing than for 0.05 mass % or more, the weight average molecular weight Mw of polyethylene glycol
It is 2,000,000 or more, therefore there is the dense of the smooth and foam for using rear skin, and can be discharged from distributor.
Specific embodiment
Hereinafter, being explained in detail to liquid skin detergent of the invention.
Liquid skin detergent of the invention is containing fatty acid soaps, cationization polygalactomannan and poly- second two
The liquid skin detergent of alcohol, the neutralization ratio of fatty acid soaps are 90mol% or more 99mol% hereinafter, the poly- gala that is cationized is sweet
Reveal glycan relative to liquid skin detergent total amount containing than for 0.05 mass % or more, the weight average molecular weight Mw of polyethylene glycol
It is 2,000,000 or more.
Hereinafter, being explained in detail to each ingredient.
(fatty acid soaps)
Fatty acid soaps used in the present invention are to make fatty acid salt made of fatty acid neutralization with alkali.As composition fatty acid
The fatty acid of salt can enumerate capric acid, lauric acid, myristic acid, palmitinic acid, stearic acid, isostearic acid, oleic acid, linoleic acid, peanut
Sour, behenic acid, lignoceric acid, coco-nut oil fatty acid etc..
In addition, potassium hydroxide can be enumerated as alkali.
The neutralization ratio of fatty acid soaps be 90mol% or more 99mol% hereinafter, preferably 93mol% or more 96mol% with
Under.By making neutralization ratio 90mol% or more, even if viscosity rises in a low temperature of such as 5 DEG C, can also be arranged from distributor
Out.In addition, by for 99%mol hereinafter, smooth using rear skin to have.
Here, the neutralization ratio of fatty acid soaps is total amount of the fatty acid amount (mol) by that will be neutralized divided by fatty acid
(mol) value found out.
From the viewpoint of ensuring cleaning force and blistering, fatty acid soaps relative to liquid skin detergent total amount containing than
Preferably 5 mass % or more, 30 mass % hereinafter, more preferably 10 mass % or more, 25 mass % hereinafter, further preferably 15
Quality % or more 25 mass % or less.
(cationization polygalactomannan)
The polygalactomannan that is cationized is to be made of main chain mannose, the high water solubility that side chain is made of galactolipin
Obtained by molecule is cationized.The cationization polygalactomannan that the ratio of galactolipin and mannose is 1:2 is claimed
For the guar gum that is cationized, the cationization polygalactomannan that the ratio of galactolipin and mannose is 1:3 is known as sun
Tara gum is ionized, the cationization polygalactomannan that the ratio of galactolipin and mannose is 1:4 is known as being cationized
Locust bean gum.The cationization polygalactomannan of any ratio can be used in the present invention.
Cationization polygalactomannan makes galactomannans react and obtain with cationic agent.Cation
Agent can be used comprising can be with the tertiary amino for the group that reactive hydrogen ion reacts present in galactomannans
Close object or quaternary ammonium compound.It can enumerate for example, the chloro- 2- hydroxyl of 2- dialkylaminoethyl chloride and quaternary ammonium compound such as 3-
Base hydroxypropyltrimonium chloride and 2,3- epoxy-hydroxypropyltrimonium chloride.As preference, glycidyl three can be enumerated
Alkylammonium salt and the halogenated -2- hydroxypropyl ammonium salt of 3-, such as glycidyltrimetiiylammonium ammonium chloride, glycidyl
Triethyl ammonium chloride, glycidyl tripropyl ammonium chloride, glycidyl ethyl alkyl dimethyl ammonium chloride, glycidyl diethyl
Methyl ammonium and bromide corresponding with them and iodide；3- chlorine-2-hydroxyl hydroxypropyltrimonium chloride, 3- are chloro-
2- hydroxypropyl triethyl ammonium chloride, 3- chlorine-2-hydroxyl propyl tripropyl ammonium chloride, 3- chlorine-2-hydroxyl ethyl dimethyl
Ammonium chloride and bromide corresponding with them and iodide；Compound with quaternary ammonium compound for example comprising imidazoline ring
Halide.
One kind can be used only in the polygalactomannan that is cationized, and can also be applied in combination two kinds or more.
As commercially available product, the ラ ボ ー Le ガ system CG- of five Xie フ ー De & ケ ミ カ Le Co. Ltd. system of DSP can be enumerated
M6L (N containing ratio 1.0~1.5%), ラ ボ ー Le ガ system CG-M (N containing ratio 1.7~2.3%), ラ ボ ー Le ガ system CG-M8M
(N containing ratio 2.2~2.8%), Toho Chemical Industry Co., Ltd. (JP) Tokyo-To, Japan カ チ ナ ー Le CG-100S (N containing ratio 1.0~
1.7%).
The N containing ratio of cationization polygalactomannan is preferably 0.2% or more 3.0% hereinafter, further preferably
0.5% or more 2.5% or less.
Here, so-called N containing ratio is the value found out by the ratio (weight %) for the nitrogen-atoms for including in ingredient.
From by the discharge with pump or the container etc. of distributor viewpoint with prevent wire drawing from the viewpoint of, it is of the invention
The molecular weight of cationization polygalactomannan used in liquid skin detergent be preferably 10,000 or more 1,000 ten thousand hereinafter,
More preferably 30,000 or more 300 ten thousand hereinafter, further preferably 100,000 or more 200 ten thousand or less.
Be cationized polygalactomannan relative to liquid skin detergent total amount containing than for 0.05 mass % with
On.From by the discharge with pump or the container etc. of distributor viewpoint with prevent wire drawing from the viewpoint of, the upper limit is preferably 1.0
Quality % is hereinafter, more preferably 0.1 mass % or more, 0.5 mass % or less.
(polyethylene glycol)
The weight average molecular weight Mw of polyethylene glycol used in the present invention is 2,000,000 or more.The upper limit is preferably 8,000,000 or less.
Further preferably greater than 3,000,000 and be 7,000,000 or less.
In addition, polyethylene glycol is relative to liquid skin detergent total amount containing than being preferably 0.01 mass % or more 0.20
Quality % hereinafter, more preferably 0.01 mass % or more, 0.10 mass % hereinafter, further preferably 0.02 mass % or more
0.05 mass % or less.By that foam can be made dense for 0.01 mass % or more.In addition, by for 0.20 mass % hereinafter,
Blistering can be prevented to be deteriorated, the volume of foam is reduced.
Here, the weight average molecular weight Mw of polyethylene glycol is to analyze the value found out by column.
In commercially available product, can enumerating the bright ア Le U ッ Network ス E-300 at chemical industry Co. Ltd. system, (weight average molecular weight is about
700 ten thousand), ア Le U ッ Network ス E-240 (weight average molecular weight about 5,000,000), ア Le U ッ Network ス E-160 (weight average molecular weight about 400
Ten thousand), ア Le U ッ Network ス E-100 (weight average molecular weight about 3,000,000), ア Le U ッ Network ス E-75 (weight average molecular weight about 2,000,000), ダ
Port リ オ ッ Network ス WSR 301 (weight average molecular weight about 4,000,000), the Port リ オ ッ Network ス WSR of ウ ケ ミ カ Le Amada Co., Ltd.
N60K CG (weight average molecular weight about 2,000,000), Port リ オ ッ Network ス N80 (weight average molecular weight 220,000), Sumitomo Seika Co., Ltd's system
PEO-27P (weight average molecular weight about 7,200,000), PEO-18P (weight average molecular weight about 4,800,000), PEO-15P (weight average molecular weight about 400
Ten thousand), PEO-8P (weight average molecular weight about 2,000,000) etc..
(the cationization polymer other than cationization polygalactomannan)
As cationization polymer, cationized cellulose, cationic starch, poly (dially dialkyl) base season can be enumerated
Ammonium salt/acrylamide copolymer, poly (dially dialkyl) based quaternary ammonium salt/acrylamide/acrylic acid copolymer etc..Wherein, preferably
Cationized cellulose, poly (dially dialkyl) based quaternary ammonium salt/acrylamide copolymer, more preferably poly (dially dialkyl) base quaternary ammonium
Salt/acrylamide copolymer.
As poly (dially dialkyl) based quaternary ammonium salt/acrylamide copolymer, can enumerate for example, マ ー コ ー ト 550 is (heavy equal
Molecular weight: 160,000, cationic charge density: 4.22meq/g), マ ー コ ー ト 2200 (weight average molecular weight: 90,000, cationic charge
Density: 4.22meq/g), マ ー コ ー ト S (weight average molecular weight: 260,000, cationic charge density: 4.22meq/g) [more than, day
This ル ー Block リ ゾ ー Le society, the copolymer of acrylamide and diallyl dimethyl ammonium salt], Port イ ズ C-60H (Weight-average molecular
Amount: 600,000, cationic charge density: 1.07~1.78meq/g), カ チ セ ロ M-80 (weight average molecular weight: 800,000, cation electrodeposition
Lotus density: 0.93~1.21meq/g), Port イ ズ C-150L (weight average molecular weight: 1,500,000, cationic charge density: 0.71~
1.07meq/g) [more than, Hua Wangshe, cationized cellulose (chlorination O- [2- hydroxyl -3- (trimethyl ammonium) propyl] hydroxyl second
Base cellulose)].
(dihydric alcohol)
Liquid skin detergent of the invention can further contain dihydric alcohol.As dihydric alcohol, can enumerate propylene glycol,
Dipropylene glycol, butanediol, isoprene etc..Dihydric alcohol has the function of moisturizer.
Dihydric alcohol is relative to liquid skin detergent total amount containing than being preferably 1 or more 15 hereinafter, more preferably 4 or more
10 or less.
From make from the discharge of distributor it is good from the viewpoint of, dihydric alcohol relative to cationization polygalactomannan
Mass ratio, that is, dihydric alcohol quality/cationization polygalactomannan quality be preferably 16 or more, more preferably 20 with
On.From the viewpoint of keeping blistering good, the upper limit is preferably 30 or less.Further preferred range is 22 or more 28 or less.
(other ingredients)
In liquid skin detergent of the invention, within the scope of the effect of the invention, can containing it is other at
Point.As other ingredients, can enumerate for example, anionic surfactant, nonionic surfactant, amophoteric surface active
Agent, thickener, polyalcohol, chelating agent, moisturizer, aqueous carrier, pH adjusting agent, fragrance.
As anionic surfactant, Texapon Special, polyoxyethylene lauryl ether ammonium sulfate, laurel can be enumerated
Base sulfuric acid triethylamine, polyoxyethylene lauryl ether sulfuric acid triethylamine, triethanolamine lauryl sulfate, polyoxyethylene lauryl ether sulphur
Triethylenetetraminehexaacetic acid hydramine, lauryl sulfate monoethanolamine, polyoxyethylene lauryl ether diethanolamine, lauryl sulfate diethanol
Amine, polyoxyethylene lauryl ether sulfate, lauryl monoglyceride sodium sulphate, NaLS, lauryl polyoxy
Ethylene ether sodium sulfate, lauryl potassium sulfate, polyoxyethylene lauryl ether potassium sulfate, sodium lauryl sarcosinate, Hamposyl L
Sodium, cocoyl sarcosine, cocoyl sarcosine, cocounut oil acyl sulfate ammonium, lauroyl ammonium sulfate, coconut palm sodium oleyl sulfate, lauroyl sulphur
Sour sodium, cocounut oil acyl sulfate potassium, lauryl potassium sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, cocounut oil acyl sulphur
Sour monoethanolamine, lauryl sulfate monoethanolamine and their combination.
The reaction life for the fatty acid for being esterified furthermore, it is possible to enumerate with isethionic acid, and having been neutralized with sodium hydroxide
At object (for example, fatty acid is by coconut oil or palm kernel oil-derivation) and the fatty acid amide of methyl tauride sodium or
Sylvite (for example, fatty acid is by coconut oil or palm kernel oil-derivation).
Nonionic surfactant is commonly defined as the change of the hydrophilic composition comprising hydrophobic combination and nonionic
Close object.As the example of hydrophobic combination, alkyl, alkyl aromatic, dialkylsiloxane, polyoxyalkylene and by fluorine can be enumerated
Instead of alkyl.The example of hydrophilic composition is polyoxyalkylene, phosphine oxide, sulfoxide, amine oxide and amide.As non-
Other examples of ionic surfactant can enumerate alkyl polysaccharide class, for example, alkyl polysaccharide class.
As amphoteric surfactant, amine oxide, sulfobetaines and carboxybetaine etc. can be enumerated.
As thickener, it can be cited for example that, NaCl, NH4Cl、KCl、Na2SO4, aliphatic alcohol, aliphatic ester, fatty acid
Amide, aliphatic alcohol polyglycol ether, D-sorbite polyglycol ether, coconut oleoyl amine single ethanol amide (coconut oleoyl amine MEA), coconut palm
Oleamide diglycollic amide, Cocoamidopropyl betaine, clay, silica, cellulose-based polymer and xanthan gum.
As polyalcohol, glycerol, D-sorbite, xylitol and maltitol etc. can be enumerated.
As chelating agent, preferably for example selected from ethane -1- hydroxyl -1,1- di 2 ethylhexyl phosphonic acid, ethylenediamine tetra-acetic acid, the sweet ammonia of methyl
Sour oxalic acid, hydroxyethyliminodiacetic acid, ethylenediamine disuccinic acid, Pidolidone-N, N- oxalic acid, N-2- hydroxyethyl
One or more of iminodiacetic acid, citric acid, succinic acid and their salt.
As aqueous carrier, the lower alcohol of Purified Water, carbon atom number 2~6 can be enumerated.Preferably Purified Water.Aqueous load
Body contains 30 mass % or more, 70 mass % or less preferably with respect to liquid skin detergent total amount.
Liquid skin detergent of the invention can be filled in such as container with one touch type lid or liquid distributor, and
Liquid skin cleaning article is made.
Embodiment
Hereinafter, illustrating the present invention in further detail by embodiment, but the present invention is not limited by these embodiments.This
Outside, the use level in following embodiment etc. means that quality % as long as no specializing.
[embodiment 1~17, comparative example 1~8]
Manufacture has the liquid skin detergent formed documented by following table 1~4 by conventional method, evaluates from liquid
The discharge of distributor uses the smooth and foam dense of rear skin.
The discharge > of slave liquid distributor under < low temperature (5 DEG C)
The row of slave liquid distributor under low temperature (5 DEG C) to evaluate liquid skin detergent based on the following metewand
Property out.
Will be added to the sample of container with liquid distributor to save 24 hours in 5 DEG C of thermostat, as it is following that
The workability of distributor after sample evaluation just taking-up.Distributor has used generally Co., Ltd. used in liquid cleaner lucky
The wild made P-308 of industry.
(evaluation criteria)
A: sample can easily be discharged.
B: it although distributor feels that the recovery of the distributor after weight or discharge is slow (less than 10 seconds), can be discharged.
C: cannot be discharged, or not restore within distributor 10 seconds or more after discharge.
< uses smooth, foam the dense > of rear skin
The questionnaire survey that following items are carried out after each sample, base are used by common application method by 5 special group members
Average score is obtained in result.
Use the smooth of rear skin: the skin after flushing is smooth.
Foam it is dense: foam have elastic force.
1: being not considered as completely so
2: being not considered as so
4: thinking such
5: thinking very much such
(evaluation criteria)
Based on above-mentioned average score, evaluate as described below.
AA: average score >=4.5
A:4.5 > average score > 3.5
B:2.5≤average score≤3.5
C: average score < 2.5
By evaluation result it is shown in table 1 together with the cooperation of material~table 4 in.
[table 1]
[table 2]
[table 3]
[table 4]
The details of material in above-mentioned 1~table of table 4 is as described below.
(polygalactomannan)
Melon ear trimethyl ammonium chloride (low N containing ratio): ラ ボ ー Le ガ system CG-M6L (five Xie フ ー of DSP
De & ケ ミ カ Le Co. Ltd. system)
Melon ear trimethyl ammonium chloride (middle N containing ratio): ラ ボ ー Le ガ system CG-M (five Xie フ ー De & of DSP
ケ ミ カ Le Co. Ltd. system)
Melon ear trimethyl ammonium chloride (high N containing ratio): ラ ボ ー Le ガ system CG-M8M (five Xie フ ー of DSP
De & ケ ミ カ Le Co., Ltd.)
Guar gum (nonionic): Meyprogat 90-S (three brilliant Co. Ltd. systems)
(polyethylene glycol)
Weight average molecular weight (about 7,000,000): ア Le U ッ Network ス E-300 (bright at chemical industry Co. Ltd. system)
Weight average molecular weight (about 5,000,000): ア Le U ッ Network ス E-240 (bright at chemical industry Co. Ltd. system)
Weight average molecular weight (about 4,000,000): ア Le U ッ Network ス E-160 (bright at chemical industry Co. Ltd. system)
Weight average molecular weight (about 3,000,000): ア Le U ッ Network ス E-100 (bright at chemical industry Co. Ltd. system)
Weight average molecular weight (about 2,000,000): ア Le U ッ Network ス E-75 (bright at chemical industry Co. Ltd. system)
Weight average molecular weight (about 220,000): Port リ オ ッ Network ス WSR N80 (ダ ウ ケ ミ カ Le Amada Co., Ltd. system)
As shown in Table 1, be cationized polygalactomannan N containing ratio be 1.0~2.8% Examples 1 to 3 in,
Pump discharge property under low temperature is good, uses the smooth and foam dense also good of rear skin.In particular, N containing ratio is 1.0
In~2.3% embodiment 2 and 3, good result is obtained in all evaluations.
On the other hand, it has used the comparative example 1 of nonionic guar gum and has gathered without using the poly- galactomannan that is cationized
In the comparative example 2 of sugar, the smooth difference of rear skin is used.In addition, cationization polygalactomannan and polyethylene glycol are all free of
In some comparative examples 3, using rear skin smooth and foam it is dense poorer than embodiment.
As shown in Table 2, the comparative example 4 that molecular weight is 220,000 polyethylene glycol and the ratio without using polyethylene glycol have been used
Compared in example 5, the dense difference of foam compared with having used the embodiment 4~7 of polyethylene glycol of 2,000,000 or more molecular weight.
As shown in Table 3, cationization polygalactomannan is relative to liquid skin detergent total amount containing than being less than
In the comparative example 6 of 0.05 mass %, the smooth poorer than embodiment of rear skin is used.
As shown in Table 4, for the neutralization ratio of fatty acid soaps down in the comparative example 7 of 87mol%, the discharge from distributor is poor.
On the other hand, in the comparative example 8 of the excessively a height of 102mol% of neutralization ratio, the dense difference of the smooth and foam of rear skin is used.
(prescription example)
Hereinafter, enumerating the prescription example of liquid skin detergent of the invention.The present invention is not by any restriction of prescription example.Separately
Outside, use level is all by the quality % expression relative to total product amount.
Prescription example 1: the neutralization ratio of fatty acid soaps is 93mol%.
The discharge of the slave liquid distributor of prescription example 1 is commented using smooth and foam dense all A of rear skin
Valence.
Prescription example 2: the neutralization ratio of fatty acid soaps is 95mol%.
The discharge of the slave liquid distributor of prescription example 2 is commented using smooth and foam dense all A of rear skin
Valence.
Claims (7)
1. a kind of liquid skin detergent, containing fatty acid soaps, be cationized polygalactomannan and polyethylene glycol,
The neutralization ratio of the fatty acid soaps be 90mol% or more and 99mol% hereinafter,
The cationization polygalactomannan is relative to the liquid skin detergent total amount containing than for 0.05 matter
% or more is measured,
The weight average molecular weight Mw of the polyethylene glycol is 2,000,000 or more.
2. liquid skin detergent according to claim 1, the polyethylene glycol is relative to the liquid skin detergent
Total amount containing than for 0.01 mass % or more and 0.10 mass % or less.
3. liquid skin detergent according to claim 1 or 2 further contains the poly- galactomannan of cationization
Cationization polymer other than glycan.
4. liquid skin detergent described in any one of claim 1 to 3, the cationization polygalactomannan
N containing ratio be 0.2% or more and 3.0% or less.
5. liquid skin detergent according to any one of claims 1 to 4, further contains dihydric alcohol.
6. liquid skin detergent according to claim 5, the dihydric alcohol is sweet relative to the poly- gala of cationization
Mass ratio, that is, dihydric alcohol quality/cationization polygalactomannan the quality for revealing glycan is 20 or more.
7. a kind of liquid skin cleaning article is that liquid skin detergent according to any one of claims 1 to 6 is filled in
Made of container.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016083176A JP6254638B2 (en) | 2016-04-18 | 2016-04-18 | Liquid skin cleansers and liquid skin cleansing products |
| JP2016-083176 | 2016-04-18 | ||
| PCT/JP2017/015256 WO2017183571A1 (en) | 2016-04-18 | 2017-04-14 | Liquid skin cleanser and liquid skin cleansing product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109069392A true CN109069392A (en) | 2018-12-21 |
| CN109069392B CN109069392B (en) | 2020-04-10 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780023756.XA Active CN109069392B (en) | 2016-04-18 | 2017-04-14 | Liquid skin cleanser and liquid skin cleansing product |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP6254638B2 (en) |
| KR (1) | KR101991289B1 (en) |
| CN (1) | CN109069392B (en) |
| SG (1) | SG11201809105XA (en) |
| TW (1) | TW201739445A (en) |
| WO (1) | WO2017183571A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7422541B2 (en) | 2019-12-27 | 2024-01-26 | 花王株式会社 | skin cleansing composition |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02142900A (en) * | 1988-11-25 | 1990-05-31 | Lion Corp | Liquid soap composition |
| CN1780602A (en) * | 2003-05-01 | 2006-05-31 | 宝洁公司 | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase comprising a water in oil emulsion |
| JP2007031293A (en) * | 2005-07-22 | 2007-02-08 | Toho Chem Ind Co Ltd | Cosmetic composition comprising low-cationized galactomannan polysaccharide |
| CN1914229A (en) * | 2004-01-30 | 2007-02-14 | 东邦化学工业株式会社 | Cation-modified purified galactomannan polysaccharide and cosmetic composition containing the substance |
| JP2010180181A (en) * | 2009-02-06 | 2010-08-19 | Kracie Home Products Ltd | Detergent composition |
| CN102307979A (en) * | 2009-02-13 | 2012-01-04 | 花王株式会社 | Cleaner |
| JP2012126805A (en) * | 2010-12-15 | 2012-07-05 | Kao Corp | Skin cleaning composition |
| CN103108946A (en) * | 2010-09-28 | 2013-05-15 | 荷兰联合利华有限公司 | Liquid soap compositions |
| CN103800213A (en) * | 2012-11-08 | 2014-05-21 | 花王株式会社 | Detergent composition |
| CN104159562A (en) * | 2012-03-02 | 2014-11-19 | 花王株式会社 | Skin cleanser composition |
| WO2015014604A1 (en) * | 2013-08-01 | 2015-02-05 | Unilever Plc | Foamable personal care composition comprising a continuous oil phase |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4965452A (en) | 1972-10-23 | 1974-06-25 | ||
| JPS5436778A (en) | 1977-08-26 | 1979-03-17 | Horiba Ltd | Photosound effect type analyzer |
| DE2845310A1 (en) | 1978-10-18 | 1980-04-24 | Bayer Ag | TIRES FOR SLOW DRIVING VEHICLES |
| DE10113054A1 (en) | 2001-03-15 | 2002-09-26 | Beiersdorf Ag | Self-foaming product used for skin care contains an emulsifier system, a lipid phase, gas, inorganic thickener, organic hydrocolloid and solid body |
| CN103800214B (en) * | 2012-11-08 | 2018-12-25 | 花王株式会社 | Cleanser compositions |
-
2016
- 2016-04-18 JP JP2016083176A patent/JP6254638B2/en active Active
-
2017
- 2017-04-14 SG SG11201809105XA patent/SG11201809105XA/en unknown
- 2017-04-14 CN CN201780023756.XA patent/CN109069392B/en active Active
- 2017-04-14 WO PCT/JP2017/015256 patent/WO2017183571A1/en active Application Filing
- 2017-04-14 KR KR1020187030228A patent/KR101991289B1/en active IP Right Grant
- 2017-04-17 TW TW106112731A patent/TW201739445A/en unknown
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02142900A (en) * | 1988-11-25 | 1990-05-31 | Lion Corp | Liquid soap composition |
| CN1780602A (en) * | 2003-05-01 | 2006-05-31 | 宝洁公司 | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase comprising a water in oil emulsion |
| CN1914229A (en) * | 2004-01-30 | 2007-02-14 | 东邦化学工业株式会社 | Cation-modified purified galactomannan polysaccharide and cosmetic composition containing the substance |
| JP2007031293A (en) * | 2005-07-22 | 2007-02-08 | Toho Chem Ind Co Ltd | Cosmetic composition comprising low-cationized galactomannan polysaccharide |
| JP2010180181A (en) * | 2009-02-06 | 2010-08-19 | Kracie Home Products Ltd | Detergent composition |
| CN102307979A (en) * | 2009-02-13 | 2012-01-04 | 花王株式会社 | Cleaner |
| CN103108946A (en) * | 2010-09-28 | 2013-05-15 | 荷兰联合利华有限公司 | Liquid soap compositions |
| JP2012126805A (en) * | 2010-12-15 | 2012-07-05 | Kao Corp | Skin cleaning composition |
| CN104159562A (en) * | 2012-03-02 | 2014-11-19 | 花王株式会社 | Skin cleanser composition |
| CN103800213A (en) * | 2012-11-08 | 2014-05-21 | 花王株式会社 | Detergent composition |
| WO2015014604A1 (en) * | 2013-08-01 | 2015-02-05 | Unilever Plc | Foamable personal care composition comprising a continuous oil phase |
Non-Patent Citations (1)
| Title |
|---|
| 刘程等编: "《表面活性剂性质理论与应用》", 30 June 2003, 北京工业大学出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20180120271A (en) | 2018-11-05 |
| KR101991289B1 (en) | 2019-06-20 |
| SG11201809105XA (en) | 2018-11-29 |
| WO2017183571A1 (en) | 2017-10-26 |
| CN109069392B (en) | 2020-04-10 |
| TW201739445A (en) | 2017-11-16 |
| JP6254638B2 (en) | 2017-12-27 |
| JP2017193494A (en) | 2017-10-26 |
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