CN109053124A - Using the preparation flood control of shale Extra-fine sand for the method for anti-stone - Google Patents

Using the preparation flood control of shale Extra-fine sand for the method for anti-stone Download PDF

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Publication number
CN109053124A
CN109053124A CN201811236149.4A CN201811236149A CN109053124A CN 109053124 A CN109053124 A CN 109053124A CN 201811236149 A CN201811236149 A CN 201811236149A CN 109053124 A CN109053124 A CN 109053124A
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CN
China
Prior art keywords
stone
fine sand
extra
flood control
shale
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811236149.4A
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Chinese (zh)
Inventor
张金良
景来红
路新景
符勇
吴向东
于洋
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Yellow River Engineering Consulting Co Ltd
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Yellow River Engineering Consulting Co Ltd
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Publication date
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Priority to CN201811236149.4A priority Critical patent/CN109053124A/en
Publication of CN109053124A publication Critical patent/CN109053124A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of using the preparation flood control of shale Extra-fine sand for the method for anti-stone, it is that a certain amount of calcined clay, slag powders, flyash and sodium silicate are added in shale Extra-fine sand, standby anti-stone briquet is added water and stirred uniformly and be squeezed into after being aged 2 hours, standby anti-stone finished product is obtained after conserving;Wherein shale Extra-fine sand and calcined clay, slag powders, the percent mass proportioning of flyash and sodium silicate are as follows: shale Extra-fine sand 60% ~ 70%, calcined clay 10% ~ 15%, slag powders 5% ~ 10%, flyash 5% ~ 10%, sodium silicate 3% ~ 5%;Additional water is the 13%-15% of material total amount.The raw materials used in the present invention is easy to get, and preparation method is simple, waste utilization, energy conservation and environmental protection.The standby anti-stone shape and volume size of preparation can be adjusted according to actual needs.After tested, finished product can substitute building stones as flood control and use for anti-stone for anti-stone uniaxial compressive strength in 25MPa or more.

Description

Using the preparation flood control of shale Extra-fine sand for the method for anti-stone
Technical field
The present invention relates to hydraulic engineering technologies, prepare flood control using shale Extra-fine sand more particularly, to a kind of for the side of anti-stone Method.
Background technique
The silt that the Yellow River is carried along into the Bohai Sea is above tens million of tons every year, yellow with the substantial increase of middle and upper reaches water River part silt particle is deposited again in middle and lower reaches riverbed, and the silt particle of these siltations is based on shale Extra-fine sand, and also known as the Yellow River is in soil.
The flood control of the Yellow River middle and lower reaches will lay in a large amount of building stones every year.Since many locations of middle and lower reaches are located in Plain, Away from stone pit kilometers up to a hundred, so long range freight charges reinforce the policy of environmental protection plus country, the flood control is set to be in for the price of anti-building stones The gesture to rise steadily.If can on the spot with the preparation flood control of the Yellow River shale Extra-fine sand for anti-building stones, on the one hand can slow down under The siltation for swimming riverbed, can substantially reduce flood control on the other hand for the price of anti-building stones, play the role of killing two birds with one stone.
Summary of the invention
The purpose of the present invention is to provide a kind of using the preparation flood control of shale Extra-fine sand for the method for anti-stone, and this method is simple Easy, energy conservation and environmental protection has good economic benefit and social benefit.
To achieve the above object, the present invention can take following technical proposals:
It is of the present invention using shale Extra-fine sand preparation flood control for anti-stone method, be added in shale Extra-fine sand it is a certain amount of Calcined clay, slag powders, flyash and sodium silicate, add water and stir uniformly and be squeezed into standby anti-stone briquet, warp after being aged 2 hours Standby anti-stone finished product is obtained after maintenance;Wherein the shale Extra-fine sand and calcined clay, slag powders, the quality of flyash and sodium silicate Per distribution ratio are as follows: shale Extra-fine sand 60% ~ 70%, calcined clay 10% ~ 15%, slag powders 5% ~ 10%, flyash 5% ~ 10%, sodium silicate 3%~5%;Additional water is the 13%-15% of material total amount.
The shale Extra-fine sand is the deposit of lower reaches of river;Main component is based on quartz, content >=90%, shale Ingredient is clay, content < 5%.
The calcined clay is that clay (cohesive soil gathered materials on the spot, loess or silt) is calcined through 750 ~ 800 DEG C, so Afterwards grinding at 150-200 mesh powder.
The slag powders be powder of the blast-furnace cinder through fineness 300-400 mesh made of grinding, main component be calcium oxide, Silica and aluminium oxide, wherein calcium oxide content be 35% ~ 40%, silica content be 30% ~ 35%, alumina content be 10% ~ 15%, also containing a small amount of magnesia, iron oxide etc..
The flyash is flying dust caused by coal burning, and main component is silica and aluminium oxide, wherein silica Content is generally 45% ~ 50%, and alumina content is generally 30% ~ 35%, secondly also contains a small amount of calcium oxide and iron oxide.
The sodium silicate is the solid powder of modulus 2.0.
The external adding water uses tap water or free of contamination natural water, and water temperature is 30 ~ 50 DEG C, if water temperature is too low, flower bulb Alkali is not easy to melt, and water temperature is too high, easily scald operator, causes industrial accident.
Standby anti-stone shape and volume size prepared by the present invention can be adjusted according to actual needs.After tested, finished product Standby anti-stone uniaxial compressive strength can substitute building stones as flood control and use for anti-stone in 25MPa or more.
The advantage of the invention is that it is glutinous to add a small amount of calcining using the shale Extra-fine sand that the Yellow River middle and lower reaches are deposited as major ingredient Soil, slag powders, flyash and sodium silicate preparation flood control are for anti-stone, and raw material is easy to get, and preparation method is simple, and slag powders and flyash are The waste material of iron and steel enterprise and coal-burning utilities, waste utilization, energy conservation and environmental protection;The standby anti-stone monolithic quality of preparation is larger, is suitble to machinery The problem of change is speedily carried out rescue work, and very good solution root stone is wandered away;It needs to cut into a mountain fried stone with the standby anti-stone of tradition, and by long-distance transport from adopting The method that the transport of stone field comes is compared, and greatly reduces transportation cost and flood control cost, while the conjunction to shale Extra-fine sand on the spot Reason utilizes the siltation for slowing down middle and lower reaches riverbed again.
Specific embodiment
The method of the present invention is relatively suitable for Yellow River basin.
More detailed explanation is done to the present invention below by specific embodiment, in order to the reason of those skilled in the art Solution.
Embodiment 1
In Yellow River basin Huayuankou, for the silt particle of siltation through detecting, shale Extra-fine sand content accounts for 95%.
The present invention is using the preparation flood control of shale Extra-fine sand for the method for anti-stone are as follows: it is glutinous that calcining is added in shale Extra-fine sand Soil, slag powders, flyash and sodium silicate, wherein the weight percent of each material matches are as follows: shale Extra-fine sand: calcined clay: slag Powder: flyash: sodium silicate=70%:10%:10%:5%:5%;Stirrer for mixing will be put into after all raw materials in proportion precise Uniformly, the water (30 DEG C≤water temperature≤50 DEG C) that material total amount 13% is then added continues stirring 3 minutes, forms pug;Pug is old Change 2 hours, standard brick blank is squeezed into brickmaking machine, natural curing 7 days, the standby anti-stone finished product of intensity 25MPa can be obtained.
Embodiment 2
In Yellow River basin Lankao section, for the silt particle of siltation through detecting, shale Extra-fine sand content accounts for 91%.
The present invention is using the preparation flood control of shale Extra-fine sand for the method for anti-stone are as follows: it is glutinous that calcining is added in shale Extra-fine sand Soil, slag powders, flyash and sodium silicate, wherein the weight percent of each material matches are as follows: shale Extra-fine sand: calcined clay: slag Powder: flyash: sodium silicate=65%:15%:10%:7%:3%;Stirrer for mixing will be put into after all raw materials in proportion precise Uniformly, the water (30 DEG C≤water temperature≤50 DEG C) that material total amount 13 ~ 15% is then added continues stirring 3 minutes, forms pug;By mud Material ageing 2 hours, is squeezed into standard brick blank in brickmaking machine, natural curing 7 days, can be obtained the standby anti-stone of intensity 27MPa at Product.
Embodiment 3
In Yellow River basin Jinan section, for the silt particle of siltation through detecting, shale Extra-fine sand content accounts for 94%.
The present invention is using the preparation flood control of shale Extra-fine sand for the method for anti-stone are as follows: it is glutinous that calcining is added in shale Extra-fine sand Soil, slag powders, flyash and sodium silicate, wherein the weight percent of each material matches are as follows: shale Extra-fine sand: calcined clay: slag Powder: flyash: sodium silicate=60%:15%:10%:10%:5%;It will be put into blender and mix after all raw materials in proportion precise It closes uniformly, then the water (30 DEG C≤water temperature≤50 DEG C) of addition material total amount 13 ~ 15% continues stirring 3 minutes, forms pug;It will Pug is aged 2 hours, and more standard brick blanks are squeezed into brickmaking machine, supports natural curing 7 days, the standby of intensity 25MPa can be obtained Anti- stone finished product.
When practical preparation, addition can be forged according to the concrete content of shale Extra-fine sand in different section shoal materials The dosage for burning clay, slag powders, flyash and sodium silicate carries out appropriate adjustment, is subject to and meets needs.

Claims (7)

1. a kind of prepare flood control using shale Extra-fine sand for the method for anti-stone, it is characterised in that: be added one in shale Extra-fine sand Quantitative calcined clay, slag powders, flyash and sodium silicate adds water and stirs uniformly and is squeezed into standby anti-stone base after being aged 2 hours Block obtains standby anti-stone finished product after conserving;Wherein the shale Extra-fine sand and calcined clay, slag powders, flyash and sodium silicate Percent mass proportioning are as follows: shale Extra-fine sand 60% ~ 70%, calcined clay 10% ~ 15%, slag powders 5% ~ 10%, flyash 5% ~ 10%, Sodium silicate 3% ~ 5%;Additional water is the 13%-15% of material total amount.
2. according to claim 1 prepare flood control using shale Extra-fine sand for the method for anti-stone, it is characterised in that: the mud Matter Extra-fine sand is the deposit of lower reaches of river;Quartz content >=90% therein, clay content < 5%.
3. according to claim 1 prepare flood control using shale Extra-fine sand for the method for anti-stone, it is characterised in that: described to forge Burn clay be clay through 750 ~ 800 DEG C calcine, then grinding at 150-200 mesh powder.
4. according to claim 1 prepare flood control using shale Extra-fine sand for the method for anti-stone, it is characterised in that: the mine Ground-slag is powder of the blast-furnace cinder through fineness 300-400 mesh made of grinding, calcium oxide content 35% ~ 40% therein, silica Content 30% ~ 35%, alumina content 10% ~ 15%.
5. according to claim 1 prepare flood control using shale Extra-fine sand for the method for anti-stone, it is characterised in that: the powder Coal ash is flying dust caused by coal burning, and wherein silica content is 45% ~ 50%, and alumina content is 30% ~ 35%.
6. according to claim 1 prepare flood control using shale Extra-fine sand for the method for anti-stone, it is characterised in that: the bubble Flower alkali is the solid powder of modulus 2.0.
7. according to claim 1 prepare flood control using shale Extra-fine sand for the method for anti-stone, it is characterised in that: described outer Add water using tap water or free of contamination natural water, water temperature is 30 ~ 50 DEG C.
CN201811236149.4A 2018-10-23 2018-10-23 Using the preparation flood control of shale Extra-fine sand for the method for anti-stone Pending CN109053124A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111548102A (en) * 2020-06-29 2020-08-18 郑州大学 Mortar and preparation method and application thereof
CN113493328A (en) * 2021-07-15 2021-10-12 黄河水利委员会黄河水利科学研究院 Flood prevention backup stone material and preparation method thereof
CN113603431A (en) * 2021-09-15 2021-11-05 黄河勘测规划设计研究院有限公司 Preparation method of waterproof toughened sandy soil consolidation agent
CN115159941A (en) * 2022-06-28 2022-10-11 河南建博新材料科技有限公司 Fine sand consolidation agent and preparation method thereof

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CN107417203A (en) * 2017-06-27 2017-12-01 黄河勘测规划设计有限公司 A kind of moisturizing self-maintenance concrete pouring material
CN108503288A (en) * 2018-05-14 2018-09-07 大连理工大学 A kind of artificial reserved bricks and preparation method thereof based on carbonating complex excitation

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111548102A (en) * 2020-06-29 2020-08-18 郑州大学 Mortar and preparation method and application thereof
CN113493328A (en) * 2021-07-15 2021-10-12 黄河水利委员会黄河水利科学研究院 Flood prevention backup stone material and preparation method thereof
CN113603431A (en) * 2021-09-15 2021-11-05 黄河勘测规划设计研究院有限公司 Preparation method of waterproof toughened sandy soil consolidation agent
CN113603431B (en) * 2021-09-15 2022-04-19 黄河勘测规划设计研究院有限公司 Preparation method of waterproof toughened sandy soil consolidation agent
CN115159941A (en) * 2022-06-28 2022-10-11 河南建博新材料科技有限公司 Fine sand consolidation agent and preparation method thereof

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Application publication date: 20181221

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