CN109020491A - A kind of high resistance to compression pervious floor tile - Google Patents
A kind of high resistance to compression pervious floor tile Download PDFInfo
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- CN109020491A CN109020491A CN201811155896.5A CN201811155896A CN109020491A CN 109020491 A CN109020491 A CN 109020491A CN 201811155896 A CN201811155896 A CN 201811155896A CN 109020491 A CN109020491 A CN 109020491A
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Abstract
The present invention relates to water-permeable brick field more particularly to a kind of high resistance to compression pervious floor tiles.The present invention provides a kind of high resistance to compression pervious floor tile, while guarantee pervious floor tile good permeable effect, also has stronger anti-pressure ability, and preparation process is simple, the period is short.High resistance to compression pervious floor tile of the invention, with waste ceramic, building barren rock material, iron tailings etc. for primary raw material, the raw materials such as nano-titanium dioxide, zirconium oxide are added simultaneously, be conducive to improve weatherability, toughness and the anti-aging property etc. of water-permeable brick, so that pervious floor tile produced by the present invention is while with good water permeability, also there is excellent resistance to compression, wear-resisting, self-cleaning function, long service life.High resistance to compression pervious floor tile of the invention is successively mixed by raw material, is kneaded, heating extrusion forming, the preparation of high-temperature calcination technique, and process flow is simple, short preparation period, and preparation efficiency is high, is suitable for a wide range of promote and apply.
Description
Technical field
The present invention relates to water-permeable brick field more particularly to a kind of high resistance to compression pervious floor tiles.
Background technique
In urban road, urban is gone on a journey and kept in order to facilitate people, and pavement is carried out by being laid with brick
Cure process.Existing road hardening is that cement, marble, glazed tile etc. are laid with to it, due to the impermeability of these materials
Can, so that rainwater must drain from sewer whenever rainy, if on the one hand draining will result in the water logging in street not in time,
The underground water in another aspect city cannot supplement, and influence the normal growth of vegetation.To solve the above problems, environmentally protective is new
Type building material product water-permeable brick comes into being, and is developed rapidly.
Water-permeable brick is the pavement brick with very strong absorbent function, and when brick body is filled water, moisture will be to underground venting.
Water-permeable brick has good permeable, permeability, and rainwater can be made to rapidly permeate into underground, supplements the soil water and underground water, keeps soil
Earth humidity improves the life condition of urban ground plant and edaphon.
The Chinese patent of Publication No. CN106186874A discloses a kind of ecological permeable bricks prepared using building waste,
Including fabric and base-material, mix by stirring, ultrasonic vibration, compression moulding, maintaining process preparation, but this method is to after molding
Adobe needs first to conserve 2-3 days indoors, then obtains after carrying out natural curing 10-20 days, and manufacturing cycle is longer, low efficiency.Together
When existing water-permeable brick, while meeting pervious function, compression strength is lower, influences the service life of water-permeable brick.
Summary of the invention
In view of the above technical problems, the present invention provides a kind of high resistance to compression pervious floor tile, is guaranteeing that pervious floor tile is good
While water effect, also there is stronger anti-pressure ability, and preparation process is simple, the period is short.
The invention adopts the following technical scheme:
A kind of high resistance to compression pervious floor tile, the pervious floor tile include the raw material of following parts by weight: 80-120 parts of waste ceramic, being built
Build 100-200 parts of barren rock material, 20-40 parts of iron tailings, 10-20 parts of zirconium oxide, 8-18 parts of nano silicon micronization, 8-20 parts of montmorillonite,
4-10 parts of silica sand, 3-12 parts of nano-titanium dioxide, 4-12 parts of methenamine, 5-10 parts of binder, 3-9 parts of cleanser.
Further, pervious floor tile includes the raw material of following parts by weight: 100 parts of waste ceramic, 150 parts of barren rock material are built,
30 parts of iron tailings, 15 parts of zirconium oxide, 13 parts of nano silicon micronization, 14 parts of montmorillonite, 7 parts of silica sand, 8 parts of nano-titanium dioxide, Wu Luo
8 parts of tropine, 8 parts of binder, 6 parts of cleanser.
Further, cleanser is by 30% nano diatomite, 10% 3 silicic acid, two magnesium, 20% modified Na-LTA/MCM-42
Composite molecular screen, 10% expanded perlite, 10% activated magnesia, 20% chitin composition.Modified Na-LTA/MCM-42
The interlamellar spacing of composite molecular screen expands, specific surface area increases, porosity improves, and so that interlayer is become lipophilic from hydrophily, reduces
Its surface energy；Nano diatomite can increase the contact area of composite molecular screen and metal ion, adsorbance be improved, so that cleanser
With excellent metal ion clean-up effect, the detergent power of pervious floor tile can be improved.
Further, which is prepared by following steps:
(1) each component is weighed by raw material proportioning, grinder is added after waste ceramic, building barren rock material, iron tailings are mixed
Middle grinding, sieving obtains mixture A later；
(2) it dries, zirconium oxide, nano silicon micronization, montmorillonite, silica sand are added later and glue after being cleaned mixture A
Agent is tied, is added in blender and stirs after being sufficiently mixed, obtain mixture B；
(3) nano-titanium dioxide, methenamine, cleanser are added in mixture B, is added in kneading machine after being sufficiently mixed
It is kneaded, obtains mixture C；
(4) mixture C is injected in floor brick die, heating extrusion forming obtains floor tile blank；
(5) floor tile blank is added in calcining furnace and is formed by a firing, calcination temperature is 1200-1400 DEG C, calcines constant temperature after 2h
1h, slow cooling to 800 DEG C, constant temperature 1h takes out, as pervious floor tile after being finally slowly cooled to room temperature later.
Further, the blender in step (2) first stirs 20min with the rate of 200-400r/min, then with 4000-
The rate of 5000r/min stirs 30min.
Further, melting temperature is 200-240 DEG C in step (3), time 30-50min.
Further, briquetting pressure is 8-12MPa in step (4).
High resistance to compression pervious floor tile of the invention is realized with waste ceramic, building barren rock material, iron tailings etc. for primary raw material
The secondary use of solid waste resource, energy conservation and environmental protection, and help to improve the intensity of pervious floor tile；The nanometer two of addition simultaneously
Titanium oxide has good dispersibility and weatherability, has uvioresistant, antibacterial, self-cleaning and anti-aging property, be conducive to enhance
The service performance of pervious floor tile；The zirconium oxide of addition has resistance to compression, wear-resisting property, and the toughness of pervious floor tile can be improved；The present invention
Pervious floor tile, water permeability is good, at the same also have excellent resistance to compression, wear-resisting, self-cleaning function, long service life.
High resistance to compression pervious floor tile of the invention is successively mixed by raw material, is kneaded, heats extrusion forming, high temperature is forged
Firing technique preparation, process flow is simple, short preparation period, and preparation efficiency is high, is suitable for a wide range of promote and apply.
Specific embodiment
Below in conjunction with specific embodiment, clear, complete description is carried out to technical solution of the present invention, it is clear that retouched
The embodiment stated is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, originally
Field those skilled in the art all other embodiment obtained without making creative work belongs to this
The protection scope of invention.
Embodiment 1
A kind of high resistance to compression pervious floor tile, the pervious floor tile include the raw material of following parts by weight: 80 parts of waste ceramic, building is useless
100 parts of stone material, 20 parts of iron tailings, 12 parts of zirconium oxide, 10 parts of nano silicon micronization, 10 parts of montmorillonite, 4 parts of silica sand, nanometer titanium dioxide
3 parts of titanium, 6 parts of methenamine, 5 parts of binder, 3 parts of cleanser.
The high resistance to compression pervious floor tile of the present embodiment is prepared by following steps:
(1) each component is weighed by raw material proportioning, grinder is added after waste ceramic, building barren rock material, iron tailings are mixed
Middle grinding, sieving obtains mixture A later；
(2) it dries, zirconium oxide, nano silicon micronization, montmorillonite, silica sand are added later and glue after being cleaned mixture A
Agent is tied, is added in blender and stirs after being sufficiently mixed, 20min is first stirred with the rate of 200r/min, then with the speed of 4000r/min
Rate stirs 30min, obtains mixture B；
(3) nano-titanium dioxide, methenamine, cleanser are added in mixture B, is added in kneading machine after being sufficiently mixed
It is kneaded, melting temperature is 200 DEG C, and time 30min obtains mixture C；
(4) mixture C is injected in floor brick die, heating extrusion forming, briquetting pressure 12MPa obtains floor tile blank；
(5) floor tile blank being added in calcining furnace and is formed by a firing, calcination temperature is 1200 DEG C, constant temperature 1h after 2h is calcined, it
Slow cooling to 800 DEG C, constant temperature 1h take out, as pervious floor tile after being finally slowly cooled to room temperature afterwards.
The compression strength of pervious floor tile obtained is 45.2MPa, permeation rate 2.1mm/s in the present embodiment.
Embodiment 2
A kind of high resistance to compression pervious floor tile, the pervious floor tile include the raw material of following parts by weight: 120 parts of waste ceramic, building
200 parts of barren rock material, 40 parts of iron tailings, 18 parts of zirconium oxide, 16 parts of nano silicon micronization, 20 parts of montmorillonite, 10 parts of silica sand, nano-silica
Change 10 parts of titanium, 12 parts of methenamine, 10 parts of binder, 8 parts of cleanser.
The high resistance to compression pervious floor tile of the present embodiment is prepared by following steps:
(1) each component is weighed by raw material proportioning, grinder is added after waste ceramic, building barren rock material, iron tailings are mixed
Middle grinding, sieving obtains mixture A later；
(2) it dries, zirconium oxide, nano silicon micronization, montmorillonite, silica sand are added later and glue after being cleaned mixture A
Agent is tied, is added in blender and stirs after being sufficiently mixed, 20min is first stirred with the rate of 400r/min, then with the speed of 5000r/min
Rate stirs 30min, obtains mixture B；
(3) nano-titanium dioxide, methenamine, cleanser are added in mixture B, is added in kneading machine after being sufficiently mixed
It is kneaded, melting temperature is 240 DEG C, and time 50min obtains mixture C；
(4) mixture C is injected in floor brick die, heating extrusion forming, briquetting pressure 10MPa obtains floor tile blank；
(5) floor tile blank being added in calcining furnace and is formed by a firing, calcination temperature is 1400 DEG C, constant temperature 1h after 2h is calcined, it
Slow cooling to 800 DEG C, constant temperature 1h take out, as pervious floor tile after being finally slowly cooled to room temperature afterwards.
The compression strength of pervious floor tile obtained is 45.8MPa, permeation rate 2.1mm/s in the present embodiment.
Embodiment 3
A kind of high resistance to compression pervious floor tile, the pervious floor tile include the raw material of following parts by weight: 90 parts of waste ceramic, building is useless
120 parts of stone material, 23 parts of iron tailings, 10 parts of zirconium oxide, 8 parts of nano silicon micronization, 8 parts of montmorillonite, 5 parts of silica sand, nano-titanium dioxide 5
Part, 4 parts of methenamine, 6 parts of binder, 4 parts of cleanser.
The high resistance to compression pervious floor tile of the present embodiment is prepared by following steps:
(1) each component is weighed by raw material proportioning, grinder is added after waste ceramic, building barren rock material, iron tailings are mixed
Middle grinding, sieving obtains mixture A later；
(2) it dries, zirconium oxide, nano silicon micronization, montmorillonite, silica sand are added later and glue after being cleaned mixture A
Agent is tied, is added in blender and stirs after being sufficiently mixed, 20min is first stirred with the rate of 225r/min, then with the speed of 4200r/min
Rate stirs 30min, obtains mixture B；
(3) nano-titanium dioxide, methenamine, cleanser are added in mixture B, is added in kneading machine after being sufficiently mixed
It is kneaded, melting temperature is 210 DEG C, and time 35min obtains mixture C；
(4) mixture C is injected in floor brick die, heating extrusion forming, briquetting pressure 8MPa obtains floor tile blank；
(5) floor tile blank being added in calcining furnace and is formed by a firing, calcination temperature is 1250 DEG C, constant temperature 1h after 2h is calcined, it
Slow cooling to 800 DEG C, constant temperature 1h take out, as pervious floor tile after being finally slowly cooled to room temperature afterwards.
The compression strength of pervious floor tile obtained is 45.6MPa, permeation rate 2.2mm/s in the present embodiment.
Embodiment 4
A kind of high resistance to compression pervious floor tile, the pervious floor tile include the raw material of following parts by weight: 110 parts of waste ceramic, building
180 parts of barren rock material, 35 parts of iron tailings, 18 parts of zirconium oxide, 18 parts of nano silicon micronization, 16 parts of montmorillonite, 10 parts of silica sand, nano-silica
Change 12 parts of titanium, 12 parts of methenamine, 9 parts of binder, 8 parts of cleanser.
The high resistance to compression pervious floor tile of the present embodiment is prepared by following steps:
(1) each component is weighed by raw material proportioning, grinder is added after waste ceramic, building barren rock material, iron tailings are mixed
Middle grinding, sieving obtains mixture A later；
(2) it dries, zirconium oxide, nano silicon micronization, montmorillonite, silica sand are added later and glue after being cleaned mixture A
Agent is tied, is added in blender and stirs after being sufficiently mixed, 20min is first stirred with the rate of 380r/min, then with the speed of 4800r/min
Rate stirs 30min, obtains mixture B；
(3) nano-titanium dioxide, methenamine, cleanser are added in mixture B, is added in kneading machine after being sufficiently mixed
It is kneaded, melting temperature is 235 DEG C, and time 45min obtains mixture C；
(4) mixture C is injected in floor brick die, heating extrusion forming, briquetting pressure 11MPa obtains floor tile blank；
(5) floor tile blank being added in calcining furnace and is formed by a firing, calcination temperature is 1350 DEG C, constant temperature 1h after 2h is calcined, it
Slow cooling to 800 DEG C, constant temperature 1h take out, as pervious floor tile after being finally slowly cooled to room temperature afterwards.
The compression strength of pervious floor tile obtained is 45.3MPa, permeation rate 2.2mm/s in the present embodiment.
Embodiment 5
A kind of high resistance to compression pervious floor tile, the pervious floor tile include the raw material of following parts by weight: 95 parts of waste ceramic, building is useless
140 parts of stone material, 24 parts of iron tailings, 16 parts of zirconium oxide, 15 parts of nano silicon micronization, 10 parts of montmorillonite, 8 parts of silica sand, nanometer titanium dioxide
9 parts of titanium, 9 parts of methenamine, 7 parts of binder, 4 parts of cleanser.
The high resistance to compression pervious floor tile of the present embodiment is prepared by following steps:
(1) each component is weighed by raw material proportioning, grinder is added after waste ceramic, building barren rock material, iron tailings are mixed
Middle grinding, sieving obtains mixture A later；
(2) it dries, zirconium oxide, nano silicon micronization, montmorillonite, silica sand are added later and glue after being cleaned mixture A
Agent is tied, is added in blender and stirs after being sufficiently mixed, 20min is first stirred with the rate of 280r/min, then with the speed of 4400r/min
Rate stirs 30min, obtains mixture B；
(3) nano-titanium dioxide, methenamine, cleanser are added in mixture B, is added in kneading machine after being sufficiently mixed
It is kneaded, melting temperature is 223 DEG C, and time 32min obtains mixture C；
(4) mixture C is injected in floor brick die, heating extrusion forming, briquetting pressure 9MPa obtains floor tile blank；
(5) floor tile blank being added in calcining furnace and is formed by a firing, calcination temperature is 1280 DEG C, constant temperature 1h after 2h is calcined, it
Slow cooling to 800 DEG C, constant temperature 1h take out, as pervious floor tile after being finally slowly cooled to room temperature afterwards.
The compression strength of pervious floor tile obtained is 45.7MPa, permeation rate 2.2mm/s in the present embodiment.
Embodiment 6
A kind of high resistance to compression pervious floor tile, the pervious floor tile include the raw material of following parts by weight: 100 parts of waste ceramic, building
150 parts of barren rock material, 30 parts of iron tailings, 15 parts of zirconium oxide, 13 parts of nano silicon micronization, 14 parts of montmorillonite, 7 parts of silica sand, nano-silica
Change 8 parts of titanium, 8 parts of methenamine, 8 parts of binder, 6 parts of cleanser.
The high resistance to compression pervious floor tile of the present embodiment is prepared by following steps:
(1) each component is weighed by raw material proportioning, grinder is added after waste ceramic, building barren rock material, iron tailings are mixed
Middle grinding, sieving obtains mixture A later；
(2) it dries, zirconium oxide, nano silicon micronization, montmorillonite, silica sand are added later and glue after being cleaned mixture A
Agent is tied, is added in blender and stirs after being sufficiently mixed, 20min is first stirred with the rate of 300r/min, then with the speed of 4500r/min
Rate stirs 30min, obtains mixture B；
(3) nano-titanium dioxide, methenamine, cleanser are added in mixture B, is added in kneading machine after being sufficiently mixed
It is kneaded, melting temperature is 220 DEG C, and time 40min obtains mixture C；
(4) mixture C is injected in floor brick die, heating extrusion forming, briquetting pressure 8MPa obtains floor tile blank；
(5) floor tile blank being added in calcining furnace and is formed by a firing, calcination temperature is 1300 DEG C, constant temperature 1h after 2h is calcined, it
Slow cooling to 800 DEG C, constant temperature 1h take out, as pervious floor tile after being finally slowly cooled to room temperature afterwards.
The compression strength of pervious floor tile obtained is 46.2MPa, permeation rate 2.1mm/s in the present embodiment.
From the foregoing, it will be observed that the compression strength of pervious floor tile of the invention is greater than 45MPa, permeation rate is and existing in 2mm/s or so
The permeation rate of the compression strength and 1mm/s or so that have common water-permeable brick 20MPa or so is compared, preferable guaranteeing to have
Under the premise of permeation rate, the compression strength of pervious floor tile of the invention has obtained large increase, helps to improve pervious floor tile
Service life, and expand its application range.
The present invention is further described by specific embodiment above, it should be understood that, here specifically
Description, should not be construed as the restriction for the essence of the present invention with range, and one of ordinary skilled in the art is reading this explanation
The various modifications made after book to above-described embodiment belong to the range that the present invention is protected.
Claims (7)
1. a kind of high resistance to compression pervious floor tile, which is characterized in that the pervious floor tile includes the raw material of following parts by weight: waste ceramic
80-120 parts, 100-200 parts of barren rock material are built, 20-40 parts of iron tailings, 10-20 parts of zirconium oxide, 8-18 parts of nano silicon micronization, is covered
De- 8-20 parts of soil, 4-10 parts of silica sand, 3-12 parts of nano-titanium dioxide, 4-12 parts of methenamine, 5-10 parts of binder, cleanser 3-
9 parts.
2. high resistance to compression pervious floor tile according to claim 1, which is characterized in that the pervious floor tile includes following parts by weight
Raw material: 100 parts of waste ceramic, build 150 parts of barren rock material, 30 parts of iron tailings, 15 parts of zirconium oxide, 13 parts of nano silicon micronization, cover
De- 14 parts, 7 parts of silica sand, 8 parts of nano-titanium dioxide, 8 parts of methenamine, 8 parts of binder, 6 parts of cleanser of soil.
3. high resistance to compression pervious floor tile according to claim 1 or 2, which is characterized in that the cleanser is by 30% nano-silicon
Diatomaceous earth, 10% 3 silicic acid, two magnesium, 20% modified Na-LTA/MCM-42 composite molecular screen, 10% expanded perlite, 10% active oxygen
Change magnesium, 20% chitin composition.
4. high resistance to compression pervious floor tile according to claim 3, which is characterized in that prepared by following steps:
(1) each component is weighed by raw material proportioning, is added in grinder and grinds after waste ceramic, building barren rock material, iron tailings are mixed
Mill, sieving obtains mixture A later；
(2) it is dried after being cleaned mixture A, zirconium oxide, nano silicon micronization, montmorillonite, silica sand and binder is added later,
It is added in blender and stirs after being sufficiently mixed, obtain mixture B；
(3) nano-titanium dioxide, methenamine, cleanser are added in mixture B, is added in kneading machine and mixes after being sufficiently mixed
Refining, obtains mixture C；
(4) mixture C is injected in floor brick die, heating extrusion forming obtains floor tile blank；
(5) floor tile blank being added in calcining furnace and is formed by a firing, calcination temperature is 1200-1400 DEG C, constant temperature 1h after 2h is calcined, it
Slow cooling to 800 DEG C, constant temperature 1h take out, as pervious floor tile after being finally slowly cooled to room temperature afterwards.
5. high resistance to compression pervious floor tile according to claim 4, which is characterized in that the blender in step (2) is first with 200-
The rate of 400r/min stirs 20min, then stirs 30min with the rate of 4000-5000r/min.
6. high resistance to compression pervious floor tile according to claim 4, which is characterized in that melting temperature is 200-240 in step (3)
DEG C, time 30-50min.
7. high resistance to compression pervious floor tile according to claim 4, which is characterized in that briquetting pressure is 8- in step (4)
12MPa。
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| CN201811155896.5A CN109020491A (en) | 2018-09-30 | 2018-09-30 | A kind of high resistance to compression pervious floor tile |
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| CN110183143A (en) * | 2019-04-29 | 2019-08-30 | 柳州柳晶环保科技有限公司 | A kind of high resistance to compression water-permeable brick and preparation method thereof |
| CN113480291A (en) * | 2021-08-11 | 2021-10-08 | 信阳科美新型材料有限公司 | Ceramic water permeable brick prepared from devitrified perlite and preparation method thereof |
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