CN109020328A - A kind of diatom ooze clay material - Google Patents
A kind of diatom ooze clay material Download PDFInfo
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- CN109020328A CN109020328A CN201811015588.2A CN201811015588A CN109020328A CN 109020328 A CN109020328 A CN 109020328A CN 201811015588 A CN201811015588 A CN 201811015588A CN 109020328 A CN109020328 A CN 109020328A
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- diatom ooze
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/001—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
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Abstract
The embodiment of the invention discloses a kind of diatom ooze clay material, the component including following parts by weight: 30-40 parts of diatomite, 15-20 parts of kaolin, 5-8 parts of feldspar, 5-10 parts of calcium hydroxide powder, 5-10 parts of white clay, 3-8 parts of attapulgite, 1-3 parts of nanometer Tao Jing, 1-3 parts of nano-titanium dioxide, 1-4 parts of talcum, 1 part of citrate, 5-10 parts of emulsion modifying agent, suppression alkaline agent 2-5 parts, 1-4 parts of inorganic pigment, 1-5 parts of polypropylene fibre.The formula of the embodiment of the present invention is applicant by test gained many times, each component plays synergistic effect in formula, clay material obtained has stronger adsorption capacity, indoor pernicious gas can be effectively absorbed to achieve the purpose that purify the air of a room, adsorption rate is fast, adsorption range is wide, the embodiment of the present invention is using several mineral materials such as white clay, kaolin, attapulgites as adhesive simultaneously, it is strong with wearability, long service life, material is pure natural to add without chemistry, environmentally protective, production cost is low, advantage applied widely.
Description
Technical field
The present invention relates to building material technical fields, and in particular to a kind of diatom ooze clay material.
Background technique
With the development of society, the progress of science and technology, requirement of the people to interior decoration is higher and higher, oneself is through no longer single heavy
Depending on the aesthetics fitted up, but increasingly pay attention to comfort, safety, the environment-friendly type etc. of living environment.
Diatomite main component is silicic acid matter, and there are countless pores on surface, and peculiar smell adsorbable, in decomposition air has and adjusts
Wet, deodorization functions.The building materials for using diatomite to produce for raw material not only have non-ignitable, dehumidifying, deodorization and permeability good
Feature, but also air, antibacterial disinfection, sound insulation, waterproof and heat-insulated can be purified.
The high production cost for the diatom ooze sold on the market at present is added to largely artificial synthesized add in diatom ooze
Add agent, effect needs to be further improved.
Summary of the invention
Of the existing technology in order to solve the problems, such as, the purpose of the present invention is to provide a kind of diatom ooze clay materials.
To achieve the above object, the technical solution of the present invention is as follows: a kind of diatom ooze clay material, including following parts by weight
Component: it is 30-40 parts of diatomite, 15-20 parts of kaolin, 5-8 parts of feldspar, 5-10 parts of calcium hydroxide powder, 5-10 parts of white clay, recessed
3-8 parts of convex stick powder, 1-3 parts of nanometer Tao Jing, 1-3 parts of nano-titanium dioxide, 1-4 parts of talcum, 1 part of citrate, emulsion modifying agent
5-10 parts, suppression alkaline agent 2-5 parts, 1-4 parts of inorganic pigment, 1-5 parts of polypropylene fibre.
Further, the component including following parts by weight: 36 parts of diatomite, 18 parts of kaolin, 6 parts of feldspar, hydroxide
7 parts of calcium powder, 8 parts of white clay, 1 part of 4 part, nanometer Tao Jing of attapulgite, 2 parts of nano-titanium dioxide, 2 parts of talcum, citrate 1
Part, 7 parts of emulsion modifying agent, suppression 2 parts of alkaline agent, 3 parts of inorganic pigment, 1 part of polypropylene fibre.
Further, the component including following parts by weight: 38 parts of diatomite, 16 parts of kaolin, 7 parts of feldspar, hydroxide
8 parts of calcium powder, 6 parts of white clay, 2 parts of 6 part, nanometer Tao Jing of attapulgite, 1 part of nano-titanium dioxide, 3 parts of talcum, citrate 1
Part, 6 parts of emulsion modifying agent, suppression 2 parts of alkaline agent, 2 parts of inorganic pigment, 2 parts of polypropylene fibre.
Further, the partial size of the diatomite is 500-1000nm.
Further, the partial size of the nanometer Tao Jing is 800-1500nm.
Further, the partial size of the nano-titanium dioxide is 1000-4000nm.
Further, the citrate is selected from any one of citric acid sylvite, sodium citrate salt, calcium citrate salts.
Further, the suppression alkaline agent is unsetting silica.
Further, the inorganic pigment includes any one of iron oxide red, iron oxide yellow, iron oxide black.
Further, the preparation method of the diatom ooze clay material includes:
1) each component is weighed according to parts by weight；
2) successively diatomite, kaolin, feldspar, calcium hydroxide powder, white clay, attapulgite, nanometer are made pottery in blender
Crystalline substance, nano-titanium dioxide, talcum, citrate, emulsion modifying agent, suppression alkaline agent, inorganic pigment and polypropylene fibre, are sufficiently stirred
Up to diatom ooze clay material after uniformly.
Main material performance of the present invention is as follows:
Diatom: it is a kind of unicellular alga occurred on earth earliest, survives in seawater or lake water, body is extremely
It is small, generally only several microns to more than ten microns.Diatom can be carried out photosynthesis, make organic matter by oneself.Usually at an amazing speed
Growth and breeding.Its remains deposit to form diatomite.Diatomite main component is silicic acid matter, and there are a countless pores on surface, adsorbable,
The peculiar smell in air is decomposed, there is damping, deodorization functions.Use diatomite for raw material building materials produced, not only have it is non-ignitable,
Dehumidifying, deodorization and the good feature of permeability, but also air, sound insulation, waterproof and heat-insulated can be purified, and cost is not also high.
Kaolin: the pure kaolin of matter has that whiteness is high, matter is soft, easy dispersion suspends in water, good plasticity and height
Caking property, excellent electrical insulation capability；With good antiacid dissolubility, very low cation exchange capacity (CEC), preferable fire resistance
Etc. physicochemical properties.Therefore kaolin has become tens industry institutes such as papermaking, ceramics, rubber, chemical industry, coating, medicine and national defence
Required raw mineral materials.
Feldspar: the potassium constructed by the rack-like that oxygen-octahedron forms, sodium, calcium aluminium silicate mineral, chemical component are
SiO2、Al2O3、Fe2O3, K2O and Na2O etc..
Calcium hydroxide powder: being a kind of white powdery solids.Chemical formula Ca (OH)2, it is commonly called as white lime, calcium hydroxide, it is water-soluble
Liquid, which is referred to as, clarifies limewash.Calcium hydroxide has the general character of alkali, is a kind of highly basic.Carbon dioxide in calcium hydroxide and air is anti-
Calcium carbonate should be generated, the whiteness of coating, hardness can be improved and is helped solidifying.
White clay: being both plastic clay and a kind of rich in fluxed feldspar raw material.With stronger plasticity, glue
The features such as knot property, adsorptivity and higher whiteness.It applies in terms of coating, adhesive force, covering power and the suspension of coating can be improved
Property, thixotropy.In addition it can antiultraviolet, anti-aging, acid-alkali-corrosive-resisting etc..
Attapulgite: it is a kind of crystalloid hydration alumina magnesia silicate, there is unique layer chain structure feature, in its knot
There are crystal lattices in structure.Attapulgite has the good adhesive tape property such as unique dispersion, high temperature resistant, salt resistance alkali and higher
Adsorption bleaching ability.
Nanometer Tao Jing: being with the rare nonmetallic minerals substance such as pure natural clay, attapulgite and sepiolite clay, sepiolite
Mainly to form, there is the air purifying preparation of absorption nanoscale polar gas compound.
Nano-titanium dioxide: environment harmful gas can be divided into indoor harmful gas and Pollution Gas.Indoor nocuousness gas
Body mainly has methyl mercaptan, hydrogen sulfide and the ammonia etc. generated in the formaldehyde and living environment of the releasings such as ornament materials.Nano-silica
Change these substance decompositions oxidation that titanium can will be adsorbed in its surface by photocatalysis, to make the dense of these substances in air
Degree reduces, and environment sense of discomfort is mitigated or eliminated.In addition, TiO2Inhibition to microorganism in environment or killing effect under light illumination,
Therefore, nano-titanium dioxide can purify air, have deodorization functions.
Talcum: since talcum has lubricity, anti-stick, helps stream, fire resistance, acid-resisting, insulating properties, fusing point high, chemically
The excellent Wuli-Shili-Renli system approach such as torpescence, covering power good, softness, good luster, strong adsorption force, the application master in coating
It embodies are as follows: in coating, talcum powder can play skeleton function as filler, reduce the paint that manufacturing cost improves coating simultaneously
Film hardness.It mainly can increase the stabilization of shape of product, increase tensile strength, shear strength, flexing intensity, the intensity of pressure, reduction
The features such as deformation, extension rate, thermal expansion coefficient, whiteness is high, epigranular dispersibility is strong.
Suppression alkaline agent: cement antalkaline is a kind of containing unsetting highly reactive form of oxygen SiClx and high sorbent material, be can significantly reduce
The content of free calcium hydroxide in material plays the generation for inhibiting cement mortar surface accumulation of salt in the surface soil phenomenon, fundamentally solves building
Material accumulation of salt in the surface soil problem.
Polypropylene fibre: being synthetic fibers made of the isotactic polypropylene obtained using propylene polymerization is spinned as raw material.Research
Show when in cement-based material or mortar mixed with a certain amount of polypropylene fibre, the cracking situation of material surface is mitigated.
The present invention has the advantage that
The formula of the embodiment of the present invention is applicant by obtained by test many times, each component plays collaboration and makees in formula
There is stronger adsorption capacity with, clay material obtained, can effectively absorb indoor pernicious gas and reach and purify the air of a room
Purpose, adsorption rate is fast, and adsorption range is wide, while the embodiment of the present invention is with a variety of mines such as white clay, kaolin, attapulgite
Substance is adhesive, has wearability strong, long service life, and material is pure natural to add without chemistry, environmentally protective, production cost
Low, applied widely advantage.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
Embodiment 1
A kind of diatom ooze clay material of the present embodiment, the component including following parts by weight: 30 parts of diatomite, kaolin
18 parts, 5 parts of feldspar, 9 parts of calcium hydroxide powder, 5 parts of white clay, 3 parts of 8 part, nanometer Tao Jing of attapulgite, 3 parts of nano-titanium dioxide,
1 part of talcum, 1 part of citrate, 5 parts of emulsion modifying agent, suppression 2 parts of alkaline agent, 4 parts of inorganic pigment, 1 part of polypropylene fibre.
Wherein, the partial size of diatomite is 500nm, and the partial size of nanometer Tao Jing is 1000nm, and the partial size of nano-titanium dioxide is
1000nm, citrate are potassium citrate, and suppression alkaline agent is unsetting silica, and inorganic pigment is iron oxide red.
The preparation method of the diatom ooze clay material includes:
1) according to parts by weight than weighing each component；
2) successively diatomite, kaolin, feldspar, calcium hydroxide powder, white clay, attapulgite, nanometer are made pottery in blender
Crystalline substance, nano-titanium dioxide, talcum, citrate, emulsion modifying agent, suppression alkaline agent, inorganic pigment and polypropylene fibre, are sufficiently stirred
Up to diatom ooze clay material after uniformly.
Purification air performance: it is 0.4mg/m that clay material made from the present embodiment, which is placed in initial concentration of formaldehyde,3It is close
Close in space, for 24 hours after, after tested, concentration of formaldehyde 0.006mg/m3。
Embodiment 2
A kind of diatom ooze clay material of the present embodiment, the component including following parts by weight: 36 parts of diatomite, kaolin
18 parts, 6 parts of feldspar, 7 parts of calcium hydroxide powder, 8 parts of white clay, 1 part of 4 part, nanometer Tao Jing of attapulgite, 2 parts of nano-titanium dioxide,
2 parts of talcum, 1 part of citrate, 7 parts of emulsion modifying agent, suppression 2 parts of alkaline agent, 3 parts of inorganic pigment, 1 part of polypropylene fibre.
Wherein, the partial size of diatomite is 800nm, and the partial size of nanometer Tao Jing is 800nm, and the partial size of nano-titanium dioxide is
2000nm, citrate are calcium citrate, and suppression alkaline agent is unsetting silica, and inorganic pigment is iron oxide yellow.
The preparation method is the same as that of Example 1 for the diatom ooze clay material of the present embodiment.
Purification air performance: it is 0.5mg/m that clay material made from the present embodiment, which is placed in initial concentration of formaldehyde,3It is close
Close in space, for 24 hours after, after tested, concentration of formaldehyde 0.005mg/m3。
Embodiment 3
A kind of diatom ooze clay material of the present embodiment, the component including following parts by weight: 40 parts of diatomite, kaolin
15 parts, 5 parts of feldspar, 10 parts of calcium hydroxide powder, 8 parts of white clay, 1 part of 3 part, nanometer Tao Jing of attapulgite, nano-titanium dioxide 3
Part, 1 part of talcum, 1 part of citrate, 9 parts of emulsion modifying agent, suppression 5 parts of alkaline agent, 1 part of inorganic pigment, 2 parts of polypropylene fibre.
Wherein, the partial size of diatomite is 500nm, and the partial size of nanometer Tao Jing is 1200nm, and the partial size of nano-titanium dioxide is
1500nm, citrate are sodium citrate, and suppression alkaline agent is unsetting silica, and inorganic pigment is iron oxide yellow.
The preparation method is the same as that of Example 1 for the diatom ooze clay material of the present embodiment.
Purification air performance: it is 0.4mg/m that clay material made from the present embodiment, which is placed in initial concentration of formaldehyde,3It is close
Close in space, for 24 hours after, after tested, concentration of formaldehyde 0.007mg/m3。
Embodiment 4
A kind of diatom ooze clay material of the present embodiment, the component including following parts by weight: 38 parts of diatomite, kaolin
16 parts, 7 parts of feldspar, 8 parts of calcium hydroxide powder, 6 parts of white clay, 2 parts of 6 part, nanometer Tao Jing of attapulgite, 1 part of nano-titanium dioxide,
3 parts of talcum, 1 part of citrate, 6 parts of emulsion modifying agent, suppression 2 parts of alkaline agent, 2 parts of inorganic pigment, 2 parts of polypropylene fibre.
Wherein, the partial size of diatomite is 1000nm, and the partial size of nanometer Tao Jing is 1500nm, and the partial size of nano-titanium dioxide is
1000nm, citrate are sodium citrate, and suppression alkaline agent is unsetting silica, and inorganic pigment is iron oxide black.
The preparation method is the same as that of Example 1 for the diatom ooze clay material of the present embodiment.
Purification air performance: it is 0.4mg/m that clay material made from the present embodiment, which is placed in initial concentration of formaldehyde,3It is close
Close in space, for 24 hours after, after tested, concentration of formaldehyde 0.005mg/m3。
Embodiment 5
A kind of diatom ooze clay material of the present embodiment, the component including following parts by weight: 32 parts of diatomite, kaolin
20 parts, 8 parts of feldspar, 5 parts of calcium hydroxide powder, 10 parts of white clay, 1 part of 5 part, nanometer Tao Jing of attapulgite, nano-titanium dioxide 1
Part, 4 parts of talcum, 1 part of citrate, 5 parts of emulsion modifying agent, suppression 2 parts of alkaline agent, 4 parts of inorganic pigment, 5 parts of polypropylene fibre.
Wherein, the partial size of diatomite is 500nm, and the partial size of nanometer Tao Jing is 800nm, and the partial size of nano-titanium dioxide is
4000nm, citrate are potassium citrate, and suppression alkaline agent is unsetting silica, and inorganic pigment is iron oxide black.
The preparation method is the same as that of Example 1 for the diatom ooze clay material of the present embodiment.
Purification air performance: it is 0.4mg/m that clay material made from the present embodiment, which is placed in initial concentration of formaldehyde,3It is close
Close in space, for 24 hours after, after tested, concentration of formaldehyde 0.006mg/m3。
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention are fallen within the scope of the claimed invention.
Claims (10)
1. a kind of diatom ooze clay material, which is characterized in that the component including following parts by weight: 30-40 parts of diatomite, kaolinite
15-20 parts native, 5-8 parts of feldspar, 5-10 parts of calcium hydroxide powder, 5-10 parts of white clay, 3-8 parts of attapulgite, nanometer Tao Jing 1-3
Part, presses down alkaline agent 2-5 parts, is inorganic 1-3 parts of nano-titanium dioxide, 1-4 parts of talcum, 1 part of citrate, 5-10 parts of emulsion modifying agent
1-4 parts of pigment, 1-5 parts of polypropylene fibre.
2. diatom ooze clay material according to claim 1, which is characterized in that the component including following parts by weight: silicon
36 parts of diatomaceous earth, 18 parts of kaolin, 6 parts of feldspar, 7 parts of calcium hydroxide powder, 8 parts of white clay, 1 part of 4 part, nanometer Tao Jing of attapulgite,
2 parts of nano-titanium dioxide, 2 parts of talcum, 1 part of citrate, 7 parts of emulsion modifying agent, suppression 2 parts of alkaline agent, 3 parts of inorganic pigment, poly- third
1 part of alkene fiber.
3. diatom ooze clay material according to claim 1, which is characterized in that the component including following parts by weight: silicon
38 parts of diatomaceous earth, 16 parts of kaolin, 7 parts of feldspar, 8 parts of calcium hydroxide powder, 6 parts of white clay, 2 parts of 6 part, nanometer Tao Jing of attapulgite,
1 part of nano-titanium dioxide, 3 parts of talcum, 1 part of citrate, 6 parts of emulsion modifying agent, suppression 2 parts of alkaline agent, 2 parts of inorganic pigment, poly- third
2 parts of alkene fiber.
4. diatom ooze clay material according to claim 1, which is characterized in that the partial size of the diatomite is 500-
1000nm。
5. diatom ooze clay material according to claim 1, which is characterized in that the partial size of the nanometer Tao Jing is 800-
1500nm。
6. diatom ooze clay material according to claim 1, which is characterized in that the partial size of the nano-titanium dioxide is
1000-4000nm。
7. diatom ooze clay material according to claim 1, which is characterized in that the citrate is selected from potassium citrate
Any one of salt, sodium citrate salt, calcium citrate salts.
8. diatom ooze clay material according to claim 1, which is characterized in that the suppression alkaline agent is unsetting titanium dioxide
Silicon.
9. diatom ooze clay material according to claim 1, which is characterized in that the inorganic pigment include iron oxide red,
Any one of iron oxide yellow, iron oxide black.
10. diatom ooze clay material according to claim 1, which is characterized in that the preparation of the diatom ooze clay material
Method includes:
1) each component is weighed according to parts by weight；
2) in blender successively diatomite, kaolin, feldspar, calcium hydroxide powder, white clay, attapulgite, nanometer Tao Jing, receive
Rice titanium dioxide, talcum, citrate, emulsion modifying agent, suppression alkaline agent, inorganic pigment and polypropylene fibre, stir
Afterwards up to diatom ooze clay material.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110981425A (en) * | 2019-10-31 | 2020-04-10 | 醴陵振美艺术陶瓷有限公司 | Daily-use porcelain and processing technology thereof |
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| CN104829212A (en) * | 2015-05-14 | 2015-08-12 | 张辉权 | Diatom ooze ceramic clay material |
| CN104860609A (en) * | 2015-05-14 | 2015-08-26 | 汪培杰 | Diatomite decorative material |
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| CN102633475A (en) * | 2012-04-27 | 2012-08-15 | 青岛泉佳美硅藻泥科技有限公司 | Non-glue diatom ooze building material |
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