CN109016549A - A kind of composite box processing method for building - Google Patents
A kind of composite box processing method for building Download PDFInfo
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- CN109016549A CN109016549A CN201810715437.1A CN201810715437A CN109016549A CN 109016549 A CN109016549 A CN 109016549A CN 201810715437 A CN201810715437 A CN 201810715437A CN 109016549 A CN109016549 A CN 109016549A
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- Prior art keywords
- composite box
- graphene
- building
- plate
- processing method
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
- B29C67/248—Moulding mineral fibres or particles bonded with resin, e.g. for insulating or roofing board
Abstract
The present invention relates to building product fields, disclose a kind of composite box processing method for building, it is characterized in that: the first step, by graphene, acrylonitrile monemer, it mixes under nitrogen protection, heating, through precipitating, centrifugation, washing, it is dry, the graphene of polyacrylonitrile graft is made, second step, the graphene of polyacrylonitrile graft is made into fiber cloth to be put into plate mold, third step, in a mold by the filling liquid casting of molten condition, it is cooled to room temperature, plate A is made, 4th step, the periphery plate A is subjected to outer deburring, and smooth treatment is carried out to the surface plate A using grinding wheel, 5th step, the top cover of container is made in plate A after two pieces or more deburrings are polished by way of splicing, floor and side wall.It is poor to solve existing composite box intensity for building, subject to damage in handling process, carrying is very difficult, increases the difficulty and cost of carrying, existing composite box for building is difficult to solve the problems, such as the balance of intensity and weight.
Description
Technical field
The present invention relates to building product fields, are concretely a kind of composite box processing methods for building.
Background technique
Composite material casing using very extensive, especially be unable to do without transport box and for building in the transport of international and army
Composite box.It can guarantee that institute's freight cannot suffer a loss using transport box and composite box for building.For example, meeting
Wind, rain, snow, hail, the product of need for confidentiality are required to transport box and composite box for building.Though existing building composite box
So become system substantially, the so-called system that becomes is to have principle type specification in huge specification substantially.But existing building
With composite box is many kinds of, material is different, because composite box for building is needed the cargo transport whole world, it should have easy
Handling protect commercial articles safety, facilitate the characteristics such as privacy of user, existing composite box intensity for building is poor, in handling process
Subject to damage, and since composite box own wt for building is larger, carry it is very difficult, increase carrying difficulty and at
This, existing composite box for building is difficult to solve the balance of intensity and weight, therefore, it is difficult to form the body of more systematicization
System.
Therefore, it is necessary to a kind of intensity height, light weight, a kind of safe and reliable, good confidentiality composite box processing for building
Method.
Summary of the invention
The present invention is poor for existing composite box intensity for building, subject to damage in handling process, and due to building
It builds and uses composite box own wt larger, carrying is very difficult, increases the difficulty and cost of carrying, existing for building compound
Cabinet is difficult to solve the problems, such as the balance of intensity and weight, provides a kind of composite box processing method for building.
The present invention solves above-mentioned technical problem, the technical solution adopted is that, a kind of composite box processing method for building, packet
Include following steps:
The first step mixes graphene, acrylonitrile monemer under nitrogen protection, heats, through precipitating, centrifugation, washing, drying, system
Obtain the graphene of polyacrylonitrile graft;
The graphene of polyacrylonitrile graft is made into fiber cloth and is put into plate mold by second step;
Third step in a mold by the filling liquid casting of molten condition is cooled to room temperature, plate A is made;
The periphery plate A is carried out outer deburring, and carries out smooth treatment to the surface plate A using grinding wheel by the 4th step;
Top cover, floor and the side of container is made in 5th step, the plate A after two pieces or more deburrings are polished by way of splicing
Wall.
The purpose designed in this way is that the primary raw materials of graphene or graphene oxide is graphite, and raw material sources are extensively, easily
It obtains, is low in cost, being prepared for the polyacrylonitrile graft graphene presoma and stable polypropylene of highly dissoluble simple and easyly
Nitrile graft grapheme colloidal sol.
Meanwhile the carbon fiber by being laid with fiber cloth shape in plate, the strong of composite box for building can be greatly improved
Degree, may be implemented the architecture of composite box for building, is conducive to the mating normalized production of composite box for building, solve existing
The composite box intensity for building having is poor, subject to damage in handling process, and due to composite box own wt for building
It is larger, it carries very difficult, increases the difficulty and cost of carrying, existing composite box for building is difficult to solve intensity and again
The problem of balance of amount.
Further, in the first step, graphene and acrylonitrile monemer weight ratio are 1:1.
Further, in the first step, heating temperature is 50 DEG C~95 DEG C.
Further, in second step, fiber cloth is fenestral fabric, and the size of grid is 5cm × 5cm.
Further, in third step, filling liquid is resin or aluminium alloy.
Further, resin is the mixed of ABS unsaturated-resin, unsaturated polyester resin, graphene dispersion slurry and emulsifier
Close object.
Further, resin includes by weight ratio for 20~40 parts of ABS unsaturated-resin, 5~10 parts of unsaturation
Polyester resin, 2~6 parts of graphene dispersion slurry, 2~4 parts of emulsifier.
Optionally, resin includes by weight ratio for 25 parts of ABS unsaturated-resin, 7 parts of unsaturated polyester resin, 3
The graphene dispersion slurry, 3 parts of emulsifier of part.
Further, in the 4th step, plate A is square plate.
By the way that aluminium alloy or resin to be filled in the fiber cloth that carbon fiber is made into, wherein resin is ABS unsaturation tree
Rouge, unsaturated polyester resin, graphene dispersion are starched and the mixture of emulsifier, can improve composite box machinery for building by force
Under the premise of degree, the weight of composite box for building is greatly reduced.
It is bonded by using epoxy resin, epoxy resin has excellent glue to the surface of metal and nonmetallic materials
Intensity is connect, dielectric properties are good, and deformation retract rate is small, and product size stability is good, and hardness is high, and flexibility is preferable, to alkali and greatly
Partial solvent is stablized.
Beneficial effects of the present invention are at least following one:
1. the primary raw materials of graphene or graphene oxide is graphite, raw material sources are extensive, are easy to get, are low in cost, simple and easy
Ground be prepared for highly dissoluble polyacrylonitrile graft graphene presoma and stable polyacrylonitrile graft graphene sol.
2. the intensity of composite box for building can be greatly improved by the carbon fiber for being laid with fiber cloth shape in plate,
The architecture that composite box for building may be implemented is conducive to the mating normalized production of composite box for building, solves existing
Composite box intensity for building it is poor, subject to damage in handling process, and due to composite box own wt for building compared with
Greatly, carrying is very difficult, increases the difficulty and cost of carrying, and existing composite box for building is difficult to solve intensity and weight
Balance the problem of.
3. wherein resin is ABS unsaturated by the way that aluminium alloy or resin to be filled in the fiber cloth that carbon fiber is made into
Resin, unsaturated polyester resin, graphene dispersion are starched and the mixture of emulsifier, can improve composite box machinery for building
Under the premise of intensity, the weight of composite box for building is greatly reduced.
4. being bonded by using epoxy resin, epoxy resin has the surface of metal and nonmetallic materials excellent
Adhesive strength, dielectric properties are good, and deformation retract rate is small, and product size stability is good, and hardness is high, and flexibility is preferable, to alkali and
Most of solvent-stable.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments to the present invention
It is described in further detail.It should be appreciated that specific embodiment described herein is used only for explaining the present invention, it is not used to limit
The fixed present invention.
Embodiment 1
The first step mixes graphene, acrylonitrile monemer under nitrogen protection, heats, through precipitating, centrifugation, washing, drying, system
Obtain the graphene of polyacrylonitrile graft;
The graphene of polyacrylonitrile graft is made into fiber cloth and is put into plate mold by second step;
Third step in a mold by the filling liquid casting of molten condition is cooled to room temperature, plate A is made;
The periphery plate A is carried out outer deburring, and carries out smooth treatment to the surface plate A using grinding wheel by the 4th step;
Top cover, floor and the side of container is made in 5th step, the plate A after two pieces or more deburrings are polished by way of splicing
Wall.
In use, the primary raw materials of graphene or graphene oxide is graphite, raw material sources are extensive, are easy to get, are low in cost
, it is prepared for the polyacrylonitrile graft graphene presoma and stable polyacrylonitrile graft graphene of highly dissoluble simple and easyly
Colloidal sol.By being laid with the carbon fiber of fiber cloth shape in plate, the intensity of composite box for building, Ke Yishi can be greatly improved
The architecture of existing composite box for building, is conducive to the mating normalized production of composite box for building, solves existing building
It is poor with composite box intensity, subject to damage in handling process, and since composite box own wt for building is larger, it carries
It is very difficult, the difficulty and cost of carrying are increased, existing composite box for building is difficult to solve the balance of intensity and weight
The problem of.
Embodiment 2
The first step mixes graphene, acrylonitrile monemer under nitrogen protection, heats, through precipitating, centrifugation, washing, drying, system
The graphene of polyacrylonitrile graft is obtained, graphene and acrylonitrile monemer weight ratio are 1:1;
The graphene of polyacrylonitrile graft is made into fiber cloth and is put into plate mold by second step;
Third step in a mold by the filling liquid casting of molten condition is cooled to room temperature, plate A is made;
The periphery plate A is carried out outer deburring, and carries out smooth treatment to the surface plate A using grinding wheel by the 4th step;
Top cover, floor and the side of container is made in 5th step, the plate A after two pieces or more deburrings are polished by way of splicing
Wall.
In use, the primary raw materials of graphene or graphene oxide is graphite, raw material sources are extensive, are easy to get, are low in cost
, it is prepared for the polyacrylonitrile graft graphene presoma and stable polyacrylonitrile graft graphene of highly dissoluble simple and easyly
Colloidal sol.By being laid with the carbon fiber of fiber cloth shape in plate, the intensity of composite box for building, Ke Yishi can be greatly improved
The architecture of existing composite box for building, is conducive to the mating normalized production of composite box for building, solves existing building
It is poor with composite box intensity, subject to damage in handling process, and since composite box own wt for building is larger, it carries
It is very difficult, the difficulty and cost of carrying are increased, existing composite box for building is difficult to solve the balance of intensity and weight
The problem of.
Embodiment 3
The first step mixes graphene, acrylonitrile monemer under nitrogen protection, heats, through precipitating, centrifugation, washing, drying, system
The graphene of polyacrylonitrile graft is obtained, graphene and acrylonitrile monemer weight ratio are 1:1, and heating temperature is 50 DEG C;
The graphene of polyacrylonitrile graft is made into fiber cloth and is put into plate mold by second step;
Third step in a mold by the filling liquid casting of molten condition is cooled to room temperature, plate A is made;
The periphery plate A is carried out outer deburring, and carries out smooth treatment to the surface plate A using grinding wheel by the 4th step;
Top cover, floor and the side of container is made in 5th step, the plate A after two pieces or more deburrings are polished by way of splicing
Wall.
In use, the primary raw materials of graphene or graphene oxide is graphite, raw material sources are extensive, are easy to get, are low in cost
, it is prepared for the polyacrylonitrile graft graphene presoma and stable polyacrylonitrile graft graphene of highly dissoluble simple and easyly
Colloidal sol.By being laid with the carbon fiber of fiber cloth shape in plate, the intensity of composite box for building, Ke Yishi can be greatly improved
The architecture of existing composite box for building, is conducive to the mating normalized production of composite box for building, solves existing building
It is poor with composite box intensity, subject to damage in handling process, and since composite box own wt for building is larger, it carries
It is very difficult, the difficulty and cost of carrying are increased, existing composite box for building is difficult to solve the balance of intensity and weight
The problem of.
Embodiment 4
The first step mixes graphene, acrylonitrile monemer under nitrogen protection, heats, through precipitating, centrifugation, washing, drying, system
The graphene of polyacrylonitrile graft is obtained, graphene and acrylonitrile monemer weight ratio are 1:1, and heating temperature is 95 DEG C;
The graphene of polyacrylonitrile graft is made into fiber cloth and is put into plate mold by second step, and fiber cloth is fenestral fabric,
The size of grid is 5cm × 5cm;
Third step in a mold by the filling liquid casting of molten condition is cooled to room temperature, and plate A is made, and filling liquid is aluminium conjunction
Gold;
The periphery plate A is carried out outer deburring, and carries out smooth treatment to the surface plate A using grinding wheel by the 4th step;
Top cover, floor and the side of container is made in 5th step, the plate A after two pieces or more deburrings are polished by way of splicing
Wall.
In use, the primary raw materials of graphene or graphene oxide is graphite, raw material sources are extensive, are easy to get, are low in cost
, it is prepared for the polyacrylonitrile graft graphene presoma and stable polyacrylonitrile graft graphene of highly dissoluble simple and easyly
Colloidal sol.By being laid with the carbon fiber of fiber cloth shape in plate, the intensity of composite box for building, Ke Yishi can be greatly improved
The architecture of existing composite box for building, is conducive to the mating normalized production of composite box for building, solves existing building
It is poor with composite box intensity, subject to damage in handling process, and since composite box own wt for building is larger, it carries
It is very difficult, the difficulty and cost of carrying are increased, existing composite box for building is difficult to solve the balance of intensity and weight
The problem of.
Embodiment 5
The first step mixes graphene, acrylonitrile monemer under nitrogen protection, heats, through precipitating, centrifugation, washing, drying, system
The graphene of polyacrylonitrile graft is obtained, graphene and acrylonitrile monemer weight ratio are 1:1, and heating temperature is 95 DEG C;
The graphene of polyacrylonitrile graft is made into fiber cloth and is put into plate mold by second step, and fiber cloth is fenestral fabric,
The size of grid is 5cm × 5cm;
Third step in a mold by the filling liquid casting of molten condition is cooled to room temperature, plate A is made, and filling liquid is resin,
Resin includes by weight ratio for 20 parts of ABS unsaturated-resin, 5 parts of unsaturated polyester resin, 2 parts of graphene dispersion
Slurry, 2 parts of emulsifier;
The periphery plate A is carried out outer deburring, and carries out smooth treatment to the surface plate A using grinding wheel by the 4th step;
Top cover, floor and the side of container is made in 5th step, the plate A after two pieces or more deburrings are polished by way of splicing
Wall.
In use, the primary raw materials of graphene or graphene oxide is graphite, raw material sources are extensive, are easy to get, are low in cost
, it is prepared for the polyacrylonitrile graft graphene presoma and stable polyacrylonitrile graft graphene of highly dissoluble simple and easyly
Colloidal sol.By being laid with the carbon fiber of fiber cloth shape in plate, the intensity of composite box for building, Ke Yishi can be greatly improved
The architecture of existing composite box for building, is conducive to the mating normalized production of composite box for building, solves existing building
It is poor with composite box intensity, subject to damage in handling process, and since composite box own wt for building is larger, it carries
It is very difficult, the difficulty and cost of carrying are increased, existing composite box for building is difficult to solve the balance of intensity and weight
The problem of.Embodiment 6
The first step mixes graphene, acrylonitrile monemer under nitrogen protection, heats, through precipitating, centrifugation, washing, drying, system
The graphene of polyacrylonitrile graft is obtained, graphene and acrylonitrile monemer weight ratio are 1:1, and heating temperature is 50 DEG C;
The graphene of polyacrylonitrile graft is made into fiber cloth and is put into plate mold by second step, and fiber cloth is fenestral fabric,
The size of grid is 5cm × 5cm;
Third step in a mold by the filling liquid casting of molten condition is cooled to room temperature, plate A is made, and filling liquid is resin,
Resin includes by weight ratio for 40 parts of ABS unsaturated-resin, 10 parts of unsaturated polyester resin, 6 parts of graphene dispersion
Slurry, 4 parts of emulsifier;
The periphery plate A is carried out outer deburring, and carries out smooth treatment to the surface plate A using grinding wheel by the 4th step;
Top cover, floor and the side of container is made in 5th step, the plate A after two pieces or more deburrings are polished by way of splicing
Wall.
In use, the primary raw materials of graphene or graphene oxide is graphite, raw material sources are extensive, are easy to get, are low in cost
, it is prepared for the polyacrylonitrile graft graphene presoma and stable polyacrylonitrile graft graphene of highly dissoluble simple and easyly
Colloidal sol.By being laid with the carbon fiber of fiber cloth shape in plate, the intensity of composite box for building, Ke Yishi can be greatly improved
The architecture of existing composite box for building, is conducive to the mating normalized production of composite box for building, solves existing building
It is poor with composite box intensity, subject to damage in handling process, and since composite box own wt for building is larger, it carries
It is very difficult, the difficulty and cost of carrying are increased, existing composite box for building is difficult to solve the balance of intensity and weight
The problem of.
Embodiment 6
The first step mixes graphene, acrylonitrile monemer under nitrogen protection, heats, through precipitating, centrifugation, washing, drying, system
The graphene of polyacrylonitrile graft is obtained, graphene and acrylonitrile monemer weight ratio are 1:1, and heating temperature is 50 DEG C;
The graphene of polyacrylonitrile graft is made into fiber cloth and is put into plate mold by second step, and fiber cloth is fenestral fabric,
The size of grid is 5cm × 5cm;
Third step in a mold by the filling liquid casting of molten condition is cooled to room temperature, plate A is made, and filling liquid is resin,
Resin includes by weight ratio for 25 parts of ABS unsaturated-resin, 7 parts of unsaturated polyester resin, 3 parts of graphene dispersion
Slurry, 3 parts of emulsifier;
The periphery plate A is carried out outer deburring, and carries out smooth treatment to the surface plate A using grinding wheel by the 4th step;
Top cover, floor and the side of container is made in 5th step, the plate A after two pieces or more deburrings are polished by way of splicing
Wall.
In use, the primary raw materials of graphene or graphene oxide is graphite, raw material sources are extensive, are easy to get, are low in cost
, it is prepared for the polyacrylonitrile graft graphene presoma and stable polyacrylonitrile graft graphene of highly dissoluble simple and easyly
Colloidal sol.By being laid with the carbon fiber of fiber cloth shape in plate, the intensity of composite box for building, Ke Yishi can be greatly improved
The architecture of existing composite box for building, is conducive to the mating normalized production of composite box for building, solves existing building
It is poor with composite box intensity, subject to damage in handling process, and since composite box own wt for building is larger, it carries
It is very difficult, the difficulty and cost of carrying are increased, existing composite box for building is difficult to solve the balance of intensity and weight
The problem of.
Claims (9)
1. a kind of composite box processing method for building, it is characterised in that: the following steps are included:
The first step mixes graphene, acrylonitrile monemer under nitrogen protection, heats, through precipitating, centrifugation, washing, drying, system
Obtain the graphene of polyacrylonitrile graft;
The graphene of polyacrylonitrile graft is made into fiber cloth and is put into plate mold by second step;
Third step in a mold by the filling liquid casting of molten condition is cooled to room temperature, plate A is made;
The periphery plate A is carried out outer deburring, and carries out smooth treatment to the surface plate A using grinding wheel by the 4th step;
Top cover, floor and the side of container is made in 5th step, the plate A after two pieces or more deburrings are polished by way of splicing
Wall.
2. a kind of composite box processing method for building according to claim 1, it is characterised in that: in the first step,
Graphene and acrylonitrile monemer weight ratio are 1:1.
3. a kind of composite box processing method for building according to claim 2, it is characterised in that: in the first step,
Heating temperature is 50 DEG C~95 DEG C.
4. a kind of composite box processing method for building according to claim 1, it is characterised in that: in the second step,
Fiber cloth is fenestral fabric, and the size of grid is 5cm × 5cm.
5. a kind of composite box processing method for building according to claim 1, it is characterised in that: in the third step,
Filling liquid is resin or aluminium alloy.
6. a kind of composite box processing method for building according to claim 5, it is characterised in that: the resin is ABS
Unsaturated-resin, unsaturated polyester resin, graphene dispersion are starched and the mixture of emulsifier.
7. a kind of composite box processing method for building according to claim 6, it is characterised in that: the resin includes pressing
Weight proportion is 20~40 parts of ABS unsaturated-resin, 5~10 parts of unsaturated polyester resin, 2~6 parts of graphene dispersion
Slurry, 2~4 parts of emulsifier.
8. a kind of composite box processing method for building according to claim 7, it is characterised in that: the resin includes pressing
Weight proportion is 25 parts of ABS unsaturated-resin, 7 parts of unsaturated polyester resin, 3 parts of graphene dispersion slurry, 3 parts of emulsification
Agent.
9. a kind of composite box processing method for building according to claim 8, it is characterised in that: in the 4th step,
Plate A is square plate.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102586951A (en) * | 2012-01-18 | 2012-07-18 | 浙江大学 | Preparation method for composite carbon fiber based on graphene/ polyacrylonitrile |
CN102586922A (en) * | 2012-01-18 | 2012-07-18 | 浙江大学 | Preparation method for macroscopic fiber of polyacrylonitrile grafted graphene |
CN107263888A (en) * | 2017-05-31 | 2017-10-20 | 成都协恒科技有限公司 | A kind of light composite material container processing method |
CN108000062A (en) * | 2017-11-30 | 2018-05-08 | 成都龙泉马龙机械厂 | A kind of container house processing method |
-
2018
- 2018-06-29 CN CN201810715437.1A patent/CN109016549A/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102586951A (en) * | 2012-01-18 | 2012-07-18 | 浙江大学 | Preparation method for composite carbon fiber based on graphene/ polyacrylonitrile |
CN102586922A (en) * | 2012-01-18 | 2012-07-18 | 浙江大学 | Preparation method for macroscopic fiber of polyacrylonitrile grafted graphene |
CN107263888A (en) * | 2017-05-31 | 2017-10-20 | 成都协恒科技有限公司 | A kind of light composite material container processing method |
CN108000062A (en) * | 2017-11-30 | 2018-05-08 | 成都龙泉马龙机械厂 | A kind of container house processing method |
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Application publication date: 20181218 |