CN109010105B - Multi-effect composition and preparation method and application thereof - Google Patents
Multi-effect composition and preparation method and application thereof Download PDFInfo
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- CN109010105B CN109010105B CN201810947126.8A CN201810947126A CN109010105B CN 109010105 B CN109010105 B CN 109010105B CN 201810947126 A CN201810947126 A CN 201810947126A CN 109010105 B CN109010105 B CN 109010105B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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Abstract
The invention relates to a multi-effect composition, a preparation method and application thereof, belonging to the field of skin care products. The all-in-one composition comprises the following components in parts by weight: 60-95 parts of water, 1-5 parts of polyglycerol-4 decanoate, 1-5 parts of disodium cocoyl amphodiacetate, 0.5-6 parts of a humectant, 1-10 parts of an efficacy additive, 0.1-5 parts of erythritol, 1-8 parts of butanediol, 0.5-8 parts of 1, 3-propylene glycol, 0.01-0.5 part of lactic acid and 0.1-0.7 part of 1, 2-hexanediol. The composition disclosed by the invention uses the cocoyl amphodiacetate disodium as a surfactant, so that the composition has a good makeup removing effect without irritating the skin, and is compounded with the lactic acid and the erythritol to enhance the moisturizing and moistening effects of the composition, so that the prepared composition integrates moisturizing, face cleaning, makeup removing and relieving functions, almost has no irritation to the skin and mucous membranes, and has high safety.
Description
Technical Field
The invention relates to a multi-effect composition, a preparation method and application thereof, belonging to the field of skin care products.
Background
Beauty is the female nature, and makeup has since ancient times, can increase the beauty of women on the one hand, and on the other hand also be respected by others on the social etime, not only is a basic etiquette, but also can promote self-confidence. However, after the cosmetics are used, if the makeup is not completely removed, the cosmetics remain on the face and block pores, so that the skin health is affected.
The main makeup removing varieties on the market are as follows: (1) the cream type is characterized in that a water-in-oil or pure oil system is destroyed or dissolved by massaging and utilizing grease and an emulsifier contained in the system, so that the purpose of makeup removal is achieved, and the cream type has the defects of weak makeup removal capability and heavy skin burden; (2) the pure oil and the surfactant are firstly massaged and then emulsified by water, so that makeup is removed, although the makeup removing capability is strong, the sticky feeling is easy to appear after cleaning, and the moisture retention and the after-use feeling of the skin are poor due to high intermiscibility of grease and sebum and excessive degreasing; (3) the hydrophilic emulsifier is added into a pure water system, and the makeup removing force is insufficient when the amount of the emulsifier is small; when the amount of the emulsifier is large, the irritation becomes large and the smoothness during cleaning is insufficient.
At present, the makeup removing products sold on the market have single functions, and basically have some defects in formula and function, so that the using effect of consumers is influenced. Although the makeup removing effect of part of makeup removing products is good, the phenomena of dry and unsmooth skin and desquamation often occur after the makeup removing products are used, and the traditional makeup removing products are low in safety and often cause allergic inflammation.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a multi-effect composition which integrates the functions of moisturizing, cleaning face, removing makeup and relieving, almost has no stimulation to skin and mucous membrane and has higher safety, and a preparation method and application thereof.
In order to achieve the purpose, the invention adopts the technical scheme that: the all-in-one composition comprises the following components in parts by weight: 60-95 parts of water, 1-5 parts of polyglycerol-4 decanoate, 1-5 parts of disodium cocoyl amphodiacetate, 0.5-6 parts of a humectant, 1-10 parts of an efficacy additive, 0.1-5 parts of erythritol, 1-8 parts of butanediol, 0.5-8 parts of 1, 3-propylene glycol, 0.01-0.5 part of lactic acid and 0.1-0.7 part of 1, 2-hexanediol.
Polyglycerol-4 decanoate is an emulsifier for high water content self-emulsifying oil systems, and is particularly suitable for body wash, soap lye, bath oil and wet wipes; the cocoyl amphodiacetate disodium is a mild amphoteric surfactant used in shampoos and skin cleansing products, and enhances the conditioning effect on the skin under the acidic pH condition; erythritol is a widely used polyol, is a unique sugar alcohol prepared by a fermentation process, is 100% natural, has safe components, can remarkably increase skin moisture, prevent skin dryness, increase skin flexibility and softness, prevent skin burst, maintain skin barrier, and has an ice-cold skin feeling effect; 1, 3-propanediol is a 100% natural source formed by fermenting sugar from plants, can continuously keep the moisture content of the stratum corneum which is improved at the moment of use by compounding with butanediol, can endow smooth, fine, moist, non-sticky and moist and fine use feeling after use, and has the bacteriostatic effect which is changed along with the concentration; lactic acid is naturally present in human bodies, is a natural moisturizing factor, is helpful for keeping moisture in skin, and has multiple functions, such as moisturizing, pH adjustment, bacteriostasis, whitening, cutin removal, skin softening and the like.
As a preferred embodiment of the all-in-one composition according to the present invention, the composition comprises the following components in parts by weight: 67.9-85.2 parts of water, 1.5-3 parts of polyglycerol-4-decanoate, 2-4.5 parts of disodium cocoyl amphodiacetate, 0.8-3 parts of a humectant, 2-5 parts of an efficacy additive, 0.5-2 parts of erythritol, 1.8-2 parts of butanediol, 0.5-5 parts of 1, 3-propylene glycol, 0.01-0.1 part of lactic acid and 0.4-0.5 part of 1, 2-hexanediol. Research proves that when the water accounts for 67.9-85.2 parts by weight, the polyglycerol-4 decanoate accounts for 1.5-3 parts by weight, the disodium cocoyl amphodiacetate accounts for 2-4.5 parts by weight, the humectant accounts for 0.8-3 parts by weight, the efficacy additive accounts for 2-5 parts by weight, the erythritol accounts for 0.5-2 parts by weight, the butanediol accounts for 1.8-2 parts by weight, the 1, 3-propanediol accounts for 0.5-5 parts by weight, the lactic acid accounts for 0.01-0.1 part by weight, and the 1, 2-hexanediol accounts for 0.4-0.5 part by weight, the obtained composition has better effects of moisturizing, cleansing, makeup removing and relieving.
As a preferred embodiment of the all-in-one composition according to the present invention, the composition comprises the following components in parts by weight: 84.4 parts of water, 2 parts of polyglycerol-4 decanoate, 2.2 parts of disodium cocoyl amphodiacetate, 1.2 parts of humectant, 5 parts of efficacy additive, 2 parts of erythritol, 1.8 parts of butanediol, 3 parts of 1, 3-propylene glycol, 0.1 part of lactic acid and 0.5 part of 1, 2-hexanediol. Research shows that when the water is 84.4 parts by weight, the polyglycerol-4 decanoate is 2 parts by weight, the cocoyl amphodiacetate is 2.2 parts by weight, the humectant is 1.2 parts by weight, the efficacy additive is 5 parts by weight, the erythritol is 2 parts by weight, the butanediol is 1.8 parts by weight, the 1, 3-propanediol is 3 parts by weight, the lactic acid is 0.1 part by weight, and the 1, 2-hexanediol is 0.5 part by weight, the obtained composition has the best effects of moisturizing, cleaning the face, removing makeup and relieving.
As a preferred embodiment of the all-in-one composition, the humectant is a mixture of diethylhexyl carbonate, polyglycerol-4 laurate, phenoxyethanol and dilauryl alcohol citrate, and the humectant is preferably one that wins the Industrial group
Product Wipe DE PF.
The Wipe DE PF product is a ready-to-use concentrated solution, can be prepared into a very stable oil-in-water nano emulsion by simple processing, is suitable for being prepared into an emulsion impregnation liquid for wet tissues without polyethylene glycol, has an excellent makeup removing effect, and provides fresh and non-greasy skin feel.
As a preferred embodiment of the all-in-one composition of the present invention, the efficacy additive is a mixture of water, glycerin, stem extract of dendrobium nobile lindl, leaf extract of aloe barbadensis, root extract of sophora flavescens ait, fruit extract of lycium barbarum, and extract of echinacea purpurea, and the efficacy additive is preferably AQP Free product of vast seng biotechnology limited beijing oriental. The AQP Free product is a plant moisturizing effect raw material for cosmetics for solving the problem of dry skin by combining the thought of 'whole body and syndrome differentiation' of traditional Chinese medicine and by four ways of 'tonifying, clearing, fixing and nourishing', the AQP Free extracts the inspiration from 'thousand year moisturizing prescription', the effect of dendrobium nobile fluid supplementing and fluid production promoting is taken according to the formula principle of 'monarch, minister, assistant and guide', the effects of radix sophorae flavescentis for clearing heat and diminishing inflammation are adopted, the water retention and protection screen of the echinacea pallida is fixed, the benefits of aloe vera and Ningxia medlar for nourishing yin and moisturizing are obtained, the formula synergy is realized by optimizing the proportion between groups, the expression of aquaporin AQP3 in keratinocyte is promoted, the fluid is supplemented and the fluid is generated, fine lines and scurf caused by drying are smoothed in time, the skin is durably moisturized, and the skin feel is smooth.
In a second aspect, the present invention provides a method for preparing the above all-in-one composition, comprising the steps of:
(1) adding water into an emulsifying pot, starting stirring, sequentially adding polyglycerol-4 decanoate, disodium cocoyl amphodiacetate, a humectant, an efficacy additive, erythritol and butanediol, and uniformly mixing to obtain a mixture;
(2) putting 1, 3-propylene glycol, lactic acid and 1, 2-hexanediol into a stainless steel barrel, stirring uniformly, putting into the mixture obtained in the step (1), and continuing to stir uniformly;
(3) filtering with filter cloth, and discharging to obtain the composition.
As a preferred embodiment of the method for preparing the all-in-one composition according to the present invention, in the step (1), the number of stirring revolutions is 30 revolutions per minute.
As a preferred embodiment of the method for preparing the all-in-one composition according to the present invention, in the step (3), the mesh number of the filter cloth is 300 meshes.
In a third aspect, the invention provides the application of the all-in-one composition in preparing skin care products.
Compared with the prior art, the invention has the beneficial effects that: the composition provided by the invention adopts water, polyglycerol-4 decanoate, disodium cocoyl amphodiacetate, a humectant, an effect additive, erythritol, butanediol, 1, 3-propanediol, lactic acid and 1, 2-hexanediol which are special components, and the disodium cocoyl amphodiacetate is used as a surfactant, so that the composition has a good makeup removing effect without irritating the skin, and is compounded with the lactic acid and the erythritol to enhance the moisturizing and moistening effects of the composition.
Detailed Description
To better illustrate the objects, aspects and advantages of the present invention, the present invention will be further described with reference to specific examples.
The humectant in the embodiment of the invention is purchased from the winning industry group
The Wipe DE PF product, the efficacy additive was purchased from AQP Free, a product of vast Sen Biotech, Inc., Beijing Oriental, with the remaining ingredients being commercially available.
Example 1
An example of the all-in-one composition of the present invention is shown in table 1.
The preparation method of the all-in-one composition described in this example is as follows:
(1) adding water into an emulsifying pot, stirring at 30 r/min, sequentially adding polyglycerol-4 decanoate, disodium cocoamphodiacetate, and water,
Mixing Wipe DE PF, AQP Free, erythritol and butanediol uniformly to obtain a mixture;
(2) putting 1, 3-propylene glycol, lactic acid and 1, 2-hexanediol into a stainless steel barrel, stirring uniformly, putting into the mixture obtained in the step (1), and continuing to stir uniformly;
(3) filtering with 300 mesh filter cloth to obtain the composition.
Examples 2 to 7
The components of the all-in-one composition described in examples 2 to 7 are shown in table 1, and the preparation method of the all-in-one composition described in examples 2 to 7 is the same as that of example 1.
TABLE 1
Comparative examples 1 to 5
The compositions of comparative examples 1 to 5 are shown in Table 2, and the preparation methods of the compositions of comparative examples 1 to 5 are the same as those of example 1.
TABLE 2
Effect example 1
Hemocyte hemolysis test in examples 1 to 7 of the present invention
Test methods referring to the authentic Test method for testing product irritation, Red Blood Cell (RBC) Test System, certified by the european alternative certification center, fresh rat Blood was taken, the integrity of collected Red Blood cells was examined according to the rules of the RBC Test System method, and the morphology of Red Blood cells and the integrity of Cell membranes were observed under a microscope. H of erythrocytes50About 28.7X 10-6And satisfies (29.4 +/-3.7) × 10 specified in Test System Standard-6. Under the microscope, the red blood cell morphology and cell membrane were intact.
The compositions of examples 1 to 7 of the present invention were dissolved in water and tested for irritation at higher concentrations. The sample was diluted with PBS (phosphate buffered saline) to a final concentration of 1.0% as specified in the RBC test System method, and the concentration of the test sample in the system was 3.20X 10-4The stimulation in g/mL is reflected by measuring the degree of damage to the red blood cells of the sample, and the lower the hemolysis rate, the less obvious the stimulation of the sample.
The test results show that the concentration of the compositions of examples 1 to 7 of the present invention in the system is 3.20X 10-4At g/mL, the hemolysis rate is below 10%, and no obvious hemolyzing phenomenon of red blood cells occurs, which shows that the compositions of the embodiments 1-7 of the invention do not cause obvious damage and stimulation to the red blood cells, and hardly stimulate the skin and mucosa.
Effect example 2
Moisturizing effect test of examples 1 to 7 and comparative examples 1 to 5 of the present invention
Randomly selecting 120 healthy male and female subjects, wherein the ages of the subjects are 18-65 years, the subjects have no serious system diseases, no immune defects or autoimmune diseases, no allergic diseases, no use of various cosmetics during the test period and the like, and the subjects can finish the specified contents according to the experimental requirements. The test subjects were divided into 12 groups of 10 persons each, and the compositions prepared in examples 1 to 7 and comparative examples 1 to 5 were used for the test, and before the test, two hours of the test, the moisture content of the skin of the test subjects was measured, and the average value was taken, thereby judging the moisturizing effect of the product.
The whitening effect products (cosmetics, external medicines or internal health care products) cannot be used for 2-3 days before the face of the subject, and the subject needs to uniformly clean the facial skin by using the compositions of the examples 1-7 and the comparative examples 1-5 of the invention. The test area comprises a forehead area with the middle of the eyebrow center being 2cm upward, a chin area with the middle of the lower lip being 2cm downward, and left and right cheek areas at the intersection line of the nose tip and the pupil. The test instrument is a skin elasticity Cotomer MPA580 host machine of Courage + Khazaka company, Germany, and the probe used is a skin moisture content Cornemeter CM825 test probe. The test results are shown in table 3.
TABLE 3
As can be seen from Table 3, the moisturizing effect of the test area of the subject was good after using the compositions of examples 1 to 7, and the increase in moisture was significant after 2 hours of the test. In comparative examples 1 to 3, the moisturizing effect was inferior to that of the present invention due to the absence of some of the components of the composition of the present invention; in comparative examples 4 to 5, the composition was not fully within the scope of the present invention in terms of weight parts, and the moisturizing effect was inferior to that of the present invention. Therefore, the components of the composition are combined together according to the weight part of the invention, and the composition has good moisturizing effect. Moreover, when 67.9-85.2 parts by weight of water, 1.5-3 parts by weight of polyglycerol-4 decanoate, 2-4.5 parts by weight of disodium cocoyl amphodiacetate, 0.8-3 parts by weight of humectant, 2-5 parts by weight of efficacy additive, 0.5-2 parts by weight of erythritol, 1.8-2 parts by weight of butanediol, 0.5-5 parts by weight of 1, 3-propanediol, 0.01-0.1 part by weight of lactic acid and 0.4-0.5 part by weight of 1, 2-hexanediol, the obtained composition has a better moisturizing effect; when 84.4 parts by weight of water, 2 parts by weight of polyglycerol-4 decanoate, 2.2 parts by weight of disodium cocoyl amphodiacetate, 1.2 parts by weight of humectant, 5 parts by weight of efficacy additive, 2 parts by weight of erythritol, 1.8 parts by weight of butanediol, 3 parts by weight of 1, 3-propanediol, 0.1 part by weight of lactic acid and 0.5 part by weight of 1, 2-hexanediol, the obtained composition has the best moisturizing effect.
Effect example 3
Cleansing and makeup removal effect test of examples 1 to 7 and comparative examples 1 to 5 of the present invention
Randomly selecting 120 male and female subjects as study objects, selecting equivalent BB cream (W/O type) for full-face makeup within the age of 18-65 years, dividing the subjects into 12 groups of 10 persons, respectively using the compositions prepared in examples 1-7 and comparative examples 1-5 for makeup removal, dividing makeup removal effects into three grades of good, general and poor, dividing skin feel after makeup removal into two grades of relaxation and tightness, and counting the evaluation number of the makeup removal effects and the skin feel evaluation number of each grade after makeup removal. The results are shown in Table 4.
TABLE 4
As can be seen from Table 4, the compositions of examples 1 to 7 were used, and the subjects evaluated the makeup removal effect well, and the skin feel after makeup removal was smooth. In comparative examples 1 to 3, the makeup removing effect and the skin feel after makeup removal were inferior to those of the present invention due to the absence of some of the components of the composition of the present invention; in comparative examples 4 to 5, the compositions were not in the range of the present invention in terms of parts by weight, and the makeup removing effect and the skin feel after makeup removal were inferior to those of the present invention. Therefore, the components of the composition are combined together according to the weight parts of the invention, and the composition has good makeup removing effect and skin feel after makeup removal. Moreover, when 67.9-85.2 parts by weight of water, 1.5-3 parts by weight of polyglycerol-4 decanoate, 2-4.5 parts by weight of disodium cocoyl amphodiacetate, 0.8-3 parts by weight of humectant, 2-5 parts by weight of efficacy additive, 0.5-2 parts by weight of erythritol, 1.8-2 parts by weight of butanediol, 0.5-5 parts by weight of 1, 3-propanediol, 0.01-0.1 part by weight of lactic acid and 0.4-0.5 part by weight of 1, 2-hexanediol, the obtained composition has better makeup removal effect and skin feel after makeup removal; when 84.4 parts by weight of water, 2 parts by weight of polyglycerol-4 decanoate, 2.2 parts by weight of disodium cocoyl amphodiacetate, 1.2 parts by weight of humectant, 5 parts by weight of efficacy additive, 2 parts by weight of erythritol, 1.8 parts by weight of butanediol, 3 parts by weight of 1, 3-propanediol, 0.1 part by weight of lactic acid and 0.5 part by weight of 1, 2-hexanediol, the obtained composition has the best makeup removal effect and skin feel after makeup removal.
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the protection scope of the present invention, and although the present invention is described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions can be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.
Claims (6)
1. The all-in-one composition is characterized by comprising the following components in parts by weight: 84.4 parts of water, 2 parts of polyglycerol-4 decanoate, 2.2 parts of disodium cocoyl amphodiacetate, 1.2 parts of a humectant, 5 parts of an efficacy additive, 2 parts of erythritol, 1.8 parts of butanediol, 3 parts of 1, 3-propylene glycol, 0.1 part of lactic acid and 0.5 part of 1, 2-hexanediol, wherein the humectant is a mixture of diethylhexyl carbonate, polyglycerol-4 laurate, phenoxyethanol and dilauryl alcohol citrate.
2. The all-in-one composition according to claim 1, wherein the efficacy additive is a mixture of water, glycerin, stem extract of dendrobium nobile, leaf extract of aloe barbadensis, root extract of sophora flavescens ait, fruit extract of lycium barbarum, and echinacea purpurea extract.
3. The method of preparing the all-in-one composition of claim 1 or 2, comprising the steps of:
(1) adding water into an emulsifying pot, starting stirring, sequentially adding polyglycerol-4 decanoate, disodium cocoyl amphodiacetate, a humectant, an efficacy additive, erythritol and butanediol, and uniformly mixing to obtain a mixture;
(2) putting 1, 3-propylene glycol, lactic acid and 1, 2-hexanediol into a stainless steel barrel, stirring uniformly, putting into the mixture obtained in the step (1), and continuing to stir uniformly;
(3) filtering with filter cloth, and discharging to obtain the composition.
4. The method of preparing the all-in-one composition according to claim 3, wherein the number of stirring revolutions is 30 revolutions per minute in the step (1).
5. The method of preparing the all-in-one composition according to claim 3, wherein the filter cloth has a mesh size of 300 mesh in the step (3).
6. Use of the all-in-one composition according to claim 1 or 2 for the preparation of a skin care product.
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| CN111617006A (en) * | 2020-06-30 | 2020-09-04 | 广州市瑞芬化妆品有限公司 | Layered emulsion integrating three effects of cleaning face, removing makeup and bathing and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1250906A2 (en) * | 2001-04-20 | 2002-10-23 | Hans Schwarzkopf GmbH & Co. KG | Compositions for skin and/or hair treatment |
| CN106821908A (en) * | 2017-02-15 | 2017-06-13 | 云南白药集团股份有限公司 | Makeup-removing wet tissue and its compound method with moisture-keeping function |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1250906A2 (en) * | 2001-04-20 | 2002-10-23 | Hans Schwarzkopf GmbH & Co. KG | Compositions for skin and/or hair treatment |
| CN106821908A (en) * | 2017-02-15 | 2017-06-13 | 云南白药集团股份有限公司 | Makeup-removing wet tissue and its compound method with moisture-keeping function |
Non-Patent Citations (1)
| Title |
|---|
| 天然活性化妆品的现状与发展趋势;施昌松;《日用化学品科学》;20121231;第35卷(第2期);第1-5页 * |
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