CN108976984A - A kind of bamboo handicraft product environmental protection paint - Google Patents
A kind of bamboo handicraft product environmental protection paint Download PDFInfo
- Publication number
- CN108976984A CN108976984A CN201810667512.1A CN201810667512A CN108976984A CN 108976984 A CN108976984 A CN 108976984A CN 201810667512 A CN201810667512 A CN 201810667512A CN 108976984 A CN108976984 A CN 108976984A
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- parts
- environmental protection
- handicraft product
- paint
- product environmental
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to artworks to handle industrial field, disclose a kind of bamboo handicraft product environmental protection paint, using epoxy resin E-51 and acrylic acid as performed polymer, modification is optimized to polymerization reaction using composite nano inoganic material, it participates in curing cross-linking reaction, enhance the toughness of lotion, effective solution problem of the bamboo material surface smooth texture to paint vehicle compatibility difference, paint film adhesion is strong after film, good light stability, flexibility is good, paint film is plentiful, acid and alkali-resistance, tool has good wearability and stain resistance, the present invention provides a kind of a kind of effective means for realizing raising bamboo handicraft product environmental protection paint paint film comprehensive performance, process is easy to operate, it is high-efficient, with easy to operate, securely and reliably, the advantages that maintaining the service life long, it is a kind of technical solution being extremely worth of widely use.
Description
Technical field
The invention belongs to artworks to handle industrial technology field, and in particular to a kind of bamboo handicraft product environmental protection paint.
Background technique
Traditional bamboo handicraft has long history, is rich in the crystallization that Chinese nation working people works hard, bamboo weaving
Craftwork is divided into fillagree product and crin bamboo handicraft product.It is proved according to archaeological materials, the mankind start after settling down life, are just engaged in
Simple agricultural and Animal husbandry production, the meter Su obtained and the food slight surplus hunted, for the possible period of want or need, just food and
Drinking-water storage is got up.It at this time just gathers materials on the spot, is cut using tools such as various zaxs, stone knives and carry out the branch of plant and weave into basket, basket
Equal vessel.In practice, it has been found that bamboo is crisp, cracking behavior is strong, high resilience and toughness, and can compile and easily knit, firm resistance to
With.Then, bamboo has become the main material of vessel establishment at that time.
Into after 21 century, bamboo handicraft loses market competitiveness youngster gradually and comes down, and weaves skill at " non-
Matter input ".However, also there is many bamboo weaving art men still to pursue new art tireless, new works exist
Slowly stand out.Bamboo handicraft product paint can not only meet people while pursuing rich in color, and extension work can be reached by having
The effect in skill product service life.And the material special due to bamboo product, adhesive force of the general environmental protection paint on surface are bad, it is not resistant to water
The environmental attacks such as gas, soda acid, are easy to appear the problems such as the fading that fall off, and need to seek a kind of durability suitable for bamboo product to this
Environmental protection paint.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of bamboo handicraft product environmental protection paint, effective solution are provided
Problem of the bamboo material surface smooth texture to paint vehicle compatibility difference, paint film adhesion is strong after film, good light stability, flexibility
Good, paint film is plentiful, acid and alkali-resistance.
The present invention is achieved by the following technical solutions:
A kind of bamboo handicraft product environmental protection paint, is made of following component in parts by weight: 45-55 parts of epoxy resin E-51, third
30-34 parts of olefin(e) acid, 10-12 parts of polyoxyethylene amine, 8-10 parts of zinc-base silane, 6-7 parts of hexamethyldisilazane, azodiisobutyronitrile
2-3 parts, 1.0-1.2 parts of composite Nano base emulsions, 0.8-1.0 parts of dimethylethanolamine, 5-8 parts of pentaerythrite, defoaming agent
0.4-0.6 parts, 0.3-0.5 parts of levelling agent, 140-160 parts of water, the composite Nano base emulsions preparation method includes following step
It is rapid:
(1) it weighs 4.5-5.0 grams of nano zircite to be scattered in 20-25 ml deionized water, is heated to 45-55 DEG C under stirring,
5-6 milliliters of linseed oil fatty acids and 1.6-2.0 grams of polyvinyl alcohol is added, continues to be placed on reaction kettle in high-speed stirred 30-40 minutes
In；
(2) heating is heated to 120-130 DEG C, reacts 3-4 hours, and 1.0-1.5 milliliters of pyridines are added dropwise, continue to cover after mixing evenly
Reaction, reaction temperature rise to 150-160 DEG C, and when reaction is 2-3 hour a length of, after reaction natural cooling, standing 12-15 hours
Afterwards, sodium carbonate liquor is added and adjusts pH value to neutrality.
It is further described as to above scheme, the composite Nano base emulsions are preheated in epoxy resin E-51
It is added after 50-60 DEG C.
It is further described as to above scheme, step (1) the nano zircite particle size is in 40-50 nanometer
Between.
It is further described as to above scheme, step (1) the high-speed stirred speed is 1200-1400 revs/min.
It is further described as to above scheme, step (2) the sodium carbonate liquor mass concentration is 20-25%.
The present invention has the advantage that poor in order to solve existing bamboo handicraft product environmental protection paint film durability compared with prior art
The problem of, the present invention provides a kind of bamboo handicraft product environmental protection paints, using epoxy resin E-51 and acrylic acid as performed polymer, use
Composite nano inoganic material optimizes modification to polymerization reaction, participates in curing cross-linking reaction, enhances the toughness of lotion, has
Effect solves the problems, such as that bamboo material surface smooth texture is poor to paint vehicle compatibility, and paint film adhesion is strong after film, good light stability,
Flexibility is good, and paint film is plentiful, acid and alkali-resistance, and tool has good wearability and stain resistance, and the present invention provides a kind of realization raisings
A kind of bamboo handicraft product effective means of environmental protection paint paint film comprehensive performance, process is easy to operate, high-efficient, has operation side
Just, securely and reliably, the advantages that maintaining the service life long is a kind of technical solution being extremely worth of widely use.
Specific embodiment
To make the purpose of the present invention, technical solution and effect clearer, clear and definite, combined with specific embodiments below to this hair
It is bright to be described further, it should be understood that the specific embodiments described herein are merely illustrative of the present invention, is not used to limit
Technical solution provided by the present invention.
Embodiment 1
A kind of bamboo handicraft product environmental protection paint, is made of following component in parts by weight: 45 parts of epoxy resin E-51, propylene
Sour 30 parts, 10 parts of polyoxyethylene amine, 8 parts of zinc-base silane, 6 parts of hexamethyldisilazane, 2 parts of azodiisobutyronitrile, composite Nano
1.0 parts of base emulsions, 0.8 part of dimethylethanolamine, 5 parts of pentaerythrite, 0.4 part of defoaming agent, 0.3 part of levelling agent, 140 parts of water,
The composite Nano base emulsions preparation method the following steps are included:
(1) 4.5 grams of nano zircites are weighed to be scattered in 20 ml deionized waters, 45 DEG C are heated under stirring, 5 milliliters of Asias are added
Sesame oil fatty acid and 1.6 grams of polyvinyl alcohol continue high-speed stirred and are placed in reaction kettle for 30 minutes；
(2) heating is heated to 120 DEG C, reacts 3 hours, 1.0 milliliters of pyridines are added dropwise, and continues to cover reaction, reaction after mixing evenly
Temperature rises to 150 DEG C, and when reaction is 2 hours a length of, and natural cooling, after standing 12 hours, is added sodium carbonate liquor after reaction
PH value is adjusted to neutrality.
It is further described as to above scheme, the composite Nano base emulsions are preheated to 50 in epoxy resin E-51
It is added after DEG C.
It is further described as to above scheme, step (1) the nano zircite particle size is in 40-50 nanometer
Between.
It is further described as to above scheme, step (1) the high-speed stirred speed is 1200 revs/min.
It is further described as to above scheme, step (2) the sodium carbonate liquor mass concentration is 20%.
Embodiment 2
A kind of bamboo handicraft product environmental protection paint, is made of following component in parts by weight: 50 parts of epoxy resin E-51, propylene
It is 32 parts of acid, 11 parts of polyoxyethylene amine, 9 parts of zinc-base silane, 6.5 parts of hexamethyldisilazane, 2.5 parts of azodiisobutyronitrile, compound
1.1 parts of nanomatrix lotion, 0.9 part of dimethylethanolamine, 6 parts of pentaerythrite, 0.5 part of defoaming agent, 0.4 part of levelling agent, water 150
Part, the composite Nano base emulsions preparation method the following steps are included:
(1) 4.8 grams of nano zircites are weighed to be scattered in 22 ml deionized waters, 50 DEG C are heated under stirring, are added 5.5 milliliters
Linseed oil fatty acid and 1.8 grams of polyvinyl alcohol continue high-speed stirred and are placed in reaction kettle for 35 minutes；
(2) heating is heated to 125 DEG C, reacts 3.5 hours, 1.2 milliliters of pyridines are added dropwise, and continues to cover reaction after mixing evenly, instead
Temperature is answered to rise to 155 DEG C, when reaction is 2.5 hours a length of, and natural cooling, after standing 13 hours, is added sodium carbonate after reaction
Solution adjusts pH value to neutrality.
It is further described as to above scheme, the composite Nano base emulsions are preheated to 55 in epoxy resin E-51
It is added after DEG C.
It is further described as to above scheme, step (1) the nano zircite particle size is in 40-50 nanometer
Between.
It is further described as to above scheme, step (1) the high-speed stirred speed is 1300 revs/min.
It is further described as to above scheme, step (2) the sodium carbonate liquor mass concentration is 22%.
Embodiment 3
A kind of bamboo handicraft product environmental protection paint, is made of following component in parts by weight: 55 parts of epoxy resin E-51, propylene
Sour 34 parts, 12 parts of polyoxyethylene amine, 10 parts of zinc-base silane, 7 parts of hexamethyldisilazane, 3 parts of azodiisobutyronitrile, composite Nano
1.2 parts of base emulsions, 1.0 parts of dimethylethanolamine, 8 parts of pentaerythrite, 0.6 part of defoaming agent, 0.5 part of levelling agent, 160 parts of water,
The composite Nano base emulsions preparation method the following steps are included:
(1) 5.0 grams of nano zircites are weighed to be scattered in 25 ml deionized waters, 55 DEG C are heated under stirring, 6 milliliters of Asias are added
Sesame oil fatty acid and 2.0 grams of polyvinyl alcohol continue high-speed stirred and are placed in reaction kettle after forty minutes；
(2) heating is heated to 130 DEG C, reacts 4 hours, 1.5 milliliters of pyridines are added dropwise, and continues to cover reaction, reaction after mixing evenly
Temperature rises to 160 DEG C, and when reaction is 3 hours a length of, and natural cooling, after standing 15 hours, is added sodium carbonate liquor after reaction
PH value is adjusted to neutrality.
It is further described as to above scheme, the composite Nano base emulsions are preheated to 60 in epoxy resin E-51
It is added after DEG C.
It is further described as to above scheme, step (1) the nano zircite particle size is in 40-50 nanometer
Between.
It is further described as to above scheme, step (1) the high-speed stirred speed is 1400 revs/min.
It is further described as to above scheme, step (2) the sodium carbonate liquor mass concentration is 25%.
Comparative example 1
Difference with embodiment 1 is only that, omits the preparation addition of the composite Nano base emulsions, remaining is consistent.
Comparative example 2
Difference with embodiment 2 is only that the proportion of epoxy resin E-51 and acrylic acid is 1:1 in environmental protection paint, remaining keeps one
It causes.
Comparative example 3
Difference with embodiment 3 is only that, in the preparation of composite Nano base emulsions, omits linseed oil fatty acid in step (1)
With the addition of polyvinyl alcohol, remaining is consistent.
Comparative example 4
Difference with embodiment 3 is only that, in the preparation of composite Nano base emulsions, omits the addition of pyridine in step (2),
It is remaining to be consistent.
Comparative experiments
Bamboo handicraft product environmental protection paint is prepared using the method for embodiment 1-3 and comparative example 1-4 respectively, while with existing poly- third
Olefin(e) acid Waterborne wood paint as a control group, uses 100 millimeters long, 50 millimeters wide, thick 5 millimeters of bamboo clappers as subjects, respectively
Film is carried out using each group paint vehicle, keeps irrelevant variable consistent in film, paint film property detection case is counted, tie
Fruit is as shown in the table:
The present invention provides a kind of a kind of effective means for realizing raising bamboo handicraft product environmental protection paint paint film comprehensive performance, processes
It is easy to operate, it is high-efficient, have easy to operate, securely and reliably, the advantages that maintaining the service life long is a kind of to be extremely worth of widely use
Technical solution.
Claims (5)
1. a kind of bamboo handicraft product environmental protection paint, which is characterized in that be made in parts by weight of following component: epoxy resin
45-55 parts of E-51,30-34 parts of acrylic acid, 10-12 parts of polyoxyethylene amine, 8-10 parts of zinc-base silane, hexamethyldisilazane 6-7
Part, 2-3 parts of azodiisobutyronitrile, 1.0-1.2 parts of composite Nano base emulsions, 0.8-1.0 parts of dimethylethanolamine, pentaerythrite
5-8 parts, 0.4-0.6 parts of defoaming agent, 0.3-0.5 parts of levelling agent, 140-160 parts of water, composite Nano base emulsions preparation side
Method the following steps are included:
(1) it weighs 4.5-5.0 grams of nano zircite to be scattered in 20-25 ml deionized water, is heated to 45-55 DEG C under stirring,
5-6 milliliters of linseed oil fatty acids and 1.6-2.0 grams of polyvinyl alcohol is added, continues to be placed on reaction kettle in high-speed stirred 30-40 minutes
In；
(2) heating is heated to 120-130 DEG C, reacts 3-4 hours, and 1.0-1.5 milliliters of pyridines are added dropwise, continue to cover after mixing evenly
Reaction, reaction temperature rise to 150-160 DEG C, and when reaction is 2-3 hour a length of, after reaction natural cooling, standing 12-15 hours
Afterwards, sodium carbonate liquor is added and adjusts pH value to neutrality.
2. a kind of bamboo handicraft product environmental protection paint as described in claim 1, which is characterized in that the composite Nano base emulsions exist
Epoxy resin E-51 is added after being preheated to 50-60 DEG C.
3. a kind of bamboo handicraft product environmental protection paint as described in claim 1, which is characterized in that step (1) described nano zircite
Particle size is between 40-50 nanometers.
4. a kind of bamboo handicraft product environmental protection paint as described in claim 1, which is characterized in that step (1) the high-speed stirred speed
Degree is 1200-1400 revs/min.
5. a kind of bamboo handicraft product environmental protection paint as described in claim 1, which is characterized in that step (2) described sodium carbonate liquor
Mass concentration is 20-25%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810667512.1A CN108976984A (en) | 2018-06-26 | 2018-06-26 | A kind of bamboo handicraft product environmental protection paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810667512.1A CN108976984A (en) | 2018-06-26 | 2018-06-26 | A kind of bamboo handicraft product environmental protection paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108976984A true CN108976984A (en) | 2018-12-11 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810667512.1A Pending CN108976984A (en) | 2018-06-26 | 2018-06-26 | A kind of bamboo handicraft product environmental protection paint |
Country Status (1)
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112045806A (en) * | 2020-09-02 | 2020-12-08 | 安徽嘉美工艺品有限公司 | Method for pre-treating masson pine wood before dyeing |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937369A (en) * | 2014-04-16 | 2014-07-23 | 中山大桥化工集团有限公司 | Environment-friendly anticorrosive coating material for automobile parts and preparation method thereof |
| CN107880716A (en) * | 2017-11-22 | 2018-04-06 | 浙江加州国际纳米技术研究院台州分院 | A kind of nanometer strengthens water-based anticorrosive paint |
-
2018
- 2018-06-26 CN CN201810667512.1A patent/CN108976984A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937369A (en) * | 2014-04-16 | 2014-07-23 | 中山大桥化工集团有限公司 | Environment-friendly anticorrosive coating material for automobile parts and preparation method thereof |
| CN107880716A (en) * | 2017-11-22 | 2018-04-06 | 浙江加州国际纳米技术研究院台州分院 | A kind of nanometer strengthens water-based anticorrosive paint |
Non-Patent Citations (1)
| Title |
|---|
| 邓爱民等: "丙烯酸接枝改性环氧树脂的研究", 《化学与黏合》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112045806A (en) * | 2020-09-02 | 2020-12-08 | 安徽嘉美工艺品有限公司 | Method for pre-treating masson pine wood before dyeing |
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Application publication date: 20181211 |
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