CN108976593B - Flame-retardant polyolefin composition and preparation method thereof - Google Patents
Flame-retardant polyolefin composition and preparation method thereof Download PDFInfo
- Publication number
- CN108976593B CN108976593B CN201810635059.6A CN201810635059A CN108976593B CN 108976593 B CN108976593 B CN 108976593B CN 201810635059 A CN201810635059 A CN 201810635059A CN 108976593 B CN108976593 B CN 108976593B
- Authority
- CN
- China
- Prior art keywords
- flame retardant
- polyolefin composition
- composition according
- flame
- retardant polyolefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a flame-retardant polyolefin composition which comprises the following components in parts by weight: 100 parts of polyolefin resin; 0.5-10 parts of tri (2, 3-dibromopropyl) isocyanurate; 0.5-10 parts of phosphorus flame retardant; 0.1-2 parts of flame-retardant synergist. The phosphorus flame retardant is at least one selected from hypophosphite, phosphate and polyphosphate. The flame-retardant polyolefin composition has the advantages of excellent flame retardance, surface gloss, transparency and the like, and particularly has better surface gloss under the condition of compounding the tris (2, 3-dibromopropyl) isocyanurate, hypophosphite or phosphate and a flame-retardant synergist.
Description
Technical Field
The invention relates to the technical field of macromolecules, in particular to a flame-retardant polyolefin composition and a preparation method thereof.
Background
The polyolefin resin comprises polyethylene, polypropylene, polyvinyl acetate and various olefin copolymers, wherein the polypropylene is one of the most widely used general plastics due to excellent comprehensive performance, good cost performance and wider processing and forming conditions. Polyolefin resin is mostly flammable material, for example, polypropylene has a limited oxygen index of 17-18%, is extremely easy to burn, cannot be self-extinguished after being ignited, and the polyolefin resin such as polypropylene must be subjected to flame retardant modification along with the gradual increase of the safety requirement of the material.
The flame retardant for polyolefin is mainly divided into brominated flame retardant and halogen-free flame retardant, and in the existing flame-retardant modified polyolefin, in order to meet the requirement of non-halogenation, flame retardant containing phosphorus, nitrogen or a compound system of phosphorus and nitrogen is required to be added. At present, the most common phosphorus-containing flame retardant and the composition thereof mainly comprise an intumescent flame retardant system taking phosphate and ammonium polyphosphate as main bodies and the like. However, compared with the traditional bromine-antimony compound flame retardant system, the flame retardant system has the defects of large addition amount, poor physical properties and the like, and has great limitation in wide application.
Chinese patent 201010154587.3 discloses a flame retardant composition with phosphinate and melamine hydrobromide as main components, which can make polypropylene reach UL 94V-2 flame retardant level, but the flame retardant synergist in the components contains elements such as antimony, bismuth and the like, which can reduce the transparency of the material. Meanwhile, antimony and compounds thereof are used as typical heavy metal non-renewable mineral resources, so that the price is high, the problems of environmental pollution and health damage are easily caused in the processing process, and the antimony-free flame-retardant formula system effectively solves the problems. Chinese patent 200980131213.5 discloses a polypropylene composition containing a mixture of tris (tribromoneopentyl) phosphate and a carbon-carbon initiator as a flame retardant component, which does not contain antimony trioxide, can meet the flame retardant rating of UL94V-1 or V-0, but has a higher flame retardant addition amount.
With the continuous improvement of application requirements of downstream industries, besides the requirements on conventional performances such as flame retardant performance, physical performance and the like, more and more products are expected to have better surface gloss and transparency, and the performances of the conventional flame retardant systems such as bromine-antimony, halogen-free expansion and the like are difficult to satisfy in the aspects.
Disclosure of Invention
The invention aims to provide a flame-retardant polyolefin composition which has the advantages of excellent flame retardance, surface gloss, transparency and the like, and particularly has the best surface gloss when tris (2, 3-dibromopropyl) isocyanurate, hypophosphite or phosphate and a flame-retardant synergist are compounded.
It is another object of the present invention to provide a method for preparing the above flame retardant polyolefin composition.
The invention is realized by the following technical scheme:
a flame-retardant polyolefin composition comprises the following components in parts by weight:
100 parts of polyolefin resin;
0.5-10 parts of tri (2, 3-dibromopropyl) isocyanurate;
0.5-10 parts of phosphorus flame retardant;
0.1-2 parts of flame-retardant synergist.
Preferably, the composition comprises the following components in parts by weight:
100 parts of polyolefin resin;
1-5 parts of tri (2, 3-dibromopropyl) isocyanurate;
1-5 parts of a phosphorus flame retardant;
0.15-1 part of flame-retardant synergist.
More preferably, the composition comprises the following components in parts by weight:
100 parts of polyolefin resin;
1-3 parts of tri (2, 3-dibromopropyl) isocyanurate;
1-3 parts of a phosphorus flame retardant;
0.2 to 0.5 portion of flame retardant synergist.
The average particle diameter of the tri (2, 3-dibromopropyl) isocyanurate is 1-10 microns; preferably, the average particle size of the tris (2, 3-dibromopropyl) isocyanurate is 1 to 5 microns. The particle size is too large, the dispersing effect of the flame retardant is poor, and the surface gloss and transparency of the product are reduced more.
The phosphorus flame retardant is at least one selected from hypophosphite, phosphate and polyphosphate; preferably, at least one selected from hypophosphite and phosphate; the hypophosphite is selected from at least one of aluminum hypophosphite, calcium hypophosphite, dimethyl aluminum hypophosphite, diethyl aluminum hypophosphite and methyl ethyl aluminum hypophosphite; the phosphate is selected from at least one of triphenyl phosphate, resorcinol bis (diphenyl phosphate), bisphenol A-bis (diphenyl phosphate) and oligomeric aryl phosphate; the polyphosphate is selected from at least one of ammonium polyphosphate, melamine phosphate, melamine pyrophosphate and melamine polyphosphate. Wherein the polymerization degree of the oligomeric aryl phosphate is 2-10.
The average grain diameter of the phosphorus flame retardant is 1-10 microns; preferably, the average particle size of the phosphorus flame retardant is 1-5 microns. The particle size is too large, the dispersing effect of the flame retardant is poor, and the surface gloss and transparency of the product are reduced more.
The flame retardant synergist is selected from at least one of a compound (I) and/or at least one of a compound (II);
the general formula of the compound (I) is
Wherein R1, R2, R3 or R4 are respectively any one of C1-12 alkyl, C1-12 alkoxy, C6-12 aryl or C6-12 aryloxy; preferably C1-12 alkyl; more preferably C1-4 alkyl; x or Y is any one of H, C1-12 alkyl, C1-12 alkoxy, C6-12 aryl, C6-12 aryloxy, halogen, nitro, sulfonic group or polysubstituted aryl; preferably H or C1-12 alkyl;
the compound (II) has the general formula
Wherein R5 is any one of C1-12 alkyl, C1-12 alkoxy, C6-12 aryl or C6-12 aryloxy; preferably C1-12 alkyl; more preferably C1-4 alkyl; n is 2 to 20; preferably 2 to 10; more preferably 3-6.
Flame retardant synergist such as poly (1, 4-diisopropylbenzene) (n is 3-10), 2, 3-dimethyl-2, 3-diphenylbutane.
The polyolefin resin is at least one selected from polyethylene resin and polypropylene resin. Such as random copolymer polypropylene, homo-polypropylene, high density polyethylene, etc.
0-1 part of antioxidant and 0-1 part of processing aid are also included according to the parts by weight; the antioxidant is selected from at least one of phenols, amines, phosphites, semi-hindered phenols, calixarenes and dilauryl thiodipropionate; the processing aid is at least one of low molecular weight lipid, metal soap, stearic acid composite ester and amide. Such as: the processing aid can be lubricant calcium stearate; the antioxidant can be antioxidant 1010 and antioxidant 168.
The flame-retardant polyolefin composition has the surface gloss of more than or equal to 74 degrees, the light transmittance of more than or equal to 69 percent and the haze of less than or equal to 91 percent, wherein the surface gloss adopts the GB 8807-1988 standard, the light transmittance adopts the GB/T2410-2008 standard, and the haze adopts the GB/T2410-2008 standard.
Preferably, the surface gloss of the flame-retardant polyolefin composition is more than or equal to 79 degrees, the light transmittance is more than or equal to 74 percent, the haze is less than or equal to 86 percent, the surface gloss adopts GB 8807-1988 standard, the light transmittance adopts GB/T2410-2008 standard, and the haze adopts GB/T2410-2008 standard.
According to the flame-retardant polyolefin composition, the influence of the reserved particle size of the flame retardant in the product on the surface gloss, the light transmittance and the haze is large, the dispersion of the flame retardant in the product is nonuniform due to the large particle size of the flame retardant, and the surface gloss, the light transmittance and the haze are reduced and increased.
The preparation method of the flame-retardant polyolefin composition comprises the following steps:
A) weighing polyolefin resin, tris (2, 3-dibromopropyl) isocyanurate, a phosphorus flame retardant and a flame retardant synergist in proportion, and uniformly mixing the materials by a high-speed mixer;
B) and melting, extruding, granulating and drying at 180-200 ℃ by a double-screw extruder to obtain the flame-retardant polyolefin composition.
Antioxidants and processing aids can also be added in the step A).
The invention has the following beneficial effects:
according to the invention, the tri (2, 3-dibromopropyl) isocyanurate, the phosphorus flame retardant and the flame retardant synergist are compounded, so that the flame retardant polyolefin composition can have the flame retardant rating of UL-94V-2 (0.8-3.2 mm) under the condition of only adding a small amount of flame retardant, and the flame retardant polyolefin composition has the advantages of excellent surface gloss and transparency. Particularly, under the condition of compounding the tri (2, 3-dibromopropyl) isocyanurate, the phosphate or the hypophosphite and the flame retardant synergist, the surface gloss of the composition is better.
Detailed Description
The present invention is further illustrated by the following specific examples, which are, however, not intended to limit the scope of the invention.
The raw materials used in the examples and comparative examples are the following raw materials, and the rest raw materials are commercially available, but the present invention is not limited by the following raw materials:
high density polyethylene: dow chemical company;
homo-polypropylene: exxon Mobil corporation;
random copolymerized polypropylene: exxon Mobil corporation;
2, 3-dimethyl-2, 3-diphenylbutane: tanzhou Zhufeng Fine chemical Co., Ltd;
poly 1, 4-diisopropylbenzene: n is 3 to 10; tanzhou Zhufeng Fine chemical Co., Ltd;
poly 1, 4-diisopropylbenzene: n is 3 to 6; tanzhou Zhufeng Fine chemical Co., Ltd;
tris (2, 3-dibromopropyl) isocyanurate a: the average particle size was 2.0 microns;
tris (2, 3-dibromopropyl) isocyanurate B: the average particle size was 6.0 microns;
aluminum hypophosphite A: the average particle size was 1.5 microns;
aluminum hypophosphite B: the average particle size was 5.5 microns;
ammonium polyphosphate: the average particle size was 2.0 microns;
the rest of the raw materials are commercially available.
Examples, comparative examples preparation of flame retardant polyolefin compositions:
weighing polyolefin resin, tris (2, 3-dibromopropyl) isocyanurate, a phosphorus flame retardant, a flame retardant synergist, an antioxidant and a processing aid in proportion, uniformly mixing the materials by a high-speed mixer, then performing melt extrusion at 200 ℃ by a double-screw extruder, granulating and drying to obtain the flame retardant polyolefin composition.
The performance test method comprises the following steps:
(1) UL-94, 3.2 mm: according to the UL-94 standard, the thickness of the test sample strip is 3.2 mm;
(2) UL-94, 1.6 mm: according to the UL-94 standard, the thickness of the test sample strip is 1.6 mm;
(3) UL-94, 0.8 mm: according to the UL-94 standard, the thickness of the test sample strip is 0.8 mm;
(4) surface gloss: the angle is tested to be 60 degrees according to the GB 8807-1988 standard;
(5) light transmittance: according to the GB/T2410-2008 standard, the thickness of a test sample is 1.0 mm;
(6) haze: according to the GB/T2410-2008 standard, the thickness of a test sample is 1.0 mm;
note: the criterion for transparency includes both light transmittance and haze, the higher the light transmittance and the lower the haze the better the transparency.
(7) The detection method of the average particle size of the flame retardant comprises the following steps: preparing the compound into a sample, freezing the sample in liquid nitrogen for 5 minutes, then brittle fracture, observing the shape and size of the flame retardant with the section of 50 x 50 microns by adopting SEM, and counting the average particle size of the flame retardant within the range
Table 1: examples and comparative examples the respective component ratios (parts by weight) and the respective performance test results
TABLE 1
Note: NR means that the lowest level is not reached
As can be seen from examples 1-7, the present invention achieves a flame retardant rating of UL-94V-2 with a lower amount of flame retardant and has high surface gloss and transparency, wherein the lower the amount of flame retardant used, the higher the surface gloss and transparency; from example 2/8/9, it can be seen that when tris (2, 3-dibromopropyl) isocyanurate, phosphate or hypophosphite and a flame retardant synergist are compounded, the surface gloss of the product is higher; it can be seen from examples 2 and 13 that when the average particle diameter of tris (2, 3-dibromopropyl) isocyanurate and the phosphorus-based flame retardant is 1 to 5 μm, the surface gloss and the light transmittance are high. It can be seen from examples 2 and 9 that the flame retardant synergist is used in an amount exceeding 0.5 parts, which does not improve the flame retardant performance, but reduces the transparency. As can be seen from examples 2 and 15, the clarity of the examples using poly (1, 4-diisopropylbenzene) (n is 3 to 6) is better.
Claims (17)
1. The flame-retardant polyolefin composition is characterized by comprising the following components in parts by weight:
the flame-retardant synergist is selected from a compound (II),
the compound (II) has the general formula
Wherein R5 is any one of C1-12 alkyl, C1-12 alkoxy, C6-12 aryl or C6-12 aryloxy, and n is 2-20;
the average particle diameter of the tri (2, 3-dibromopropyl) isocyanurate is 1-10 mu m, and the average particle diameter of the phosphorus flame retardant is 1-10 mu m.
2. The flame retardant polyolefin composition according to claim 1, comprising the following components in parts by weight:
the flame-retardant synergist is selected from a compound (II),
the compound (II) has the general formula
Wherein R5 is any one of C1-12 alkyl, C1-12 alkoxy, C6-12 aryl or C6-12 aryloxy, and n is 2-20;
the average particle diameter of the tri (2, 3-dibromopropyl) isocyanurate is 1-10 mu m, and the average particle diameter of the phosphorus flame retardant is 1-10 mu m.
3. The flame retardant polyolefin composition according to claim 2, comprising the following components in parts by weight:
the flame-retardant synergist is selected from a compound (II),
the compound (II) has the general formula
Wherein R5 is any one of C1-12 alkyl, C1-12 alkoxy, C6-12 aryl or C6-12 aryloxy, and n is 2-20;
the average particle diameter of the tri (2, 3-dibromopropyl) isocyanurate is 1-10 mu m, and the average particle diameter of the phosphorus flame retardant is 1-10 mu m.
4. A flame retardant polyolefin composition according to any of claims 1-3 wherein the tris (2, 3-dibromopropyl) isocyanurate has an average particle size of from 1 to 5 μm.
5. A flame retardant polyolefin composition according to any of claims 1-3 wherein the phosphorus based flame retardant is selected from at least one of hypophosphite salts, phosphate esters, polyphosphate salts.
6. The flame retardant polyolefin composition according to claim 5, wherein the phosphorus-based flame retardant is at least one selected from the group consisting of hypophosphite and phosphate.
7. Flame retardant polyolefin composition according to claim 5 wherein the hypophosphite salt is selected from at least one of aluminium hypophosphite, calcium hypophosphite, aluminium dimethyl hypophosphite, aluminium diethyl hypophosphite, aluminium methyl ethyl hypophosphite; the phosphate is selected from at least one of triphenyl phosphate, resorcinol bis (diphenyl phosphate), bisphenol A-bis (diphenyl phosphate) and oligomeric aryl phosphate; the polyphosphate is selected from at least one of ammonium polyphosphate, melamine phosphate, melamine pyrophosphate and melamine polyphosphate.
8. A flame retardant polyolefin composition according to any of claims 1-3 wherein the phosphorus based flame retardant has an average particle size of 1-5 μm.
9. The flame retardant polyolefin composition according to any of claims 1-3 wherein R5 is a C1-12 alkyl group.
10. The flame retardant polyolefin composition of claim 9 wherein R5 is C1-4 alkyl.
11. A flame retardant polyolefin composition according to any of claims 1 to 3 wherein n is from 2 to 10.
12. The flame retardant polyolefin composition according to claim 11 wherein n is 3 to 6.
13. The flame retardant polyolefin composition according to any one of claims 1 to 3, wherein the polyolefin resin is at least one selected from the group consisting of polyethylene resins and polypropylene resins.
14. The flame retardant polyolefin composition according to any of claims 1 to 3, further comprising 0 to 1 part by weight of an antioxidant, 0 to 1 part by weight of a processing aid; the antioxidant is selected from at least one of phenols, amines, phosphites, semi-hindered phenols, calixarenes and dilauryl thiodipropionate; the processing aid is at least one of low molecular weight lipid, metal soap, stearic acid composite ester and amide.
15. The flame retardant polyolefin composition according to any one of claims 1-14, wherein the flame retardant polyolefin composition has a surface gloss of 74 degrees or more, a light transmittance of 69% or more and a haze of 91% or less, the surface gloss is determined by GB 8807-.
16. The flame retardant polyolefin composition according to any one of claims 2-14, wherein the flame retardant polyolefin composition has a surface gloss of 79 ℃ or more, a light transmittance of 74% or more and a haze of 86% or less, the surface gloss is determined by GB 8807-.
17. A process for the preparation of a flame retardant polyolefin composition according to any of claims 1 to 16, characterized in that it comprises the following steps:
A) weighing polyolefin resin, tris (2, 3-dibromopropyl) isocyanurate, a phosphorus flame retardant and a flame retardant synergist in proportion, and uniformly mixing the materials by a high-speed mixer;
B) and melting, extruding, granulating and drying at 180-200 ℃ by a double-screw extruder to obtain the flame-retardant polyolefin composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810635059.6A CN108976593B (en) | 2018-06-20 | 2018-06-20 | Flame-retardant polyolefin composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810635059.6A CN108976593B (en) | 2018-06-20 | 2018-06-20 | Flame-retardant polyolefin composition and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108976593A CN108976593A (en) | 2018-12-11 |
| CN108976593B true CN108976593B (en) | 2020-11-03 |
Family
ID=64541447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810635059.6A Active CN108976593B (en) | 2018-06-20 | 2018-06-20 | Flame-retardant polyolefin composition and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108976593B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112321942B (en) * | 2020-10-16 | 2022-12-09 | 广东聚石化学股份有限公司 | Low-gloss halogen-free flame-retardant alloy material and preparation method thereof |
| CN115322491B (en) * | 2022-08-26 | 2023-05-16 | 金发科技股份有限公司 | Polypropylene composition and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004041919A2 (en) * | 2002-11-04 | 2004-05-21 | Ciba Specialty Chemicals Holding Inc. | Flame retardant compositions |
| JP2016501963A (en) * | 2012-12-20 | 2016-01-21 | ポリアド サービシズ エルエルシー | Flame retardant polymer composition |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4395840B2 (en) * | 2004-09-01 | 2010-01-13 | 第一工業製薬株式会社 | Brominated flame retardant composition for plastics |
| CN102924752B (en) * | 2012-10-26 | 2014-07-02 | 清远市普塞呋磷化学有限公司 | Composition of fire retardant capable of enabling flame-retardant level of polypropylene to reach V2-level |
| CN103073744B (en) * | 2013-01-28 | 2014-12-03 | 武汉理工大学 | Phosphorus, nitrogen and bromine compound system fire retardant and preparation method thereof |
| CN104004270A (en) * | 2014-06-17 | 2014-08-27 | 青岛职业技术学院 | Low-halogen polypropylene flame-resistant materials and preparing method thereof |
-
2018
- 2018-06-20 CN CN201810635059.6A patent/CN108976593B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004041919A2 (en) * | 2002-11-04 | 2004-05-21 | Ciba Specialty Chemicals Holding Inc. | Flame retardant compositions |
| JP2016501963A (en) * | 2012-12-20 | 2016-01-21 | ポリアド サービシズ エルエルシー | Flame retardant polymer composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108976593A (en) | 2018-12-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109135046B (en) | Flame-retardant polyolefin composition and preparation method thereof | |
| CN109135048B (en) | Flame-retardant polyolefin composition and preparation method thereof | |
| CN108976595B (en) | Flame-retardant polyolefin composition and preparation method thereof | |
| CN112409693B (en) | Halogen-free flame retardant with good flame retardance and processability and flame-retardant resin composition | |
| CN109233101B (en) | Heat-resistant flame-retardant polypropylene composition and preparation method thereof | |
| US9856420B2 (en) | Polyolefin-based flame retardant resin composition and molded product | |
| KR101205126B1 (en) | flame retardant polymeric compositions | |
| CN111333960A (en) | Antimony-free flame-retardant polypropylene composition and preparation method thereof | |
| CN109206829B (en) | High-yellowing-resistance precipitation-resistance halogen-free flame-retardant thermoplastic elastomer composition and preparation method thereof | |
| CN108976593B (en) | Flame-retardant polyolefin composition and preparation method thereof | |
| KR20010058527A (en) | Flame retardant polypropylene resin composition | |
| CN110591350A (en) | Smoke-inhibiting polyamide composition and preparation method thereof | |
| KR101697814B1 (en) | Polypropylene flame retardant resin composition and extrusion tubing molded product | |
| EP1646683A1 (en) | Fire-retarded polycarbonate resin composition | |
| CN111032829A (en) | Composition and flame-retardant resin composition | |
| CN112080074B (en) | Flame-retardant polypropylene composition and preparation method and application thereof | |
| CN109749334A (en) | A kind of halogen-free flame-retardant thermoplastic elastomer and its preparation method and application of the anti-UV of xenon lamp | |
| CN108976594B (en) | Flame-retardant polyolefin composition and preparation method thereof | |
| CN112739767B (en) | Flame retardant polypropylene composition | |
| CN103476865A (en) | Flame-retardant thermoplastic molding composition | |
| KR101613768B1 (en) | Poly(arylene ether) resin composition and covering material produced therefrom | |
| CN112679826A (en) | Flame-retardant polyethylene composition and preparation method thereof | |
| KR101703392B1 (en) | Polyolefin flame retardant resin composition and molded product | |
| CN106957520B (en) | Halogen-free fire-retardant polyphenyl ether composition and product prepared therefrom | |
| CN112646276A (en) | Flame-retardant polypropylene composition and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yang Youqiang Inventor after: Jian Siqiang Inventor after: Li Cong Inventor after: Wu Jun Inventor after: Huang Xianbo Inventor after: Ye Nanbiao Inventor after: Jiang Xiangxin Inventor after: Yang Xiaoyun Inventor after: Lu Zhanquan Inventor after: Lu Xiang Inventor after: Wang Yanan Inventor after: Yin Chaoqing Inventor before: Zhao Wangyang Inventor before: Huang Xianbo Inventor before: Ye Nanbiao Inventor before: Lu Zhanquan Inventor before: Wu Jun Inventor before: Liu Lewen Inventor before: Yang Xiaoyun |