CN108976417A - A kind of covalent organic polymer of triazine ring, electrode material and its preparation method and application - Google Patents
A kind of covalent organic polymer of triazine ring, electrode material and its preparation method and application Download PDFInfo
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- CN108976417A CN108976417A CN201810571107.XA CN201810571107A CN108976417A CN 108976417 A CN108976417 A CN 108976417A CN 201810571107 A CN201810571107 A CN 201810571107A CN 108976417 A CN108976417 A CN 108976417A
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- Prior art keywords
- organic polymer
- covalent organic
- triazine ring
- preparation
- electrode material
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- 229920000620 organic polymer Polymers 0.000 title claims abstract description 78
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 239000007772 electrode material Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 37
- 238000002242 deionisation method Methods 0.000 claims abstract description 42
- 238000001179 sorption measurement Methods 0.000 claims abstract description 38
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 38
- 239000012528 membrane Substances 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000007787 solid Substances 0.000 claims abstract description 19
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 19
- 239000011592 zinc chloride Substances 0.000 claims abstract description 19
- 230000008569 process Effects 0.000 claims abstract description 15
- 150000002825 nitriles Chemical class 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 11
- BHXFKXOIODIUJO-UHFFFAOYSA-N benzene-1,4-dicarbonitrile Chemical compound N#CC1=CC=C(C#N)C=C1 BHXFKXOIODIUJO-UHFFFAOYSA-N 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 9
- 238000010521 absorption reaction Methods 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 8
- 239000006258 conductive agent Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 5
- 230000005611 electricity Effects 0.000 claims description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 2
- 125000004193 piperazinyl group Chemical group 0.000 claims description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 2
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical group C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 239000002245 particle Substances 0.000 abstract description 8
- 238000010612 desalination reaction Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 3
- 230000010148 water-pollination Effects 0.000 abstract description 3
- 125000005842 heteroatom Chemical group 0.000 abstract description 2
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 description 18
- 150000003839 salts Chemical class 0.000 description 18
- 230000008929 regeneration Effects 0.000 description 12
- 238000011069 regeneration method Methods 0.000 description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 239000003990 capacitor Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000003729 cation exchange resin Substances 0.000 description 7
- 238000009938 salting Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 238000013019 agitation Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000007773 negative electrode material Substances 0.000 description 6
- 230000002572 peristaltic effect Effects 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000000741 silica gel Substances 0.000 description 6
- 229910002027 silica gel Inorganic materials 0.000 description 6
- 229960001866 silicon dioxide Drugs 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 5
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical group CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 5
- 239000003957 anion exchange resin Substances 0.000 description 5
- 229940113088 dimethylacetamide Drugs 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000007774 positive electrode material Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 239000012267 brine Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000012544 monitoring process Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- -1 aeroge Chemical compound 0.000 description 2
- 239000003708 ampul Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000011033 desalting Methods 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 238000002484 cyclic voltammetry Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- XQZYPMVTSDWCCE-UHFFFAOYSA-N phthalonitrile Chemical compound N#CC1=CC=CC=C1C#N XQZYPMVTSDWCCE-UHFFFAOYSA-N 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0638—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with at least three nitrogen atoms in the ring
- C08G73/0644—Poly(1,3,5)triazines
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4691—Capacitive deionisation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46133—Electrodes characterised by the material
Abstract
The present invention relates to a kind of covalent organic polymers of triazine ring, electrode material and its preparation method and application.The preparation method of the covalent organic polymer of triazine ring, includes the following steps: S1: nitrile monomer and zinc chloride being mixed, 40 ~ 80h is reacted under zinc chloride molten condition and obtains black solid；The molar ratio of the nitrile monomer and zinc chloride is 1:1 ~ 15；S2: black solid obtained by S1 is dissolved, filter, is drying to obtain the covalent organic polymer of the triazine ring.The preparation method simple process and low cost of the covalent organic polymer of triazine ring provided by the invention, is easy to large-scale production, has very big application space in membrane capacitance deionization desalination field.The covalent organic polymer of the triazine ring being prepared, because the hetero atom effect and micropore effect of N doping have good electro adsorption capacity, with excellent hydrophily, chemical stability, thermal stability and electronics conduction efficiency, adsorption process generates electric double layer, and large capacity adsorbs charged particle.
Description
Technical field
The invention belongs to capacitive deionization electrode material fields, and in particular to a kind of covalent organic polymer of triazine ring, electricity
Pole material and its preparation method and application.
Background technique
Membrane capacitance deionization technology is as a kind of emerging water treatment technology, compared to traditional water treatment technology such as reverse osmosis
Thoroughly, electrodialysis, distillation etc., since it is simple, safety, low energy consumption and the advantages such as without secondary pollution cause more and more passes
Note.By impressed DC voltage, charged particle in fluid is made to be adsorbed to the electrode of oppositely charged under the action of electric field force
On material, and electrode surface formed electric double layer, and electrode surface covering anion-cation exchange resin film effectively reduce altogether from
Interference of the son desorption to capacitive deionization desalting technology, improves Electro Sorb efficiency.After reaching adsorption saturation, pass through reversed polarity direct current
Voltage realizes electrode regeneration rapidly and efficiently.The core of capacitive deionization technology is the selection and preparation of electrode material, compares
Traditional carbon-based material, such as active carbon, aeroge, carbon nanotube, graphene are played, the covalent organic polymer of triazine ring has excellent
Different pore structure and good conductivity, there is very big application potential in Electro Sorb field.
Currently, the method and process of the synthesis covalent organic polymer of triazine ring is cumbersome, need in glove box inert gas shielding
Lower mixed raw material, be placed in ampoule bottle vacuumized with high temperature tube sealing, if residual moisture also has ampoule bottle in raw material
The danger burst.This process cost is very high, is unfavorable for production application.
Therefore, a kind of preparation method of simple process is developed to obtain that there is excellent pore structure and good conductivity
The covalent organic polymer of triazine ring have important research significance and application value.
Summary of the invention
It is an object of the invention to overcome, the preparation process of the covalent organic polymer of triazine ring in the prior art is cumbersome, cost
High defect and deficiency provides a kind of preparation method of covalent organic polymer of triazine ring.Preparation method provided by the invention
The covalent organic polymer of triazine ring can successfully be prepared, simple process and low cost is easy to large-scale production, in membrane capacitance
There is very big application space in deionization desalination field.And because the covalent Organic Polymer Chemistry stability of triazine ring is good, in Industry Waste
Equally there is good application potential in the processing disposition of water.The covalent organic polymer of the triazine ring being prepared has excellent
Pore structure and good conductivity, surface wetting properties are good, and circular regeneration effect is good.
Another object of the present invention is to provide the covalent organic polymers of triazine ring that above-mentioned preparation method is prepared.
Another object of the present invention is to a kind of covalent organic polymer films capacitive deionization adsorption electrode materials of triazine ring.
Another object of the present invention is to provide the preparation methods of above-mentioned electrode material.
Another object of the present invention is to provide application of the above-mentioned electrode material in water process.
For achieving the above object, the present invention adopts the following technical scheme:
A kind of preparation method of the covalent organic polymer of triazine ring, includes the following steps:
S1: nitrile monomer and zinc chloride are mixed under infrared light photograph, 40 ~ 80h is reacted under zinc chloride molten condition and obtains black
Solid；The molar ratio of the nitrile monomer and zinc chloride is 1:1 ~ 15；
S2: black solid obtained by S1 is dissolved, filter, is drying to obtain the covalent organic polymer of the triazine ring.
The covalent organic polymer of triazine ring using nitrile monomer as raw material, based on cyano dynamic reversible trimerization cyclisation construct and
At, zinc chloride is not only used as catalyst, but also as solvent, reacts at high temperature a couple of days, nitrile due to Lewis soda acid interact,
Sufficiently reaction forms the covalent organic polymer of triazine ring for a long time.The triazine ring that preparation method provided by the invention obtains covalently has
The functional group modification of machine polymer is controllable, with the fabulous electronics conduction efficiency of pi-conjugated system, inhales in gas absorption, selectivity
There is extremely wide application prospect in the fields such as attached, heterogeneous catalysis；And nitrogen content is high, effectively increases the hydrophily and electricity of material
The electroactive area of pole.
Preferably, the molar ratio of terephthalonitrile described in S1 and zinc chloride is 1:5.
Preferably, the nitrile monomer is terephthalonitrile, 1,3,5- benzene, three nitrile, 4,4 '-biphenyl dintrile or 2,6- pyridine two
One of formonitrile HCN etc..
Preferably, it is reacted at 400 ~ 500 DEG C in S1.
Preferably, the time reacted in S1 is 40h.
Preferably, the black solid is sequentially placed into stir in water, dilute hydrochloric acid solution and tetrahydrofuran in S2 and is impregnated, mistake
Filter.
Preferably, the soaking time is for 24 hours.
Preferably, the dilute hydrochloric acid mass concentration is 5%.
Preferably, dry under vacuum condition in S2.
Preferably, the temperature of the drying is 150 DEG C, and the time is for 24 hours.
The covalent organic polymer of triazine ring that above-mentioned preparation method obtains is claimed in the present invention.
A kind of covalent organic polymer films capacitive deionization adsorption electrode material of triazine ring, including above-mentioned triazine ring covalently have
Machine polymer, conductive agent and binder.
Preferably, the mass ratio of the covalent organic polymer of the triazine ring, conductive agent and binder is 1:0.08 ~ 0.2:
0.08~0.2。
It is further preferable that the mass ratio of the covalent organic polymer of the triazine ring, conductive agent and binder is 1:0.125:
1。
Preferably, the conductive agent is conductive black or acetylene black.
Preferably, the binder is Kynoar, polytetrafluoroethylene (PTFE) or polyvinyl alcohol.
The preparation method of above-mentioned electrode material, including following preparation step: by the covalent organic polymer of triazine ring, conductive agent
It is mixed with binder, dispersion solvent is added, be dispersed with stirring uniformly, be drying to obtain the electrode material.
Preferably, the dispersion solvent is dimethyl acetamide or dimethylformamide.
Preferably, the stirring is magnetic agitation, and the speed of the magnetic agitation is 300 rpm, and the time is for 24 hours.
Preferably, the process of the drying are as follows: coated in titanium net, be dried in vacuo.
Preferably, the titanium net is 3 × 2 cm specifications, 100 mesh twill weave square hole nets.
Preferably, the vacuum drying temperature is 40 DEG C, time 3h.
Preferably, the mass ratio of the dispersion solvent and the covalent organic polymer of the triazine ring is 5 ~ 20ml:1g.
Application of the above-mentioned electrode material in water process is also within the scope of the present invention.
Preferably, the electrode material is preparing the application in membrane capacitance deionization adsorption electrode water treatment facilities.
Electrode material provided by the invention has very big application space in membrane capacitance deionization desalination field.In addition, because of three
The covalent Organic Polymer Chemistry stability of piperazine ring is good, equally has good application potential in the processing disposition of industrial wastewater.
A kind of membrane capacitance deionization adsorption electrode device is also claimed in the present invention, including by above-mentioned electrode material as just
The anode and cathode that pole electrode material and negative electrode material obtain.
Anode and cathode can be obtained using electrode material provided by the invention as positive electrode and negative electrode material, can be applied to
In various types of films capacitive deionization adsorption electrode device in the prior art.
Membrane capacitance deionization adsorption electrode device provided by the invention has high adsorption capacity and power of regeneration etc.；It is logical
It crosses conductivity meter analysis and learns that the absorption ration for the membrane capacitance deionizer equipped out is up to 18.29 mg/g, in 1 M chlorination
Capacitor is 103.07 ~ 129.61 F/g when 1 mV/s of scanning speed in sodium electrolyte, and the electrode passes through multiple circular regeneration still
There is very high adsorption capacity.
Preferably, the surface of the anode and cathode has been covered each by anion-exchange resin membrane and cation exchange resin
Film.
Electrode surface covering anion-cation exchange resin film can effectively reduce coion desorption to capacitive deionization desalination skill
Efficient desalination and rapid regeneration are realized in the interference of art.
Preferably, the membrane capacitance deionization adsorption electrode device further includes the built-in silicagel pad using organic glass as supporting plate
Piece, two panels electrodes face are placed in one, external direct current power supply, which connects peristaltic pump and conductivity meter, the membrane capacitance
It circulates in deionization adsorption electrode device through salt water.
It is further preferable that 5 × 5 cm of length and width of the membrane capacitance deionization adsorption electrode device；The built-in silica gel pad
Area be 3 × 3cm；The pipe that the peristaltic pump is configured is 25#, and flowing velocity is 10 rpm, and sink water is 80mL；Salt water
Concentration is 50 ~ 500 mg/L；It is the V of 0.8 V ~ 1.4 that the anode and cathode, which are just connecing impressed DC voltage,.
Using charged particle in device absorption salt water.It, can be anti-by external DC voltage positive and negative anodes when adsorption saturation
It connects, to realize electrode regeneration.
Preferably, the reversal connection impressed DC voltage is the V of 1.2 V ~ 1.4.
Compared with prior art, the invention has the following beneficial effects:
The preparation method simple process and low cost of the covalent organic polymer of triazine ring provided by the invention, is easy to scale metaplasia
It produces, has very big application space in membrane capacitance deionization desalination field.The covalent organic polymer of the triazine ring being prepared, because of nitrogen
The hetero atom effect and micropore effect of doping have good electro adsorption capacity, have excellent hydrophily, chemical stability, heat
Stability and electronics conduction efficiency, adsorption process generate electric double layer, large capacity adsorb charged particle, electrode surface cover yin-yang from
Sub-exchange resin film effectively reduces coion and interference to capacitive deionization desalting technology is desorbed, and realizes efficient desalination and quickly
Regeneration.
Detailed description of the invention
Fig. 1 is the covalent organic polymer scanning electron microscope (SEM) photograph of triazine ring prepared by embodiment 1；
It is de- that Fig. 2 is that the covalent organic polymer of triazine ring for preparing of embodiment 1 capacitive deionization in about 500 mg/L salting liquids is inhaled
Attached curve graph；
Fig. 3 be embodiment 1 prepare the covalent organic polymer of triazine ring under the scanning speed of 1mV/s cyclic voltammetry curve figure；
It is de- that Fig. 4 is that the covalent organic polymer of triazine ring for preparing of embodiment 1 capacitive deionization in about 500 mg/L salting liquids is inhaled
Attached regeneration curve graph；
It is de- that Fig. 5 is that the covalent organic polymer of triazine ring for preparing of embodiment 2 capacitive deionization in about 200 mg/L salting liquids is inhaled
Attached curve graph.
Fig. 6 is the covalent organic polymer XRD spectra of triazine ring prepared by embodiment 5.
Fig. 7 is fourier infrared linear light spectrogram under the conditions of differential responses in each embodiment.
Specific embodiment
Below with reference to embodiment, the present invention is further explained.These embodiments are merely to illustrate the present invention rather than limitation
The scope of the present invention.Test method without specific conditions in lower example embodiment usually according to this field normal condition or is pressed
The condition suggested according to manufacturer；Used raw material, reagent etc., unless otherwise specified, being can be from the business such as conventional market
The raw materials and reagents that approach obtains.The variation for any unsubstantiality that those skilled in the art is done on the basis of the present invention
And replacement belongs to scope of the present invention.
Embodiment 1
A kind of preparation method of the covalent organic polymer of triazine ring, includes the following steps:
(1) it weighs to 1g terephthalonitrile (7.81mmol) in crucible, weighs 5.32 g zinc chloride under infrared light photograph
(39.03mmol) is mixed with terephthalonitrile, covers crucible cover, is placed in Muffle furnace, and reaction 40 hours is carried out at 500 DEG C.
(2) reaction terminates to be cooled to room temperature, by gained black solid is sequentially placed into deionized water in crucible and dilute hydrochloric acid is molten
Stirring is impregnated 24 hours in liquid and tetrahydrofuran, is dried in vacuo 24 hours i.e. for 150 DEG C of obtained solid powder after separation of solid and liquid
Obtain the covalent organic polymer of triazine ring.
The covalent organic polymer of the triazine ring that the present embodiment obtains can be used as electrode material.The preparation process of the electrode material
It is as follows:
(3) by the covalent organic polymer of triazine ring, conductive black and the Kynoar that are obtained after step (2) processing by 8:1:
1 mixing, is added appropriate dimethyl acetamide as dispersion solvent, magnetic agitation is uniformly dispersed.
(4) the resulting electrode material even application of step (3) is dried in vacuo in titanium net.
Electrode material provided in this embodiment can be used as positive electrode and negative electrode material obtains anode and cathode, be applied to film
In capacitive deionization adsorption electrode device.It can be assembled by the following method and obtain a kind of membrane capacitance deionization adsorption electrode device,
And salting liquid is handled.
(5) by step (4) resulting electrode assembling to making by oneself in capacitor deionizing instrument, using organic glass as built in supporting plate
Hollow silica gel gasket, positive and negative electrode electrode surface are covered each by anion and cation exchange resin film, about 500 mg/L in 80 ml sinks
Salt water enters in capacitor deionizing instrument by peristaltic pump, salt water bottom in and top out, makes salt under the effect of external dc 1.2V voltage
Charged particle is adsorbed in the covalent organic polymer of triazine ring in water, and effluent recycling to crude brine sink, sink is interior to dispose conductivity
The variation of its concentration of instrument real-time monitoring.
(6) when adsorption saturation, external 1.4 V voltage positive and negative anodes of direct current are reversely connected, to realize electrode regeneration.
Fig. 2 is the capacitive deionization adsorption desorption effect picture of made device, as shown in Figure 2, the covalent organic polymer of triazine ring
Absorption ration is 18.29mg/g at 1.2 V.
Fig. 3 is electricity of the prepared covalent organic polymer of triazine ring under 1M sodium chloride electrolysis matter solution three-electrode system
Chemical property figure, the rectangle reflect its good electric double layer performance, and in 1 mV/s, specific capacitance is 103.07 F/g.
Embodiment 2
A kind of preparation method of the covalent organic polymer films of triazine ring, includes the following steps:
(1) 1g terephthalonitrile is weighed in crucible, is weighed 5.32g zinc chloride under infrared light photograph and is mixed with terephthalonitrile, covers
Crucible cover is placed in Muffle furnace, and reaction 60 hours is carried out at 500 DEG C.
(2) reaction terminates to be cooled to room temperature, by gained black solid is sequentially placed into deionized water in crucible and dilute hydrochloric acid is molten
Stirring is impregnated 24 hours in liquid and tetrahydrofuran, is dried in vacuo 24 hours i.e. for 150 DEG C of obtained solid powder after separation of solid and liquid
Obtain the covalent organic polymer of triazine ring.
The covalent organic polymer of the triazine ring that the present embodiment obtains can be used as electrode material.The preparation process of the electrode material
It is as follows:
(3) by the covalent organic polymer of triazine ring, conductive black and the Kynoar that are obtained after step (2) processing by 8:1:
1 mixing, is added appropriate dimethyl acetamide as dispersion solvent, magnetic agitation is uniformly dispersed.
(4) the resulting electrode material even application of step (3) is dried in vacuo in titanium net.
Electrode material provided in this embodiment can be used as positive electrode and negative electrode material obtains anode and cathode, be applied to film
In capacitive deionization adsorption electrode device.It can be assembled by the following method and obtain a kind of membrane capacitance deionization adsorption electrode device,
And salting liquid is handled.
(5) by step (4) resulting electrode assembling to making by oneself in capacitor deionizing instrument, using organic glass as built in supporting plate
Hollow silica gel gasket, positive and negative electrode electrode surface are covered each by anion and cation exchange resin film, about 200 mg/L in 80 ml sinks
Salt water enters in capacitor deionizing instrument by peristaltic pump, salt water bottom in and top out, makes salt under the effect of 1.2 V voltage of external dc
Charged particle is adsorbed in the covalent organic polymer of triazine ring in water, and effluent recycling to crude brine sink, sink is interior to dispose conductivity
The variation of its concentration of instrument real-time monitoring.
(6) when adsorption saturation, external 1.2 V voltage positive and negative anodes of direct current are reversely connected, to realize electrode regeneration.
Capacitive deionization process absorption ration is 11.58 mg/g.
Embodiment 3
A kind of preparation method of the covalent organic polymer films of triazine ring, includes the following steps:
(1) 1g terephthalonitrile is weighed in crucible, is weighed 5.32g zinc chloride under infrared light photograph and is mixed with terephthalonitrile, covers
Crucible cover is placed in Muffle furnace, and reaction 40 hours is carried out at 400 DEG C.
(2) reaction terminates to be cooled to room temperature, by gained black solid is sequentially placed into deionized water in crucible and dilute hydrochloric acid is molten
Stirring is impregnated 24 hours in liquid and tetrahydrofuran, is dried in vacuo 24 hours i.e. for 150 DEG C of obtained solid powder after separation of solid and liquid
Obtain the covalent organic polymer of triazine ring.
The covalent organic polymer of the triazine ring that the present embodiment obtains can be used as electrode material.The preparation process of the electrode material
It is as follows:
(3) by the covalent organic polymer of triazine ring, conductive black and the Kynoar that are obtained after step (2) processing by 8:1:
1 mixing, is added appropriate dimethyl acetamide as dispersion solvent, magnetic agitation is uniformly dispersed.
(4) the resulting electrode material even application of step (3) is dried in vacuo in titanium net.
Electrode material provided in this embodiment can be used as positive electrode and negative electrode material obtains anode and cathode, be applied to film
In capacitive deionization adsorption electrode device.It can be assembled by the following method and obtain a kind of membrane capacitance deionization adsorption electrode device,
And salting liquid is handled.
(5) by step (4) resulting electrode assembling to making by oneself in capacitor deionizing instrument, using organic glass as built in supporting plate
Hollow silica gel gasket, positive and negative electrode electrode surface are covered each by anion and cation exchange resin film, about 500 mg/L in 80 ml sinks
Salt water enters in capacitor deionizing instrument by peristaltic pump, salt water bottom in and top out, makes salt under the effect of 1.2 V voltage of external dc
Charged particle is adsorbed in the covalent organic polymer of triazine ring in water, and effluent recycling to crude brine sink, sink is interior to dispose conductivity
The variation of its concentration of instrument real-time monitoring.
(6) when adsorption saturation, external 1.2 V voltage positive and negative anodes of direct current are reversely connected, to realize electrode regeneration.
Capacitive deionization process reached adsorption saturation at 20 minutes, and absorption ration is 8.5 mg/g.
Embodiment 4
A kind of preparation method of the covalent organic polymer of triazine ring, select 1g(5.12mmol) 1,3,5- benzene three nitrile replace embodiment
Terephthalonitrile and zinc chloride and 1 in 1,3,5- benzene, three nitrile reaction time be 80h outside, remaining condition with embodiment 1 one
It causes, obtains a kind of covalent organic polymer of triazine ring.
In addition, can be according to the method or item in embodiment 1 according to the covalent organic polymer of triazine ring provided in this embodiment
Part obtains electrode material and membrane capacitance deionization adsorption electrode device, and molten to salt using membrane capacitance deionization adsorption electrode device
Liquid is handled.
Embodiment 5
A kind of preparation method of the covalent organic polymer of triazine ring, except selecting 1.06g(7.81mmol) in addition to zinc chloride, remaining condition
It is consistent with embodiment, obtain a kind of covalent organic polymer of triazine ring (such as Fig. 5).
In addition, can be according to the method or item in embodiment 1 according to the covalent organic polymer of triazine ring provided in this embodiment
Part obtains electrode material and membrane capacitance deionization adsorption electrode device, and molten to salt using membrane capacitance deionization adsorption electrode device
Liquid is handled.
Embodiment 6
A kind of preparation method of the covalent organic polymer of triazine ring, except selecting 15.90g(117.15mmol) in addition to zinc chloride, remaining
Condition is consistent with embodiment, obtains a kind of covalent organic polymer of triazine ring.
In addition, can be according to the method or item in embodiment 1 according to the covalent organic polymer of triazine ring provided in this embodiment
Part obtains electrode material and membrane capacitance deionization adsorption electrode device, and molten to salt using membrane capacitance deionization adsorption electrode device
Liquid is handled.
Comparative example 1
A kind of preparation method of the covalent organic polymer films of triazine ring, includes the following steps:
(1) it weighs to 1g benzene dinitrile in crucible, weighs 5.32 g zinc chloride under infrared light photograph and mixed with terephthalonitrile, covered
Crucible cover is placed in Muffle furnace, and reaction 20 hours is carried out at 400 DEG C.
(2) reaction terminates to be cooled to room temperature, by gained black solid is sequentially placed into deionized water in crucible and dilute hydrochloric acid is molten
Stirring is impregnated 24 hours in liquid and tetrahydrofuran, is dried in vacuo 24 hours i.e. for 150 DEG C of obtained solid powder after separation of solid and liquid
Obtain the covalent organic polymer of triazine ring.
The covalent organic polymer of the triazine ring that this reference examples obtains can be used as electrode material.The preparation process of the electrode material
It is as follows:
(3) by the covalent organic polymer of triazine ring, conductive black and the Kynoar that are obtained after step (2) processing by 8:1:
1 mixing, is added appropriate dimethyl acetamide as dispersion solvent, is uniformly dispersed within magnetic agitation 24 hours.
(4) the resulting electrode material even application of step (3) is dried in vacuo in titanium net.
The electrode material that this reference examples provides can be used as positive electrode and negative electrode material obtains anode and cathode, be applied to film
In capacitive deionization adsorption electrode device.It can be assembled by the following method and obtain a kind of membrane capacitance deionization adsorption electrode device,
And salting liquid is handled.
(5) by step (4) resulting electrode assembling to making by oneself in capacitor deionizing instrument, using organic glass as built in supporting plate
Hollow silica gel gasket, positive and negative electrode electrode surface are covered each by anion and cation exchange resin film, about 500 mg/L in 80 ml sinks
Salt water enters in capacitor deionizing instrument by peristaltic pump, salt water bottom in and top out, makes salt under the effect of 1.2 V voltage of external dc
Charged particle is adsorbed in the covalent organic polymer of triazine ring in water, and effluent recycling to crude brine sink, sink is interior to dispose conductivity
The variation of its concentration of instrument real-time monitoring.
(6) when adsorption saturation, external 1.4 V voltage positive and negative anodes of direct current are reversely connected, to realize electrode regeneration.
Capacitive deionization process has been rapidly achieved adsorption saturation in 20 minutes, and absorption ration is 4.40 mg/g.1
Its specific capacitance is 111.82 F/g under the scanning speed of mV/s.
Claims (10)
1. a kind of preparation method of the covalent organic polymer of triazine ring, which comprises the steps of:
S1: nitrile monomer and zinc chloride are mixed under infrared light photograph, 40 ~ 80h is reacted under zinc chloride molten condition and obtains black
Solid；The molar ratio of the nitrile monomer and zinc chloride is 1:1 ~ 15；
S2: black solid obtained by S1 is dissolved, filter, is drying to obtain the covalent organic polymer of the triazine ring.
2. the preparation method of the covalent organic polymer of triazine ring according to claim 1, which is characterized in that benzene described in S1
The molar ratio of dintrile and zinc chloride is 1:5.
3. the preparation method of the covalent organic polymer of triazine ring according to claim 1, which is characterized in that the nitrile monomer
For terephthalonitrile, three nitrile of 1,3,5- benzene, 4,4 '-biphenyl dintrile or 2,6- pyridine dimethoxy nitrile.
4. the preparation method of the covalent organic polymer of triazine ring according to claim 1, which is characterized in that in S1 in 400 ~
It is reacted at 700 DEG C.
5. the covalent organic polymer of triazine ring that any preparation method of claim 1 ~ 4 obtains.
6. a kind of covalent organic polymer films capacitive deionization adsorption electrode material of triazine ring, which is characterized in that wanted including right
Ask the covalent organic polymer of 5 triazine rings, conductive agent and binder.
7. electrode material according to claim 6, which is characterized in that the covalent organic polymer of the triazine ring, conductive agent and
The mass ratio of binder is 1:0.08 ~ 0.2:0.08 ~ 0.2.
8. the preparation method of any electrode material of claim 6 ~ 7, which is characterized in that including following preparation step: by three
The covalent organic polymer of piperazine ring, conductive agent and binder mixing, are added dispersion solvent, are dispersed with stirring uniformly, are drying to obtain described
Electrode material.
9. application of any electrode material of claim 6 ~ 7 in water process.
10. applying according to claim 9, which is characterized in that the electrode material is preparing membrane capacitance deionization absorption electricity
Application in the water treatment facilities of pole.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109517187A (en) * | 2018-12-12 | 2019-03-26 | 中国科学院兰州化学物理研究所 | A kind of preparation method of covalent triazine framework polymer under open system |
| CN109867781A (en) * | 2019-01-29 | 2019-06-11 | 江汉大学 | A kind of porous conjugated polymer material and preparation method thereof |
| CN110479379A (en) * | 2019-08-28 | 2019-11-22 | 浙江工业大学 | A kind of covalent organic frame material catalyst and its preparation method and application based on load Ru nano particle |
| CN111115770A (en) * | 2019-12-31 | 2020-05-08 | 天津万峰环保科技有限公司 | Electrode material for capacitive deionization and capacitive deionization device |
| CN112164789A (en) * | 2019-11-04 | 2021-01-01 | 多氟多化工股份有限公司 | Application of triazine-carbazole polymer in organic electrode material |
| CN112657472A (en) * | 2020-12-21 | 2021-04-16 | 吉林师范大学 | Ionic covalent triazine skeleton polymer material and preparation method and application thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101765620A (en) * | 2007-06-15 | 2010-06-30 | 马克斯-普郎克科学促进学会 | Method of preparing organic porous solids and solids obtainable by this method |
| CN105295040A (en) * | 2015-11-05 | 2016-02-03 | 大连理工大学 | Porous polymer material used for preparing supercapacitor electrode and preparation method thereof |
| CN106084217A (en) * | 2016-05-27 | 2016-11-09 | 山西师范大学 | A kind of triazine radical porous polymer material, Ag/ triazine radical porous polymer catalyst and be the application of acetylenic acid by carbon dioxide conversion |
-
2018
- 2018-06-05 CN CN201810571107.XA patent/CN108976417B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101765620A (en) * | 2007-06-15 | 2010-06-30 | 马克斯-普郎克科学促进学会 | Method of preparing organic porous solids and solids obtainable by this method |
| CN105295040A (en) * | 2015-11-05 | 2016-02-03 | 大连理工大学 | Porous polymer material used for preparing supercapacitor electrode and preparation method thereof |
| CN106084217A (en) * | 2016-05-27 | 2016-11-09 | 山西师范大学 | A kind of triazine radical porous polymer material, Ag/ triazine radical porous polymer catalyst and be the application of acetylenic acid by carbon dioxide conversion |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109517187A (en) * | 2018-12-12 | 2019-03-26 | 中国科学院兰州化学物理研究所 | A kind of preparation method of covalent triazine framework polymer under open system |
| CN109517187B (en) * | 2018-12-12 | 2020-12-01 | 中国科学院兰州化学物理研究所 | Preparation method of covalent triazine framework polymer under open system |
| CN109867781A (en) * | 2019-01-29 | 2019-06-11 | 江汉大学 | A kind of porous conjugated polymer material and preparation method thereof |
| CN110479379A (en) * | 2019-08-28 | 2019-11-22 | 浙江工业大学 | A kind of covalent organic frame material catalyst and its preparation method and application based on load Ru nano particle |
| CN110479379B (en) * | 2019-08-28 | 2022-07-22 | 浙江工业大学 | Covalent organic framework material catalyst based on loaded Ru nanoparticles and preparation method and application thereof |
| CN112164789A (en) * | 2019-11-04 | 2021-01-01 | 多氟多化工股份有限公司 | Application of triazine-carbazole polymer in organic electrode material |
| CN112164789B (en) * | 2019-11-04 | 2022-02-22 | 多氟多新材料股份有限公司 | Application of triazine-carbazole polymer in organic electrode material |
| CN111115770A (en) * | 2019-12-31 | 2020-05-08 | 天津万峰环保科技有限公司 | Electrode material for capacitive deionization and capacitive deionization device |
| CN112657472A (en) * | 2020-12-21 | 2021-04-16 | 吉林师范大学 | Ionic covalent triazine skeleton polymer material and preparation method and application thereof |
| CN112657472B (en) * | 2020-12-21 | 2024-02-13 | 吉林师范大学 | Ionic covalent triazine skeleton polymer material and preparation method and application thereof |
| CN114736370A (en) * | 2022-04-25 | 2022-07-12 | 吉林师范大学 | Fluorine-doped covalent triazine skeleton polymer and sulfur-containing compound thereof, and preparation method and application thereof |
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