A kind of reinforcing agent and application modified for acidity aggregate asphalt
Technical field
The present invention relates to pavement construction material technical fields, more particularly to a kind of acidity aggregate asphalt that is used for be modified
Reinforcing agent and application.
Background technique
The common building stone of asphalt concrete pavement has caustic lime rock and partial neutral basalt, these materials because its with
Pitch has preferable adhesiveness and is widely used.Since the very fast development speed of the finiteness and highway of natural resources makes
The high-quality situation for having reached that supply falls short of demand of gathering materials largely used is obtained, brings great pressure to the exploitation and supply gathered materials,
Basalt and limestone become more and more in short supply as the ideal coarse aggregate of bituminous concrete.However, acidity aggregate and pitch
Adhesiveness does not often reach requirement, using under the corrosion function of water, making through alternate load after the pavement forming of acidity aggregate
Pitch and mineral aggregate are detached from, until loosely falling grain, pit slot occur, lead to pavement destruction, and then influence communications and transportation.
Summary of the invention
The present invention provides a kind of reinforcing agents and application modified for acidity aggregate asphalt, solve existing skill
The problem of art.
Used technical solution is the present invention to solve above-mentioned technical problem:
A kind of reinforcing agent modified for acidity aggregate asphalt, including the modifier A and modifying agent being used cooperatively
B;The quality of modifier A is the 0.2%-2% of acidity aggregate asphalt mesostroma asphalt quality, and the quality of modifying agent B is
The 0.4%-1% of acidity aggregate asphalt gross mass;
The modifier A is silane coupling agent;Modifying agent B is bitumen solid powder.
The partial size of the modifying agent B bitumen solid powder is 300-600 mesh.
The silane coupling agent is KH550 or KH570.
The bitumen is the bitumen of asphaltenes and glial component.
Application of the reinforcing agent modified for acidity aggregate asphalt in acidity aggregate asphalt,
Including following operating procedure:
(1) it according to acidity aggregate asphalt total amount to be prepared and prepares acidity aggregate matrix used for asphalt mixture and drips
Green quality, determines the quality of modifier A and modifying agent B;Prepare matrix pitch, acidity aggregate, miberal powder, modifier A and modification
Agent B, it is spare;
(2) matrix pitch is heated to 140-160 DEG C, then the modifier A of step (1) is added in matrix pitch and is mixed
Time 20-60min is closed, modified pitch is obtained;
(3) modified pitch of step (2) is added in acidity aggregate by 160-200 DEG C of computer heating control acidity aggregate temperature,
Mix 90s obtains product 1;
(4) modifying agent B is added to together with miberal powder in the product 1 that step (3) obtains, in 150-170 DEG C of mix 90s,
Up to the molding acidity aggregate asphalt that can pave at 120-150 DEG C.
Beneficial effects of the present invention:
The reinforcing agent modified for acidity aggregate asphalt is relative to other common modifying agent, bulk composition
For bitumen, cost is more advantageous;It is asphalitine and glial component that bitumen, which selects 300-600 mesh, ingredient, with base
Matter bitumen compatibility is good, low to the quality requirement of matrix pitch;Wet-process modified pitch can effectively be avoided using dry mixed
Generally existing isolation, the problems such as stability is poor.
The asphalt modified compared to rock asphalt, mineral etc., the present invention using silane coupling agent to matrix pitch into
Row is modified, then mix acidity aggregate and modified pitch, then by bitumen and above-mentioned material mix by the way of dry method, this
Sample can fully play bitumen and the respective performance advantage of coupling agent, and forming properties are complementary, solve acidity aggregate not
The problem of asphalt aggregate can be used as.Silane coupling agent can make the acidity aggregates such as pitch and granite with chemical bond phase
Even, contain Si-OH in the asphalt component specially after admixture silane coupling agent, there are HO-Si, the two combination shapes for granite face
At Si-O-Si chemical bond;Contain a large amount of asphalitine component in bitumen, the high-temperature behavior of pitch can be improved.
The mix temperature of currently used asphalt reinforcing agent is higher, increases the cost of fuel consumption;Except this it
Outside, heat ageing reaction, the discharge of toxic gas and exhaust gas of pitch result in environmental pollution.This is used for the mixing of acidity aggregate pitch
Modified reinforcing agent is expected when being applied to laying of roadway, and mix temperature and forming temperature are reduced compared with ordinary hot mix asphalt
It tens degree, saves energy consumption, the effective degree of aging for weakening pitch, while the reduction of mix temperature can reduce poison gas
The discharge of body reduces the harm to human and environment to the greatest extent, has ideal social benefit, economic benefit and Environmental Effect
Benefit.
Specific embodiment
In order to clarify the technical characteristics of the invention, being explained in detail below by specific embodiment the present invention
It states.
Embodiment 1
A kind of reinforcing agent modified for above-mentioned acidity aggregate asphalt, including the modifier A being used cooperatively and changes
Property agent B;The quality of modifier A is the 0.2% of above-mentioned matrix pitch quality, and the quality of modifying agent B is the mixing of acidity aggregate pitch
Expect the 1% of gross mass;
Modifier A is Silane coupling agent KH550, and modifying agent B is the bitumen solid powder of 300 mesh.
The specific proportion such as the following table 1 of acidity aggregate asphalt suitable for road cutting optimal:
Table 1
Upper 1 mesostroma asphalt content of table uses inner blending method.
The present embodiment reinforcing agent is added on the basis of the above-mentioned acidity aggregate asphalt for road cutting optimal to carry out
It is modified, obtain the modified asphalt for acidity aggregate.
The reinforcing agent modified for acidity aggregate asphalt is dripped in the above-mentioned acidity aggregate for road cutting optimal
Application in green mixture, including following operating procedure:
(1) modifier A for accounting for upper 1 mesostroma asphalt quality 0.2% of table is added in matrix pitch first, mesostroma
Asphalt heating temperature is 160 DEG C, and duration of mixing 60min obtains modified pitch;
(2) then by temperature be 180 DEG C acidity aggregate and the obtained modified pitch of step (1) be added to mix in pot and stir
90 seconds, wherein mix temperature was 150 DEG C;
(3) finally the miberal powder of the modifying agent B and upper table 1 that account for acidity aggregate asphalt gross mass 1% are added to and are mixed
It is stirred 90 seconds in pot, obtains asphalt;Obtained asphalt can pave molding at 130 DEG C.
The following table 2 is to add the mix parameter and vehicle of the modified obtained acidity aggregate asphalt of the present embodiment reinforcing agent
Rut dynamic stability test result.Wherein, blank group is the acidity aggregate for road cutting optimal for not adding reinforcing agent of the present invention
Asphalt, SBS modifier group are to add on the basis of table 1 is suitable for the acidity aggregate asphalt of road cutting optimal
Account for the SBS modifier of matrix pitch 5%.Its dynamic stability of the asphalt of 1 test group of embodiment is far longer than blank group drip
Green mixture, heating temperature, the mix temperature of mixture and the compacting temperature ratio SBS of 1 test group mesostroma pitch of embodiment change
Property agent group reduce about 20-40 DEG C, and performance is slightly above SBS modifier group, table 2 specific as follows:
2 acidity aggregate asphalt track stability test result of table
Embodiment 2
A kind of reinforcing agent modified for above-mentioned acidity aggregate asphalt, including the modifier A being used cooperatively and changes
Property agent B;The quality of modifier A is the 2% of above-mentioned matrix pitch quality, and the quality of modifying agent B is acidity aggregate asphalt
The 0.4% of gross mass;
Modifier A is silane coupling agent KH570, and modifying agent B is the bitumen solid powder of 600 mesh.
The acidity aggregate asphalt of surface layer suitable for road, specific proportion such as the following table 3:
Table 3
Upper 3 mesostroma asphalt content of table uses inner blending method.
It is carried out above-mentioned for the present embodiment reinforcing agent to be added on the basis of the acidity aggregate asphalt of surface layer in road
It is modified, obtain the modified asphalt for acidity aggregate.
The reinforcing agent modified for acidity aggregate asphalt is in the above-mentioned acidity aggregate drip for surface layer in road
Application in green mixture, including following operating procedure:
(1) modifier A for accounting for upper 3 mesostroma asphalt quality 2% of table is added in matrix pitch first, mesostroma drip
Green heating temperature is 140 DEG C, and duration of mixing 20min obtains modified pitch;
(2) then by temperature be 160 DEG C acidity aggregate and the obtained modified pitch of step (1) be added to mix in pot and stir
90 seconds, wherein mix temperature was 170 DEG C;
(3) finally the miberal powder of the modifying agent B and upper table 3 that account for acidity aggregate asphalt gross mass 0.4% are added to
It mixes in pot and stirs 90 seconds, obtain asphalt;Obtained asphalt can pave molding at 150 DEG C.
The following table 4 is the acidity aggregate asphalt mixture mixing parameter and track dynamic stability that the embodiment of the present invention 2 obtains
Test result, wherein blank group is not add the acidity aggregate pitch mixing suitable for road cutting optimal of reinforcing agent of the present invention
Material, SBS modifier group are to have added to account for matrix drip on the basis of table 3 is suitable for the acidity aggregate asphalt of road cutting optimal
The SBS modifier of blueness 4.5%;Its dynamic stability of the asphalt of 2 test group of embodiment is far longer than the mixing of blank group pitch
Material, heating temperature, the mix temperature of mixture and the compacting temperature of 2 test group mesostroma pitch of embodiment are than SBS modifier group
About 20-40 DEG C is reduced, and performance is slightly above SBS modifier group, table 4 specific as follows.
4 acidity aggregate asphalt track stability test result of table
Embodiment 3
A kind of reinforcing agent modified for above-mentioned acidity aggregate asphalt, including the modifier A being used cooperatively and changes
Property agent B;The quality of modifier A is the 1% of above-mentioned matrix pitch quality, and the quality of modifying agent B is acidity aggregate asphalt
The 0.7% of gross mass;
Modifier A is Silane coupling agent KH550, and modifying agent B is the bitumen solid powder of 400 mesh.
Suitable for the acidity aggregate asphalt of road upper layer, specific proportion such as the following table 5:
Table 5
The dosage of pitch and fiber in upper table 5 is all made of inner blending method.
The present embodiment reinforcing agent is added on the basis of the above-mentioned acidity aggregate asphalt for road upper layer to carry out
It is modified, obtain the modified asphalt for acidity aggregate.
The reinforcing agent modified for acidity aggregate asphalt is in the acidity aggregate pitch for being suitable for road upper layer
Application in mixture, including following operating procedure:
(1) modifier A for accounting for upper 5 mesostroma asphalt quality 1% of table is added in matrix pitch first, mesostroma drip
Green heating temperature is 150 DEG C, and duration of mixing 40min obtains modified pitch;
(2) then by temperature be 200 DEG C acidity aggregate and the obtained modified pitch of step (1) be added to mix in pot and stir
90 seconds, wherein mix temperature was 160 DEG C;
(3) finally the miberal powder of the modifying agent B and upper table 5 that account for acidity aggregate asphalt gross mass 0.7% are added to
It mixes in pot and stirs 90 seconds, obtain asphalt;Obtained asphalt can pave molding at 140 DEG C.
The following table 6 is the acidity aggregate asphalt mixture mixing parameter and track dynamic stability that the embodiment of the present invention 3 obtains
Test result, wherein blank group is not add the acidity aggregate pitch mixing suitable for road upper layer of reinforcing agent of the present invention
Material, SBS modifier group have added on the basis of being the acidity aggregate asphalt to be suitable for road upper layer in table 5 and have accounted for matrix
The SBS modifier of pitch 5.5%;It is mixed that its dynamic stability of the asphalt of 3 test group of embodiment is far longer than blank group pitch
Material is closed, heating temperature, the mix temperature of mixture and the compacting temperature of 3 test group mesostroma pitch of embodiment compare SBS modifier
Group reduces about 20-40 DEG C, and performance is slightly above SBS modifier group, table 6 specific as follows.
6 acidity aggregate asphalt track stability test result of table
Classification |
Asphalt heating temperature (DEG C) |
Mix temperature (DEG C) |
Compacting temperature (DEG C) |
Dynamic stability DS (secondary/mm) |
Blank group |
160 |
155 |
130 |
6987 |
3 test group of embodiment |
160 |
150 |
130 |
11052 |
SBS modifier group |
180 |
185 |
170 |
10690 |
Above-mentioned acidity aggregate is granite, basalt or other acidity aggregates;Miberal powder is limestone mineral powder;Matrix pitch is
70# matrix pitch, in addition, all 70#, 90# for meeting JTG F40-2004 " Ministry of Communications's bi tumenf orr oad technical requirements ",
The pitches such as 110# are suitable for the present invention.
Comparative example 1
With the acidity aggregate asphalt suitable for road cutting optimal of table 1 in embodiment 1, with accounting for matrix pitch quality
2.5% modifier A and the modifying agent B of asphalt gross mass 0.3% are modified, specific steps are as follows:
(1) modifier A for accounting for matrix pitch quality 2.5% is added in matrix pitch first, wherein matrix pitch adds
Hot temperature is 150 DEG C, and duration of mixing 40min obtains modified pitch;
(2) then by temperature be 200 DEG C acidity aggregate and the obtained modified pitch of step (1) be added to mix in pot and stir
90 seconds, wherein mix temperature was 160 DEG C;
(3) finally miberal powder in the modifying agent B and table 1 that account for acidity aggregate asphalt gross mass 0.3% is added to and is mixed
It is stirred 90 seconds in pot, obtains asphalt;Obtained asphalt can pave molding at 140 DEG C.
The following table 7 is the asphalt track dynamic stability test of this comparative example acidity aggregate as a result, wherein blank group is same
The blank group of embodiment 1.
Table 7
Classification |
Dynamic stability DS (secondary/mm) |
Blank group |
4630 |
1 test group of comparative example |
4238 |
As shown in Table 7, modifier A, modifying agent B volume not within the scope of the present invention when, acquisition modified pitch mixing
The dynamic stability of material is poor.
Comparative example 2
With the acidity aggregate asphalt suitable for road cutting optimal of table 1 in embodiment 1, with accounting for matrix pitch quality
1.2% modifier A and the modifying agent B of asphalt gross mass 0.5% are modified, specific steps are as follows:
(1) above-mentioned modifier A and modifying agent B are added in matrix pitch together, wherein matrix pitch heating temperature is
150 DEG C, duration of mixing 40min obtains modified pitch;
(2) the mixing in pot for modified pitch addition of the temperature acidity aggregate for being 190 DEG C and step (1) is stirred 90 seconds, is mixed
Close 160 DEG C of temperature;
(3) miberal powder is included in mix in pot and is stirred 90 seconds, obtained the asphalt of acidity aggregate, paved at 150 DEG C
Type.
The following table 8 is the asphalt track dynamic stability test of this comparative example acidity aggregate as a result, wherein blank group is same
The blank group of embodiment 1.
Table 8
As shown in Table 8, the track dynamic stability of the asphalt of the acidity aggregate obtained after modified operating procedure changes
It is poor to spend result.
Above-mentioned specific embodiment cannot function as limiting the scope of the invention, for the technology people of the art
For member, any alternate modification or transformation made to embodiment of the present invention are fallen within the scope of protection of the present invention.
Place is not described in detail by the present invention, is the well-known technique of those skilled in the art of the present technique.