CN108950396B - Corrosion-resistant metal coating of 20CrMnTi steel passive helical gear of differential mechanism - Google Patents
Corrosion-resistant metal coating of 20CrMnTi steel passive helical gear of differential mechanism Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/32—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for gear wheels, worm wheels, or the like
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/073—Metallic material containing MCrAl or MCrAlY alloys, where M is nickel, cobalt or iron, with or without non-metal elements
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/131—Wire arc spraying
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/18—After-treatment
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Abstract
The invention provides a corrosion-resistant metal coating of a 20CrMnTi steel passive helical gear of a differential mechanism, which comprises the following chemical element components in percentage by mass: c: 0.18% -0.22%, Si: 0.25% -0.3%, Mn: 0.5% -0.9%, Cr: 1.2% -2.0%, Ti: 0.02% -0.08%, P <0.04%, S <0.04%, the balance being iron; the corrosion-resistant metal coating comprises the following chemical element components in percentage by mass: c: 0.06-0.08%, Cr: 20-30%, Ni: 12.25-15.43%, Al 1.5-3%, Ti 0.1-0.2%, Cu: 0.3-0.5%, Mg: 0.13-0.15%, Re 0.3-0.5%, La: 0.32-0.38%, Ce: 0.2-0.52%, the balance being iron; the corrosion-resistant metal coating is prepared by preparing powder core wires, performing surface treatment, spraying and secondary tempering. The corrosion-resistant metal coating can improve the corrosion resistance and the wear resistance of the passive helical gear and prolong the service life of the passive helical gear.
Description
Technical Field
The invention relates to the technical field of improving the corrosion resistance and the wear resistance of mechanical parts, in particular to a corrosion-resistant metal coating of a 20CrMnTi steel passive helical gear of a differential mechanism.
Background
Corrosion is a slow chemical or electrochemical process, which refers to the natural phenomenon of the metal material acting with oxygen, water, etc. to cause its own failure and destruction. Because the transmission part needs long-term operation, the temperature of operation is high, and the air is moist, causes the corruption to parts such as transmission shaft and drive gear to the problem that leads to the equipment to damage has brought huge loss for production. Therefore, it is necessary to spray a layer of anti-corrosion metal coating on the transmission component to improve the corrosion resistance of the transmission component and prolong the service life of the transmission component. However, different spraying processes can affect the porosity of the metal coating, and the influence of the porosity on the performance of the metal coating is crucial, the general spraying process of the anti-corrosion metal coating only sprays the surface of the transmission part, and is not improved by combining the forging process of the transmission part, the porosity of the sprayed anti-corrosion coating is large, and further the compactness of the metal coating is poor, the corrosion resistance of the metal coating is not strong, and the requirement of the corrosion resistance of the transmission part cannot be met. Therefore, there is a need to develop a new corrosion-resistant metal coating for transmission components.
Disclosure of Invention
The invention aims to provide a corrosion-resistant metal coating of a 20CrMnTi steel passive helical gear of a differential mechanism, aiming at improving the corrosion resistance and the wear resistance of the passive helical gear and further prolonging the service life of the passive helical gear.
The invention provides a corrosion-resistant metal coating of a 20CrMnTi steel passive helical gear of a differential mechanism, wherein the 20CrMnTi steel passive helical gear comprises the following chemical element components in percentage by mass: c: 0.18% -0.22%, Si: 0.25% -0.3%, Mn: 0.5% -0.9%, Cr: 1.2% -2.0%, Ti: 0.02% -0.08%, P <0.04%, S <0.04%, the balance being iron; the corrosion-resistant metal coating comprises the following chemical element components in percentage by mass: c: 0.06-0.08%, Cr: 20-30%, Ni: 12.25-15.43%, Al 1.5-3%, Ti 0.1-0.2%, Cu: 0.3-0.5%, Mg: 0.13-0.15%, Re 0.3-0.5%, La: 0.32-0.38%, Ce: 0.2-0.52%, the balance being iron; the treatment process of the corrosion-resistant metal coating is carried out according to the following steps:
step S1: preparing a powder core wire material: mixing, molding and drawing C, Cr, Ni, Al, Ti, Cu, Mg, Re, La and Ce to obtain powder core wires;
step S2: surface treatment: after two-stage quenching, the differential 20CrMnTi steel driven bevel gear is put into an RX3 box-type electric furnace for first tempering treatment;
step S3: the spraying process comprises the following steps: immediately spraying a powder core wire material on the surface of the gear to form a corrosion-resistant metal coating after the differential 20CrMnTi steel passive helical gear is tempered for the first time;
step S4: and (3) tempering for the second time: and then carrying out secondary tempering treatment on the sprayed 20CrMnTi steel passive helical gear of the differential.
As a further improvement of the present invention, the process of the first tempering treatment in step S2 is: the tempering temperature is 500-650 ℃, the temperature is kept for 2h, and the oil is cooled to the room temperature.
As a further improvement of the present invention, the process of the second tempering treatment in step S4 is: the tempering temperature is 650 plus 700 ℃, the temperature is kept for 1.5h, and the air is blown and cooled to the room temperature.
As a further improvement of the present invention, the spraying process parameters in step S3 are: the voltage is 28-30V, the current is 160-240A, the spraying distance is 80-100mm, and the pressure of compressed air is 0.4-0.6 MPa.
As a further improvement of the present invention, the spraying process parameters in step S3 are: the voltage is 30V, the current is 220A, the spraying distance is 80mm, and the pressure of compressed air is 0.4 MPa.
As a further improvement of the invention, the corrosion-resistant metal coating comprises the following components in percentage by mass: c: 0.07-0.08%, Cr: 25-30%, Ni: 14.25-15.43%, Al 2.0-3%, Ti 0.15-0.2%, Cu: 0.4-0.5%, Mg: 0.14-0.15%, Re 0.4-0.5%, La: 0.35-0.38%, Ce: 0.35-0.52%, the balance being iron.
As a further improvement of the invention, the thickness of the corrosion-resistant metal coating is: 0.3-0.5 mm.
Compared with the prior art, the invention has the following beneficial effects:
1. the method is different from the common spraying process of spraying the anti-corrosion metal coating on the surface of the finished transmission part, is improved by combining the production heat treatment process when the passive helical gear is not formed into a finished product, and has the advantages of small porosity of the sprayed anti-corrosion coating, high compactness of the metal coating and high anti-stripping strength of the metal coating, so that the obtained anti-corrosion metal coating has high anti-corrosion performance.
2. According to the invention, the passive helical gear is sprayed after the first tempering, the stay time of the passive helical gear and the elements such as Cr, C, Ni and Ce in the anti-corrosion metal coating is long at high temperature, the elements such as Cr, C, Ni and Ce in the anti-corrosion metal coating are transferred into the passive helical gear, and then the elements transferred into the passive helical gear are tempered for the second time, so that the elements such as Ce play a role, the internal structure of the passive helical gear is refined, the internal stress is eliminated and the cracks after quenching are repaired, the content limit of the elements such as Cr, C and Ce in the forging process of the passive helical gear is also expanded, the content of the elements such as Cr, C and Ni in the passive helical gear is improved in a coating mode.
3. The rare earth element Ce is adopted, the structure performance of the material can be obviously improved, the grain refinement degree is improved, the compactness of the powder core wire is increased, the pores on the surface of the coating are further reduced, the coating is sprayed on the high-temperature surface after the first tempering to form the coating, the time for the coating to contact with a high-temperature matrix is long, and the element Ce permeates into the passive helical gear, so that the grains of the passive helical gear are finer and more disordered, the original austenite grains are effectively segmented, the growth space of a second tempering phase change structure is limited, the refined structure is achieved, the substructure in the original austenite grains is diversified, and the impact toughness of the passive helical gear is increased.
Detailed Description
The technical solution of the present invention will be clearly and completely described below with reference to specific embodiments. It is to be understood that the described embodiments are merely a few embodiments of the invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments of the present invention without any inventive step, are within the scope of the present invention.
The invention discloses a corrosion-resistant metal coating of a 20CrMnTi steel passive helical gear of a differential mechanism, and the specific implementation mode is as follows.
Example 1
The invention provides a corrosion-resistant metal coating of a 20CrMnTi steel passive helical gear of a differential mechanism, wherein the 20CrMnTi steel passive helical gear comprises the following chemical element components in percentage by mass: c: 0.18% -0.22%, Si: 0.25% -0.3%, Mn: 0.5% -0.9%, Cr: 1.2% -2.0%, Ti: 0.02% -0.08%, P <0.04%, S <0.04%, the balance being iron; the corrosion-resistant metal coating comprises the following chemical element components in percentage by mass: c: 0.0%, Cr: 20%, Ni: 12.25%, Al 1.5%, Ti 0.1%, Cu: 0.3%, Mg: 0.13%, Re:0.3%, La: 0.32%, Ce: 0.2%, the balance being iron; the treatment process of the corrosion-resistant metal coating is carried out according to the following steps:
step S1: preparing a powder core wire material: mixing, molding and drawing C, Cr, Ni, Al, Ti, Cu, Mg, Re, La and Ce to obtain powder core wires;
step S2: surface treatment: after two-stage quenching, the differential 20CrMnTi steel driven helical gear is put into an RX3 box type electric furnace for the first tempering treatment of tempering temperature of 500 ℃, heat preservation for 2 hours and oil cooling to room temperature;
step S3: the spraying process comprises the following steps: immediately spraying a powder core wire material on the surface of the gear to form a corrosion-resistant metal coating under the conditions that the parameters of the powder core wire material are 28-30V of voltage, 160-240A of current, 80-100mm of spraying distance and 0.4-0.6MPa of compressed air after the first tempering of the differential 20CrMnTi steel passive helical gear, wherein the thickness of the corrosion-resistant coating is 0.3 mm;
step S4: and (3) tempering for the second time: and then carrying out secondary tempering treatment on the sprayed 20CrMnTi steel driven helical gear of the differential mechanism at the tempering temperature of 650 ℃, preserving heat for 1.5h, and carrying out air blast cooling to room temperature.
Example 2
The invention provides a corrosion-resistant metal coating of a 20CrMnTi steel passive helical gear of a differential mechanism, wherein the 20CrMnTi steel passive helical gear comprises the following chemical element components in percentage by mass: c: 0.18% -0.22%, Si: 0.25% -0.3%, Mn: 0.5% -0.9%, Cr: 1.2% -2.0%, Ti: 0.02% -0.08%, P <0.04%, S <0.04%, the balance being iron; the corrosion-resistant metal coating comprises the following chemical element components in percentage by mass: c: 0.08%, Cr: 30%, Ni: 15.43%, Al 3%, Ti 0.2%, Cu: 0.5%, Mg: 0.15%, Re 0.5%, La: 0.38%, Ce: 0.52%, the balance being iron; the treatment process of the corrosion-resistant metal coating is carried out according to the following steps:
step S1: preparing a powder core wire material: mixing, molding and drawing C, Cr, Ni, Al, Ti, Cu, Mg, Re, La and Ce to obtain powder core wires;
step S2: surface treatment: after two-stage quenching, the differential 20CrMnTi steel driven helical gear is put into an RX3 box type electric furnace for the first tempering treatment of tempering temperature of 650 ℃, heat preservation for 2 hours and oil cooling to room temperature;
step S3: the spraying process comprises the following steps: immediately spraying a powder core wire material on the surface of the gear to form a corrosion-resistant metal coating under the conditions that the parameters of the powder core wire material are 28-30V of voltage, 160-240A of current, 80-100mm of spraying distance and 0.4-0.6MPa of compressed air after the first tempering of the differential 20CrMnTi steel passive helical gear, wherein the thickness of the corrosion-resistant coating is 0.5 mm;
step S4: and (3) tempering for the second time: and then carrying out secondary tempering treatment on the sprayed 20CrMnTi steel driven helical gear of the differential mechanism at the tempering temperature of 700 ℃, preserving the heat for 1.5h, and carrying out air blast cooling to the room temperature.
Example 3
The invention provides a corrosion-resistant metal coating of a 20CrMnTi steel passive helical gear of a differential mechanism, wherein the 20CrMnTi steel passive helical gear comprises the following chemical element components in percentage by mass: c: 0.18% -0.22%, Si: 0.25% -0.3%, Mn: 0.5% -0.9%, Cr: 1.2% -2.0%, Ti: 0.02% -0.08%, P <0.04%, S <0.04%, the balance being iron; the corrosion-resistant metal coating comprises the following chemical element components in percentage by mass: c: 0.07%, Cr: 25%, Ni: 14.25%, Al 2%, Ti 0.15%, Cu: 0.4%, Mg: 0.14%, Re:0.4%, La: 0.35%, Ce: 0.35%, the balance being iron; the treatment process of the corrosion-resistant metal coating is carried out according to the following steps:
step S1: preparing a powder core wire material: mixing, molding and drawing C, Cr, Ni, Al, Ti, Cu, Mg, Re, La and Ce to obtain powder core wires;
step S2: surface treatment: after two-stage quenching, the differential 20CrMnTi steel driven helical gear is put into an RX3 box-type electric furnace to be subjected to first tempering treatment at the tempering temperature of 600 ℃, heat preservation for 2 hours and oil cooling to room temperature;
step S3: the spraying process comprises the following steps: immediately spraying a powder core wire material on the surface of the gear to form a corrosion-resistant metal coating under the conditions that the parameters of the powder core wire material are 28-30V of voltage, 160-240A of current, 80-100mm of spraying distance and 0.4-0.6MPa of compressed air after the first tempering of the differential 20CrMnTi steel passive helical gear, wherein the thickness of the corrosion-resistant coating is 0.4 mm;
step S4: and (3) tempering for the second time: and then carrying out secondary tempering treatment on the sprayed 20CrMnTi steel driven helical gear of the differential mechanism at the tempering temperature of 680 ℃, preserving the heat for 1.5h, and carrying out air blast cooling to the room temperature.
The prepared passive helical gear is selected as a sample to be tested for the adhesion performance according to GB/T9286-1998, the salt water resistance performance is tested according to the GB 1763-: table 1 shows the corrosion resistance test results of the passive helical gear.
The results of examples 1-3 show that the corrosion-resistant metal coating provided by the invention has good adhesion performance and high salt water and salt mist resistance.
The corrosion-resistant metal coating of the differential 20CrMnTi steel passive helical gear provided by the invention is provided. The principles and embodiments of the present invention are explained herein using specific examples, which are set forth only to help understand the method and its core ideas of the present invention. It should be noted that, for those skilled in the art, it is possible to make various improvements and modifications to the present invention without departing from the principle of the present invention, and those improvements and modifications also fall within the scope of the claims of the present invention.
Claims (1)
1. The utility model provides a differential mechanism 20CrMnTi steel passive helical gear's corrosion-resistant metal coating which characterized in that: the 20CrMnTi steel passive helical gear comprises the following chemical element components in percentage by mass: c: 0.18% -0.22%, Si: 0.25% -0.3%, Mn: 0.5% -0.9%, Cr: 1.2% -2.0%, Ti: 0.02-0.08%, P <0.04%, S <0.04%, and the balance of iron; the corrosion-resistant metal coating comprises the following components in percentage by mass: c: 0.07-0.08%, Cr: 25-30%, Ni: 14.25-15.43%, Al 2.0-3%, Ti 0.15-0.2%, Cu: 0.4-0.5%, Mg: 0.14-0.15%, Re 0.4-0.5%, La: 0.35-0.38%, Ce: 0.35-0.52%, the rest is iron; the treatment process of the corrosion-resistant metal coating is carried out according to the following steps:
step S1: preparing a powder core wire material: mixing, molding and drawing C, Cr, Ni, Al, Ti, Cu, Mg, Re, La and Ce to obtain powder core wires;
step S2: surface treatment: after two-stage quenching, the differential 20CrMnTi steel driven helical gear is placed into an RX3 box-type electric furnace for first tempering treatment, the tempering temperature is 500-650 ℃, the temperature is kept for 2h, and the oil is cooled to the room temperature;
step S3: the spraying process comprises the following steps: the differential 20CrMnTi steel passive helical gear after the first tempering immediately sprays the powder core wire to the surface of the gear to form a corrosion-resistant metal coating, and the spraying process parameters are as follows: the voltage is 30V, the current is 220A, the spraying distance is 80mm, and the pressure of compressed air is 0.4 MPa;
step S4: and (3) tempering for the second time: then carrying out secondary tempering treatment on the sprayed 20CrMnTi steel passive helical gear of the differential at the tempering temperature of 650-700 ℃, preserving heat for 1.5h, and carrying out air blast cooling to room temperature;
the thickness of the corrosion-resistant metal coating is as follows: 0.3-0.5 mm.
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| CN106498290B (en) * | 2016-10-13 | 2018-02-13 | 南京创贝高速传动机械有限公司 | A kind of corrosion resistant metal coating of gear case external surface |
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| WO2017142430A1 (en) * | 2016-02-15 | 2017-08-24 | Общество с ограниченной ответственностью "Технологические системы защитных покрытий" | Composition of a corrosion resistant coating for protecting petrochemical equipment |
| WO2018096387A1 (en) * | 2016-11-24 | 2018-05-31 | Arcelormittal | Hot-rolled and coated steel sheet for hot-stamping, hot-stamped coated steel part and methods for manufacturing the same |
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