CN108948821A - A kind of modified rubber powder emulsion paint - Google Patents

A kind of modified rubber powder emulsion paint Download PDF

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Publication number
CN108948821A
CN108948821A CN201810321686.2A CN201810321686A CN108948821A CN 108948821 A CN108948821 A CN 108948821A CN 201810321686 A CN201810321686 A CN 201810321686A CN 108948821 A CN108948821 A CN 108948821A
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CN
China
Prior art keywords
parts
rubber powder
modified rubber
weight
emulsion paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810321686.2A
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Chinese (zh)
Inventor
孙巨福
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianchang Julong Car and Ship Coating Co Ltd
Original Assignee
Tianchang Julong Car and Ship Coating Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianchang Julong Car and Ship Coating Co Ltd filed Critical Tianchang Julong Car and Ship Coating Co Ltd
Priority to CN201810321686.2A priority Critical patent/CN108948821A/en
Publication of CN108948821A publication Critical patent/CN108948821A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of modified rubber powder emulsion paint, raw material includes: 20-40 parts of silicone acrylic emulsion, 5-10 parts of quartz sand, 3-8 parts of cobalt powder, 2-5 parts of precipitated calcium carbonate, 1-4 parts of ammonium polyphosphate, 10-25 parts of vinyl acetate, 2-7 parts of modified rubber powder, 1-4 parts of dodecyl sodium sulfate, 1-5 parts of bentonite, 2-6 parts of organic silicon defoamer, 1-5 parts of film forming agent by weight.The present invention has higher anti-corrosive properties and excellent heat preservation, sound insulation and cracking resistance.

Description

A kind of modified rubber powder emulsion paint
Technical field
The present invention relates to emulsion paint fields, and in particular to a kind of modified rubber powder emulsion paint.
Background technique
Emulsion paint is being commonly called as latex paint, is born in mid-to-late 1970s, is with acrylic ester copolymer Lotion is a major class synthetic resin emulsion coating of representative.Emulsion paint is water-dispersible paint, it is to be with synthetic resin emulsion The refined coating of various auxiliary agents is added in base-material, filler after grinding distribution.Emulsion paint has and traditional metope coating Different many merits, such as being easy to, brushing, drying is rapid, paint film is water-fast, scrub resistance is good.In China, people traditionally Synthetic resin emulsion is base-material, using water as decentralized medium, pigment, filler (also known as extender pigment) and auxiliary agent is added, through certain work Coating made of skill process is called emulsion paint, is also latex paint.
In the prior art, although emulsion paint has the performance of some aspects, comprehensive performance is poor, is increasingly unable to satisfy The demand in market.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of modified rubber powder emulsion paint, present invention tools There are higher anti-corrosive properties and excellent heat preservation, sound insulation and cracking resistance.
A kind of modified rubber powder emulsion paint proposed by the present invention, raw material include: by weight 20-40 parts of silicone acrylic emulsion, 5-10 parts of quartz sand, 3-8 parts of cobalt powder, 2-5 parts of precipitated calcium carbonate, 1-4 parts of ammonium polyphosphate, 10-25 parts of vinyl acetate, modified rubber 2-7 parts of rubber powder, 1-4 parts of dodecyl sodium sulfate, 1-5 parts of bentonite, 2-6 parts of organic silicon defoamer, 1-5 parts of film forming agent.
Preferably, the modified rubber powder the preparation method comprises the following steps: rubber powder is mixed with sodium hydroxide solution, stirring is equal It is even, granular polystyrene and surfactant is added, is stirred to react, obtains modified rubber powder.
Preferably, the modified rubber powder the preparation method comprises the following steps: by the matter of the rubber powder of 1 parts by weight and 1-1.5 parts by weight Measure score be 15-20wt% sodium hydroxide solution mix, stir evenly, be added 0.5-0.8 parts by weight granular polystyrene and The surfactant of 0.1-0.3 parts by weight, is stirred to react, and obtains modified rubber powder.
Preferably, the temperature being stirred to react is 40-60 DEG C, time 50-70min.
Preferably, the fineness of the quartz sand is 120-200 mesh.
A kind of modified rubber powder emulsion paint of the invention, raw material include silicone acrylic emulsion, vinyl acetate, modified rubber Powder, quartz sand, cobalt powder, precipitated calcium carbonate, ammonium polyphosphate, dodecyl sodium sulfate, bentonite, organic silicon defoamer, film forming agent, Deionized water, wherein the two compatibility is good using silicone acrylic emulsion, vinyl acetate as basic raw material, have preferable anti-corrosion and Effect of prestressed, and make final coating that there is excellent heat preservation and sound insulation value after compounding with modified rubber powder, quartz sand, cobalt powder, The anti-corrosion and cracking resistance of coating are further enhanced simultaneously;In preferred embodiment, first rubber powder is modified with sodium hydroxide, is subtracted Insoluble impurities in few rubber powder, is then modified it using granular polystyrene, has preferable thermal insulation property and sound insulation Performance is added surfactant, can effectively improve the caking property of modified rubber powder, while strengthening sound insulation and heat insulation effect. Precipitated calcium carbonate, ammonium polyphosphate, dodecyl sodium sulfate are added in the present invention, it is good with silicone acrylic emulsion, vinyl acetate compatibility, Three's mutual cooperation effect, makes coating have good antibacterial and wear-resisting property.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of modified rubber powder emulsion paint, raw material include: 20 parts of silicone acrylic emulsion, 10 parts of quartz sand, cobalt powder 3 by weight Part, 5 parts of precipitated calcium carbonate, 1 part of ammonium polyphosphate, 25 parts of vinyl acetate, 2 parts of modified rubber powder, 4 parts of dodecyl sodium sulfate, 1 part of bentonite, 6 parts of organic silicon defoamer, 1 part of film forming agent.
Embodiment 2
A kind of modified rubber powder emulsion paint, raw material include: 40 parts of silicone acrylic emulsion, 5 parts of quartz sand, cobalt powder 8 by weight Part, 2 parts of precipitated calcium carbonate, 4 parts of ammonium polyphosphate, 10 parts of vinyl acetate, 7 parts of modified rubber powder, 1 part of dodecyl sodium sulfate, 5 parts of bentonite, 2 parts of organic silicon defoamer, 5 parts of film forming agent;
Wherein, the modified rubber powder the preparation method comprises the following steps: rubber powder is mixed with sodium hydroxide solution, stir evenly, Granular polystyrene and surfactant is added, is stirred to react, obtains modified rubber powder.
Embodiment 3
A kind of modified rubber powder emulsion paint, raw material include: 25 parts of silicone acrylic emulsion, 7 parts of quartz sand, cobalt powder 5 by weight Part, 3.5 parts of precipitated calcium carbonate, 3.5 parts of ammonium polyphosphate, 17 parts of vinyl acetate, 5 parts of modified rubber powder, dodecyl sodium sulfate 2.5 parts, 3 parts of bentonite, 4 parts of organic silicon defoamer, 3 parts of film forming agent;
Wherein, the modified rubber powder the preparation method comprises the following steps: by the mass fraction of the rubber powder of 1 parts by weight and 1 parts by weight It mixes, stirs evenly for the sodium hydroxide solution of 20wt%, the granular polystyrene of 0.5 parts by weight and the surface of 0.3 parts by weight is added Activating agent is stirred to react, and obtains modified rubber powder.
Embodiment 4
A kind of modified rubber powder emulsion paint, raw material include: 30 parts of silicone acrylic emulsion, 9 parts of quartz sand, cobalt powder 4 by weight Part, 4 parts of precipitated calcium carbonate, 2 parts of ammonium polyphosphate, 22 parts of vinyl acetate, 3 parts of modified rubber powder, 3 parts of dodecyl sodium sulfate, 2 parts of bentonite, 5 parts of organic silicon defoamer, 2 parts of film forming agent;
Wherein, the modified rubber powder the preparation method comprises the following steps: by the quality of the rubber powder of 1 parts by weight and 1.5 parts by weight point The sodium hydroxide solution that number is 15wt% mixes, and stirs evenly, and the granular polystyrene of 0.8 parts by weight and the table of 0.1 parts by weight is added Face activating agent, is stirred to react, and obtains modified rubber powder;
The temperature being stirred to react is 60 DEG C, time 50min;
The fineness of the quartz sand is 200 mesh.
Embodiment 5
A kind of modified rubber powder emulsion paint, raw material include: 35 parts of silicone acrylic emulsion, 6 parts of quartz sand, cobalt powder 7 by weight Part, 3 parts of precipitated calcium carbonate, 3 parts of ammonium polyphosphate, 13 parts of vinyl acetate, 6 parts of modified rubber powder, 2 parts of dodecyl sodium sulfate, 4 parts of bentonite, 3 parts of organic silicon defoamer, 4 parts of film forming agent;
Wherein, the modified rubber powder the preparation method comprises the following steps: by the quality of the rubber powder of 1 parts by weight and 1.3 parts by weight point The sodium hydroxide solution that number is 17wt% mixes, and stirs evenly, and the granular polystyrene of 0.6 parts by weight and the table of 0.2 parts by weight is added Face activating agent, is stirred to react, and obtains modified rubber powder;
The temperature being stirred to react is 40 DEG C, time 70min;
The fineness of the quartz sand is 120 mesh.
Test example 1
As a comparison case with emulsion paint on the market, with according to a conventional method emulsion paint made of embodiment 1-3 is compared Compared with item compared and result are as shown in Table 1:
1 embodiment 1-3 of table and comparative example the performance test results
As can be seen from Table 1, modified rubber powder emulsion paint provided by the invention is in anti-corrosive properties, heat insulating ability, sound-proofing, cracking resistance Property etc. is superior to comparative example.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (5)

1. a kind of modified rubber powder emulsion paint, which is characterized in that its raw material includes: 20-40 parts of silicone acrylic emulsion, quartz by weight 5-10 parts of sand, 3-8 parts of cobalt powder, 2-5 parts of precipitated calcium carbonate, 1-4 parts of ammonium polyphosphate, 10-25 parts of vinyl acetate, modified rubber powder 2-7 parts, 1-4 parts of dodecyl sodium sulfate, 1-5 parts of bentonite, 2-6 parts of organic silicon defoamer, 1-5 parts of film forming agent.
2. modified rubber powder emulsion paint according to claim 1, which is characterized in that the preparation method of the modified rubber powder Are as follows: rubber powder is mixed with sodium hydroxide solution, is stirred evenly, granular polystyrene and surfactant is added, is stirred to react, obtains Modified rubber powder.
3. modified rubber powder emulsion paint according to claim 2, which is characterized in that the preparation method of the modified rubber powder Are as follows: the rubber powder of 1 parts by weight is mixed with the sodium hydroxide solution that the mass fraction of 1-1.5 parts by weight is 15-20wt%, is stirred Uniformly, the granular polystyrene of 0.5-0.8 parts by weight and the surfactant of 0.1-0.3 parts by weight is added, is stirred to react, is modified Rubber powder.
4. the modified rubber powder emulsion paint according to Claims 2 or 3, which is characterized in that the temperature being stirred to react is 40- 60 DEG C, time 50-70min.
5. modified rubber powder emulsion paint according to claim 1, which is characterized in that the fineness of the quartz sand is 120-200 Mesh.
CN201810321686.2A 2018-04-11 2018-04-11 A kind of modified rubber powder emulsion paint Withdrawn CN108948821A (en)

Priority Applications (1)

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CN201810321686.2A CN108948821A (en) 2018-04-11 2018-04-11 A kind of modified rubber powder emulsion paint

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Application Number Priority Date Filing Date Title
CN201810321686.2A CN108948821A (en) 2018-04-11 2018-04-11 A kind of modified rubber powder emulsion paint

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CN108948821A true CN108948821A (en) 2018-12-07

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113175177A (en) * 2021-04-25 2021-07-27 广东博智林机器人有限公司 Floor sound insulation structure and paving method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585636A (en) * 2012-02-29 2012-07-18 株洲时代新材料科技股份有限公司 Environmentally-friendly aqueous damping coating with constrained damping structure and using method of environmentally-friendly aqueous damping coating
CN104312347A (en) * 2014-11-04 2015-01-28 徐妍玲 Preparation method of aqueous mildewproof undercoat
CN105086673A (en) * 2015-08-06 2015-11-25 天长市巨龙车船涂料有限公司 Antistatic latex paint added with nano-graphite and preparing method thereof
CN106867348A (en) * 2017-01-18 2017-06-20 华南理工大学 A kind of waterborne heat-insulating flame-retardant wide temperature zone high damping properties coating and preparation method thereof
CN107384083A (en) * 2017-09-05 2017-11-24 东莞市长安沃土装饰材料店 Wear-resisting type emulsion paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585636A (en) * 2012-02-29 2012-07-18 株洲时代新材料科技股份有限公司 Environmentally-friendly aqueous damping coating with constrained damping structure and using method of environmentally-friendly aqueous damping coating
CN104312347A (en) * 2014-11-04 2015-01-28 徐妍玲 Preparation method of aqueous mildewproof undercoat
CN105086673A (en) * 2015-08-06 2015-11-25 天长市巨龙车船涂料有限公司 Antistatic latex paint added with nano-graphite and preparing method thereof
CN106867348A (en) * 2017-01-18 2017-06-20 华南理工大学 A kind of waterborne heat-insulating flame-retardant wide temperature zone high damping properties coating and preparation method thereof
CN107384083A (en) * 2017-09-05 2017-11-24 东莞市长安沃土装饰材料店 Wear-resisting type emulsion paint

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113175177A (en) * 2021-04-25 2021-07-27 广东博智林机器人有限公司 Floor sound insulation structure and paving method thereof

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Application publication date: 20181207

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