CN108941561A - A kind of bionical components of coupling of high temperature resistant erosive wear - Google Patents

A kind of bionical components of coupling of high temperature resistant erosive wear Download PDF

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CN108941561A
CN108941561A CN201810888660.6A CN201810888660A CN108941561A CN 108941561 A CN108941561 A CN 108941561A CN 201810888660 A CN201810888660 A CN 201810888660A CN 108941561 A CN108941561 A CN 108941561A
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bionical
hole
high temperature
water chestnut
components
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CN108941561B (en
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周宏�
苗树森
荆政委
杨妙
王蕾
兴树森
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Jilin Asia Pacific alloy steel manufacturing Co.,Ltd.
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Jilin University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/20Direct sintering or melting
    • B22F10/28Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/02Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y80/00Products made by additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/058Alloys based on nickel or cobalt based on nickel with chromium without Mo and W
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0047Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
    • C22C32/0052Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/80Data acquisition or data processing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F12/00Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
    • B22F12/40Radiation means
    • B22F12/41Radiation means characterised by the type, e.g. laser or electron beam
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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Abstract

The present invention relates to a kind of bionical components of coupling of high temperature resistant erosive wear, which includes matrix and the bionical working lining for being prepared in matrix working face;Matrix is chromium nickel series heat-resistant steel;Bionical working lining includes the grid frame of bionical unsymmetric structure made of ni-based self-fluxing alloy and the nickel based metal ceramics two parts for being filled in grid frame hole and having bulge-structure;Grid frame hole includes the cylindrical pore successively arranged along abrasive material erosion direction, water chestnut cylindricality hole and regular hexagonal prism shape hole;Cylindrical pore and regular hexagonal prism shape hole are respectively staggered, and the transition region between cylindrical pore and regular hexagonal prism shape hole is filled by water chestnut cylindricality hole and completes transition.The present invention can significantly improve the high temperature erosive resistance of heat-resisting components, while can take into account the performance requirement of hardness and toughness, have preferable impact resistance and anti-fatigue ability, improve the service life of components, while significantly reducing production cost.

Description

A kind of bionical components of coupling of high temperature resistant erosive wear
Technical field:
The invention belongs to high temperature resistant erosion parts technical fields, and in particular to a kind of coupling of high temperature resistant erosive wear is imitative Raw components.
Background technique:
Abrasion is to cause the major reason of material loss and damage of facilities, in metallurgy, electric power, mine, building materials and chemical industry etc. Industrial circle can all cause huge waste and loss due to the abrasion and corrosion of material every year.Wherein erosive wear accounts for about work The 8% of wear-out failure sum, especially high-temperature erosion abrasion are even more serious to destroying caused by material and equipment in industry production.? Under the conditions of high temperature wear, hardness is to determine the principal element of wearability.As long as the hard of component surface can be improved greatly Degree, can significantly improve its wearability.But under normal circumstances, the hardness of heat resisting cast steel is higher, toughness with it is antifatigue Ability is also poorer, in order to improve the service life of heat-resistant part, it is necessary to combine wearability and toughness.
The method for improving components high-temperature erosion abrasion performance in production at present, which is mainly taken, designs and develops new material, system The methods of standby wear-resistant coating, wherein wear-resistant ceramic is a component part of new material, since there is other materials not had for it Various excellent performances, the physical characteristics such as high temperature resistant, high intensity, light-weight, wear-resisting, corrosion-resistant, its energy in national economy The everyways such as source, electronics, aerospace, machinery, automobile, metallurgy, petrochemical industry and biology have broad application prospects, and become Indispensable critical material in each industrial technology especially sophisticated technology.But the brittleness of ceramic material is larger, resists impact Ability it is poor, affect the performance of itself excellent wearability in practical applications, it is raw in industry to also limit ceramic material Application in production has become important research direction how to solve this problem.
Mainly have in production using the concrete technology method that ceramic material improves component surface wear-resisting property at present as follows It is several:
1. Ceramic Coating on Metal Surface technology
Cermet composite coating is composed composite wood after being mixed by metal or alloy and one or more of ceramics Material.Using paint-on technique appropriate, optimal coating material is prepared, to improve the service life and application of material Energy.(technology and research and prospects of cermet composite coating, Liu Jia, Guo Chunli, ceramic [J], 2010.No.5)
There are the problem of: firstly, Laser Surface Cladding Technology ceramic process, thermally expanded since ceramic material and metallic matrix exist The larger difference of the performances such as coefficient, elasticity modulus and thermal coefficient will be produced using component surface entirety coating processes on surface Raw biggish thermal stress, the crackle easily generated under the collective effect of thermal stress and extraneous load, since coat hardness is higher, only Split that ability is poor, crackle easily extension removing for leading to coating and matrix under action of pulling stress influences the wearability of material surface; Secondly, Laser Surface Cladding Technology ceramic process belongs to the bulk modified technique of component surface, cost of manufacture is higher, and still without Method solves the problems, such as that component surface impact resistance difference and anti-fatigue ability are weak at all.
2. metal matrix ceramic composites technology of preparing
Its cardinal principle is with metal by heat-resist, hardness is big, but not impact-resistant metal oxide, carbide, nitrogen Compound etc. is bonded together, the certain plastic deformation generated under external force by ductility phase (metal) particle or crystal boundary position It moves the creep generated and absorbs portion of energy, alleviate stress and concentrate, to achieve the purpose that increase toughness.(ceramic on metal is compound Material preparation technology progress and application, Fu Peng, Hao Xunuan, Gao Yahong, Gu Yudan, Chen Huanming, material Leader net print [J], The 2009.12 Volume Four fourth phases)
There are the problem of: so far, the processing technology of metal matrix ceramic composites is still incomplete, and there are no formation Large-scale serial production, restraining factors mainly have difficulty of processing height, long processing time etc., since manufacturing cost is high, stability is poor The problems such as, its application process is hindered, especially for for large scale components, manufacturing cost is excessively high, and still has High rigidity, high-wearing feature and toughness and anti-fatigue performance conflict.In addition, the interface of metal matrix ceramic composites is tied Structure is combined in the form of interfacial reaction, is affected by the control of process and temperature parameter, its performance is seriously affected Performance;
The various special abilities that nature biotechnology evolves to adapt to living environment, and realize the micro- of these abilities Compound, macroscopical perfect structure is seen, is the inexhaustible source that the mankind generate various technical ideas and invention and create.Utilize nature The foundation that biosystem construction and vital movement process are designed as technological innovation, constantly finds the answer side for solving Scientific And Technical Problems Method.Researcher's discovery, the ability for the various adaptation environment that biology is presented not only are embodied in single factors, but pass through two What the coupling of the synergistic effect of a or more than two different pieces or different factors was realized, this coupling phenomenon is biological Build-in attribute in vitality is constantly presented, especially superpower shows in the various of biological function in biological long-term evolution In, it is generally existing always and plays an important role, is natural selection and the evolution by billions of years as a result, this coupling is existing As providing new research ideas and the mode of thinking for bionics especially engineering bionics.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of bionical components of coupling of high temperature resistant erosive wear, the couplings Bionical components can overcome in the past using the heat-resisting components of chromium nickel system are bulk modified or process of surface treatment existing for be processed into The problem that this height, surface toughness be poor, fatiguability, service life are low.
In order to solve the above technical problems, the bionical components of coupling of high temperature resistant erosive wear of the invention include matrix and system For in the bionical working lining of matrix working face;The matrix is chromium nickel series heat-resistant steel;Bionical working lining includes by Ni-based from molten Property alloy made of bionical unsymmetric structure grid frame and be filled in grid frame hole and the nickel with bulge-structure Based ceramic metal two parts;Grid frame hole includes the cylindrical pore successively arranged along abrasive material erosion direction, water chestnut cylindricality Hole and regular hexagonal prism shape hole;Cylindrical pore is staggered, and arrangement area is the 1/3~1/2 of bionical working lining area, and The diameter d variation range of cylindrical pore is 5~20mm;Regular hexagonal prism shape hole is staggered, inscribed circle diameter D, D= 2d;Transition region between cylindrical pore and regular hexagonal prism shape hole is filled by water chestnut cylindricality hole completes transition, water chestnut cylindricality hole Interior angle be 60 °, 120 °, and its long-diagonal direction is perpendicular to erosion direction.
The spacing of adjacent column shape hole is S1, and the size range of S1 is 2~3mm, between adjacent regular hexagonal prism shape hole Away from for S2, S2=2S1, the spacing between water chestnut cylindricality hole and adjacent cylindrical pore is S5, water chestnut cylindricality hole and adjacent Spacing between regular hexagonal prism shape hole is S6, S5=S6=S1;The cylindrical pore and adjacent regular hexagonal prism shape hole Central cross spacing is S3, is S4, S3=S4=(d+S1)/2 with adjacent water chestnut cylindricality hole central cross spacing.
Arc transition at the water chestnut cylindricality hole crest line, radius of corner are 1~2mm.
There are two medial surfaces to be parallel to erosion direction, circle at regular hexagonal prism shape hole crest line in the regular hexagonal prism shape hole Arc transition, radius of corner are 1~2mm.
The height H1 of the grid frame is 1~2mm, and the height H2 of nickel based metal ceramic boss structure is 2mm;Wherein justify Nickel based metal ceramic boss structure in cylindricality hole is spherical shape, and the nickel based metal ceramic boss structure in water chestnut cylindricality hole is water chestnut Taper, the nickel based metal ceramic boss structure in regular hexagonal prism shape hole are positive six prismatic table shapes.
The edge of the water chestnut tapered protrusion structure and positive six prismatic table shapes bulge-structure and the rounded transition of matrix working face, circle Angular radius is equal to the height of projection H2-H1 of bulge-structure.
The grid frame is made up of nickel base self-fluxing alloy powder of laser 3D printing method, and chemical component presses matter Measure percentage composition are as follows: C:0.4~1.1, Si:3.5~5.5, B:2.0~4.5, Cr:14~26.5, Fe :≤5.0, Ni: surplus; Alloy powder particle size range is -150~+320 mesh.
The nickel based metal ceramics are WC that 10wt%~30wt% is added in nickel based metal self-fluxing alloyed powder Grain mixes, and wherein the chemical component of nickel based metal self-fluxing alloyed powder presses mass percentage are as follows: C:0.4~1.1, Si:3.5~5.5, B:2.0~4.5, Cr:14~26.5, Fe :≤5.0, Ni: surplus;Nickel based metal self-fluxing alloyed powder grain Degree range is -150~+320 mesh;WC particle partial size is 2~100 μm.
The present invention use bionics principle combination laser 3D printing technology, imitate desert lizard body carry on the back unsymmetric structure, The morphological feature of non-smooth surface, in the resistance to heat seal of nickel chromium triangle system in such a way that a variety of coupling members such as material, structure, form intercouple Auri body running face prepares bionical high temperature resistant erosive wear working lining using laser 3D printing technology, will have outstanding wearability, High temperature resistant, corrosion resistance nickel based metal ceramic material be filled under high temperature with high tenacity, high corrosion-resistant it is Ni-based from molten Property Alloy by Laser 3D printing at bionical unsymmetric structure grid frame in, and with certain height of projection structure feature, it is whole Body forms the bionical working lining of the high temperature resistant erosive wear with soft and hard alternation, tough combination, and it is resistance to can to significantly improve nickel chromium triangle system Service performance and service life of the hot components under high-temperature erosion abrasion operating condition.
Existing process mainly uses Laser Surface Cladding Technology ceramics material when manufacturing high temperature resistant erosive wear components Expect technique or metal matrix ceramic composites preparation process, belong to components or entire surface modified technique, there is abrasion-proof gauge The disadvantages of face poor toughness, fatiguability, easy to fall off, the service life is low, complex technical process, and machining accuracy is low, quality is difficult to control.
For shortcoming of the prior art in the raising heat-resisting components high temperature resistant erosive wear of chromium nickel system, the present invention is opened It issues one kind and is suitable for high temperature small size abrasive material erosion operating condition, make for a long time under 900 DEG C of maximum operating temperature or so of operating condition High temperature resistant erosive wear components.Compared with prior art, the present invention uses laser 3D printing technology, is suitble to preparation multiple The Bionic wear-resisting surface of miscellaneous pattern has the features such as formed precision height, simple process, big design flexibility, can significantly improve The high temperature erosive resistance of heat-resisting components, while the performance requirement of hardness and toughness can be taken into account, there is preferable anti-impact The advantages that hitting ability and anti-fatigue ability, improving the service life of components, while production cost is greatly reduced.
The present invention breaches previous manufacturing process, using laser 3D printing technology combination bionics principle, passes through laser The method of 3D printing by with outstanding wearability, high temperature resistant, corrosion resistance nickel based metal ceramic material and high temperature under have High tenacity, high corrosion-resistant ni-based self-fluxing alloy Bionic wear-resisting working lining is made, and heat-resisting base steel is distributed in certain rule Unsymmetric structure, non-smooth surface morphological feature are formed on body, solve the heat-resisting components of nickel chromium triangle system in previous processing technology It is difficult to take into account the problem of surface toughness and wearability, is conducive to improve components for the adaptability of complex working condition, extends and use Service life improves production efficiency, reduces cost.
Detailed description of the invention:
Invention is further described in detail with reference to the accompanying drawings and detailed description.
Fig. 1 is the plan view of the bionical components of coupling of high temperature resistant erosive wear of the invention.
Fig. 2 is the sectional view along A-A of Fig. 1.
Fig. 3 is the perspective view that bionical unsymmetric structure grid frame is prepared on the bionical components of coupling.
Fig. 4 is the perspective view for coupling bionical components.
Fig. 5 a, Fig. 5 b, the partial enlarged view that Fig. 5 c is Fig. 1.
Specific embodiment
Thinking of the invention is to imitate the unsymmetric structure and non-smooth surface of desert lizard body surface using bionics principle Morphological feature, in nickel chromium triangle system, heat-resisting component surface is used in such a way that a variety of coupling members such as material, structure, form intercouple The mode of laser 3D printing manufactures bionical high temperature resistant erosive wear working lining, gives full play to the excellent Wear resistance and Anti corrosion of ceramic material The impact resistance and anti-fatigue performance that component surface can be taken into account while energy again make it have excellent erosion resistant to high temperatures mill Performance is damaged, improves service life, reduces cost.
The present invention utilizes bionics principle combination laser 3D printing technology, develops a kind of suitable for high-temperature erosion abrasion work The heat-resisting components of chromium nickel system used under condition, while toughness and anti-fatigue performance can be taken into account again, manufacture simple with processing technology At low cost, the advantages that design flexibility is big, the accuracy of manufacture is high, the heat-resisting components of chromium nickel system can be significantly improved in high temperature complexity work Service life under condition achievees the purpose that reduce cost.
As shown in figures 1-4, the bionical components of coupling of high temperature resistant erosive wear of the invention include chromium nickel series heat-resistant steel base Body 1 and bionical working lining;The bionical working lining includes the grid of the bionical unsymmetric structure made of ni-based self-fluxing alloy Skeleton 2 and the nickel based metal ceramics two parts for being filled in grid frame hole and having bulge-structure;2 edge of grid frame Abrasive material erosion direction successively arrange cylindrical pore 23, water chestnut cylindricality hole 22 and regular hexagonal prism shape hole 21;Cylindrical pore 21 are staggered, and arrangement area is the 1/3~1/2 of bionical working lining area, and 21 diameter d variation range of cylindrical pore is 5 ~20mm;Regular hexagonal prism shape hole 23 is staggered, inscribed circle diameter D, D=2d;Cylindrical pore 21 and regular hexagonal prism Transition region between shape hole 23 is filled by water chestnut cylindricality hole 22 completes transition, and the interior angle of water chestnut cylindricality hole 22 is 60 °, 120 °, And its long-diagonal direction is perpendicular to erosion direction.The spacing of adjacent column shape hole 21 is S1, the size range of S1 is 2~ 3mm, the spacing of adjacent regular hexagonal prism shape hole 23 are S2, S2=2S1, water chestnut cylindricality hole 22 and adjacent cylindrical pore 21 it Between spacing be S5, spacing between water chestnut cylindricality hole 22 and adjacent regular hexagonal prism shape hole 23 is S6, S5=S6=S1;Institute Stating cylindrical pore 21 and adjacent 23 central cross spacing of regular hexagonal prism shape hole is S3, with adjacent 22 center of water chestnut cylindricality hole Horizontal spacing is S4, S3=S4=(d+S1)/2.Arc transition at 22 crest line of water chestnut cylindricality hole, radius of corner be 1~ 2mm.Erosion direction, circular arc at 23 crest line of regular hexagonal prism shape hole are parallel to there are two side in the regular hexagonal prism shape hole 23 Transition, radius of corner are 1~2mm.The height H2 of the grid frame 2 is 1~2mm, the nickel being filled in grid frame hole The height H1 of based ceramic metal bulge-structure is 2mm;Wherein ceramic 3 bulge-structures of the nickel based metal in cylindrical pore 21 are ball Shape, ceramic 4 bulge-structures of nickel based metal in water chestnut cylindricality hole 22 are water chestnut taper, the nickel based metal in regular hexagonal prism shape hole 23 Ceramic 5 bulge-structures are positive six prismatic table shapes.The edge and matrix of the water chestnut tapered protrusion structure and positive six prismatic table shapes bulge-structure The rounded transition of working face, radius of corner are equal to the height H2-H1 of bulge-structure.
The grid frame 2 is made up of nickel base self-fluxing alloy powder of laser 3D printing method, and chemical component is pressed Mass percentage are as follows: C:0.4~1.1, Si:3.5~5.5, B:2.0~4.5, Cr:14~26.5, Fe :≤5.0, Ni: remaining Amount;Alloy powder particle size range is -150~+320 mesh.The nickel based metal ceramics are in nickel based metal self-fluxing alloyed powder The WC particle of middle addition 10wt%~30wt% mixes, and wherein the chemical component of nickel based metal self-fluxing alloyed powder presses matter Measure percentage composition are as follows: C:0.4~1.1, Si:3.5~5.5, B:2.0~4.5, Cr:14~26.5, Fe :≤5.0, Ni: surplus; Nickel based metal self-fluxing alloyed powder particle size range is -150~+320 mesh;WC particle partial size is 2~100 μm.
The preparation process of the bionical components of coupling of high temperature resistant erosive wear of the present invention is divided into following steps:
(1), according to bionics principle, there is high abrasion in the case where nickel chromium triangle system heat-resisting alloy matrix working face designs high temperature The bionical working lining of property, high corrosion-resistant, high tenacity and highly anti-fatigue ability, the bionical working lining is by bionical unsymmetric structure It grid frame 2 and is filled in grid frame hole nickel based metal ceramics two parts and forms.
(2), according to the characteristic parameter and location information of bionical working lining, bionical work is designed using 3D Morphing Software The whole pattern of layer simultaneously carries out three-dimensional modeling, and confirmation is accurately docked with the realization of nickel chromium triangle system heat-resisting alloy matrix working face, is then carried out The slicing delamination of bionical work layer model is handled, and obtains scanning track and demixing scan path file is imported 3D printer;
(3), prepare nickel base self-fluxing alloy powder and nickel based metal ceramic powders, be packed into stuffing box;
(4), nickel chromium triangle system heat-resisting alloy matrix is subjected to removing surface and is put into printing machine platform, called in after adjusting position Simultaneously print parameters are arranged in mimeograph documents, and laser selects CO2 laser, and output power 500w~5000w is set according to actual needs Print parameters are set, are continuously introduced into powder by powder feeder using synchronous blowing method, while conveying protective gas (N2 or Ar) and arriving and swashing Light irradiates the molten bath to be formed, laser 3D printing forming;It is beaten according to design scheme in step 2 in chromium nickel series heat-resistant steel matrix surface The grid frame 2 of bionical unsymmetric structure is printed off, and completes removing surface;Printed material is replaced, by nickel based metal ceramic powders It inserts in the grid frame hole printed, surface is cleared up after the completion of printing;
In the step 2, using the softwares such as UG, Pro/E, CATIA carry out 3D modeling, then using Cura, The Slice Softwares such as EasyPrint3D carry out slicing treatment to bionical working lining, and by the file storage after slice at .gcode lattice Formula, then software is controlled by 3D printer, * .gcode file is sent to printer;
The surface treatment of nickel chromium triangle system heat-resisting alloy matrix in the step 4, using the method oil removing of heated at constant temperature, then Grinding derusting, is finally blown off with compressed gas, removes greasy dirt and the corrosion at matrix cladding position, keep cladding material more preferable with matrix Combination, prevent crackle, peel off the defects of.
Table 1 is practical effect;
2 grid frame of table and nickel based metal ceramics chemical component;
1 practical effect of table
Note: in table 1,1-, 2- ... 9- is the specimen coding according to different chemical composition layout.
2 grid frame of table and nickel based metal ceramics chemical component
Key point of the invention is:
First, the morphological feature of desert lizard body surface is imitated using bionics principle, it is more using material, structure, form etc. Bionical working lining of the mode that kind coupling member intercouples in the preparation high temperature resistant erosive wear of nickel chromium triangle series heat-resistant steel matrix working face, tool There are bionical unsymmetric structure, non-smooth surface feature, can adapt to each position of heat-resisting components due to the variation pair of erosion operating condition The influence of overall wear resistance, such as the variation of abrasive material size, shock loading, erosion direction factor, can dramatically improve Heat-resisting components high temperature resistant erosive wear ability, while there are the performance characteristics of soft and hard alternation, tough combination, improve heat-resisting zero Component shock resistance, antifatigue performance, help to improve service life, reduce cost.
Second, imitative in the preparation high temperature resistant erosive wear of nickel chromium triangle series heat-resistant steel matrix working face by the way of laser 3D printing Raw working lining, the accuracy of manufacture for improving bionical working lining of high degree, and prepared for mimic biology body surface complex topography Bionical working lining provides technical support;To have high rigidity, high-wearing feature and height resistance under high temperature using laser 3D printing technology Corrosion nickel based metal ceramic material insertion have high tenacity, high corrosion-resistant nickel base self-fluxing alloy powder made of it is bionical non- In the grid frame of symmetrical structure, can be realized wear-resistant material and the good metallurgical bonding of matrix surface, by soft matrix and The bionical good coating function of unsymmetric structure grid frame can high degree improve the bionical impact-resistant performance of working lining, prevent The only generation of bionical working lining fatigue and peeling phenomenon, improves the service life of heat-resisting components.This method has technique letter The features such as list, high production efficiency, design flexibility are big, the accuracy of manufacture is high, service life is high, manufacturing cost is low.
In addition, being formed in heat-resisting component surface has certain regularly arranged asymmetric bulge-structure, it is described non-right Title type bulge-structure can be according to the difference of heat-resisting components each position actual wear operating condition in actual production, such as along erosion The variation of the factors such as the direction abrasive material size of abrasion, shock loading, erosion direction, for the specific wear working condition in each position of components It designs and the positive six prismatic table shapes protrusion knot of large scale is changed by intensive small size hemisphere jut along abrasive material erosive wear direction The bionical asymmetric bulge-structure feature of structure.Intensive small size hemisphere jut structure distribution in the front end of heat-resisting components, Abrasive material is contacted first, can be given full play to the preferable impact resistance of hemisphere jut structure, be resisted biggish impact, while small ruler Very little hemisphere jut structure intensity distribution, can effectively prevent by means of the coating function of high tenacity grid frame and soft matrix The extension of crackle improves antifatigue ability;Positive six prismatic table shape of large scale is distributed in the end of heat-resisting components, the impact of abrasive material Effect is obviously reduced, and the occupancy face of hard nickel based metal ceramic material can be significantly improved by staggered distribution mode Product, can be obviously improved the erosion-wear-resisting performance of heat-resisting components entirety;The bulge-structure of asymmetric distribution can also change The way of contact and motion state of erosion abrasive material and component surface make abrasive material be in rolling condition in component surface and tend to State of minimum energy reduces abrasive material and acts on the plow of soft matrix, to significantly reduce abrasive material to the mill of heat-resisting components Damage behavior, the groove formed among adjacent protrusion structure can weaken the speed and kinetic energy of abrasive material again, to reduce abrasive material pair The impact of rib significantly reduces the abrasion loss of component surface.
The more previous processing technology of the present invention, prepares bionical working lining by the way of laser 3D printing, significant to drop The influence being heated in low bionical working lining preparation process can be greatly reduced finished surface and be heated stress and crack Tendency, help to improve service life, and by means of the higher processing and manufacturing precision of laser 3D printing, help to reduce resistance to The stress concentration of hot component surface, while the difficulty of processing is also reduced, more previous manufacturing method, in bionical work Whole design and the processing and manufacturing etc. for making layer provide bigger application and development space.

Claims (8)

1. a kind of bionical components of coupling of high temperature resistant erosive wear, it is characterised in that including matrix (1) and be prepared in matrix (1) The bionical working lining of working face;The matrix (1) is chromium nickel series heat-resistant steel;Bionical working lining includes by ni-based self-fluxing alloy The grid frame (2) of manufactured bionical unsymmetric structure and the Ni-based gold for being filled in grid frame hole and having bulge-structure Belong to ceramic two parts;Grid frame hole includes the cylindrical pore (23) successively arranged along abrasive material erosion direction, water chestnut cylindricality Hole (22) and regular hexagonal prism shape hole (21);Cylindrical pore (21) is staggered, and arrangement area is bionical working lining area 1/3~1/2, and the diameter d variation range of cylindrical pore (21) be 5~20mm;Regular hexagonal prism shape hole (23) staggered row Column, inscribed circle diameter D, D=2d;Transition region between cylindrical pore (21) and regular hexagonal prism shape hole (23) is by water chestnut column Transition is completed in shape hole (22) filling, and the interior angle of water chestnut cylindricality hole (22) is 60 °, 120 °, and its long-diagonal direction perpendicular to Erosion direction.
2. the bionical components of coupling of high temperature resistant erosive wear according to claim 1, it is characterised in that adjacent column shape The spacing of hole (21) is S1, and the size range of S1 is 2~3mm, and the spacing of adjacent regular hexagonal prism shape hole (23) is S2, S2= 2S1, spacing between water chestnut cylindricality hole (22) and adjacent cylindrical pore (21) are S5, water chestnut cylindricality hole (22) and adjacent Spacing between regular hexagonal prism shape hole (23) is S6, S5=S6=S1;The cylindrical pore (21) and adjacent positive six rib Cylindricality hole (23) central cross spacing is S3, is S4, S3=S4=(d+ with adjacent water chestnut cylindricality hole (22) central cross spacing S1)/2。
3. the bionical components of coupling of high temperature resistant erosive wear according to claim 1, it is characterised in that the water chestnut cylindricality Arc transition at hole (22) crest line, radius of corner are 1~2mm.
4. the bionical components of coupling of high temperature resistant erosive wear according to claim 1, it is characterised in that positive six rib There are two medial surfaces to be parallel to erosion direction, arc transition at regular hexagonal prism shape hole (23) crest line, circle in cylindricality hole (23) Angular radius is 1~2mm.
5. the bionical components of coupling of high temperature resistant erosive wear according to claim 1, it is characterised in that the grid bone The height H1 of frame (2) is 1~2mm, and the height H2 of nickel based metal ceramic boss structure is 2mm;Wherein in cylindrical pore (21) Nickel based metal ceramic boss structure be spherical shape, the nickel based metal ceramic boss structure in water chestnut cylindricality hole (22) is water chestnut taper, Nickel based metal ceramic boss structure in regular hexagonal prism shape hole (23) is positive six prismatic table shapes.
6. the bionical components of coupling of high temperature resistant erosive wear according to claim 5, it is characterised in that the water chestnut taper The edge of bulge-structure and positive six prismatic table shapes bulge-structure and the rounded transition of matrix (1) working face, radius of corner are equal to protrusion The height of projection H2-H1 of structure.
7. the bionical components of coupling of high temperature resistant erosive wear according to claim 1, it is characterised in that the grid bone Frame (2) is made up of nickel base self-fluxing alloy powder of laser 3D printing method, and chemical component presses mass percentage are as follows: C: 0.4~1.1, Si:3.5~5.5, B:2.0~4.5, Cr:14~26.5, Fe :≤5.0, Ni: surplus;Alloy powder particle size range For -150~+320 mesh.
8. the bionical components of coupling of high temperature resistant erosive wear according to claim 1 or claim 7, it is characterised in that described Ni-based Cermet is that the WC particle of addition 10wt%~30wt% in nickel based metal self-fluxing alloyed powder mixes, wherein nickel The chemical component of Base Metal self-fluxing alloyed powder presses mass percentage are as follows: and C:0.4~1.1, Si:3.5~5.5, B:2.0~ 4.5, Cr:14~26.5, Fe :≤5.0, Ni: surplus;Nickel based metal self-fluxing alloyed powder particle size range is -150~+320 Mesh;WC particle partial size is 2~100 μm.
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